Quantum tunneling allows particles to pass through barriers that they could not surmount classically. It occurs because quantum particles exhibit wave-like properties, giving them a probability of being located within classically forbidden regions. Two devices that exploit quantum tunneling are the scanning tunneling microscope (STM) and atomic force microscope (AFM). The STM uses tunneling current between a tip and sample to image individual atoms, while the AFM senses attractive and repulsive forces between a cantilever tip and sample for high-resolution imaging and manipulation. Both were important advances that allowed direct observation and manipulation of matter at the atomic scale.
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Tunnel Effect &AFM-STM
Quantum tunneling allows particles to pass through barriers that they could not surmount classically. It occurs because quantum particles exhibit wave-like properties, giving them a probability of being located within classically forbidden regions. Two devices that exploit quantum tunneling are the scanning tunneling microscope (STM) and atomic force microscope (AFM). The STM uses tunneling current between a tip and sample to image individual atoms, while the AFM senses attractive and repulsive forces between a cantilever tip and sample for high-resolution imaging and manipulation. Both were important advances that allowed direct observation and manipulation of matter at the atomic scale.
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What is Quantum Tunneling?
At the quantum level, matter has
corpuscular and wave-like properties Tunneling can only be explained by the wave nature of matter as described by quantum mechanics Classically, when a particle is incident on a barrier of greater energy than the particle, reflection occurs When described as a wave, the particle has a probability of existing within the barrier region, and even on the other side of it Quantum tunnelling (Tunnel effect) Quantum tunnelling (Tunnel effect): When a particle is made to incident on a potential barrier of a limited width, and if its total energy is less than the barrier height, classically it cannot penetrate the barrier and will be reflected back.
However in quantum mechanics the particle has some probability of penetrating through the potential barrier even if its energy is less than the barrier height. This effect is known as quantum tunnelling or the tunnel effect. Thus the wave function can penetrate through the barrier as shown below.
2 Tunnel effect . The above equation shows that T can be nonzero i.e, there is a finite probability of finding particle in region III.
) ( 2 where E U m C
CL e T 2 _
An approximate expression for the transmission
coefficient, when T << 1 is 3 Quantum tunnelling was first used to explain alpha decay. Alpha particles coming out of the nucleus have energy of 4-5 MeV, still they can tunnel out from the nucleus with binding energy of the order 25 MeV.
However the probability of emission of an alpha particle is 1 in 10 38 events. In a tunnel diode, the charge carriers tunnel through the potential barrier (depletion layer). Quantum tunnelling has found many applications in various fields.
Quantum tunnelling (Tunnel effect) STM The Scanning Tunneling Microscope was invented in 1981 by Gerd Binnig and Heinrich Rohrer When a metal tip, usually made of tungsten or platinum- iridium, is brought within .4-.7nm of the sample, electrons tunnel across the gap and create a current in the tip This current is then fed to a computer and used to generate an image of the atomic surface of the sample At this distance the coulomb force between the tip and an atom of the sample is actually enough to move the atom This has allowed physicists to create images and structures on the atomic level
STM : Scanning tunnelling Microscope STM 1 Scanning tunnelling microscope: A scanning tunnelling microscope (STM) is an instrument for imaging surfaces at the atomic level. It was developed in 1981 by Gerd-Binnig and Heinrich-Rohrer (at IBM Zrich), and for their invention they got the Nobel Prize in Physics in 1986. The basic principle behind an STM is quantum tunnelling.
2 When a conducting tip is brought near to the sample surface, a bias voltage applied between the two can allow electrons to tunnel through the vacuum between them. The resulting tunnelling current is a function of tip position, applied voltage, and electronic nature of the sample. Information is acquired by monitoring the current as the tip's position scans across the surface, and is usually displayed in image form. 3 STM requires extremely clean and stable surfaces, sharp tips, excellent vibration control, and sophisticated electronics. The tip is scanned over the surface using a piezoelectric probe. Using STM individual atoms can be imaged and manipulated. For a current to flow the substrate being scanned must be conductive. Insulators cannot be scanned through the STM. STM has become a very important tool in research and technology development at the nano-scale.
Scanning Tunnelling Microscope Tungsten STM tip (photo taken with an SEM) STM Images AFM 1 Atomic force microscope (AFM): The atomic force microscope (AFM) is a very powerful microscope invented by Binnig, Quate and Gerber in 1986. Besides imaging at the atomic level it is also one of the foremost tools for the manipulation of matter at the nanoscale. The AFM consists of a cantilever with a sharp tip (probe) at its end that is used to scan the specimen surface.
2 AFM: The cantilever is typically silicon or silicon nitride with a tip radius of curvature on the order of nanometers. When the tip is brought near the sample surface, forces between the tip and the sample lead to a deflection of the cantilever according to Hooke's law. The deflection is measured using a laser spot reflected from the top surface of the cantilever into an array of photodiodes.
Currently AFM is the most common form of scanning probe microscopy AFM AFM- Working Principle The AFM brings a probe in close proximity to the surface The force is detected by the deflection of a spring, usually a cantilever (diving board) Forces between the probe tip and the sample are sensed to control the distance between the the tip and the sample. van der Waals force curve Two Modes Repulsive (contact) At short probe-sample distances, the forces are repulsive Attractive Force (non-contact) At large probe-sample distances, the forces are attractive The AFM cantelever can be used to measure both attractive force mode and repulsive forces.
AFM Examples View of Silicon Surface Reconstruction Carbon Nanotube Used as a Conducting AFM Tip for Local Oxidation of Si.