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    Resins

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    Shynne RPh
    This document defines resins and their derivatives. Resins are amorphous products formed in plant secretory structures as metabolic end products. They are physically hard, transparent or translucent and soften when heated. Chemically, resins are complex mixtures that can include resin acids, resin alcohols, resinotannols, esters and resenes. Resins are also found in combinations with volatile oils and gums. The document outlines various resin combinations and provides examples. It describes the principal constituents of resins and their physical and chemical properties.

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    Resins

    Uploaded by

    Shynne RPh
    131 views20 pages
    This document defines resins and their derivatives. Resins are amorphous products formed in plant secretory structures as metabolic end products. They are physically hard, transparent or translucent and soften when heated. Chemically, resins are complex mixtures that can include resin acids, resin alcohols, resinotannols, esters and resenes. Resins are also found in combinations with volatile oils and gums. The document outlines various resin combinations and provides examples. It describes the principal constituents of resins and their physical and chemical properties.

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    This document defines resins and their derivatives. Resins are amorphous products formed in plant secretory structures as metabolic end products. They are physically hard, transparent or translucent and soften when heated. Chemically, resins are complex mixtures that can include resin acids, resin alcohols, resinotannols, esters and resenes. Resins are also found in combinations with volatile oils and gums. The document outlines various resin combinations and provides examples. It describes the principal constituents of resins and their physical and chemical properties.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    131 views20 pages

    Resins

    Uploaded by

    Shynne RPh
    This document defines resins and their derivatives. Resins are amorphous products formed in plant secretory structures as metabolic end products. They are physically hard, transparent or translucent and soften when heated. Chemically, resins are complex mixtures that can include resin acids, resin alcohols, resinotannols, esters and resenes. Resins are also found in combinations with volatile oils and gums. The document outlines various resin combinations and provides examples. It describes the principal constituents of resins and their physical and chemical properties.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    of 20

    RESINS AND RESIN COMBINATIONS

    July 15, 2013

    OBJECTIVES:
    1. TO DEFINE RESIN AND ITS DERIVATIVES 2. TO KNOW THE USES, FUNCTIONS AND ITS BOTANICAL ORIGINS 3. TO BE FAMILIAR WITH RESIN COMBINATIONS 4. TO KNOW ITS PHYSICAL , CHEMICAL PROPERTIES OF RESINS

    RESINS
    AMORPHOUS PRODUCTS WITH CHEMICAL NATURE. FORMED IN SCHIZOGENOUS OR IN SCHIZOLYSIGENOUS DUCTS OR CAVITIES END PRODUCT OF METABOLISM

    PHYSICAL PROPERTIES
    HARD TRANSPARENT TRANSLUCENT WHEN HEATED- SOFT AND MELTED

    CHEMICAL PROPERTIES
    COMPLEX MIXTURE OF:
    RESIN ACID RESIN ALCOHOL RESINOTANNOLS ESTERS RESENES

    INSOLUBLE IN WATER OXIDATION PRODUCT OF TERPENES .

    MIXTURES
    RESINS+VOLATILE OILS = OLEORESINS
    EX. Ginger, Capsicum

    RESINS+ V.O.+ GUMS= OLEO-GUM-RESINS


    EX. ASAFATIDA, MYRRH,balsams

    RESINS+ GLYCOSIDES= GLUCORESINS/GLYCORESINS


    EX. JALAP,PODOPHYLLUM

    3 WAYS IN OBTAINING PHARMACEUTICAL RESIN

    EXTRACTION

    DISTILLATION COLLECTION

    PRINCIPAL CONSTITUENTS OF RESINS


    RESIN ACID RESIN ALCOHOL- RESINOL

    RESENES
    GLYCORESINS

    RESIN ACID
    CONTAIN LARGE PROPORTION OF OXYACIDS CARBOXYLIC ACID+ PHENOLS OCCUR BOTH IN FREE STATE AND AS ESTERS SOLUBLE IN ACQUEOUS SOLUTION OF ALKALIES

    RESINATES- METALLIC SALTS

    EXAMPLE

    ABIETIC ACID- ROSIN OR COLOPHONY COPAIVIC ACIDOXYCOPAIVIC ACID-

    COPAIBA

    COMMIPHORIC ACID- MYRRH

    RESIN ALCOHOL/RESINOLS
    OCCUR IN FREE STATE ESTERS IN COMBINATIONS WITH SIMPLE AROMATIC ACIDS 1. BENZOIC ACID 2. SALICYLIC ACID 3. CINNAMIC ACID 4. UMBELLIC ACID

    EXAMPLES:
    RESINOTANNOLS ALOERESINOTANNOL- ALOE PERURESINOTANNOL- BALSAM OF PERU SUMARESINOTANNOL SIARESINOTANNOLBENZOIN TOLURESINOTANNOL- BALSAM OF TOLU RESINOLS BENZORESINOL- BENZOIN STORESINOL - STORAX

    RESENES
    COMPLEX NEUTRAL SUBSTANCES DEVOID OF CHEMICAL PROPERTIES INSOLUBLE IN RESIST HYDROLYSIS IN ALKALIES

    GLYCORESINS

    SUGAR+ RESIN ACIDS

    BOTANICAL SOURCES OF RESINS


    - COLOPHONY/ROSIN

    -PODOPHYLLUM PODOPHYLLUM- FOOTLIKE LEAF PELTATUM- SHIELDLIKE -ERIODICT YON/ YERBA SANTA ERIODICTYON- WOOLY - HAIRLY LEAVES - JALAP -. MASTIC/MASTICH,MASTICH - KAVA-KAVA - CANNABIS

    OLEORESINS
    HOMOGENOUS MIXTURES OF RESINS AND VOLATILE OILS LIQUID SEMI-SOLID SOLID

    EXAMPLES
    TURPENTINE CAPSICUM ZINGIBER WHITE PINE COPAIBA

    OLEO-GUM - RESINS
    V.O, GUM, RESIN EXAMPLES: BALSAMS MYRRH ST YRAX PERUVIAN BALSAM TOLU BALSAM BENZOINUM

    BALSAM
    RESINOUS MIXTURES THAT CONTAIN CINNAMIC ACID, BENZOIC ACID, OR ESTERS OF THESE ACIDS. EX. BENZOIN PERU BALSAM TOLU BALSAM STYRAX

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