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    Titrationspreap 1

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    vishakhshukla
    Titration is a process used to determine the concentration of an unknown acid or base solution. It involves adding a known solution of acid or base until the indicator shows the equivalence point, where the acid and base are neutralized. The document provides details on performing titrations, including choosing the correct indicator, calculating molarity using titration data, and working through sample problems.

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    Titrationspreap 1

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    vishakhshukla
    342 views12 pages
    Titration is a process used to determine the concentration of an unknown acid or base solution. It involves adding a known solution of acid or base until the indicator shows the equivalence point, where the acid and base are neutralized. The document provides details on performing titrations, including choosing the correct indicator, calculating molarity using titration data, and working through sample problems.

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    Titration is a process used to determine the concentration of an unknown acid or base solution. It involves adding a known solution of acid or base until the indicator shows the equivalence point, where the acid and base are neutralized. The document provides details on performing titrations, including choosing the correct indicator, calculating molarity using titration data, and working through sample problems.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    342 views12 pages

    Titrationspreap 1

    Uploaded by

    vishakhshukla
    Titration is a process used to determine the concentration of an unknown acid or base solution. It involves adding a known solution of acid or base until the indicator shows the equivalence point, where the acid and base are neutralized. The document provides details on performing titrations, including choosing the correct indicator, calculating molarity using titration data, and working through sample problems.

    Copyright:

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    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    of 12

    Titration

    • Indicators & pH Meters: The pH range


    over which an indicator changes color is its
    transition interval.
    interval pH meters measure the
    pH using electrodes.
    • Titration is the process of adding an acid to
    base until it is neutralized. (or vice versa)
    • Indicators are used to show when
    neutralization is reached.
    More On Titrations
    • Titrations are done to find the concentration of
    the unknown acid or base.
    • The correct indicator needs to be chosen so that it
    changes color right where acid = base or very
    close to this point.
    • The place where the indicator changes color is the
    end point.
    • The place where acid = base is the equivalence
    point.
    – Titrations may be done on compounds that are not acids
    & bases if they react so that the two factors are in
    chemically equivalent amounts at the equivalence point
    & there is an indicator with an appropriate endpoint.
    For a titration with a strong acid and a
    strong base the equivalence point occurs at
    approximately a pH of 7. 7
    For a titration with a weak acid and a strong
    base the equivalence point occurs above a
    pH of 7.
    7
    Performing Titrations
    • STEPS:
    • 1.) Use burets to accurately measure acid & base
    amounts.
    • 2.) Add one to the other until the indicator just
    barely changes color.
    color
    • If the acid & base involved are both monoprotic,
    M1V1=M2V2 ( or MHVH=MOHVOH ) can be used to
    find the unknown molarity.
    • If the acid & base involved have different amounts
    of H+ and OH-, then the balanced equation will
    have to be used along with dimensional analysis.
    (p502)
    Sample Problem
    • If 20.0 mL of 0.0100 M aqueous HCl is
    required to neutralize 30.0 mL of an
    aqueous solution of NaOH, determine the
    molarity of the NaOH solution.
    • MHVH=MOHVOH
    • (0.0100M) (20.0 mL) = (MOH)(30.0mL)
    • MOH = 6.67 x 10-3 M NaOH
    Try it Out!
    • In a titration, 27.4 mL of 0.154 M LiOH is
    added to a 25.0 mL HCl solution of
    unknown concentration. What is the
    molarity of the solution?
    • MHVH=MOHVOH
    • (MH)(25.0mL) = (27.4 mL)(0.154M)
    • MH= 0.169 M HCl
    Your Turn!
    • Suppose 20.0 mL of 0.100 M aqueous Ca(OH)2 is
    required to neutralize 12.0 mL of an aqueous solution of
    HCl. What is the molarity of the HCl solution.
    • Ca(OH)2 + 2HCl → 2H2O + CaCl2
    • Moles H+ = Moles OH- at equiv point
    Calculate moles of OH- (Molarity x Volume)
    0.100 mols/L x 0.020 L = 0.0020 moles Ca(OH) 2
    0.00200 mol Ca(OH)2 x 2 mol HCl = 0.0040 mol HCl
    1 mol Ca(OH)2

    Molarity = 0.004 mols HCl = 0.33 M HCl


    Another One!
    • By titration, 17.6 mL of aqueous H2SO4 neutralized 27.4
    mL of an aqueous solution of 0.0165 M KOH. What is
    the molarity of the acid solution?
    • H2SO4 + 2KOH→ 2H2O + K2SO4
    Moles H+ = Moles OH- at equiv point
    Calculate moles of OH- (Molarity x Volume)
    0.0165 moles/L x 0.0274 L = 0.000452 moles KOH
    0.000452 moles KOH x 1 mol H2SO4 = 0.000226 mol H2SO4
    2 mol KOH
    M = 0.000226 mols H2SO4 = 0.0128 M H2SO4
    0.0176 L
    Last One!
    • By titration, 33.3 mL of aqueous H3PO4 neutralized 55.5 mL
    of an aqueous solution of 0.444 M Ba(OH)2. What is the
    molarity of the acid solution?
    2H3PO4 + 3Ba(OH)2→ 6H2O + Ba3(PO4 )2
    Moles H+ = Moles OH- at equiv point
    Calculate moles of Ba(OH)2 (Molarity x Volume)
    0.444 moles/L x 0.0555 L = 0.0246 moles
    0.0246 moles Ba(OH)2 x 2 mol H3PO4 = 0.0164 mol H3PO4
    3 mol Ba(OH)2
    M = 0.0164 mols H3PO4 = 0.493 M H3PO4
    What was the longest recorded time that a
    single person had the hiccups?
    68 Years!
    Charles Osborne had the hiccups from the age of
    28 to 96. He hiccupped an estimated 430 million
    times!

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