TRIBOLOGY

DEFINITION
The word tribology was first reported in a landmark report by Jost (1966). The word is derived from the Greek word tribein meaning to rub, so the literal translation would be ``the science of rubbing.'' Its popular English language equivalent is friction and wear or lubrication science, alternatively used. The latter term is hardly all-inclusive. Dictionaries define tribology as the science and technology of interacting surfaces in relative motion and of related subjects and practices. Tribology is the art of applying operational analysis to problems of great economic significance, namely, reliability, maintenance, and wear of technical equipment, ranging from spacecraft to household appliances. Surface interactions in a tribological interface are highly complex, and their under- standing requires knowledge of various disciplines including physics, chemistry, applied mathematics, solid mechanics, fluid mechanics, thermodynamics, heat transfer, materials science, rheology, lubrication, machine design, performance and reliability.

HISTORY
Records show the use of wheels from 3500 BC, which illustrates our ancestors' concern with reducing friction in translational motion. The transportation of large stone building blocks and monuments required the know-how of frictional devices and lubricants, such as water-lubricated sleds. Figure 1 illustrates the use of a sledge to transport a heavy statue by Egyptians Circa 1880 BC (Layard, 1853). In this transportation, 172 slaves are being used to drag a large statue weighing about 600 KN along a wooden track. One man, standing on the sledge supporting the statue, is seen pouring a liquid into the path of motion; perhaps he was one of the earliest lubrication engineers. [Dowson (1998) has estimated that each man exerted a pull of about 800 N. On this basis, the total effort, which must at least equal the friction force, becomes 172 800 N. Thus, the coefficient of friction is about 0.23.] A tomb in Egypt that was dated several thousand years BC provides the evidence of use of lubricants. A chariot in this tomb still contained some of the original animal- fat lubricant in its wheel bearings.

FIGURE 1

HISTORY
During and after the glory of the Roman empire, military engineers rose to prominence by devising both war machinery and methods of fortification, using tribological principles. It was the renaissance engineerartist Leonardo da Vinci (14521519), celebrated in his days for his genius in military construction as well as for his painting and sculpture, who first postulated a scientific approach to friction. Da Vinci deduced the laws governing the motion of a rectangular block sliding over a flat surface. He introduced, for the first time, the concept of coefficient of friction as the ratio of the friction force to normal load. His work had no historical influence, however, because his notebooks remained unpublished for hundreds of years.

Wear path of his cranes following the steady load vector

Horizontal and inclined planes apparent areas of contact frictional torques

Ball bearings for large doors and cranes

HISTORY
In 1699, the French physicist Guillaume Amontons rediscovered the laws of friction after he studied dry sliding between two flat surfaces. First, the friction force that resists sliding at an interface is directly proportional to the normal load. Second, the amount of friction force does not depend on the apparent area of contact. These observations were verified by French physicist CharlesAugustin Coulomb (better known for his work on electrostatics) (Coulomb, 1785). He added a third law that the friction force is independent of velocity once motion starts. He also made a clear distinction between static friction and kinetic friction.

HISTORY
Many other developments occurred during the 1500s, particularly in the use of improved bearing materials. In 1684, Robert Hooke suggested the combination of steel shafts and bell-metal bushes as preferable to wood shod with iron for wheel bearings. Further developments were associated with the growth of industrialization in the latter part of the eighteenth century. Early developments in the petroleum industry started in Scotland, Canada, and the United States in the 1850s (Parish, 1935; Dowson, 1998).

HISTORY
Though essential laws of viscous flow were postulated by Sir Isaac Newton in 1668; scientific understanding of lubricated bearing operations did not occur until the end of the nineteenth century. Indeed, the beginning of our understanding of the principle of hydrodynamic lubrication was made possible by the experimental studies of Beauchamp Tower (1884) and the theoretical interpretations of Osborne Reynolds (1886) and related work by N.P. Petroff (1883). Since then developments in hydrodynamic bearing theory and practice were extremely rapid in meeting the demand for reliable bearings in new machinery.

HISTORY
Wear is a much younger subject than friction and bearing development, and it was initiated on a largely empirical basis. Scientific studies of wear developed little until the mid-twentieth century. Ragnar Holm made one of the earliest substantial contributions to the study of wear (Holm, 1946).

HISTORY
The industrial revolution (17501850 AD) is recognized as a period of rapid and impressive development of the machinery of production. The use of steam power and the subsequent development of the railways in the 1830s led to promotion of manufacturing skills. Since the beginning of the twentieth century, from enormous industrial growth leading to demand for better tribology, knowledge in all areas of tribology has expanded tremendously

INDUSTRIAL SIGNIFICANCE OF INDUSTRIAL SIGNIFICANCE OF TRIBOLOGY

Tribology is crucial to modern machinery which uses sliding and rolling surfaces. Examples of productive friction are brakes, clutches, driving wheels on trains and automobiles, bolts, and nuts. Examples of productive wear are writing with a pencil, machining, polishing, and shaving. Examples of unproductive friction and wear are internal combustion and aircraft engines, gears, cams, bearings, and seals.

Automotive Braking System

INDUSTRIAL SIGNIFICANCE OF TRIBOLOGY

According to some estimates, losses resulting from ignorance of tribology amount in the United States to about 6% of its gross national product (or about $200 billion dollars per year in 1966), and approximately one-third of the world's energy resources in present use appear as friction in one form or another. Thus, the importance of friction reduction and wear control cannot be overemphasized for economic reasons and long-term reliability. According to Jost (1966, 1976), the United Kingdom could save approximately 500 million pounds per annum, and the United States could save in excess of 16 billion dollars per annum by better tribological practices. The savings are both substantial and significant, and these savings can be obtained without the deployment of large capital investment.

INDUSTRIAL SIGNIFICANCE OF INDUSTRIAL SIGNIFICANCE OF TRIBOLOGY

The purpose of research in tribology is understandably the minimization and elimination of losses resulting from friction and wear at all levels of technology where the rubbing of surfaces is involved. Research in tribology leads to greater plant efficiency, better performance, fewer breakdowns, and significant savings.

ORIGINS AND SIGNIFICANCE OF NANOTRIBOLOGY

At most interfaces of technological relevance, contact occurs at numerous asperities. Consequently, the importance of investigating a single asperity contact in studies of the fundamental tribological and mechanical properties of surfaces has been long recognized. The recent emergence and proliferation of proximal probes, in particular tip-based microscopies (the scanning tunnelling microscope and the atomic force microscope) and of computational techniques for simulating tipsurface interactions and interfacial properties, has allowed systematic investigations of interfacial problems with high resolution as well as ways and means for modifying and manipulating nanoscale structures. These advances have led to the development of the new field of microtribology, nanotribology, molecular tribology, or atomic-scale tribology.This field is concerned with experimental and theoretical investigations of processes ranging from atomic and molecular scales to microscales, occurring during adhesion, friction, wear, and thin-film lubrication at sliding surfaces.

ORIGINS AND SIGNIFICANCE OF NANOTRIBOLOGY In macrotribology, tests are conducted on components with relatively large mass under heavily loaded conditions. In these tests, wear is inevitable and the bulk properties of mating components dominate the tribological performance. In micro/nanotribology, measurements are made on components, at least one of the mating components, with relatively small mass under lightly loaded conditions. In this situation, negligible wear occurs and the surface properties dominate the tribological performance.

ORIGINS AND SIGNIFICANCE OF NANOTRIBOLOGY

The micro/nanotribological studies are needed to develop fundamental understanding of interfacial phenomena on a small scale and to study interfacial phenomena in micro- and nanostructures used in magnetic storage systems, microelectromechanical systems (MEMS) and other industrial applications. The components used in micro- and nanostructures are very light (on the order of few micrograms) and operate under very light loads (on the order of a few micrograms to a few milligrams). As a result, friction and wear (on a nanoscale) of lightly loaded micro/nanocomponents are highly dependent on the surface interactions (few atomic layers). These structures are generally lubricated with molecularly thin films. Micro- and nanotribological techniques are ideal to study the friction and wear processes of microand nanostructures. Although micro/nanotribological studies are critical to study micro- and nanostructures, these studies are also valuable in fundamental understanding of interfacial phenomena in macrostructures to provide a bridge between science and engineering.

microelectromechanical systems (MEMS)

ORIGINS AND SIGNIFICANCE OF NANOTRIBOLOGY

The scanning tunnelling microscope, the atomic force and friction force microscopes and the surface force apparatus are widely used for micro/nanotribological studies. To give a historical perspective of the field, the scanning tunnelling microscope developed by Drs Gerd Binnig and Heinrich Rohrer and their colleagues in 1981 at the IBM Zurich Research Laboratory, Forschungslabor, is the first instrument capable of directly obtaining three-dimensional (3D) images of solid surfaces with atomic resolution. STMs can only be used to study surfaces which are electrically conductive to some degree. Based on their design of STM, in 1985, Binnig et al. developed an atomic force microscope (AFM) to measure ultrasmall forces (less than 1 mN) present between the AFM tip surface and the sample surface.

ORIGINS AND SIGNIFICANCE OF NANOTRIBOLOGY

AFMs can be used for measurement of all engineering surfaces which may be either electrically conducting or insulating. AFM has become a popular surface for topographic measurements on micro- to nanoscale. AFMs modified to measure both normal and friction forces, generally called friction force microscopes (FFMs) or lateral force microscopes (LFMs), are used to measure friction on micro- and nanoscales. AFMs are also used for studies of adhesion, scratching, wear, lubrication, surface temperatures, and for measurements of elastic/plastic mechanical properties (such as indentation hardness and modulus of elasticity). Surface force apparatuses (SFAs), first developed in 1969, are used to study both static and dynamic properties of the molecularly thin liquid films sandwiched between two molecularly smooth surfaces

3D images of solid surfaces with atomic resolution

ORIGINS AND SIGNIFICANCE OF NANOTRIBOLOGY

Meanwhile, significant progress in understanding the fundamental nature of bonding and interactions in materials, combined with advances in computer-based modelling and simulation methods, have allowed theoretical studies of complex interfacial phenomena with high resolution in space and time. Such simulations provide insights into atomic-scale energetics, structure, dynamics, thermodynamics, transport and rheological aspects of tribological processes. Furthermore, these theoretical approaches guide the interpretation of experimental data and the design of new experiments, and enable the prediction of new phenomena based on atomistic principles.