Basic concepts (I)

How do you define energy?

Energy: definition related to physical forces

Definition of energy: in physics, energy is the work that a force can or could do. Forces are: gravitational (due to interaction between mass and
energy concentrations)

electric (attraction and repulsion of charged particles) magnetic (attraction and repulsion of magnetic objects) chemical (driving chemical reactions: electro-magnetic) nuclear (binding nuclei together or breaking unstable
apart)

mechanic (impact of one moving object on another)

Force of Gravity
On earth, we are constantly under the force of gravity. What types of energy does gravity produce?

Acceleration of falling objects Altitude and depth pressure gradients of the

atmosphere and the seas Part of the fusion of the earths core
F

Mechanical Force
Mechanic forces are when one object hits another. What type of energy does this produce?

Acceleration / deceleration of interacting objects Heat dissipation within the objects Change of shape of objects
v
v

Electric & magnetic forces

Cause electrons to be attracted to nuclei in atoms -> basis for chemistry Cause charges (electric current) to flow in electric circuits -> basis for energy used in electronics, lights, appliances Cause needle of compass to point north

Energy: definition, continued

Energy is can also be inherent in a system, without any forces acting on it. Types of inherent energy are:

In a steadily moving particle: mass x velocity2 In a mass: mass x (speed of light)2 = mc2 In a body at a certain temperature: In a chemical compound:

(heat capacity of body) x temperature for water, heat capacity is, 1 calorie per gram per degree Celsius or Kelvin

2 H2 + O2 -> 2 H2O , Enthalpy released = -571.6 kJ/mol

Forms of energy
Energy can take many forms kinetic (movement of a mass) electric, magnetic (movement of charges or electromagnetic
fields radiating) Electricity Radiation (light) chemical (molecules with internal energy)

heat (thermal) (statistical expression of kinetic energy of

many objects in a gas, liquid or solid - or even radiation) potential or a battery)

potential (water above a dam, a charge in an electric Other examples?

SI units for energy

The SI unit of energy is a Joule: 1 kg*m2/s2 = 1 Newton*m (Newton is the unit of Force) mass * velocity 2 mass * g * height (on earth, g = 9.81 m/s2 ) for an ideal gas = cvkBT (cv =3/2 for a monatomic
gas)

Power is energy per time: 1 Watt = 1 Joule/s = 1 kg*m2/s3 most commonly used in electricity, but also for
vehicles in horsepower (acceleration time)

Other common energy units

http://www.onlineconversion.com/energy.htm
Energy conversion Unit 1 calorie = 1 kiloWatt hour = kWh = 1 British Thermal Unit = btu Quantity 4.1868000 3600000 1055.06 to Joule Joule Joule A power of 1 kW for a duration of 1 hour. It is a is a unit of energy used in North America. Note

1 ton oil equivalent = 1 toe 1 ton coal equivalent 1 ton oil equivalent = 1 toe 1 cubic meter of natural gas 1000 Watts for one year

4.19E+010 2.93E+10 1 / 7.33 3.70E+07 3.16E+010

Joule Joule Barrel of oil Joule Joule

It is the rounded-off amount of energy that would be produced by burning one metric ton of crude oil.

or 1 / 7.1 or 1 / 7.4 ... or roughly 1000 btu/ft3 for the 2000 Watt society

1000 Watts for one year

1 horsepower

8.77E+006
7.46E+002

kWh
Watts

for the 2000 Watt society

Prefixes
Orders of magnitude Name thousand million billion trillion quadrillion quintillion sextillion septillion Quantity 1E+03 1E+06 1E+09 1E+12 1E+15 1E+18 1E+21 1E+24 Prefix kilo mega giga tera peta exa zetta yotta

How to do energy conversions (quick reminder)

Given E = 5 kWh, what is value in MJ? From table, 1 kWh = 3.6 MJ

5 kWh x (3.6 MJ / kWh) = 18 MJ

In other direction: 5 MJ = ? kWh 1 MJ = 0.28 kWh 5 MJ x (0.28 kWh / MJ) = 1.4 kWh

Basic concepts (II)

How do you use energy?

What is energy for?

How do you use energy?
Examples of:

Kinetic Electro-magnetic

Electricity Radiation (light)

Chemical Potential Heat (thermal) ?

Practical energy: what is it for?

Energy in daily life: we use it to ... stay alive (food, oxygen: chemical) move faster (transportation fuel: chemical) keep warm (heating fuel: chemical) almost everything else (keep cold, preserve food,
light and ventilate spaces, cook, run machines, communicate, measure, store data, compute,...): electricity

In industrial processes: we use it to Extract (mechanical), refine (chemical),

synthesize (chemical), shape (heat, mechanical), assemble (mechanical): produce

Properties of energy
In any process, energy can be transformed but is always conserved

Fuel + oxygen: heat, light + new

compounds Moving objects collide: heat + work on objects Falling water+turbine: electricity + heat

Basic concepts (III)

Energy conversion, conversion efficiency

Energy conversion
Energy conversion: from one type to another Examples:

Chemical to kinetic Chemical to electric Potential to electric Thermal to electric Chemical to thermal Radiation to chemical Radiation to electric Radiation to thermal Electric to thermal Electric to chemical

Why is this important? Efficiency

What is efficiency?
Output / Input
Energy out / energy in for an energy conversion process?

Energy out = energy in , so not very useful

Useful energy out / energy in

Physical work / Heat content of fuel

Electricity / physical work Food / Inputs to agriculture

Efficiencies (2)

Source: Smil 1999

Efficiencies (3)

Source: Smil 1999

More than one conversion process

The total efficiency is the product of all conversion efficiencies: Etotal = E1 x E2 x E3 x E4 x E5 x E6 x Total losses can be (and are) tremendous Most losses are in the form of radiated heat, heat exhaust But can also be non-edible biomass or nonwork bodily functions (depending on final goal of energy)

Chain of conversion efficiencies: Light bulb

t r t
c e e r

Etotal = E1 x E2 x E3 = 35% x 90% x 5% = 1.6%

Source: Tester et al 2005

Example 2: diesel irrigation

Losses: t

t,r

t,m

Example 3: Drive power

Example 4: living and eating

Need 2500 kcal/day = 10 MJ/day or 2kcal/min. 2200 for a woman, not pregnant or lactating, 2800 for a man (FAO). EU: 3200 kcal/day. Equivalent to 4.75 GJ/year vegetable calories in a vegetarian diet (including 1/3 loss of food between field and stomach) Equivalent to 26.12 GJ/year vegetable calories in a carnivorous diet (1/2 calories from meat) Vegetarians are 5.5 times more efficient in terms of vegetable calories.

Efficiency of human-powered motion

kcal/mile

EU Energy Label
A, B, C ratings for many common appliances Based on EU standard metrics for each appliance

kWh / kg for laundry % of reference appliance

for refrigerators

Importance of consumer behavior/lifestyle

EU energy label vs. temperature of washing
kWh per cycle/Energy Rating

90C wash

1.22

1.46

1.59

1.72

1.85

1.98

60C wash

0.94

1.12

1.23

1.34

1.47

1.6

40C wash

0.56

0.67

0.74

0.79

0.85

0.91

USA EnergyGuide label

EnergyStar ratings exist, but are not A,B,C grades Instead, appliances have EnergyGuide labels (usually without EnergyStar ratings)

Basic concepts (IV)

Thermodynamics and entropy

Conservation, but
Energy is ALWAYS conserved However, energy is not always useful: dissipated heat is usually not recoverable. Useful energy is an anthropocentric concept in physics: from study of thermodynamics

Thermodynamics investigates statistical phenomena (many particles, Avogadros number = 61023): energy conversion involving heat.

3+1 laws of thermodynamics

If systems A and B are in thermal equilibrium with system C, A and B are in thermal equilibrium with each other (definition of temperature). Energy is always conserved. The entropy of an isolated system not at equilibrium will tend to increase over time. As temperature approaches absolute zero, the entropy of a system approaches a constant.

Paraphrases of 2 laws of thermodynamics

You cant get something from nothing.

You cant get something from something.

1. You can't get anything without working for it. The most you can accomplish is to break even. 2. You even can't break even.

1. (economics) There is no such thing as a free lunch.

History of thermodynamics (2nd law)

Nicolas Lonard Sadi Carnot (1796-1832)

Theory of heat engines, reversible

Carnot cycle: 2nd law of thermodynamics

Ludwig Boltzmann (1844-1906)

Kinetic theory of gases (atomic) Mathematical expression of entropy as a function of probability

Entropy
The entropy function S is defined as S = kB log (W) kB = Bolzmanns constant = 1.38 1023 =Joule/Kelvin

W=Wahrscheinlichkeit
For instance: vapor, water, ice expanding gas burning fuel

= possible states Increases with increasing disorder

2nd law of thermodynamics

dS entropy 0 increases over time tim (definiti n of dt For a system a undergoing change, for S 0 an isolated system system

S S 0 an non isolated syste system environmen t for

2nd law of thermodynamics

Total entropy always increases with time.

An isolated system can evolve, but only if its entropy doesnt decrease. A subsystems entropy can increase or decrease, but the total entropy (including the subsystems environment) cannot decrease.
R. Clausius (1865): Die Energie der Welt ist konstant. Die Entropie der Welt strebt einem Maximum zu. Notion of heat death of the universe

Basic concepts (V)

Applications of thermodynamics: heat engines, Carnot cycle, maximum and real efficiencies.

Performance of energy conversion machines (Carnot cycle)

Heat engine (cycle)

Heat, cool engine fluid Diesel, internal combustion

Reversible processes:

Entropy remains constant Sc = - Sh

Irreversible processes

Real world Heat losses, no perfect insulator Heat leakage Pressure losses, friction

The Carnot Cycle (the physics)

Ideal cycle between isotherms (T=constant) and adiabats (S = constant). dE = dW - dQ
where dW = PdV dQ = TdS

Loop integral over dE = 0.

The total work from one cycle of the engine is The heat taken from the warm reservoir is The efficiency is : theoretical maximal for heat engine.

Common types of heat engines

Rankine cycle: stationary power system (power plant
for generating electricity from fossil fuels or nuclear fission), efficiency around 30%

Brayton cycle: improvement on Rankine to reduce Combined Rankine-Brayton cycle: for natural gas
only, efficiencies of 60%!

degradation of materials at high temperature (natural gas and oil power plants), efficiencies of 28%

Otto cycle: internal combustion engine, electric

spark ignition, efficiency around 30%

Diesel cycle: internal combustion engine,

compression ignition (more efficient than Otto if compression ratio is higher), efficiency around 30%

Comparison of heat engines

Coal power plant

Typical generating capacity: 500 MW 250 tonnes of coal per hour

Other types of power generation

Not based on heat (fossil combustibles or nuclear)

Use various types of energy (guess which?)

Hydraulic power: gravitational energy of water Wind power: kinetic energy of air Solar power: radiation from sun

Wind power
Power = 0.47 x x D2 x v3 Watts

= efficiency ~ 30% (59%

theoretical maximum)

D = Diameter (40 meters) v = wind speed (13 m/s) P = 500 kW

Hydroelectricity (hydro)
Uses difference in potential gravitational energy of water above and below dam

E = m x g x h + m x v2 / 2 P = x x g x h x (flow in m3/s) is the density of water = 1000 kg /m3 Efficiency can be close to 90%

Power plant & fuel cell efficiencies

% Efficiency

Source: Miroslav Havranek, 2007

Energy, entropy and economy: some history

Austrian Eduard Sacher (1834-1903) Grundzge
einer Mechanik des Gesellschaft : economies try to win energy from nature, correlates stages of cultural progress with energy consumption. Energie, verwerte Sie! concerns due to rising fuel demands and realization of thermodynamic losses resources of energy of the globe will hold out, distinguishes between energy flows in nature and fossil fuels (spending interest vs. spending capital)

Wilhelm Ostwald (1853-1932) Vergeute keine

Frederick Soddy (1877-1956) how long the natural

Basic concepts (VI)

Georgescu-Roegen and entropy applied to the economic system.

Implications of entropy for economics

Geogescu-Roegen (1906-1994), Romanian economist, wrote The Entropy Law and the Economic Process in 1971. Points out that economic processes are not circular, but take low entropy (high quality resources) as inputs and produce high entropy emissions (degraded wastes). Worries about CO2 emissions from fossil fuel burning Concludes that current entropy production is too high, advocates solar input scale for global economy.

Georgescu-Roegen (1)
The economic process is nothing but an extension of biological evolution. Therefore the most important problems of the economy must be considered through this lens.
G-Rs vision, taken up by H. Daly and ecological economics Brundtlands 1987 vision of sustainable development

Environment

Society
Economy Environ ment Econo my

Society

Georgescu-Roegen (2)
() our whole economic life feeds on low entropy, to wit, cloth, lumber, china, copper, etc., all of which are highly ordered structures. () production represents a deficit in entropy terms: it increases total entropy (). () After the copper sheet has entered into the consumption sector the automatic shuffling takes over the job of gradually spreading its molecules to the four winds. So the popular economic maxim you cannot get something for nothing should be replaced by you cannot get anything but at a far greater cost in low entropy.
The entropy law and the economic process, p. 277-279

key concepts: Economic processes feed on low entropy, produce high entropy Concentrated natural resources are gradually dispersed

[] It is not the suns finite stock of energy that sets a limit to how long the human species may survive. Instead it is the meager stock of the earths resources that constitutes the crucial scarcity. [] First, the population may increase. Second, for the same size of population we may speed up the decumulation of natural resources for satisfying man-made wants, usually extravagant wants. The conclusion is straightforward. If we stampede over details, we can say that every baby born now means one human life less in the future. But also every Cadillac produced at any time means fewer lives in the future.

Key concepts: Solar energy will still be available in the future, however the quantity (STOCK) of low entropy natural resources is limited thus the responsibility to future generations.
The entropy law and the economic process, p. 304

Global entropy global population

Meadows (1971): There are limits to economic and physical growth of human societies. Daly (1973): steady-state economy and population is a goal, but at levels supported by organic agriculture alone: population probably lower than today. Advocate of managed decline in population, economic growth.

Basic concepts (VII)

Origin of energy
How do we get energy? Where does it all come from? (not so simple...)

Energy system (primary, final, useful, energy services)

Origin of energy on earth

Food? Solar (via photosynthesis) Oxygen? Solar (via photosynthesis) Wood for burning? Solar (via photosynthesis) Fossil fuels? Solar (via photosynthesis and geological processes: geothermal heating, pressure) Hydraulic or wind? Combination of solar and earth's rotation (Coriolis effect) Geothermal? Combination of nuclear fission and gravitation.

Nuclear fission? Fossil supernova explosion energy.

How do we compare such different sources?

Energy chain

Origin of nuclear energy: supernova

Nuclear fusion, powered by gravity, is the fuel of stars. Fusion is only efficient up to iron creation (nothing heavier). Some heavy stars burn to iron, then implode under the force of gravity. The shock wave is so strong it creates heavier atoms.

Comparing energy types

Primary energy: energy initially extracted from nature Final energy: transported, transformed, converted, ready to use (electricity, gasoline, bioethanol) Useful energy: used by final consumer (light, heat, motion) These concepts are mainly applicable to fossil energy systems. Three main types of primary energy: fossil, solar-based (renewable) and nuclear

Including biomass
Source: Haberl 2001

Also advocates an approach to energy accounting similar to material flow analysis: energy density of all materials (and wastes) should be included.

Emergy
H. T. Odum Embodied (and/or Emergent) Energy

Emergy is the available energy of one kind previously used up directly and indirectly to make a product or service. Solar emergy for ecological systems.

Exergy
Refers to a process analysis in which the material
and energy flows are measured with respect to a reference state

Can be done at a large regional or global level, if Exergy studied and concept promoted by Robert
and Leslie Ayres (many references).

reference state of materials is calculated relative to their earth averages.

Calorific content: gross & net

Gross calorific value: include heat from exhaust Net calorific value: exclude latent heat of water
vapor.

water (C + H both burn with O, creating CO2 + H2O)

Difference:

Gross is 5-6% larger than net for solid + liquid fuels Gross is 10% larger than net for natural gas. Worse if fuel is damp (has water trapped inside it)

Traditional/commercial accounting
International Energy Agency compiles national statistics (since 1960s for OECD and 1970s non-OECD) Available online at

http://www.iea.org/Textbase/stats/index.asp

Source: Jochem et al 2000

Energy Services

Energy system: services & scale

Lifestyle

Building envelope
Technology solutions at different Shared heat/cold facilities geographic scales: the larger the scale, the bigger the potential savings.

But where does infrastructure like rail/highway or urban density/diversity belong? Topography of energy stream.

What is missing?

Source: Tester et al. 2005

Example: Driving a car 1 km

Useful energy displacement of car by 1 km Final Energy Gasoline/diesel consumed by car

Smart
0.5 MJ

Average
0.9 MJ

Jeep
1.3 MJ

1.7 MJ 2.1 MJ

2.9 MJ 3.6 MJ

4.5 MJ 5.6 MJ

Primary Energy Extraction, transformation, transportation

(assuming 32 MJ/liter gasoline, 41 MJ/litre diesel, engine 1/3 efficient, 25% losses primary => final)