Ansell 8thEditionChemicalResistanceGuide
Ansell 8thEditionChemicalResistanceGuide
Ansell 8thEditionChemicalResistanceGuide
EDITION
Why is a product with a shorter breakthrough time sometimes given a better rating than one with a longer breakthrough time?
One glove has a breakthrough time of just 4 minutes. It is rated very good, while another with a breakthrough time of 30 minutes is rated only fair. Why? The reason is simple: in some cases the rate is more significant than the time. Imagine connecting two hoses of the same length but different diameters to a faucet using a Y connector. When you turn on the water, what happens? Water goes through the smaller hose first because there is less space inside that needs to be filled. But when the water finally gets through the larger hose it really gushes out. In only a few minutes, the larger hose will discharge much more water than the smaller one, even though the smaller one started first. The situation is similar with gloves. A combination of a short breakthrough time and a low permeation rate may expose a glove wearer to less chemical than a combination of a longer breakthrough time and a much higher breakthrough rate, if the glove is worn long enough.
Methodology
interior side of the test cell is checked for the presence of the permeated chemical and the extent to which it may have permeated the glove material. This standard allows a variety of options in analytical technique and collection media. At Ansell, dry nitrogen is the most common medium and gas chromatography with FID detection is the most common analytical technique. Our Research Department also uses liquids such as distilled water and hexane as collecting media, and techniques such as conductivity, colorimetry, and liquid chromatography for analysis of the collecting liquid. Degradation Testing Patches of the test material are cut from the product. These patches are weighed and measured, and then completely immersed in the test chemical for 30 minutes. The percentage of change in size is determined, and the patches are then dried to calculate the percentage of weight change. Observed physical changes are also reported. Ratings are based on the combined data.
Permeation Testing Ansell conducts permeation testing in accordance with ASTM Method F 739 standards. A specimen is cut from the glove and clamped into a test cell as a barrier membrane (see illustration). The exterior side of the specimen is exposed to a hazardous chemical. At timed intervals, the unexposed
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8th Edition Form No. CRG-GC. 9/08 2008 Ansell Healthcare. All Rights Reserved.
The first square in each column for each glove type is color coded to provide an overall rating for both Degradation and Permeation. The letter in each colored square is for Degradation alone. GREEN: The glove is very well suited for application with that chemical. YELLOW: The glove is suitable for that application under careful control of its use. RED: Avoid use of the glove with this chemical. SPECIAL NOTE: The chemicals in this guide highlighted in BLUE are experimental carcinogens, according to the ninth edition of Sax Dangerous Properties of Industrial Materials. Chemicals highlighted in GRAY are listed as suspected carcinogens, experimental carcinogens at extremely high dosages, and other materials which pose a lesser risk of cancer. CHEMICAL 1. Acetaldehyde 2. Acetic Acid, Glacial, 99.7% 3. Acetone 4. Acetonitrile 5. Acrylic Acid 6. Acrylonitrile 7. Allyl Alcohol 8. Ammonia Gas 9. Ammonium Fluoride, 40% 10. Ammonium Hydroxide, Conc. (28-30% Ammonia) 11. n-Amyl Acetate 12. Amyl Alcohol 13. Aniline 14. Aqua Regia 15. Benzaldehyde 16. Benzene (Benzol) 17. Benzotrichloride 18. Benzotrifluoride 19. Bromine Water 20. 1-Bromopropane (Propyl Bromide) 21. 2-Bromopropionic Acid 22. n-Butyl Acetate 23. n-Butyl Alcohol 24. Butyl Carbitol 25. Butyl Cellosolve 26. gamma-Butyrolactone 27. Carbon Disulfide 28. Carbon Tetrachloride 29. Cellosolve (Ethyl Glycol Ether, 2-Ethoxyethanol) 30. Cellosolve Acetate (2-Ethoxyethyl Acetate, EGEAA)
NEOPRENE/ NATURAL RUBBER BLEND *CHEMI-PRO Permeation: Breakthrough Degradation Rating Permeation: Rate
BUTYL UNSUPPORTED CHEMTEK BUTYL Permeation: Breakthrough Degradation Rating Permeation: Rate
VITON/BUTYL UNSUPPORTED CHEMTEK VITON/BUTYL Permeation: Breakthrough >480 93 70 >480 >180 >480 <10 >480 >480 >480 100 253 182 <10 >480 >480 >480 138 465 105 Degradation Rating Permeation: Rate VG E F E E E VG VG F E E E E VG
I I L L L L I L E L L L L L L L L L L L L L L E L
380 150 >480 >480 >480 >480 19 >480 30 470 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480
E E E E E E E E E E E E E E E E E E E E E E
P G NR F G F L E E E E NR F NR P E E E M F F E E E NR G G G F
158 30 120 140 >480 >360 >360 198 >480 >360 >480 170 >480 23 120 75 >360 >323 470 30 150 293 90
F F E G E E G E F F E E VG F G G G
E E G E E E L E E NR E E G NR NR NR E M E NR E G E E NR NR E G
10 390 10 20 395 140 >480 >480 250 348 145 >480 >480 <10 460 270 188 180 245 128 40
F F VG VG VG F E P E F G G G F
NR NR P I NR L P NR NR G G F NR G E NR L G F E I E E E I I
143 150 >480 >360 180 >360 >360 >360 >480 >360 75 >480 120 120 >360 >360 75 >360
G G E G E E E E E G E G VG E E G E
NR F NR NR NR P E E P G F G NR NR G G M G NR G E P NR NR F P NR
45 <5 60 >360 240 12 62 120 <10 <10 180 180 397 60 <5 25 38
G G E G F F VG VG G F G
E E E E E E E E E NR E E NR G NR NR P M E NR E E E E NR NR E E
Permeation: Rate F F VG F VG VG VG VG G P VG G G G VG G
E E G E E E I E E P E E G G NR NR P M G P E E E E NR NR E E
F G VG VG E VG G F P VG G G F VG G
E E E E E E E E E E E E M E E E E M F E E
>480 >480 >480 >480 >480 >480 128 >480 >480 >480 >480 20 10 80 >480 >480 >480 7 53 >480 >480
E E G E E E F P G E E G P E E
DD DD DD E E E F E E E E E I DD E E E I E DD
31. Chlorine Gas 32. Chlorobenzene 33. 4-Chlorobenzotrifluoride 34. 2-Chlorobenzyl Chloride 35. Chloroform 36. 1-Chloronaphthalene 37. 2-Chlorotoluene 38. 4-Chlorotoluene 39. "Chromic Acid" Cleaning Solution 40. Citric Acid, 10% 41. Cyclohexane 42. Cyclohexanol 43. Cyclohexanone 44. 1,5-Cyclooctadiene 45. Diacetone Alcohol 46. Dibutyl Phthalate 47. 1,2-Dichloroethane (Ethylene Dichloride, EDC) 48. Diethylamine 49. Diisobutyl Ketone (DIBK) 50. Dimethyl Sulfoxide (DMSO) 51. Dimethylacetamide (DMAC) 52. Dimethylformamide (DMF) 53. Dioctyl Phthalate (DOP, DEHP) 54. Di-n-Octyl Phthalate (DNOP) 55. 1,4-Dioxane 56. Electroless Copper Plating Solution 57. Electroless Nickel Plating Solution 58. Epichlorohydrin 59. Ethidium Bromide, 10% 60. Ethyl Acetate 61. Ethyl Alcohol, Denatured, 92% Ethanol 62. Ethylene Glycol 63. Ethylene Oxide Gas 64. Ethyl Ether 65. Ethyl L-Lactate 66. Formaldehyde, 37% in 1/3 Methanol/Water 67. Formic acid, 90% 68. Furfural 69. Freon TF 70. Gasoline, Unleaded (Shell Premium winter blend) 71. Glutaraldehyde, 25% 72. HCFC-141B 73. n-Heptane 74. Hexamethyldisilazine 75. n-Hexane 76. HFE 7100 77. HFE 71DE 78. Hydrazine, 65% 79. Hydrobromic Acid, 48%
CHEMICAL
L L E E L L L L L L L L L L L L L L L L L L L L I L E L L L L L L L L L I L
>480 >480 120 20 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 234 >480 >480 >480 >480 >480 170 >480 >480 >480 >480 >480 164 >480
BARRIER
E E E G E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E E
NR E NR P G P F E L E F E G G NR F E E NR NR G NR E E NR L NR E E E E E F NR E E E E E E E F E E
320 120 240 >360 >360 >360 103 >480 240 >360 51 263 240 >360 >360 >360 >480 240 >360 95 273 >360 240 >360 >480 >360 92 >360 >480 >480 10 >480 >360
SOL-VEX
VG G E G E E E F G VG E E VG E G G E E E E F E E F
NR F F NR NR NR NR NR E E P NR E F NR P P E NR E G NR E E P F E E F E E E E E NR E F E E E F E E
50 200 >480 390 23 208 132 398 45 >480 >360 >360 10 113 >480 <10 125 39 >480 40 240 >480 33 42 48 >480 <10 386 >480
29-SERIES
F E VG F VG G G F E P VG E F VG VG P E E F G E F
E F E E G NR F G E I E E NR G NR NR NR E P NR NR E NR F NR F G E P NR F G G P P L G G P F NR NR
>360 >480 >360 >360 50 >360 >480 150 >360 >360 >360 30 300 >360 120 >360 125 >360 >360 >360 <10 >480 >360 >360 >480
PVA
E E E E E E G E E E F E E VG E G E E E F E E
NR F F NR NR P G E E NR NR NR NR NR NR P NR NR NR NR NR E E NR NR G E NR E E E NR NR P E NR NR P NR E NR E E
65 >360 >360 360 19 >360 >360 60 >360 15 100 >360 >360 >480 >360 >360
SNORKEL
E E E VG E G E E E
NR P F NR NR NR NR NR E E P NR E E P NR P E E E P F E E E G E E NR E E E E NR NR E NR F NR E NR E E
20 >360 103 43 20 180 15 25 5 >360 >360 5 5 15 >360 15 10 150 15 210 15 120 150 >360
F VG VG E G VG F F F VG E VG G VG VG F E VG
NR P NR P NR NR NR E E P NR E G P NR P E E E E F E F E E NR E E E E NR NR NR F P E E
G VG E E G G E F VG F VG E VG E VG G
P I E P E NR M E G E E P E F E E E E E E E E E E E E E E F F P I P E
9 75 >480 5 >480 30 >480 30 >480 >480 >480 18 231 >480 >480 >480 >480 >480 >480 >480 196 >480 >480 >480 >480 >480 20 40 10 305 5 >480
P F E P E F F E G E G E E F F F G F
F I E I E L E L L M DD M DD DD DD DD E DD E E E G E F E I E
>480 48 >480 212 >480 >480 >480 >480 >480 150 19 15 >480 >480 >480 >480 10 >480 >480 >480 >480 >480 <10 >480 >480 >480
E F E VG E E E G E G E E E F E G E
CHEMTEK BUTYL
CHEMTEK VITON/BUTYL
80. Hydrochloric Acid, 10% 81. Hydrochloric Acid, 37% (Concentrated) 82. Hydrofluoric Acid, 48% 83. Hydrofluoric Acid, 95% 84. Hydrogen Fluoride Gas 85. Hydrogen Peroxide, 30% 86. Hydroquinone, saturated solution 87. Hypophosphorus Acid, 50% 88. Isobutyl Alcohol 89. Isooctane 90. Isopropyl Alcohol 91. Kerosene 92. Lactic Acid, 85% 93. Lauric Acid, 36% in Ethanol 94. d-Limonene 95. Maleic Acid, saturated solution 96. Mercury 97. Methyl Alcohol (Methanol) 98. Methylamine, 40% 99. Methyl Amyl Ketone (MAK) 100. Methyl-t-Butyl Ether (MTBE) 101. Methyl Cellosolve 102. Methylene Bromide (DBM) 103. Methylene Chloride (DCM) 104. Methylene bis(4-Phenylisocyanate) (MDI) 105. Methyl Ethyl Ketone (MEK) 106. Methyl Ethyl Ketone (MEK)/Toluene, 1/1 107. Methyl Iodide (Iodomethane) 108. Methyl Isobutyl Ketone (MIBK) 109. Methyl Methacrylate (MMA) 110. N-Methyl-2-Pyrrolidone (NMP) 111. Mineral Spirits, Rule 66 112. Monoethanolamine 113. Morpholine 114. Naphtha, VM&P 115. Nitric Acid, 10% 116. Nitric Acid, 70% (Concentrated) 117. Nitric Acid, Red Fuming 118. Nitrobenzene 119. Nitromethane 120. 1-Nitropropane 121. 2-Nitropropane 122. n-Octyl Alcohol 123. Oleic Acid 124. Oxalic Acid, saturated solution 125. Pad Etch 1 (Ashland Chemical) 126. Palmitic Acid, saturated solution 127. Pentachlorophenol, 5% in Mineral Spirits 128. n-Pentane
L L L L L L L L L L L L L E I L E L L L L L L L L L L E L L L I L E
>480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 470 >480 20 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 368 >480 >480
E E E E E E E E E E E F E VG E E E E E E E E E E E E E E E
E E E I E E E E E E E E E E E L E E F E F NR NR NR NR P P NR E E NR E E NR NR NR F NR NR E E E E G E E
>360 >480 334 <15 >360 >360 >480 >360 >360 >360 >360 >360 >360 >480 >360 >480 103 >360 53 >360 208 45 35 >480 >360 >360 >360 30 >360 >360 >360 >360 30 >360 >360
P E E E E E E E VG E F E G F P E E E F E E E E
E E I I E E E E E E E E E NR E E E F P E NR NR P NR NR NR NR E E P G E L NR NR E F F E F E E E E G
>480 >480 >480 342 >480 108 >240 478 268 110 185 >480 >480 >480 73 153 10 10 125 400 103 >480 >480 60 30 25 218 13 >480 >360 >480 151 30
VG E E VG E G VG G F F G E G G G F E VG F G
NR NR NR NR NR NR P E NR G F NR G NR NR NR E G E G G F F F G NR E E G E NR NR NR G G E E G G P F P E G
>360 >360 >360 >480 >360 >360 30 >360 >360 90 >360 >360 >360 >360 >360 90 420 >360 >360 >480 >360 >360 60 34 5 >360
E E E E E G E E VG E E E E E G E E E G E E E F E
E E I I E E E F P G F E F G G L G E NR NR P NR NR NR NR NR NR NR F E NR F G F P NR P NR NR F F E E G F NR
>360 300 155 2 >360 >360 10 150 >360 >360 15 125 >360 >480 45 135 55 150 >480 120 >360 109 >360 90 >360 >360 75 180
E VG E E G E G VG G VG E VG E VG E
E E L I E G E E NR E NR E E NR E L E E F NR E NR NR L F F NR P P E NR E G NR G NR P F E E E E F E E G NR P
>360 290 >480 15 >360 >360 >480 15 35 >360 >360 >360 >480 12 55 <10 20 >480 5 5 75 50 20 >360 15 10 15 5 30 >360 >360 >360 5
F E VG VG E VG VG F VG E F F VG E G G G G G VG E
E E I G E E P E P E E NR E E E F NR NR NR L P NR P NR F G E E NR E NR NR F E E E E G E E E E
>360 >360 <15 >360 >360 52 57 >360 >360 >360 22 100 <10 >480 <10 47 23 57 43 >360 42 30 25 30 53 120 >360 >360 193 13
F E E E E E F E F VG G E G G E G VG G G
E L E I G F E E E G L E G E F F E E E E E E E
>480 >480 >480 58 82 57 >480 >480 155 38 >480 70 13 183 60 15 245 85 >480 >480 >480 >480 >480
E E F F G F E F P G P G G E E E
L L E L E F DD E DD L E E DD G DD DD DD I DD E E DD
>480 >480 >480 >480 >480 >480 363 >480 17 >480 >480 29 20 215 30 10 >120 235 >480 249 255
E E E F E E G G VG G F VG E E
129. Perchloric Acid, 60% 130. Perchloroethylene (PERC) 131. Phenol, 90% 132. Phosphoric Acid, 85% (Concentrated) 133. Potassium Hydroxide, 50% 134. Propane Gas 135. n-Propyl Acetate 136. n-Propyl Alcohol 137. Propylene Glycol Methyl Ether Acetate (PGMEA) 138. Propylene Glycol Monomethyl Ether (PGME) 139. Propylene Oxide 140. Pyridine 141. Rubber Solvent 142. Silicon Etch 143. Skydrol 500B-4 144. Sodium Hydroxide, 50% 145. Stoddard Solvent 146. Styrene 147. Sulfur Dichloride 148. Sulfuric Acid, 47% (Battery Acid) 149. Sulfuric Acid, 95-98% (Concentrated) 150. Sulfuric Acid, 120% (Oleum) 151. Tannic Acid, 65% 152. Tetrahydrofuran (THF) 153. Toluene (Toluol) 154. Toluene Diisocyanate (TDI) 155. Triallylamine 156. Trichloroethylene (TCE) 157. Tricresyl Phosphate (TCP) 158. Triethanolamine (TEA) 159. Turpentine 160. Vertrel MCA 161. Vertrel SMT 162. Vertrel XE 163. Vertrel XF 164. Vertrel XM 165. Vinyl Acetate 166. Vinyl Chloride Gas 167. Xylenes, Mixed (Xylol)
L L L E L L L L L E L L E L L L L L L L L E E E E L L L
>480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 >480 10 105 >480 >480 >480 >480 >480
E E E E E E E E E E E E E E E E E E E G E E E E E E
E G NR E E L F E E NR NR E NR NR E E NR P E NR E NR F NR L NR E E E E P E E E F G
>360 361 >360 >360 >480 20 >360 200 >360 >360 >360 >480 >360 >360 34 >480 >360 >360 >480 110 >480 >480 >480 18 96
VG E G E F E E E F E E E E G E E E F F
E NR E G E L P E G P NR NR E E NR E E NR NR E F F E NR NR NR NR F E NR E F E E E NR
>480 353 >360 >480 >480 323 37 43 >480 >480 139 >360 24 53 >480 253 170 23 <10 47 >480 105
G E E F G G G E F VG G F G E E
NR E F NR NR G P E G G E NR NR E G NR NR NR P P G G E G G G F G F F F E
>360 >360 120 >360 35 10 >360 >360 >360 115 >1440 >360 >360 >360 >360 >360 >360 17 40 387 10 >360
E E VG E G F E E E F E E E E E E E G VG VG G E
E NR G G E I NR F P P NR NR NR F NR G F NR G G M E NR NR P NR F E P G G G E P NR
>360 75 >360 >360 7 90 150 >480 57 >360 26 25 >360 >360 >360 13 <10 303 >480 55
VG VG VG G G E E F F E E G
F NR E F E P E G P F NR NR NR E NR NR NR E NR E NR NR G NR E G NR G F E E E NR
>360 90 >360 >360 23 13 10 >360 >360 >360 7 45 >360 <10 <10 17 337 23
VG F F G E E F F VG VG VG
E NR E G E P E G P P NR P NR E G NR NR E NR E NR NR G NR E NR G P E E E NR
>360 180 >360 >360 30 18 10 >360 10 >360 >360 65 >360 <10 <10 43 204 30
E E F F G VG E F P VG G VG
P E E E L L I L E E G E F P E NR E I I M E E P
<10 >480 135 >480 >480 >480 43 465 >480 >480 26 >480 13 20 >480 >480 58 173 18 >480 >480 27
F G E E F E E F F VG F E E F
E E DD E I L DD DD DD E E E DD E E DD E I DD DD DD DD NR E
>480 >480 <10 >480 334 >480 <10 40 >480 >480 >480 >480 10 313 >480 204 >480 >480 20 <10 398 >480 >480
E F E E F E F VG E G F E E E
L A degradation test against this chemical was not run. However, since its breakthrough time is greater than 480 minutes, the Degradation Rating is expected to be Good to Excellent. I A degradation test against this chemical was not run. However, in view of degradation tests performed with similar compounds, the Degradation Rating is expected to be Good to Excellent. M A degradation test against this chemical was not run. However, in view of data obtained with similar compounds, the Degradation Rating is expected to be Fair to Poor. *CAUTION: This product contains natural rubber latex which may cause allergic reactions in some individuals.
NOTE:
These recommendations are based on laboratory tests, and reflect the best judgement of Ansell in the light of data available at the time of preparation and in accordance with the current revision of ASTM F 739. They are intended to guide and inform qualified professionals engaged in assuring safety in the workplace. Because the conditions of ultimate use are beyond our control, and because we cannot run permeation tests in all possible work environments and across all combinations of chemicals and solutions, these recommendations are advisory only. The suitability of a product for a specific application must be determined by testing by the purchaser. The data in this guide are subject to revision as additional knowledge and experience are gained. Test data herein reflect laboratory performance of partial gloves and not necessarily the complete unit. Anyone intending to use these recommendations should first verify that the glove selected is suitable for the intended use and meets all appropriate health standards. Upon written request, Ansell will provide a sample of material to aid you in making your own selection under your own individual safety requirements. NEITHER THIS GUIDE NOR ANY OTHER STATEMENT MADE HEREIN BY OR ON BEHALF OF ANSELL SHOULD BE CONSTRUED AS A WARRANTY OF MERCHANTABILITY OR THAT ANY ANSELL GLOVE IS FIT FOR A PARTICULAR PURPOSE. ANSELL ASSUMES NO RESPONSIBILITY FOR THE SUITABILITY OR ADEQUACY OF AN END-USERS SELECTION OF A PRODUCT FOR A SPECIFIC APPLICATION. Skydrol is a registered trademark of Solutia Inc. Vertrel is a registered trademark of DuPont.
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