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    Nitrogen System

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    pradip11
    Pressure swing adsorption is a process that separates gas mixtures using an adsorbent material like zeolite. The process works by preferentially adsorbing one gas at high pressure, then desorbing it at low pressure. Using two vessels allows continuous production as one regenerates while the other produces the target gas. Common applications include hydrogen production, carbon dioxide removal from natural gas, and generating oxygen or nitrogen from air.

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    Nitrogen System

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    pradip11
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    Pressure swing adsorption is a process that separates gas mixtures using an adsorbent material like zeolite. The process works by preferentially adsorbing one gas at high pressure, then desorbing it at low pressure. Using two vessels allows continuous production as one regenerates while the other produces the target gas. Common applications include hydrogen production, carbon dioxide removal from natural gas, and generating oxygen or nitrogen from air.

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    Pressure swing adsorption is a process that separates gas mixtures using an adsorbent material like zeolite. The process works by preferentially adsorbing one gas at high pressure, then desorbing it at low pressure. Using two vessels allows continuous production as one regenerates while the other produces the target gas. Common applications include hydrogen production, carbon dioxide removal from natural gas, and generating oxygen or nitrogen from air.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as ODT, PDF, TXT or read online from Scribd
    Download as odt, pdf, or txt
    75 views3 pages

    Nitrogen System

    Uploaded by

    pradip11
    Pressure swing adsorption is a process that separates gas mixtures using an adsorbent material like zeolite. The process works by preferentially adsorbing one gas at high pressure, then desorbing it at low pressure. Using two vessels allows continuous production as one regenerates while the other produces the target gas. Common applications include hydrogen production, carbon dioxide removal from natural gas, and generating oxygen or nitrogen from air.

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    Attribution Non-Commercial (BY-NC)
    Download as ODT, PDF, TXT or read online from Scribd
    Download as odt, pdf, or txt
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    Pressure swing adsorption

    Schematic drawing of PSA process

    Pressure swing adsorption (PSA) is a technology used to separate some gas species from a mixture of gases under pressure according to the species' molecular characteristics and affinity for an adsorbent material. It operates at near-ambient temperatures and so differs from cryogenic distillation techniques of gas separation. Special adsorptive materials (e.g., zeolites) are used as a molecular sieve, preferentially adsorbing the target gas species at high pressure. The process then swings to low pressure to desorb the adsorbent material.

    [edit]Process Pressure swing adsorption processes rely on the fact that under high pressure, gases tend to be attracted to solid surfaces, or "adsorbed". The higher the pressure, the more gas is adsorbed; when the pressure is reduced, the gas is released, or desorbed. PSA processes can be used to separate gases in a mixture because different gases tend to be attracted to different solid surfaces more or less strongly. If a gas mixture such as air, for example, is passed under pressure through a vessel containing an adsorbent bed of zeolite that attracts nitrogenmore strongly than it does oxygen, part or all of the nitrogen will stay in the bed, and the gas coming out of the vessel will be enriched in oxygen. When the bed reaches the end of its capacity to adsorb nitrogen, it can be regenerated by reducing the pressure, thereby releasing the adsorbed nitrogen. It is then ready for another cycle of producing oxygen enriched air. This is exactly the process used in portable oxygen concentrators used by emphysema patients and others who require oxygen enriched air to breathe.

    Using two adsorbent vessels allows near-continuous production of the target gas. It also permits so-called pressure equalisation, where the gas leaving the vessel being depressured is used to partially pressurise the second vessel. This results in significant energy savings, and is common industrial practice. [edit]Adsorbents Aside from their ability to discriminate between different gases, adsorbents for PSA systems are usually very porous materials chosen because of their large surface areas. Typical adsorbents are activated carbon, silica gel, alumina and zeolite. Though the gas adsorbed on these surfaces may consist of a layer only one or at most a few molecules thick, surface areas of several hundred square meters per gram enable the adsorption of a significant portion of the adsorbent's weight in gas. In addition to their selectivity for different gases, zeolites and some types of activated carbon called carbon molecular sieves may utilize their molecular sieve characteristics to exclude some gas molecules from their structure based on the size of the molecules, thereby restricting the ability of the larger molecules to be adsorbed. [edit]Applications One of the primary applications of PSA is in the removal of carbon dioxide (CO2) as the final step in the large-scale commercial synthesis ofhydrogen (H2) for use in oil refineries and in the production of ammonia (NH3). Refineries often use PSA technology in the removal ofhydrogen sulfide (H2S) from hydrogen feed and recycle streams of hydrotreating and hydrocracking units. Another application of PSA is the separation of carbon dioxide from biogas to increase the methane (CH4) content. Through PSA the biogas can be upgraded to a quality similar to natural gas. Nitrogen generator units employ the PSA technique to produce high purity nitrogen gas (99.5% or greater) from a supply of compressed air. Research is currently underway for PSA to capture CO2 in large quantities from coal-fired power plants prior to geosequestration, in order to reduce greenhouse gas production from these plants.[1] PSA is an economic choice for small-scale production of reasonable purity oxygen or nitrogen from air. PSA technology has a major use in the medical industry to produce oxygen, particularly in remote or inaccessible parts of the world where bulk cryogenic or compressed cylinder storage is not possible. PSA is also used in hypoxic air fire prevention systems to produce air with a low oxygen concent. PSA has also been discussed as a future alternative to the non-regenerable sorbent technology used in space suit Primary Life Support Systems, in order to save weight and extend the operating time of the suit.[2] [edit]Variations of PSA technology Double Stage PSA (DS-PSA, sometimes referred to as Dual Step PSA). With this variation of PSA developed for use in Laboratory Nitrogen Generators [3] generation of nitrogen gas is divided into two steps: in the first step, the compressed air is forced to pass through a carbon molecular sieve to produce nitrogen at a purity of approximately 98%; in the second step this nitrogen is forced to pass into a second carbon molecular sieve and the nitrogen gas reaches a final purity up to 99.999%. The purge Gas from the second step is recycled and partially used as feed gas in the first step.

    In addition, the purge process is supported by active evacuation for better performance in the next cycle. The goals of both of these changes is to improve efficiency over a conventional PSA process.

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