Mathematical Modeling of The Melting Rate of Metallic Particles in The Electric Arc Furnace
Mathematical Modeling of The Melting Rate of Metallic Particles in The Electric Arc Furnace
9–16
1) Graduate Program in Metallurgy, Morelia Technological Institute (ITM), Av. Tecnológico 1500, Col. Lomas de Santiaguito,
58120, Morelia, Michoacán, México. 2) Department of Metallurgy, Facultad de Química, Universidad Nacional
Autónoma de México (UNAM), Edificio “D” Circuito de los Institutos s/n, Cd. Universitaria, Del. Coyoacán, 04510 México D. F.,
México. E-mail: [email protected]
(Received on May 25, 2009; accepted on September 25, 2009 )
A computational fluid dynamics model coupled to a lagrangian model of melting/solidifying particles has
been developed to describe the melting kinetics of metallic particles in an industrial Electric Arc Furnace
(EAF), assuming that liquid steel occupies the entire computational domain. The metallic particles represent
Direct Reduced Iron (DRI). The use of two previous models, an arc model and a fluid flow model has made
possible to evaluate the melting rate of injected DRI in a three phase-EAF, evaluating the influence of the
initial particle size, the initial DRI temperature, feeding position, feeding rate, arc length and some of the
metallurgical properties of DRI. The frozen shell formed in the early stage of the melting process has also
been evaluated in this model.
KEY WORDS: DRI melting; CFD; melting rate.
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ISIJ International, Vol. 50 (2010), No. 1
that the thickness of the frozen shell is negligible in com- convective boundary. This approach is able to properly
parison with the radius of the particle, therefore, in the ther- compute both the temperature distribution and the particle
mal balance the radius employed is not the radius at the liq- radius evolution, however, since the computational domain
uid–particle interface but the initial particle radius, as fol- is a single solid sphere of variable radius, the convective
lows: boundary condition is oversimplified and consequently the
local temperature and stirring conditions of the melt are not
∂Tp dr taken into account. It is the objective of this work to present
kp ⫽ ρp Δ H m ⫹ h(TC ⫺ TP ) ..............(1)
∂r dt some results describing the melting process of iron parti-
cles in its own melt in an industrial three phase EAF includ-
Sato et al.6,7) reported laboratory experimental results from ing the local temperature and stirring conditions. This new
the melting of pre-reduced pellets in liquid steel and in approach losses some details in the computation of the DRI
molten slags. They found an increase in the melting rate by melting kinetics, however its main advantage is the cou-
increasing metallization of pellets and by increasing the pling of the local temperature and stirring conditions in the
temperature of the molten bath, however, once the tempera- furnace under specific process parameters with the melting
ture reaches 1 570°C a further increase has no significant kinetics of DRI.
effect on the melting rate.
Aboutalebi et al.8) reported the influence of particle size,
2. Description of Mathematical Model
temperature and stirring conditions on the melting rate of
metallic particles in a ladle. In this work the formation of Frame of Reference: The simulation is restricted to two
the solid shell was neglected. They concluded that the melt- phases; the solid to be melted and the liquid phase. The two
ing rate increases by decreasing the particle size and by in- phase system can be described by establishing an Eulerian
creasing both superheat temperature and stirring conditions. frame of reference to describe the fluid flow and the heat
Similar results have been reported by Jiao and Themelis9) transfer in the continuous phase by solving the turbulent
and Ji et al.10) Navier–Stokes, the continuity and the energy conservations
Zhang and Oeters11) described a mathematical model to equations, additionally, a Lagrangian frame of reference is
represent the melting process of ferromanganese particles used to track the pellets trajectories by using the Newton’s
thrown into a steel ladle. They found a short time, less than second law of motion and allowing exchanges of momen-
1 s, to reach the terminal velocity inside the melt and such tum and heat between the liquid and the particle. The parti-
velocity was used to compute the heat transfer coefficient. cles are allowed to undergo phase transformations such as
A melting distribution time to represent the melting rate of melting or solidification. This Eulerian–Lagrangian ap-
all particles was used to define the melting time of a vari- proach is able to analyze the two phase system and also the
able particle distribution. It was found a higher melting rate time to solve the system of equations is shorter than the
as both the terminal velocity and melt temperature in- Eulerian–Eulerian approach.
creases. The two-phase model to simulate the melting behavior of
Several works have been reported on scrap melting in solid particles in an electric arc furnace bath is composed
Electric Arc Furnaces (EAF). Matson and Ramirez12) inves- of three sub-models, (a) an arc model, (b) an Eulerian fluid
tigated the melting process of scrap assuming spherical iron flow model and (c) a Lagrangian melting model. The first
particles. Gaye et al.13) suggested a maximum scrap size of two models have been reported elsewhere16,17) and only a
120 mm in the converter to avoid unmelted scrap at the end brief description will be outlined below. An important fea-
of the blow. Szekely et al.14) attributed a key role to carbon ture of these models is the computational domain shown in
dissolved in liquid steel to facilitate scrap melting. Li Fig. 1, which considers an industrial size, 3-phase electric
et al.15) used steel bars with various sizes to describe scrap arc furnace of 220 tons.
melting. Arc Model: This model16) is used to define the instanta-
An integral approach coupling heat, mass and fluid flow neous electric power delivered by each phase in a 3-phase
phenomena to understand the DRI melting and dissolution electric arc furnace, as a function of the main electrical pa-
processes in electric arc furnaces has not yet been carried rameters, such as arc length and arc voltage. The arc model
out. It is important to point out that most of the previous is based on the Channel Arc Model modified by Larsen.18)
models reported in the literature deal with numerically Fluid Flow Model: This model17) was developed to
solving a transient heat conduction problem with a mobile compute velocity and temperature fields in the entire com-
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ISIJ International, Vol. 50 (2010), No. 1
putational domain totally filled with liquid steel. It was as- U C ⫽ U C ⫹ U C′ ..............................(4)
sumed that the main driving forces are due to buoyancy
forces. Localized heating is quantitatively described by the
arc model. For a given set of electrical parameters, the in- 2.2. Equation of Thermal Energy Conservation
stantaneous electric power is used as boundary condition in The change of temperature in the solid with respect to
this model. time is obtained by an energy balance, included in the sub-
Melting Model: This model defines the melting rate of routine GENTRA of the commercial code Phoenics, which
DRI pellets in the electric arc furnace as a function of sev- assumes that the particle temperature changes with time
eral process variables. In order to simplify the computa- and the fraction of solid remaining in the particle, T(fs,t),
tions, the following assumptions are made. but at any instant, the temperature is uniform in the whole
– Free surface (no slag). particle.
– Constant thermo-physical properties. ∂Tp df
– Walls at constant temperature of 1 500°C. mpC p ⫽ mp ΔH m s ⫹ h(TC ⫺ TP ) ...........(5)
∂t dt
– Radiation from the walls and roof is not taken into ac-
count. where: mp is the mass of the particle, Cp is the heat capacity
– Steady state conditions in the flow. of the particle, Tp and Tc represent the temperatures for the
– Porous iron spheres of low density and uniform size to particle and the surrounded liquid, respectively, DHm is the
simulate DRI. latent heat of solidification, fs is the fraction of solid phase
– Liquid steel is the continuous phase and DRI the dis- remaining in the particle, h is the convective heat transfer
persed phase. coefficient.
– Uniform temperature in DRI particles. In the previous equation, the left hand side term repre-
– Temperature is uniform across the section of a single pel- sents the accumulation term. The two terms on the right
let but this temperature changes with time. hand side represent the amount of heat released or absorbed
Governing Equations: The equations take into consid- due to solidification or melting and the heat transfer ex-
eration heat and momentum exchange among the two change from the surrounding liquid steel to the particle. At
phases as well as the formation of a frozen shell around the the beginning of computation the Lagrangian model com-
solid phase at the beginning of the melting process. putes the size of the frozen shell. Once the shell is known,
the particle size, Rp, and mass mp remain constant. The
2.1. Equations of Motion melting rate is now controlled by the solid fraction which
The momentum equation associated with each particle is initially is unity and when melting has been completed is
given by the following expression19): zero, finishing with a fully liquid particle of mass mp, a par-
ticle size Rp and a temperature equal to the liquidus temper-
dmpU p 4 ature of the particle. In order to describe the melting rate of
⫽ πRp3 ( ρ p ⫺ ρl )g ⫹ 2πRp2CD ρ U C ⫺U p
dt 3 the particle, the radius of the remaining solid phase is di-
4 dU p rectly related to the fraction of solid (fs). This calculation
⫺ C A πRp3 ρ ...(2)
3 dt differs from previous models where only the solid particle
was considered in the computational domain and as melting
This is the second law of motion, i.e., mass times accelera- occurs the particle size decreases. Although the former
tion equals all forces acting on the particle. The term on the computational approach accurately describes the instanta-
left side of the previous equation represents the rate of neous particle radius and temperature profile within the
change of momentum associated with the particle. The particle, convection is oversimplified, only treated as a
three terms on the right side correspond to the various boundary condition for a single solid sphere. On the other
forces acting on the particle; buoyancy force, drag force hand with the approach followed in our work, there is an
and force associated with the added mass. oversimplification in the radius and temperature evolution
The instantaneous velocity of the particle is given by the of the particles, however the convection governed by the
following equation. heat transfer coefficients are included based on local bath
temperatures, turbulence and stirring conditions prevailing
dx p in a more realistic multiparticle system. The convective
Up ⫽ ..................................(3) heat transfer coefficient is computed based on the
dt
Ranz–Marshall equation20):
Where: xp represents the particle position vector, Up the
particle instantaneous velocity, mp is the mass of each parti- k c ....................(6)
h ⫽ (2 ⫹ 0.6 Re0.5 1/ 3
p Prp )
cle, Rp is the particle radius, CD is the drag coefficient, CA is Dp
a coefficient of added mass, g is the gravity constant, r p and
r l represent the densities of particle and liquid, respectively. Where: Rep and Prp represent the Reynolds number and
UC represents the instantaneous velocity associated with the Prandtl number for the particle, respectively, kc is the ther-
liquid continuous phase, UC is the time averaged velocity of mal conductivity for liquid steel and Dp is the diameter of
liquid and U⬘C is the fluctuating velocity of the liquid due to the particle.
the turbulence. These three velocities are related by the fol- The drag coefficient, CD, is taken from the correlation
lowing expression. provided by Clift, Weber and Grace,21) for spherical parti-
cles and Reynolds numbers lower than 3⫻105.
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ISIJ International, Vol. 50 (2010), No. 1
24 0.42
CD ⫽ (1⫹ 0.15 Re0.687
p )⫹
Re p 1⫹ 4.25 ⫻ 104 Re⫺p 1.16
...........................................(7)
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ISIJ International, Vol. 50 (2010), No. 1
Fig. 5. (a) Melting time as a function of arc length; (b) arc input
power as a function of the arc length for different arc
voltages.16)
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ISIJ International, Vol. 50 (2010), No. 1
Fig. 6. Effect of initial particle temperature on melting time. Fig. 9. Effect solids flow rate on the average temperature of the
molten bath.
Fig. 10. Effect of feeding position on the melting time; (a) tracer
injection, (b) melting time as a function of feeding posi-
tion.
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ISIJ International, Vol. 50 (2010), No. 1
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ISIJ International, Vol. 50 (2010), No. 1
T : Temperature
t : Time
X : Distance
U : Velocity
DH: Latent heat of solidification
r : Density
Subscripts
p : Particle
c : Continuous phase (liquid steel)
s : Solidus
l : Liquidus
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