

JEE–MAIN EXAMINATION – APRIL 2025

(HELD ON WEDNESDAY 2nd APRIL 2025) TIME : 3:00 PM TO 6:00 PM

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A d
x
d
1. If the image of the point P(1, 0, 3) in the line
Sol. 10
dx 1
f  t  dt 
dx

5xf  x   x 5  9 
joining the points A(4, 7, 1) and B(3, 5, 3) is
 10f(x) = 5f(x) + 5x f  (x) – 5x4
Q(, , ), then  +  +  is equal to
 f(x) + x4 = x f  (x)
47 46
(1) (2) dy
3 3  y  x4  x
dx
(3) 18 (4) 13
dy  1
Ans. (2)   y     x3
dx  x
Sol. P(1, 0, 3) 1 1
 ye    x3e 
 dx  dx
A(4, 7, 1), B(3, 5, 3)
x x
c

N
x 3 y 5 z 3  ye
 nx
  x3e
 nx
c
Line AB    
1 2 2
y x3
Let foot of perpendicular of P on AB be   c
x x
R  ( + 3, 2 + 5, –2 + 3)

(–2) = 0
E
 ( + 3 – 1) (1) + (2 + 5 – 0) (2) + (–2 + 3 – 3) 
y
x
  x2  c

y x3
  + 2 + 4 + 10 + 4 = 0   c
x 3
LL
4
 Put x = 1 in given equation
3
 0 = 5f(1) – 1 – 9  f(1) = 2
 5 7 17 
R , ,  2 1 5
3 3 3    cc
1 3 3
 10 14 34   7 14 25  f  3 27 5
Q    1,  0,  3    , , 
 3 3 3  3 3 3    
3 3 3
A

7  14  25 46  f(3) = 32
   
3 3
3. The number of terms of an A.P. is even; the sum of
2. Let ƒ : [1, ) [2, ) be a differentiable function, all the odd terms is 24, the sum of all the even
x terms is 30 and the last term exceeds the first by
If 10 ƒ(t)dt  5xƒ(x)  x5  9 for all x , then
21
1 . Then the number of terms which are integers
2
the value of ƒ(3) is :
in the A.P. is :
(1) 18 (2) 32 (1) 4 (2) 10
(3) 22 (4) 26 (3) 6 (4) 8
Ans. (2) Ans. (1)

1

Sol. a2 + a4 + ... + an = 30 ....(1)   2 
a1 + a3 + ... + an – 1 = 24 ....(2)  4  1,2  1 ,  2  1,   1 ,    1,  ,.......
  2  
(1) – (2)
  2 r 2
(a2 – a1) + (a4 – a3) ... (an – an – 1) = 6 2nd element of each ordered pair =
2 r 2
n
 d = 6  nd = 12 For maximum number of ordered pairs in such
2
sequence
21
an – a1 = (n – 1)d =   2 r 2
2  1 or 2 ; 1   25
2 r 2
21 21
 nd – d =  12 – =d  = 2r – 1 or  = 3.2r – 2
2 2
Case-I :  = 2r – 1
3
d= ,n=8  = 2, 22, 23, 24
2
4 r = 2, 3, 4, 5
Sum of odd terms = 2a   4  1 3  24
2 Hence maximum value of r is 5 when  = 16
3 Case-II :  = 3.2r – 2
a

N
2  = 3, 6, 12, 24
3 9 15 21 r = 2, 3, 4, 5
A.P.  ,3, ,6, ,9, ,12
2 2 2 2 Hence maximum value of r is 5 when  = 24
no. of integer terms = 4 5. If the length of the minor axis of an ellipse is equal
4. Let A = {1, 2, 3,...., 10} and R be a relation on A
E
such that R = {(a, b) : a = 2b + 1}. Let (a1, a2),
(a2, a3), (a3, a4), ...., (ak, ak+1) be a sequence of k
elements of R such that the second entry of an
to one fourth of the distance between the foci, then
the eccentricity of the ellipse is :

(1)
4
(2)
3
ordered pair is equal to the first entry of the next 17 16
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ordered pair. Then the largest integer k, for which 3 5
such a sequence exists, is equal to : (3) (4)
19 7
(1) 6 (2) 7
Ans. (1)
(3) 5 (4) 8
1
Ans. (3) Sol. 2b  (2ae)
4
Sol. a = 2b + 1
b e
2b = a – 1 
A

a 4
R = {(3, 1), (5, 2), ..., (99, 49)}
Let (2m + 1, m), (2 – 1, ) are such ordered pairs. b2
e  1
According to the condition a2
m = 2 – 1  m = odd number
e2
 1 element of ordered pair (a, b)
st e  1
16
a = 2(2 – 1) + 1 = 4 – 1
 1 
Hence a  {3, 7, ..., 99} e2 1    1
 16 
   {1, 2, ..., 25}
4
 set of sequence e
17

2

6. The line L1 is parallel to the vector 8. If the system of equation
a  3iˆ  2ˆj  4kˆ and passes through the point 2x + y + 3z = 5
(7, 6, 2) and the line L2 is parallel to the vector 3x + 2y – z = 7
b  2iˆ  ˆj  3kˆ and passes through the point
4x + 5y + z = 9
(5, 3, 4). The shortest distance between the lines L1
has infinitely many solutions, then ( +  ) is
2 2
and L2 is :
23 21 equal to :
(1) (2)
38 57 (1) 22 (2) 18
23 21 (3) 26 (4) 30
(3) (4)
57 38 Ans. (3)
Ans. (1)
2  3
  
Sol. L1 : 7iˆ  6ˆj  2k   3iˆ  2ˆj  4k  Sol.   0  3 2 1  0

:  5iˆ  3jˆ  4k     2iˆ  ˆj  3k 

4 5 
L2
Distance between skew lines  2(2 + 5) +  (–4 –3) + 3 (7) = 0

 
2iˆ  3ˆj  2kˆ . 2iˆ  17ˆj  7kˆ   4 –3 –4 + 31 = 0 ......(1)

N
 2  5
342
69 69 23 3  0  3 2 7  0
   4 5 9
342 3 38 38
7. Let (a, b) be the point of intersection of the curve  2(–17) +  (1) + 5 (7) = 0
2
E
x = 2y and the straight line y –2x –6 = 0 in the

second quadrant. Then the integral I  

b
9x 2
a 1 5
x
dx
 = –1
from equation (1)

is equal to : 4 + 3 + 4 + 31 = 0    5
LL
(1) 24 (2) 27
(3) 18 (4) 21  2  2  26
Ans. (1)
 7 4  
Sol. x2 = 2y & y = 2x + 6 9. If    ,  , then the number of solutions of
 6 3 
x2 = 4x + 12

x – 4x – 12 = 0 
2 x  6 if x  2 3 cosec2   2  
3  1 cosec  4  0, is equal to
y  18 y  2 (1) 6 (2) 8
A

 (6, 18) & (–2, 2) (3) 10 (4) 7

Here (6, 18) Rejected because (a, b) lies in 2nd
quadrant Ans. (1)
 a = –2 & b = 2
2 2 2 x 2 Sol. cosec 
2    
3  1  4 3  1  2 3  16 3
9x 9.5 .x
I=  1  5x dx   1  5x
dx 2 3

 
2 2
2
2 3  1  16  8 3
2 2
 x3  
 2I   9x dx  18  x dx  18  
2 2
2 3
2  3 0
   
0

2I = 48 2 3 1  2  2 3

 I  24 2 3

3

2 1 4 
cosec = 2 or
3 B  3  10  1
q =  III  = =
 G  1 5 3 4  3
1  3  
 sin = or 3  10 10 10 
2 2
1 1
1  3  + =7
 sin = has 3 solutions & also sin = p q
2 2
11. If the mean and the variance of 6, 4, a, 8, b, 12, 10,
 7  4  
has 3 solutions in  ,  13 are 9 and 9.25 respectively, then a + b + ab is
 6 3  equal to :
10. Given three indentical bags each containing (1) 105 (2) 103
10 balls, whose colours are as follows : (3) 100 (4) 106
Red Blue Green Ans. (2)
Bag I 3 2 5 Sol.  mean = 9
Bag II 4 3 3
 53 + a + b = 72
Bag III 5 1 4
 a + b = 19

N
A person chooses a bag at random and takes out a
ball. If the ball is Red, the probability that it is  =237
and (X)2 + 2 =
x 2
1

4 N
from bag I is p and if the balls is Green, the
probability that it is from bag III is q, then the 37 529  a  b
2 2
 81 + =
4 8
1 1
value of    is :

(1) 6
p q
E (2) 9
 648 + 74 = 529 + a2 + b2
 a + b = 193
2 2

 a + b = 19  a2 + b2 + 2ab = 361
(3) 7 (4) 8
LL
Ans. (3) 2ab = 168
 3  ab = 84
R 
 10   a + b + ab = 103
Bag I 3R 2B 5G  5 12. If the domain of the function
G 
 10  1 1
ƒ(x)   is (a, b), then
 4  10  3x  x 2 x | x |
Sol. R 
 10 
A

2 2
Bag II 4R 3B 3G (1 + a) + b is equal to :
 3  (1) 26 (2) 29
G 
 10  (3) 25 (4) 30
 5 
R  Ans. (1)
Bag III 5R 1B 4G  10 
 4  Sol. x + |x| > 0  x  (0, ) ....(1)
G 
 10  & 10 + 3x – x2 > 0
 x2 – 3x – 10 < 0
1 3 
B  3  10  1  x  (–2, 5) ....(2)
p = P I  = = from (1) & (2) x  (0, 5)
R
  1  3 4 5  4
   
3  10 10 10  a=0&b=5
 (1 + a2) + b2 = 1 + 25 = 26

4

1  cos2x  a cos 4x  b
13. 4 
0
1
 3  x  1 x
2 2
 dx – 3 loge

 3  is equal Sol. lim
x 0 x4
= finite

 (2x)2 (2x)4   (4x)2 (4x)4 

to : 1   ....  a 1   ....  b
2 4 2 4
L=    
(1) 2 + 
2 + loge 1  2  x4
 2 32 
(2) 2 – 2 – log 1  2 (1  a  b)  x 2 (2  8a)  x 4   a   x 6 ( )....
e
L= 3 3 
x4
(3) 2 + 2 – log 1  2
e
1
 1 + a – b = 0 and 2 + 8a = 0  a = –
(4) 2 – 2 + log 1 
e
2 4
b=a+1
Ans. (2) 1 3
1
=  +1=
1 4 4
Sol. 4  dx – 3ln 3
3  x  1  x2
2 1 3 1
0
a+b=  + =
1
4 4 2
3  x2  1  x2 3
= 4 dx – ln 3  10 r 1 – 1  11
10
11 –1111

N
0
(3  x )  (1  x )
2 2
2 15. If 
r 0  10 r 
 . C r 1 
1010
, then  is
 x
 
1
3 2  equal to :
= 2  3  x  l n x  3  x 
2

  2 2 0 (1) 15 (2) 11
(3) 24 (4) 20
x
2
 1
2
E 2 
1
 3
–  1  x  l n(x  1  x )   – ln3
0  2
Ans. (4)

Sol. 
10
 10 r 1  1  11
  Cr 1
 1 3   3  r 0  10 r 
= 2   4  l n(1  4)  0  l n 3 
LL
 2 2   2  10
 1 
   10  r  11C r 1
1 1   1  3 r 0  10 
–  2  l n(1  2)   0  (0)    l n 3
2 2   2  2 10   1  
r 1

 10 11 C r 1  10  11 C r 1   
 3 3 1 1  3   10  
=2 1  l n3  l n3   l n(1  2) – ln3
r 0 
 2 4 2 2  2
 10  11 C1  11C2  .....  11C11 
3 3
= 2 + 3 ln 3 – ln 3 – 2 – ln (1 + 2 )– l n3   1  
A

1 2 11
2 2  1   1 
10  11 C1    11C2    .....  11C11   
  10   10   10  
=2– 2 – ln(1+ 2)
cos  2x   a cos  4x  – b  
11
1 
14. If lim is finite, then (a+b)  10 211  1  10  1    1
x 0 x4  10  
is equal to :
1111
1  10(2)11  10   10
(1) (2) 0 1010
2
(20)11  1111
3 
(3) (4) –1 1010
4
  = 20
Ans. (1)

5

16. The number of ways, in which the letters A, B, C,  t2 = 2
D, E can be placed in the 8 boxes of the figure
below so that no row remains empty and at most  
 Q at 22 ,2at 2 = (16, 16)
one letter can be placed in a box, is : Let, S divides PQ internally in  : 1 ratio
16  4
 0
 1
1 m
 
4 n
(1) 5880 (2) 960
 m2 + n2 = 1 + 16 = 17
(3) 840 (4) 5760
Ans. (4) 18. Let a  2i – 3j  k , b  3i  2j  5k and a vector c
Sol. be such that  a – c   b  –18i – 3j  12k and
R1
a.c  3 . If b  c  d , then a.d is equal to :
R2
(1) 18 (2) 12
R3
(3) 9 (4) 15

N
Ans. (4)
= Total – [(All in R1 and R3) + (All in R2 and R3) +
Sol. a  2iˆ  3jˆ  kˆ , b  3iˆ  2ˆj  5kˆ
(All in R1 and R2)]


= 8 C5  5  5  5  6C5  5
E  i j k
a  b  2 3 1
 5(56  1  1  6)  120(48) 3 2 5
= 5760
 17iˆ  7jˆ  13kˆ
17. Let the point P of the focal chord PQ of the
parabola y2 = 16x be (1, –4). If the focus of the (a  c)  b  18iˆ  3j  12kˆ
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parabola divides the chord PQ in the ratio m : n,  (a  b)  (c  b)  18iˆ  3jˆ  12kˆ
gcd(m, n) = 1, then m2 + n2 is equal to :
(1) 17 (2) 10  b  c  (18iˆ  3jˆ  12k)
ˆ  (a  b)

(3) 37 (4) 26  (18iˆ  3jˆ  12k)

ˆ  (17i  7jˆ  13k)
ˆ
Ans. (1)
b  c  ˆi  4ˆj  kˆ
Sol. y2 = 16x ; a = 4 focus S  (4, 0)
 a  d  a  (b  c)  (2i  3j  k)  (ˆi  4ˆj  k)
ˆ
(t2)
A

l Q = –2 – 12 – 1 = –15

 S(4, 0)  a  d  15

P(t1) 19. Let the area of the triangle formed by a straight

(1, –4) Line L : x + by + c = 0 with co-ordinate axes be 48
square units. If the perpendicular drawn from the
2at1 = –4 origin to the line L makes an angle of 45° with the
 2(4)t1 = –4 positive x-axis, then the value of b2+c2 is:
1 (1) 90 (2) 93
 t1 =  (3) 97 (4) 83
2
Ans. (3)
 t1t2 = –1

6

x y SECTION-B
Sol.  1
c c / b 21. Let y = y(x) be the solution of the differential
dy
equation +2y sec2 x = 2sec2x + 3tan x.sec2 x
dx
5   
such that y(0) = . Then 12  y   – e –2  is equal
4  4 
to __________.
45° 45° Ans. (21)

I.F.  e 
2sec 2 xdx
Sol.
= e2tanx
Solution of diff. eq.
1 c2
 area of triangle =  48 y.e2 tan x   e2 tan x (2sec2 x  3tan x.sec 2 x)dx
2 b
y.e2 tan x   e2 tan x .(2sec2 x)dx   e2 tan x .(3tan x.sec2 x)dx
c2
 96
b y.e2 tan x  e2 tan x .2tan x   e2 tan x .2sec2 x  2tan xdx   e2 tan x .3tan x.sec2 xdx

N
c y.e2 tan x  2 tan x.e2 tan x   e2 tan x .tan xsec2 xdx
 –c = 
b
tan x.e2 tan x e2 tan x
y.e2 tan x  2 tan x.e2 tan x   C
b=1  c = 96
2
2 4

20.
 b + c = 97
2 2
E
Let A be a 3 × 3 real matrix such that A (A – 2I) –
4(A – I) = O, where I and O are the identity and
2
y  2 tan x 

5
tan x
2
  Ce 2 tan x
4

x = 0, y =
null matrices, respectively. If A = A + A + I,
5 2 4
LL
where ,  and  are real constants, then  +  +  c=1
is equal to:  7
y     e 2
(1) 12 (2) 20 4 4

(3) 76 (4) 4    7

Then 12  y    e 2   12    21
Ans. (1)  4  4

Sol. A3 – 2A2 – 4A + 4I = 0 22. If the sum of the first 10 terms of the series
A

4.1 4.2 4.3 m

A3 = 2A2 + 4A – 4I    ... is , where
1  4.1 1  4.2 1  4.3
4 4 4
n
A4 = 2A3 + 4A2 – 4A gcd(m, n) = 1, then m + n is equal to ________.
= 2 (2A2 + 4A – 4I) + 4A2 – 4A Ans. (441)
A4 = 8A2 + 4A – 8I 4.r
Sol. Tr 
1  4.r 4
5 3 2
A = 8A + 4A – 8A
= 8(2A2 + 4A – 4I) + 4A2 – 8A 4.r
Tr 
5 2
A = 20A + 24A – 32I (2r  2r  1)(2r 2  2r  1)
2

  = 20,  = 24,  = –32 (2r 2  2r  1)  (2r 2  2r  1)

Tr 
(2r 2  2r  1)(2r 2  2r  1)
  +  +  = 12

7

1 1 25. If the set of all a  R – {1}, for which the roots of
Tr   2
2r  2r  1 2r  2r  1
2
the equation (1 – a)x2 + 2(a – 3)x + 9 = 0 are
1 1 positive is (–, –] [, ), then 2 +  +  is
T1  
1 5 equal to _________.
1 1 Ans. (7)
T2  
5 13 Sol. Both the roots are positive
D0
1 1 4(a – 3)2 – 4×9(1 – a)  0
T10  
181 221
a2 – 6a + 9 – 9 + 9a  0
1 220 m a2 + 3a  0
S10  1   
221 221 n
a(a + 3)  0
m + n = 441
a  (–, –3]  [0, ) ……(i)
 x
23. If y = cos   cos –1  , then (x – y)2 + 3y2 is equal b
3 2  0
2a
to __________.
2(a  3)

N
Ans. (3) 0
2(a  1)
 1 x
Sol. y  cos  cos 1  cos 1  a  (–, 1)  (3, ) ……..(ii)
 2 2
f(0) = 9 > 0
1 x 1 x2 Equation (i)  (ii)
y    1 1
2 2 4

4y  x  3 4  x
2 2
4
2

2
E a  (–, –3]  [0, 1)
2 +  +  – 6 + 0 + 1 = 7
3(4 – x ) = x + 16y – 8xy
LL
12 – 3x2 = x2 + 16y2 – 8xy
4x2 + 16y2 – 8xy = 12
x2 + 4y2 – 2xy = 3
x2 + y2 – 2xy – 3y2 = 3
(x – y)2 + 3y2 = 3
24. Let A(4, –2), B(1, 1) and C(9, –3) be the vertices
of a triangle ABC. Then the maximum area of the
A

parallelogram AFDE, formed with vertices D, E

and F on the sides BC, CA and AB of the triangle
ABC respectively, is __________.
Ans. (3)
4 2 1
1
Sol. Area of ABC = 1 1 1
2
9 3 1
= 6 square units
1
Maximum area of AFDE =  6 = 3 sq. units
2

8
 ALLEN
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
JEE–MAIN EXAMINATION – APRIL 2025
(HELD ON WEDNESDAY 2nd APRIL 2025) TIME : 3:00 PM TO 6:00 PM

PHYSICS TEST PAPER WITH SOLUTION

SECTION-A 28. The moment of inertia of a circular ring of mass M
26. Given below are two statements : one is labelled and diameter r about a tangential axis lying in the
as Assertion (A) and the other is labelled as plane of the ring is :
Reason (R). 1 3
(1) Mr 2 (2) Mr 2
Assertion (A) : Net dipole moment of a polar 2 8
linear isotropic dielectric substance is not zero 3
(3) Mr 2 (4) 2 Mr2
even in the absence of an external electric field. 2
Reason (R) : In absence of an external electric Ans. (2)
field, the different permanent dipoles of a polar Sol. Diameter is given as R.
dielectric substance are oriented in random  Radius = R/2
directions. 2
3 R 3
In the light of the above statements, choose the I tan gent  m    mR 2

below :

correct explanation of (A) EN

most appropriate answer from the options given

(1) (A) is correct but (R) is not correct

(2) Both (A) and (R) are correct but (R) is not the

(3) Both (A) and (R) are correct and (R) is the
correct explanation of (A)
(4) (A) is not correct but (R) is correct
Ans. (4)
29.
2 2 8
Two water drops each of radius 'r' coalesce to from
a bigger drop. If 'T' is the surface tension, the
surface energy released in this process is :
 2

(1) 4r 2T  2  2 3 

(3) 4r 2T 1  2 
Ans. (1)



(4) 4r 2T  2  1
1

(2) 4r 2T  2  2 3 


Sol. A : Since polar dielectrics are randomly oriental

LL
4 4
Sol. 2  R 3  r 3  r  21/3 R
Pnet  0 . 3 3
R : If E is absent, polar dielectric remain polar & Ui = 2 × 4R2T
are randomly oriented. Uf = 4r2T = 4R2T22/3
27. In a moving coil galvanometer, two moving coils  Heat lost = u i  u f  4R 2 T[2  22/3 ]
M1 and M2 have the following particulars : 30. An electron with mass 'm' with an initial velocity
R1 = 5 , N1 = 15, A1 = 3.6 × 10–3 m2, B1 = 0.25 T (t = 0) v  v0ˆi (v0 > 0) enters a magnetic field
R2 = 7 , N2 = 21, A2 = 1.8 × 10–3 m2, B2 = 0.50 T B  B ˆj . If the initial de-Broglie wavelength at
A

0
Assuming that torsional constant of the springs are t = 0 is 0 then its value after time 't' would be :
same for both coils, what will be the ratio of
0 0
voltage sensitivity of M1 and M2 ? (1) (2)
2 2 2
(1) 1 : 1 (2) 1 : 4 e B0 t e2 B02 t 2
1 1 
(3) 1 : 3 (4) 1 : 2 m2 m2
Ans. (1) e 2 B02 t 2
(3)  0 1  (4) 0
 NAB m2
Sol. Voltage sensitivity = 
V cR Ans. (4)
 N A B R 15  3.6  0.25 7 1 Sol. Magnetic field does not work
Ratio =   1 1 1  2     Speed will not charge, so De-Broglie
N A B R
 2 2 2 1 21 1.8  0.5 5 1
wavelength remains same.

1

31. A sinusoidal wave of wavelength 7.5 cm travels a 34. Two large plane parallel conducting plates are kept
distance of 1.2 cm along the x-direction in 0.3 sec. 10 cm apart as shown in figure. The potential
The crest P is at x = 0 at t = 0 sec and maximum difference between them is V. The potential
displacement of the wave is 2 cm. Which equation difference between the points A and B (shown in
correctly represents this wave ? the figure) is :
(1) y = 2cos(0.83x – 3.35t) cm A
(2) y = 2sin(0.83x – 3.5t) cm

3 cm
(3) y = 2cos(3.35x – 0.83t) cm
(4) y = 2cos(0.13x – 0.5t) cm C B
Ans. (1)
dis tan ce
Sol. v 1 2
time (1) V (2) V
12 4 5
v  4 cm / s 3
0.3 (3) V (4) 1 V
4
2 2 4
k    0.83 Ans. (2)
 7.5 15
E
 4
v     vk  4   3.35 A

32.

Ans.
k
So y = A cos (kx – t)

(1) qI /0

(2)
2
(3) q 0 I
15

(2) q 0 I
(4) q0/I
EN
Given a charge q, current I and permeability of
vacuum 0. Which of the following quantity has
the dimension of momentum ? Sol.
3cm
C
4cm

Using V = E (d)
V = E (10)
V
VAB  E.4   4 
10
B

2V
5
Sol. Q = AT
LL
I=A 35. Identify the characteristics of an adiabatic process
µ0 = MLT–2 A–2 in a monoatomic gas.
P = Qx µ0y Iz = [AT]x [MLT–2A–2]y [A]z (A) Internal energy is constant.
MLT–1 = MyLyTx–2y A–2y+z+x (B) Work done in the process is equal to the charge
in internal energy.
Now; y = 1
(C) The product of temperature and volume is a
x – 2y = –1
constant.
– 2y + z = 0
(D) The product of pressure and volume is a
x=y=z=1 constant.
A

33. A solenoid having area A and length 'l' is filled (E) The work done to change the temperature from
with a material having relative permeability 2. The T1 to T2 is proportional to (T2 – T1)
magnetic energy stored in the solenoid is :
Choose the correct answer from the options given
B2 Al B2 Al below :
(1) (2)
0 2 0 (1) (A), (C), (D) only (2) (A), (C), (E) only
B2 Al (3) (B), (E) only (4) (B), (D) only
(3) B2Al (4) Ans. (3)
4 0
Sol. Q = U + W = 0  –U = W
Ans. (4)
WD = –nCvT  |WD| = nCvT  T2 – T1
U B2 B2 B2
Sol.  U V A  B & E [Only possibility]
V 2 r u 0 40 40

2

36. Assuming the validity of Bohr's atomic model for 39. Two identical objects are placed in front of convex
hydrogen like ions the radius of Li++ ion in its mirror and concave mirror having same radii of
1
ground state is given by a 0 , where X = ______. curvature of 12 cm, at same distance of
X
18 cm from the respective mirrors. The ratio of
(Where a0 is the first Bohr's radius.)
sizes of the images formed by convex mirror and
(1) 2 (2) 1
by concave mirror is :
(3) 3 (4) 9
Ans. (3) (1) 1/2 (2) 2
n2 (3) 3 (4) 1/3
Sol. r  r0 & z = 3 for Li+2 and n = 1
z Ans. (1)
2
1 r0
 r  r0  x=3 R=12cm
3 3
37. Energy released when two deuterons (1H2) fuse to 18cm
form a helium nucleus (2He4) is : O
(Given : Binding energy per nucleon of 1H2 = 1.1 MeV
Sol.

Sol.
and binding energy per nucleon of 2He4 = 7.0 MeV)
(1) 8.1 MeV
(3) 23.6 MeV
Ans. (3)
1 H  1H 2  1 He 4
2

1.1MeV 7.0MeV

EB = BEreactant – BEproduct
= 1.1 × 2 + 1.1 × 2 – 7 × 4 = –23.6 MeV
(2) 5.9 MeV
(4) 26.8 MeV
EN Using m 

m1 

O
6

18  6 2
f
u f
1

18cm
R=12cm

= Q = 23.6 MeV
LL
38. In the digital circuit shown in the figure, for the
given inputs the P and Q values are : 6 1 m2 1
m2    
1 18  6 4 m1 2
1 P
40. A sportsman runs around a circular track of radius
r such that he traverses the path ABAB. The
Q distance travelled and displacement, respectively,
are
A

(1) P = 1, Q = 1 (2) P = 0, Q = 0
A B
(3) P = 0, Q = 1 (4) P = 1, Q = 0 r
Ans. (2)
1 (1) 2r, 3r (2) 3r, r
1 0 0
0 (3) r, 3r (4) 3r, 2r
1 P
1 0 Ans. (4)
1 1
0 Sol. Displacement = 2r
Sol. 0
Q Distance = 2r + r = 3r
0 0
1 0

3

43. If 0 and 0 are the permeability and permittivity of
41. T1 free space, respectively, then the dimension of
T2
60° 30°  1 
  is :
 0 0 
mg
(1) L/T2 (2) L2/T2
A body of mass 1kg is suspended with the help of (3) T2/L (4) T2/L2
two strings making angles as shown in figure.
Ans. (2)
Magnitude of tensions T1 and T2, respectively, are
(in N) : 1 1
Sol. C   C2  L2 T 2
0 0 0 0
(1) 5, 5 3 (2) 5 3 , 5
44. Match List-I with List-II.
(3) 5 3 , 5 3 (4) 5, 5
List-I List-II
Ans. (2)
(A) Heat capacity of body (I) J kg–1
T1 T2
(B) Specific heat capacity of body (II) JK–1
60° 30°
(C) Latent heat (III) J kg–1 K–1

Sol.

42.
30°
mg

T1 = mgcos30°
T2 = mgsin30°
EN
A bi–convex lens has radius of curvature of both the
surfaces same as 1/6 cm. If this lens is required to be
(D)Thermal conductivity

(1) (A)–(III), (B)–(I), (C)–(II), (D)–(IV)

(2) (A)–(IV), (B)–(III), (C)–(II), (D)–(I)
(3) (A)–(III), (B)–(IV), (C)–(I), (D)–(II)
(4) (A)–(II), (B)–(III), (C)–(I), (D)–(IV)
(IV) Jm–1K–1s–1
Choose the correct answer from the options given
below :

Ans. (4)
LL
replaced by another convex lens having different
radii of curvatures on both sides (R1  R2), without Q
Sol. C'   JK 1
any change in lens power then possible combination T
of R1 and R2 is : Q
S  Jkg 1K 1
1 1 1 1 mT
(1) cm and cm (2) cm and cm
3 3 5 7 Q
L  Jkg 1
1 1 1 1 m
(3) cm and cm (4) cm and cm
3 7 6 9 KAT Q(L)
A

Q  K  Jm 1K 1s 1

Ans. (2) L AT
Sol. This will happen when 45. Consider a circular loop that is uniformly charged
1 1
 and has a radius a 2 . Find the position along the
f1 f 2
positive z–axis of the cartesian coordinate system
 1 1  2 where the electric field is maximum if the ring was
(  1)     (  1)  
 R1 R 2  R assumed to be placed in xy–plane at the origin :
1 1 2 a a
  (1) (2)
R1 R 2 R 2 2
(3) a (4) 0

4

Ans. (3) 48. A ray of light suffers minimum deviation when
KQr incident on a prism having angle of the prism equal
Sol. E
(x  R 2 )3/ 2
2
to 60°. The refractive index of the prism material is
dE
0 2 . The angle of incidence (in degrees) is _____.
dx
Ans. (45)
R 2a
x   a  A  m 
2 2 sin  
Sol.   2  , since A = 60°  m = 30°
SECTION-B
A
sin  
2
46. m = 2i – A [as i = e]
 i = 45°
49. The length of a light string is 1.4 m when the
10 N
tension on it is 5 N. If the tension increases to 7 N,
A wheel of radius 0.2 m rotates freely about its

wheel is ________ kg m2.

produces
EN
center when a string that is wrapped over its rim is
pulled by force of 10 N as shown in figure. The
established torque an

(Acceleration due to gravity = 10 m/s2)

Ans. (1)

angular
acceleration of 2 rad/s . Moment of inertia of the
Sol.
the length of the string is 1.56 m. The original
length of the string is _____ m.
Ans. (1)
T  K( 
 5  K(1.4 
 7  K(1.56 
5
0 )

7
)

0 )

 
1.4  1.56 
LL
0 0

R  0 = 1m

50. A satellite of mass 1000 kg is launched to revolve

F
Sol. around the earth in an orbit at a height of 270 km
FR = I from the earth's surface. Kinetic energy of the
FR 10  0.2 satellite in this orbit is ________ × 1010 J.
I  = 1 kg–m2
A

 2
(Mass of earth = 6 × 10 24 kg, Radius of earth =
47. The internal energy of air in 4 m × 4 m × 3 m sized
room at 1 atmospheric pressure will be ___ × 106 J. 6.4 × 10 6 m, Gravitational constant =
(Consider air as diatomic molecule) 6.67 × 10 –11 Nm 2 kg –2 )
Ans. (12)
Ans. (3)
Sol.
1 1 GM e GM e m GM e m
To find the internal energy of gas in the room. Sol. KE  mv 2  m  
2 2 r 2r 2(R E  h)
5RT
U  nCv T  n 6.67  1011  6  1024  6.4  106
2  = 3×1010 J
2(6.4  10  2.7  10 )
6 5
5 5
 PV   105  48  12  106 J
2 2

5
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(HELD ON WEDNESDAY 2nd APRIL 2025) TIME : 3:00 PM TO 6:00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A 52. The d-orbital electronic configuration of the
51. When a concentrated solution of sulphanilic acid complex among [Co(en)3]3+, [CoF6]3–,
and 1-naphthylamine is treated with nitrous acid
[Mn(H2O)6]2+ and [Zn(H2O)6]2+ that has the highest
(273 K) and acidified with acetic acid, the mass (g)
of 0.1 mole of product formed is : CFSE is :
(Given molar mass in g mol–1 H : 1, C : 12, N : 14, (1) t 62g e 0g (2) t 62g e g4
O : 16, S : 32)
(1) 343 (2) 330 (3) t 32g e 2g 4 2
(4) t 2g eg
(3) 33 (4) 66
Ans. (3) Ans. (1)
O Sol. In [Co(en)3]+3 S.F.L. is present and hence highest
Sol.  value of CFSE
NH2

N
NH3O–C–CH3
In rest all complexes WFL is present hence CFSE
+ CH3COOH will be low.
[Co(en)3]+3  Co+3 and en (SFL)
SO3H Co+3  [Ar]3d6
SO3H
(Sulphanilic acid)


O
NH3O–C–CH3
E O
N=N–O–C–CH3
3d6 t2g6 eg0

53. Given below are two statements :

LL
+ HNO2 + 2H2O Statement (I) : Neopentane forms only one
monosubstituted derivative.
SO3H SO3H
Statement (II) : Melting point of neopentane is
O
higher than n-pentane
N=N–O–C–CH3
In the light of the above statements, choose the
+ most appropriate answer from the options given
A

below :
SO3H NH2
(1) Statement I is correct but Statement II is
incorrect
(2) Both Statement I and Statement II are correct
HO3S N=N NH2 (3) Both Statement I and Statement II are
(Red-azo dye) incorrect

0.1 mole of red-azo dye (Molar Mass = 327 gm/mol) (4) Statement I is incorrect but Statement II is
will have 32.7 gm mass. Nearly 33 gm. correct
Ans. (2)

1

Sol. Both Statement-I and Statement-II are correct. 56. In 3, 3-dimethylhex-1-ene-4-yne, there are ____
CH3 CH3 sp3, ______ sp2 and ______ sp hybridised carbon
atoms respectively :
CH3–C–CH3 + X2 h CH3–C–CH2 – X
(1) 4, 2, 2 (2) 3, 3, 2
CH3 CH3 (3) 2, 4, 2 (4) 2, 2, 4
(X=Cl, Br)
Ans. (1)
melting point > 3 sp3
sp sp sp2
CH3
neo-pentane n-pentane
Sol. H3C–CC–C–CH=CH2
54. Which among the following molecules is (a) involved
CH sp2
in sp3d hybridization, (b) has different bond lengths sp3
sp 3

and (c) has lone pair of electrons on the central atom ? Sp3
(1) PF5 (2) XeF4 4-sp3, 2-sp2, 2-sp
(3) SF4 (4) XeF2 57. Which of the following statements are true ?
Ans. (3) (A) The subsidiary quantum number l describes the
F 3 shape of the orbital occupied by the electron.

N
F (a) Hybridisation = sp d
Sol. PF5 :- F P (b) All bonds are not identical y
F (c) No lone pair on central atom
F (B) x is the boundary surface
3 2
XeF4 :- sp d Hybridisation

SF4 :-
F
S
E
(a) Hybridisation = sp3d
F
(b) All bonds are not identical
F (c) 1 lone pair on central atom
diagram of the 2px orbital.
(C) The + and – signs in the wave function of the
F 2px orbital refer to charge.
LL
(a) Hybridisation = sp3d (D) The wave function of 2px orbital is zero
XeF2 :- F–Xe–F (b) All bonds are identical everywhere in the xy plane.
(c) 3 lone pair on central atom (1) (B) and (D) only
(2) (A), (B) and (C) only
(3) (C) and (D) only
55. Formation of Na4[Fe(CN)5NOS], a purple coloured
complex formed by addition of sodium (4) (A) and (B) only
nitroprusside in sodium carbonate extract of salt Ans. (4)
A

indicates the presence of : Sol. (A) Azimuthal quantum number () indicates the
(1) Sodium ion (2) Sulphate ion shape of orbital occupied by the electron
(3) Sulphide ion (4) Sulphite ion (B)
x px orbital
Ans. (3)
Sol. Na 2S  Na 2 [Fe(CN)5 NO]  Na 4 [Fe(CN)5 NOS]
Sodium Sodium nitro Violet Colour
(C) The + and – sign in the wave function of 2px
sulphide Prusside orbital refer to the sign (Phase) of the wave
function , not the charge
(D) The wave function of 2px orbital will be zero
in yz plane (Nodal plane).

2

58. The type of hybridization and the magnetic (i)H /H O
Sol. (A) R  C  N  2
R  CONH2
mild condition
property of [MnCl6]3– are :
(1) d2sp3, paramagnetic with four unpaired electrons Under mild condition amide is formed because this
(2) sp3d2, paramagnetic with four unpaired electrons reaction is typically slow if further more heat will

(3) d2sp3, paramagnetic with two unpaired electrons supplied then it gets convert in to –COOH.

(4) sp3d2, paramagnetic with two unpaired electrons (B) R  MgX 
2 (i)CO
  R – COOH
(ii)H3O
Ans. (2)
(i)SnCl /HCl
Sol. [MnCl6]3– contains Mn+3 (C) R  C  N 
2
  R – CHO
(ii)H3O
Mn+3 :- [Ar]3d4
PCC
Ligand  Cl– (WFL) (D) R.CH2 .OH   R – CHO

COCl H2/Pd-BaSO4 CHO

3d4 (E)

N
Br2/H2O
Hybridisation = sp3d2 COOH
(Mild oxidizing agent)
4 unpaired electrons
60. Electronic configuration of four elements A, B, C

59. Consider the following reactions. From these and D are given below :
E
reactions which reaction will give carboxylic acid
as a major product ?
(A) 1s22s22p3
(C) 1s22s22p5
(B) 1s22s22p4
(D) 1s22s22p2
(i)H /H O
(A) R  C  N  2 Which of the following is the correct order of
LL
mild condition
increasing electronegativity (Pauling's scale) ?
(i)CO
(B) R  MgX 
2

(ii) H3O (1) A < D < B < C
(i)SnCl /HCl (2) A < C < B < D
(C) R  C  N 
2
 (ii) H3O
(3) A < B < C < D
PCC
(D) R.CH2 .OH  
(4) D < A < B < C
A

(i)H |Pd  BaSO Ans. (4)

(E) COCl 
2 4
(ii) Br2 water
Sol. N :- 1s2 2s2 2p3 (Electronegativity = 3)
Choose the correct answer from the options given O :- 1s2 2s2 2p4 (Electronegativity = 3.5)
below :
F :- 1s2 2s2 2p5 (Electronegativity = 4)
(1) A and D only
C :- 1s2 2s2 2p2 (Electronegativity = 2.55)
(2) A, B and E only
Correct order = C > B > A > D
(3) B, C and E only
(4) B and E only
Ans. (4)

3

61. Match List-I with List-II
List-I List-II M M
(1) (2)
(Purification (Mixture of organic
technique) compounds) 5 10 15 5 10 15
t/°C  t/°C 
(A) Distillation (I) Diesel + Petrol
(simple)
M M
(B) Fractional (II) Aniline + Water (3) (4)
distillation
5 10 15 5 10 15
(C) Distillation (III) Chloroform + t/°C  t/°C 
under reduced Aniline Ans. (2)
pressure
Sol. Water 
Volume
 Water 
Volume increases
 Water
(D) Steam (IV) Glycerol + 1C decreases thermal exp ansion
4C 25C

distillation Spent-lye n solute

Molarity =
(Volume of solution)
Choose the correct answer from the options given

N
below : Hence
(1) (A)-(II), (B)-(III), (C)-(IV), (D)-(I) 1°C 
molarity
increases
 4°C 
molarity
decreases
 25°C
(2) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
(3) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
63. Arrange the following in order of magnitude of

Ans. (4)
Sol.
E
(4) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) work done by the system / on the system at
constant temperature :
(a) |wreversible| for expansion in infinite stage.
LL
List-I List-II (b) |wirreversible| for expansion in single stage.
(Purification technique) (Mixture of organic (c) |wreversible| for compression in infinite stage.
compounds)
(d) |wirreversible| for compression in single stage.
(A) Distillation (simple) (III) Chloroform + Aniline Choose the correct answer from the options given
below :
(B) Fractional (I) Diesel + Petrol
distillation (1) a > b > c > d
(2) d > c = a > b
(C) Distillation under (IV) Glycerol + Spent-lye
A

reduced pressure (3) c = a > d > b

(D) Steam distillation (II) Aniline + Water (4) a > c > b > d
Ans. (2)
Sol. For isothermal process
62. 'x' g of NaCl is added to water in a beaker with a |Wreversible|expansion = |Wreversible|compression
lid. The temperature of the system is raised from Vf
1°C to 25°C. Which out of the following plots, is = – nRT ln
Vi
best suited for the change in the molarity (M) of
|Wirreversible|expansion < |Wirreversible|compression
the solution with respect to temperature ?
d>c=a>b
[Consider the solubility of NaCl remains
|Wirreversible|expansion = – Pext (Vf – Vi)
unchanged over the temperature range]

4

Pext Which of the following represents the above
reaction mechanism ?
P1

Energy 

Energy 
(1) (2)
P2 rev (P  Pext) A


V D A
D
V1 V Reaction coordinate Reaction coordinate
(Reversible expansion)
Pext

Energy 

Energy 
(3) (4)
P1


A D
D A
Reaction coordinate  Reaction coordinate
P2
V Ans. (1)
V1 V2 Ea 1
Ea 2
(Single step irreversible)

N
Ea 3

Energy B
Sol. A C
D
reaction coordinate
E AB
H = +ve Ea1  High
Slow

BC Fast
LL
H = –ve Ea 2  Low
CD
H = –ve Ea3  Low

65. The nature of oxide (TeO2) and hydride (TeH2)

formed by Te, respectively are :
A

(1) Oxidising and acidic

(2) Reducing and basic
Graphical representation (3) Reducing and acidic
We can compare work by area of PV graph. (4) Oxidising and basic
Ans. (1)
64. Reactant A converts to product D through the Sol. TeO2 is oxidizing in nature because it can be
given mechanism (with the net evolution of heat) : reduced from +4 oxidation state to lower oxidation
A  B slow ; H = +ve state.
TeH2 due to less bond dissociation energy easily
B  C fast ; H = –ve breaks and hence acidic in nature.
C  D fast ; H = –ve

5

66. Match List-I with List-II 67. Consider the following chemical equilibrium of the
List-I List-II gas phase reaction at a constant temperature :
A(g) B(g) + C(g)
(Reaction) (Name of
reaction) If p being the total pressure, Kp is the pressure
equilibrium constant and  is the degree of
(A) 2 X+2Na
Dry
Ether
 (I) Lucas dissociation, then which of the following is true at
+2Na reaction equilibrium ?
(1) If p value is extremely high compared to
(B) ArN2 X 
Cu
HCl
ArCl  N2  CuX (II) Finkelstein Kp,   1
reaction (2) When p increases  decreases
(C) C2H5Br  NaI 
Dry
Acetone
C2H5 I  NaBr (III) Fittig (3) If kp value is extremely high compared to p, 
reaction becomes much less than unity
(4) When p increases  increases
(D) CH3C(OH)(CH3 )CH3 
HCl
 (IV) Gatterman
ZnCl2 Ans. (2)
CH3C(Cl)(CH3 )CH3 reaction
Sol. A(g) B(g) + C(g)
Choose the correct answer from the options given t=0 a 0 0
below : t = t a (1 – ) a a

N
(1) (A)-(III), (B)-(II), (C)-(IV), (D)-(I) a moles of A(g) taken initially and at time
Now moles fraction of A(g), B(g) and C(g) are
(2) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
a  a 1  
XA  
(3) (A)-(IV), (B)-(III), (C)-(I), (D)-(II) a  a 1  

Ans. (2)
E
(4) (A)-(IV), (B)-(I), (C)-(II), (D)-(III) XB 

XC 
a


a  a 1  
a


Sol. a  a 1  
LL
List-I List-II Now if P is total pressure then partial pressure of
A(g), B(g) and C(g) are
(Reaction) (Name of
 1  
reaction) PA   P
1  
(A) (III) Fittig   
2 X+2Na
Dry
 PB   P
1  
Ether
reaction

  
PC  
A

(B) ArN X 

Cu
ArCl  N2  CuX (IV) Gatterman P
2 HCl
reaction
1  
     
 P  P
 1    1  
(C) C H Br  NaI 
Dry
C2H5 I  NaBr (II) Finkelstein KP 
2 5 Acetone  1  
reaction  P
 1  
(D) CH3C(OH)(CH3 )CH3 
HCl
 (I) Lucas 2 P
ZnCl2
reaction
KP 
CH3C(Cl)(CH3 )CH3 1  2
As KP is only function of temperature.
So as P  

6

68. Which of the following graphs correctly represents 69. A tetrapeptide "x" on complete hydrolysis
the variation of thermodynamic properties of produced glycine (Gly), alanine (Ala), valine (Val),
Haber's process ?
leucine (Leu) in equimolar proportion each. The
300
200 H R / T number of tetrapeptides (sequences) possible
100 G R / T involving each of these amino acids is
(1) 0  T/K
H R (1) 16 (2) 32
–100 
S
–200 R (3) 8 (4) 24
Ans. (24)
200 H R
100 Sol. The number of tetrapeptides (sequences)
G R / T
0 T/K possible involving each of these amino acids
(2) HR / T
–100 (glycine, alanine, valine, leucine) ; It has three (3)
SR / T
–200
peptides linkage the number of permutations in
200 SR which they can be arranged
100 H R =4×3×2×1

N
0 /
 T T/K
G R
(3) –100 = 24
–200 70. In Dumas' method for estimation of nitrogen,
H R / T
–300 E 0.5 gram of an organic compound gave 60 mL of
300 G R / T nitrogen collected at 300 K temperature and
200
100 715 mm Hg pressure. The percentage composition
H R / T
(4) 0 T/K of nitrogen in the compound (Aqueous tension at
H R
–100 300 K = 15 mm Hg) is
LL
SR
–200
(1) 1.257 (2) 20.87
Ans. (1) (3) 18.67 (4) 12.57
Sol. N2(g) + 3H2(g)  2NH3
Ans. (4)
H° = –ve
Sol. Pressure of N2 gas = (715 – 15)
S° = –ve
(As gaseous moles decreases). = 700 mmHg
A

HoR PV
(1) As temperature increases , decreases n N2 
T RT
(2) G° = –RT ln Keq 700  60 103
n N2 
G o 760  0.0821 300
R ln Keq = –
T = 2.24 × 10–3 mol
(on increasing temperature in exothermic reaction
Mass of N2 = 2.24 × 10–3 × 28g
Keq decreases)
= 0.06272 g
H° and S° are almost constant with temperature.
0.06272
%N2 =  100 12.57
0.5

7

SECTION-B 72. 0.2 % (w/v) solution of NaOH is measured to have
71. For the reaction A  B the following graph was resistivity 870.0 m m. The molar conductivity of
obtained. The time required (in seconds) for the the solution will be _______×102 mS dm2 mol–1.
concentration of A to reduce to 2.5 g L–1 (if the (Nearest integer)
–1
initial concentration of A was 50 g L ) is _______. Ans. (23)
(Nearest integer) Sol. Given : Concentration of NaOH = 0.2% (w/v)
Given : log 2 = 0.3010  0.2 g of NaOH in 100 ml of solution.
Molarity of NaOH solution
50 moles of solute
= × 1000
Concentration of A/(gL–1)

Vml
40 0.2 / 40 0.2 2
  1000 =  1000  M
100 40 100 40
30
Given resistivity of solution = 870 m ohm m
20
= 870 × 10–3 ohm m

N
10 = 870 × 10–3 × 10 ohm dm
= 870 × 10–2 ohm dm
0
5 10 15 20 25 = 8.7 ohm dm
time/s Now conductivity

Allen Ans. (BONUS)

NTA Ans. (43)
E K
1

1
 8.7
ohm–1 dm–1

Now molar conductivity of solution is

1
LL
Sol. As it is difficult to predict order using data K 8.7 40
provided in graph. m    = 2.29 S dm2 mol–1
M 2 2  8.7
For specific time interval 0 - 5 sec, 5 – 10 sec and 40
10 – 15 sec. order comes to be zero, but graph is 2.29 × 103 m S dm2 mol–1
not a straight line.
= 22.9 × 102 m S dm2 mol–1
Assuming 1st order kinetics
= 23 × 102 m S dm2 mol–1
1 A
K  ln 0
A

t At
Br alcoholic
1 40 P Br2
K  ln KOH
Major Q
10 20 73.
Product
Time required to reduce to 2.5 g/L
1 50 Consider the above sequence of reactions. 151 g of
K  ln
t 2.5
2-bromopentane is made to react. Yield of major
1 1
ln 2  ln 20 product P is 80% whereas Q is 100%.
10 t
Mass of product Q obtained is ________g.
1.3010  10
t = 43.3 sec.
0.3010 (Given molar mass in g mol–1 H: 1, C : 12, O : 16,
Br : 80)

8

Ans. (184) 1000
y
Br 45
alc.KOH y = 22.22
Sol. 1-mole 80% Now let a and b be atomic masses of A and B
2-Bromopentane 0.8 mole P
respectively, then
(Major product)
Br A + b = 12.34 …. (i)
Br2
A + 2b = 22.22 …. (ii)
Br
100% B = 22.22 – 12.34 = 9.88
0.8 (mole) Now a = 12.34 – 9.88 = 2.46
(Q)
= 24.6 × 10–1 = 25 × 10–1
Molecular mass of Q = 230g mol–1
Mass of Q = 0.8 × 230
75. The spin-only magnetic moment value of Mn+- ion
= 184 g
formed among Ni, Zn Mn and Cu that has the least

N
74. When 1 g each of compounds AB and AB2 are
dissolved in 15 g of water separately, they enthalpy of atomisation is_____. (in nearest
increased the boiling point of water by 2.7 K and integer)
1.5 K respectively. The atomic mass of A (in amu) Here n is equal to the number of diamagnetic
E
is_______×10–1(Nearest integer)
(Given : Molal boiling point elevation constant is
0.5 K kg mol–1)
complexes among K2 [NiCl4], [Zn (H2O)6] Cl2,
K3[Mn(CN)6] and [Cu(PPh3)3I]
Ans. (0)
Ans. (25)
LL
Sol. For AB Sol. K2[NiCl4]  sp3 , Paramagnetic
Tb = 2.7 K [Zn(H2O)6]Cl2  sp3d2, Diamagnetic
   ×  × m K3[Mn(CN)6]  d2sp3, Paramagnetic
27
m [Cu(PPh3)3I]  sp3, Diamagnetic
5
Let molar mass of AB = x. Hence the value of n is 2
A

1/ x 27 Least value of enthalpy of atomisation among Ni,

So 1000 
15 5 Zn, Mn and Cu is of Zn
x = 12.34 Zn+2 :- [Ar]3d10
For AB2 µ= 0
Tb = 1.5 K
1.5 = 1 × 0.5 × m
m=3
Let molar mass of AB2 = y
1/ y
So × 1000 = 3
15

9
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