Module 3 Notes
Module 3 Notes
• Silicon wafers are thin, round disks used as the foundation for making electronic
chips.
• The size of these wafers can vary from 75 mm to 300 mm in diameter, and they are
extremely thin (less than 1 mm thick).
• Wafers come from ingots (large cylindrical blocks of silicon).
• These ingots are made using the Czochralski process, where pure silicon is melted
and then slowly solidified into a single crystal.
• The ingots are then sliced into thin wafers.
• The Czochralski (CZ) method is the most widely used process for making pure
silicon crystals.
• It ensures that the silicon forms a single, continuous crystal structure, which is
essential for high-performance electronic devices.
• The crucible (container that holds the molten silicon) is made of quartz.
• Quartz is used because it can withstand high temperatures without contaminating
the silicon.
• A seed crystal (a small, pure silicon piece) is dipped into the molten silicon.
• The seed is slowly pulled up while rotating, which helps in forming a uniform and
defect-free crystal.
• After the silicon ingot is fully formed, it is shaped using grinding machines.
• This ensures that the ingot has a uniform diameter before slicing.
• The ingot is cut into thin wafers using a special saw.
• The wafers are then polished until they have a smooth, mirror-like surface.
• This smoothness is necessary for making precise electronic circuits.
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Oxidation:
• The silicon oxidation process involves exposing silicon wafers to oxygen or water
vapor at high temperatures to form a silicon dioxide (SiO₂) layer.
• There are two primary methods for oxidizing silicon:
• Wet oxidation:
• Wet oxidation involves using water vapor (H₂O) as the oxidizing agent.
• This process operates at high temperatures.
• Wet oxidation grows the oxide layer faster than dry oxidation.
• Dry oxidation:
• Dry oxidation uses O₂ gas without water vapor.
• This method requires higher temperatures than wet oxidation to form an oxide layer at
a reasonable rate.
• When silicon is oxidized, a part of the silicon reacts with oxygen to form SiO₂,
reducing the thickness of the silicon substrate.
• Silicon dioxide takes up more space than the original silicon, causing the oxide layer
to extend above the silicon surface while also penetrating into the silicon.
• The field oxide extends both upwards and into the silicon, demonstrating the
volumetric expansion of SiO₂.
• The gate oxide is thinner than the field oxide, showing its role in MOS transistor
functionality.
• The source and drain regions are separated by the field oxide and controlled by the
poly gate.
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Selective Diffusion:
Selective diffusion is used in semiconductor fabrication to create different types of silicon with
precise placement of dopant atoms. This process involves the use of SiO₂ as a barrier to control
where dopants enter the silicon wafer.
o The silicon now has precisely doped regions, forming the basis for transistors and
other semiconductor devices.
Recent advancements consider electron beam lithography (EBL) as a more precise alternative:
Despite its advantages, EBL is not widely used in commercial semiconductor production due to:
2. Gate Oxidation
• A thin oxide layer (~200–400 Å thick) is grown in the areas where the gate of the
transistor will be placed.
• This oxide layer forms the gate dielectric (insulator) that separates the transistor's
gate from the silicon substrate.
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• The thin oxide layer acts as a mask, ensuring that doping only occurs where needed.
• N-type dopants (such as phosphorus or arsenic) are introduced into the silicon
substrate in the exposed regions (areas not covered by polysilicon).
• This forms the source and drain regions of the nMOS transistor.
• The doping depth is about 1 μm.
• Openings are made in the SiO₂ layer to allow metallic contacts to connect the
transistor terminals (source, drain, and gate).
• This is done using another photolithography and etching step.
CMOS Technologies
The p-Well Process:
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• A thick layer of silicon dioxide (SiO₂) is grown over the wafer using thermal
oxidation.
• This oxide layer acts as an insulator, preventing unwanted electrical connections.
• Etching is performed to remove SiO₂ from areas where transistors will be placed.
• A very thin layer (~500 Å) of SiO₂ (thin oxide) is grown in transistor regions.
• This thin oxide layer serves as the gate oxide for transistors.
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• Openings (contact cuts) are made in the oxide layer where metal connections will be
placed.
• A protective passivation layer (SiO₂ or Si₃N₄) is added to protect the circuit from
contaminants.
• Openings are made for bonding pads to connect the chip to external circuits.
This process enables the creation of CMOS circuits, combining NMOS and PMOS
transistors for efficient digital logic operations.