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Assignment of CH Solutions

The document contains a series of chemistry assignments related to solutions for Class 12 students. It includes questions on freezing point depression, boiling point elevation, colligative properties, and gas solubility, among others. Each question requires calculations or explanations based on principles of chemistry, particularly focusing on solutions and their properties.

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harshyudi
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16 views3 pages

Assignment of CH Solutions

The document contains a series of chemistry assignments related to solutions for Class 12 students. It includes questions on freezing point depression, boiling point elevation, colligative properties, and gas solubility, among others. Each question requires calculations or explanations based on principles of chemistry, particularly focusing on solutions and their properties.

Uploaded by

harshyudi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Assignment for chapter Solutions

Chemistry. CLASS 12

Q1 10% solution (by mass) of sucrose in water has a freezing point of


269.15 K. Calculate the freezing point of 10% glucose in water if the
freezing point of pure water is 273.15K.
[Given: (Molar mass of sucrose = 342 g mol -1), (Molar mass of glucose =
180 g mol-1)]

Q2 Gas (A) is more soluble in water than Gas (B) at the same temperature.
Which one of the two gases will have the higher value of KH (Henry’s
constant) and why?
(ii) In non-ideal solution, what type of deviation shows the formation of
maximum boiling azeotropes?

Q3 Calculate the boiling point of solution when 4 g of MgSO 4 (M =120 g


mol-1) was dissolved in 100 g of water, assuming MgSO 4 undergoes
complete ionization.
(Kb for water = 0.52 K kg mol-1) [3]
Q4 What is meant by positive deviations from Raoult’s law? Give an
example. What is the sign of ∆mixH for positive deviation?

Q5
Define azeotropes. What type of azeotrope is for-med by positive
deviation from Raoult’s law? Give an example.

Q6 3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression


in freezing point of 1.62 K. Calculate the Van’t Hoff factor and predict the
nature of solute (associated or dissociated). (Given: Molar mass of benzoic
acid = 122 g mol-1, Kf for benzene = 4.9 K kg mol-1)

Q7 At the same temperature, carbon dioxide gas is more soluble in water


than O2 gas. Which one of them will have higher value of KH and why ?

Q8 How does the size of blood cells change when placed in an aqueous
solution containing more than 0.9% (mass by volume) sodium chloride

Q9 One molal aqueous solution of an electrolyte a A2 B3 is 60% ionised


calculate the boiling point of the solution given Kb for water is equal to
0.52 Kkg per mol

Q10 The vapour pressure of A and B add 25 degree Celsius are 75 mm Hg


and 25 mm Hg respectively. If A &B are mixed such that the mole fraction
of A in a mixture is 0.4, then calculate the mole fraction of B in vapour
phase.
Q11 Define colligative property. Which colligative properties preferred for
the molar mass determination of macromolecules

Q12 Why are equimolar solution of NaCl and glucose not isotonic ?

Q13 Calculate the mass of compound (molar mass = 256 g mol -1) to be
dissolved in 75 g of benzene to lower its freezing point by 0.48 K (K f =
5.12 K kg mol-1).

Q14 Henry law constant for Co 2 water is 1.67 x 10 8. Pa. At 298


K .calculate number of moles of CO2 in 500ml of soda water when Packed
under 2.5 atm C02 pressure at 298K.

Q15 Heptane and octane form ideal solution. At 373 K, the vapour
pressure of 2 liquid components are 105.2 kPa and 46.8 kPa respectively.
What will be the vapour pressure of mixture of 26g of heptane and 35 gof
octane ?

Q16 Which of the following unit is useful in relating concentration


of solution with its vapour pressure?
(a) Mole fraction (b) Parts per million
(c) Mass percentage (d) Molality

Q17 Colligative properties depend on


(a) the nature of the solute particles dissolved in solution
(b) the number of solute particles in solution
(c) the physical properties of the solute particles dissolved in
solution
(d) the nature of solvent particle

Q18 Which of the following aqueous solution should have the


highest boiling point?
(a) l.OMNaOH (b) 1.0MNa2SO4
(c) 1.0MNH4NO3 (d) l.OMKNO3

Q19 The value of van’t Hoff factor.s for KCl, NaCl and K2SO4,
respectively, are
(a) 2, 2 and 2 (b) 2, 2 and 3 (c) 1, 1, and 2 (d) 1, 1 and 1

Q20 Value of Henry’s constant KH


(a) increases with increase in temperature
(b) decreases with increase in temperature
(c) remains constant
(d) first increases then decreases
Q21 The value of Henry’s constant KH is
(a) greater for gases with higher solubility
(b) greater for gases with lower solubility
(c) constant for all gases
(d) not related to the solubility of gases

Q22 Match the laws given in Column I with expressions given in


Column II.

Q23 At 300 K 36 gram of glucose C6 H 12 O6 present per litre in its


solution has an osmotic pressure of 4.98 bar if osmotic pressure of
another glucose solution is 1.52 bar at the same temperature calculate
the concentration of other solution

Q24 Calculate the molarity of 3.3 molal solution of KCl whose density is
1.28 g per mL

Q25 Boiling point of water at 750 mm Hg pressure is 99.68 oC. How much
sucrose (molar mass =342) is to be added to 500g of water such that it
boils at 100o C (Kb for water is 0.52 KKg/mol

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