ASSIGNMENT SHEET OF

CHEMISTRY CLASS-11TH
1.An element forms two oxides. In one oxide, one
gram of the oxide contains 0.5g of the element. Ion
another oxide, 4g of oxide contains 0.8g of the
element. Show that these data con irms tye law of
multiple proportion.
2.An oxide of copper contains 11.2% O, a chloride of
copper contains 35.86% Cl, and an oxide of chlorine
contains 18.64% O, show that these data illustrate
the law of reciprocal proportion.
3.Calculate the number of moles and molecules in 1.7
g of NH3 .
4.Calculate the number of moles and molecules
present in 64g of O2.
5.Calculate the mass of NaOH required to prepare 50
ml of N/10 NaOH solution.
6.Calculate the normality of the solution containing 5
g NaOH dissolve in 250 ml aqueous solution.
7.Calculate the molarity of NaOH solution prepared by
dissolving its 4 g in enough water to prepare 250ml
of the solution.
8.49 g of H2SO4 are present in 100ml aqueous
solution. What is the molarity of H2SO4?
9.A solution contains 25% water, 25% ethanol and
50% acetic acid by mass. Calculate the mole fraction
of each component.
10.An aqueous solution of ethanol in water is 1.54
Molal. Calculate the mass of ethanol into 250 g of
solvent.
11.The mass percentage of an organic compound is
57.8% carbon, 3.6% hydrogen and rest is oxygen.
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 The vapour density of the compound is 83. What is
its molecular formula?
12.Mass percentage in an inorganic compound is
29.11% sodium, 40.51%, sulphur and 30.28%
oxygen. What is its empirical formula?
13.Why uncertainty principle is not applicable to
macroscopic particles?
14.What is photoelectric effect?
15.How canaI rays are produced?
16.What do you mean by electromagnetic waves?
17.What are isoelectronic species?
18.Derive the de-Broglie equation.
19.State and explain Pauli exclusion Principle?
20.What is black body radiation?
21.Describe Ford α-rays scattering experiment .
Interference was drawn from this experiment.
22.Discuss the discovery of electron proton and
neutron .
23.Describe the shapes of atomic orbitals .
24.Write four properties of the nucleus .
25.Why it is better to classify the elements on the
basis of their atomic number rather than atomic
mass?
26.What is the cause of periodicity in properties of
elements?
27.Electron gain enthalpy of all the elements is
positive, why?
28.What was the need for the classi ication of
elements?
29.How do atomic radius, electron gain enthalpy,
ionisation enthalpy, electronegativity change in a
group and in a period with the increase in atomic
number?
30.Second ionisation enthalpy is always greater than
the irst why ?
31.Describe all the types of atomic radius .
32.What is screening effect?
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 33.Why the ionisation enthalpy of nitrogen is greater
than oxygen?
34.State valence bond theory.
35.State VSEPR theory .
36.What is hybridisation?
37.What is resonance?
38.Draw the energy level diagram for H2, N2, F2.
39.What is the bond order of H2, N2, O2, O2+, F2- ?
40.What is Swick and Sudgen’s rule?
41. De ine intensive and extensive properties.
42.Describe open, closed and isolated system with
examples .
43.Two moles of an ideal gas at 2atm and 300 K are
compressed isothermally to half of its volume by an
external pressure of 4 atm. Calculate the work done
in the process.
44.0.25g of a sample of common salt contained
0.158g of chlorine while another sample of
contaimned 0.1379g of chlorine. Show that these
result are in agreement of with the law of constant
proportion.
45.Calculate the inal pressure and temperature of an
ideal diatomic gas that undergoes a reversible
adiabatic compression from 25 L to 1 L at 1 atm and
298 Ke .
46.Derive the relationship between CP and CV for an
ideal gas
47.Calculate the amount of work done by two mole of
an ideal gas at 25°C in an isothermal reversible
expansion from 10 L to 20 L .
48.An ideal gas is allowed to expand isothermally and
reversibly from volume V dm3 to 2V dm3 at 300 K.
Work done by the gas is 4.754 kJ. Calculate the moles
of the ideal gas.
49.Calculate the maximum work done for isothermal
and reversible compression of ive mole of an ideal
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 gas from a pressure of 2 atm to 10 atmosphere at
298K.
50.What is Hess law of constant summation ?
51.What are the limitations of irst law of
thermodynamics?
52.Calculate the entropy change involved in the
conversion of one mole of solid ice at 2:73 K to liquid
water. Latent heat of fusion is 6025 joule/mole.
53.What is randomness?
54.Derive the relation between free energy change
and non-mechanical work.
55.What is buffer solution?
56.What is common eye effect?
57.Derive pH + pOH =14.
58.What is Le-Chatelier’s principle?
59.Where are the relation between KP and KC?
60.What are reversible and irreversible reactions?
61.De ine reaction quotient .
62.Derive the relation between Gibbs energy change,
and equilibrium constant .
63.What is Arrhenius concept of acid and bases?
64.What is Bronsted-Lowry concept of acids and
bases?
65.What is electronic concept of acids and bases?
66.Explain the electronic displacement effects.
67.What is resonance effect?
68.What is hyper conjugation effect?
69.What are electrophiles and nucleophiles?
70.Write SN1 and SN2 mechanism for the reaction of
chloro methane and hydroxide ion.
71.What is wurtz reaction?
72.What is the ozonolysis product of ethene?
73.What is the difference between enantiomer and
diasteromer?
74.What is rearrangement reaction?
75.What is Markovnikov’s rule?
76.Why only HBR is used in peroxide effect?
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 77.What happens when benzene react with excess of
chlorine?
78.What is Friedel craft alkylation and acylation?
79.What is ittig reaction?
80.What is the addition product of benzene and
hydrogen?
81.What is wurtz- ittig reaction?
82.What is the ozonolysis product of benzene?
83.Balance the following reactions by ion-electron
method:-

84.Write the IUPAC names of the following