07-10-2024

4602CJA105021240011 JM

PART-1 : PHYSICS

SECTION-I

1) One quarter sector is cut from a uniform circular disc of radius R. This sector has mass M. It is
made to rotate about a line perpendicular to its plane and passing through the center of the original

disc. Its moment of inertia about the axis of rotation is

(A)
MR2

(B)
MR2

(C)
MR2
(D) MR2

2) From a solid sphere of mass M and radius R a cube of maximum possible volume is cut. Moment
of inertia of cube about an axis passing through its centre and perpendicular to one of its faces is:-

(A)

(B)

(C)

(D)

3) A small object of uniform density rolls up a curved surface with an initial velocity v. It reaches up

to a maximum height of with respect to the initial position. The object is :-

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 (A) ring
(B) solid sphere
(C) hollow sphere
(D) disc

4) A particle performing uniform circular motion has angular momentum L. If its angular velocity is
doubled and its kinetic energy halved, then the new angular momentum is-

(A)

(B) 2L
(C) 4L

(D)

5) A small solid sphere A of mass m and radius r rolls without slipping inside a large fixed
hemispherical bowl of radius R (R >> r) as shown in figure. If the sphere starts from rest at the top
point of the hemisphere find the normal force exerted by the small sphere on the hemisphere when it

is at the point B of the hemisphere.

(A)

(B)

(C)

(D)

6) A disc of radius R is rolling purely on a flat horizontal surface, with a constant angular velocity.

The angle between the velocity and acceleration vectors of point P is

(A) zero
(B) 45°

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 (C) 135°
(D) tan–1(1/2)

7) A mass ‘m’ is supported by a massless string wound around a uniform hollow cylinder of mass m
and radius R. If the string does not slip on the cylinder, with what acceleration will the mass fall on

release?

(A)

(B) g

(C)

(D)

8) Determine the acceleration a of the supporting surface required to keep the centre G of the
circular pipe in a fixed position during the motion. No slipping takes place between pipe and its

support.

(A) g sin θ
(B) 2g sin θ
(C) g/2sin θ
(D) g sin θ

9) A uniform solid sphere rolls up (without slipping) the rough fixed inclined plane, and then back
down. Which is the correct graph of acceleration 'a' of centre of mass of solid sphere as function of
time t (for the duration sphere is on the incline) ? Assume that the sphere rolling up has a positive

velocity.

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 (A)

(B)

(C)

(D)

10) A small ball of mass m is placed on a super ball of mass M and the two balls are dropped from
height H (H is very large compared to radius of balls). How high (in m) does small ball rise after
collision? All collisions are head on elastic and (m << M). (H = 1m and g = 10 m/s2)

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 (A) 3
(B) 9
(C) 11
(D) 15

11) A wedge of mass M = 4m lies on a frictionless plane. A particle of mass m approaches the wedge
with speed v. There is no friction between the particle and the plane or between the particle and the
wedge. The maximum height climbed by the particle on the wedge is given by :-

(A)

(B)

(C)

(D)

12) Two blocks of mass 3 kg and 6 kg respectively are placed on a smooth horizontal surface. They
are connected by a light spring of force constant k = 200 N/m. Initially the spring is unstretched.
The indicated velocities are imparted to the blocks. Find the maximum extension of the spring.

(A) 30 cm
(B) 10 cm
(C)
(D) 15 cm

13) A particle moves in a circle of radius 4cm clockwise at constant speed 2 cm/sec. If and are
unit acceleration vectors along x and y-axes respectively (in cm/sec2), the acceleration of the particle

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 at the instant halfway between P and Q is given by:

(A)
(B)

(C)

(D)

14) Two particles A, B are moving on two concentric circles of radii R1 and R2 with equal angular
speed ω. At t = 0, their positions and direction of motion are shown in the figure :

The relative velocity at is given by :

(A)
(B)
(C)
(D)

15) A particle of mass m starts undergoing a circular motion of radius R. The speed of particle is
increasing as V = Kt (K is a constant), (t is time in seconds). The magnitude of net acceleration at t =
1 second is

(A) K

(B)

(C)

(D)

16) A large slab of mass 5 kg lies on a smooth horizontal surface, with a block of mass 4 kg lying on
the top of it. The coefficient of friction between the block and the slab is 0.25. If the block is pulled
horizontally by a force of F = 6 N, then the work done by the force of friction on the slab, between
the instants t = 2s to t = 3s is (g = 10 ms–2) (at t = 0 system is at rest)

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 (A) 2.4 J
(B) 5.55 J
(C) 4.44J
(D) 10 J

17) A force where K is a positive constant, acts on a particle moving in the x-y plane.
Starting from the origin, the particle is taken along the positive x-axis to the point (a, 0) and then
parallel to the y-axis to the point (a, a). The total work done by the force on the particle is :

(A) –2Ka2
(B) 2Ka2
(C) –Ka2
(D) Ka2

18) Block A of mass m is placed over a wedge B of same mass m. Assuming all surfaces to be
smooth. The displacement of block A in 1 s if the system is released from rest is

(A)

(B)

(C)

(D)

19) In the cube of side 'a' shown in the figure, the vector from the central point of the face ABOD to

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 the central point of the face BEFO will be:

(A)

(B)

(C)

(D)

20) In the figure shown if friction coefficient of block 1kg and 2kg with inclined plane is µ1=0.5 and

µ2 = 0.4 respectively, then

(A) both block will move together.

(B) both block will move separately.
(C) there is a non zero contact force between two blocks.
(D) none of these

SECTION-II

1) Find

2) The uniform solid block in figure has mass 3.0 kg and edge lengths a = 1m, b = 2m and c = 10cm.
Calculate its moment of inertia about an axis through one corner and perpendicular to the large

faces (in kg m2).

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 3) A disc of radius 12 cm is free to rotate about point O, a rope is wound which is pulled with a force
F = 10 N as shown in the figure. At point C, a light rod AC is attached to the disc, which rests on the
fixed support at the point B. If force F0 = 100k N is required to apply to the left end of the rod so
that whole system remains in balance, find the value of k. Given BC = 30 cm, AB = 15 cm OC = 4

cm.

4) A particle of mass m (2kg) is attached to a rod of mass M(5kg) and length (3m) which is free to
rotate in vertical plane about axis as shown in the figure. Find angular acceleration (in rad/s2) of
system just after the system is released from rest from the shown position.

5) A particle of mass 1 kg is moving along the line

y = x + 2 (here x and y are in metres) with speed 2 m/s.
The magnitude of angular momentum of particle about origin is (in kg-m2/s) (use )

6) A ball is dropped on an inclined plane, its strikes the plane elastically. After each collision it's

range is R1, R2 and R3 respectively. If , find a.

7) A particle of mass m Released from top of wedge. Mass of wedge is 4m. All the surface assumed
to be frictionless and radius of circle R = 16 meter then find speed (in m/s) of particle when it reach

at lowest point.

8) Two ball A and B are projected from top of towers located D distance apart as shown in figure. If

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 particles collide in mid air then value of D (in meter) is :

9) A boat moves relative to still water with a velocity which is n times greater than the river flow
velocity. Boat moves at an angle 120° to the stream direction to minimize drifting. Find the value of
n.

10) A passenger on a ship travelling due east with a speed of 18 km/hr observes that the smoke from
the ship makes an angle of 30° with the ship’s direction of motion. The wind is blowing from south to
north. Assume that the smoke acquires a velocity (with respect to the earth) equal to the velocity of
the wind, as soon as it leaves the ship. If the speed of the wind is km/hr. Find value of x

PART-2 : CHEMISTRY

SECTION-I

1) A container when is empty weighs 50 gm. After certain liquid of density 25 gm/dm3 is filled its
mass becomes equal to 100 gm. The volume of the container will be :

(A) 0.25 dm3

(B) 0.5 dm3
(C) 1 dm3
(D) 2 dm3

2) Dalton's law cannot be applied for which gaseous mixture at normal temperatures:

(A) O2 and N2
(B) NH3 and HCl
(C) He and N2
(D) CO2 and O2

3) Observe the following Z vs P graph.

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 The missing gas in the above graph can be :

(A) He
(B) Ar
(C) C5H12
(D) All are correct

4) Degree of Hydrolysis of solution of KCN is (Given Ka = 1.6 × 10–9)

(A) 2.5 × 10–3

(B) 2.5 × 10–2
(C) 2.5 × 10–4
(D) 2.5 × 10–5

5) What volume of 0.2 M NH4Cl solution should be added to 100 ml of 0.1 M NH4OH solution to
produce a buffer solution of pH = 8.7?
Given : pKb of NH4 OH = 4.7 ; log 2 = 0.3

(A) 50 ml
(B) 100 ml
(C) 200 ml
(D) None of these

6) How many litres of water must be added to 1 litre of an aqueous solution of HCl with a pH of 1 to
create an aqueous solution with pH of 2?

(A) 0.1 L
(B) 0.9 L
(C) 10.0 L
(D) 9.0 L

7)

For the reaction

CuSO4.5H2O(s) ⇌ CuSO4.3H2O(s)+ 2H2O(g).
Which one is correct representation :–

Kp =
(A)

2
(B) Kc = [H2O]
2
(C) Kp = Kc(RT)
(D) All

8)

For the following three reactions, 1, 2 and 3 equilibrium, constants are given :

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 (1) CO(g) + H2O(g) ⇌ CO2(g) + H2(g) ; K1
(2) CH4(g) + H2O(g) ⇌ CO(g) + 3H2(g) ; K2
(3) CH4(g) + 2H2O(g) ⇌ CO2(g) + 4H2(g) ; K3
Which of the following relations is correct ?

(A)
(B)
(C)
(D)

9) In the reaction PCl5 ⇌ PCl3 + Cl2 the amount of each PCl5, PCl3 and Cl2 is 2 mole at equilibrium
and total pressure is 3 atmosphere. The value of Kp will be :-

(A) 1.0 atm.

(B) 3.0 atm.
(C) 2.9 atm.
(D) 6.0 atm.

10) Which of the following is not a redox reaction ?

(A) BaO2 + H2SO4 → BaSO4 + H2O2

(B) 2BaO + O2 → 2BaO2
(C) 2KClO3 → 2KCl + 3O2
(D) SO2 + 2H2S → 2H2O + 3S

11) The volume of 0.1N dibasic acid sufficient to neutralize 1 g of a base that furnishes 0.04 mole of
OH– in aqueous solution is :

(A) 400 mL
(B) 200 mL
(C) 600 mL
(D) 800 mL

12) An example of a disproportionation reaction is :

(A) 2KMnO4 → K2MnO4 + MnO2 + O2

(B) +10I– +16H+ → 2Mn2++5I2 + 8H2O
(C) 2CuBr → CuBr2 + Cu
(D) 2NaBr + Cl2 → 2NaCl+Br2

13) 100 mL of a water sample contains 0.81 g of calcium bicarbonate and 0.73 of magnesium
bicarbonate. The hardness of this water sample expressed in terms of equivalents of CaCO3 is :-
(molar mass of calcium bicarbonate is 162 g mol–1 and magnesium bicarbonate is 146 gmol–1)

(A) 1,000 ppm

(B) 10,000 ppm

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 (C) 100 ppm
(D) 5,000 ppm

14) Which of the following equation represents a reaction that provides the heat of formation of
ethane (CH3CH3)?

(A) 2 C(s) + 6 H(g) → CH3CH3(g)

(B) 2 C(s) + 3 H2(g) → CH3CH3(g)
(C) CH2 = CH2(g) + 2 H2(g) → CH3CH3(g)
(D) CH≡CH(g) + 2 H2O(g) → CH3CH3(g) + O2(g)

15) If 100 mole of H2O2 decomposes at 1 bar and 300 K, the work done (kJ) by of O2(g) as it expands
against 1 bar pressure is:
2H2O2(l) ⇌ H2O(l) + O2(g)
(R = 8.3 JK–1 mol–1)

(A) 124.50
(B) 249.00
(C) 498.00
(D) 62.65

16) A green bulb and a red bulb are emitting the radiations with equal power. The correct relation
between numbers of photons emitted by the bulbs per second is

(A) ng = nr
(B) ng < nr
(C) ng > nr
(D) unpredictable

17) Which of the following contain largest number of carbon atoms ?

(A) 15 gm ethane, C2H6

(B) 40.2 gm sodium oxalate, Na2C2O4
(C) 72 gm glucose, C6H12O6
(D) 35 gm pentene, C5H10

18) Among the following, the molecule with highest dipole moment is :

(A) CH3Cl
(B) CH2Cl2
(C) CHCl3
(D) CCl4

19) An ionic bond between A and B is most likely to be formed when :

(A) the ionization energy of A is high and the electron gain enthalpy of B is low

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 (B) the ionization energy of A is low and the electron gain enthalpy of B is high
(C) the ionization energy of A and the electron gain enthalpy of B both are high
(D) the ionization energy of A and the electron gain enthalpy of B both are low

20) The structure of XeF2 involves hybridization of the type :

(A) sp3
(B) sp2
(C) sp3d
(D) sp3d2

SECTION-II

1) In a rigid closed vessel, the pressure exerted by gas is 57 cm Hg at 40°C. If it is heated to 80°C,
the final pressure of gas (in cm Hg) becomes.

2) What will be the resultant pH when 200 ml of an aqueous solution of HCl (pH = 2.0) is mixed with
300 ml of an aqueous solution of NaOH (pH = 12.0) ?

3) 3A(g) 2B(g) Kp = 2 bar–1

At what total pressure , the A is 75% dissociated

4) For the reaction 3 A (g) + B (g) 2 C (g) at a given temperature, KC = 9.0. What must be the
volume (in litre) of the flask, if a mixture of 2.0 mol each of A, B and C exist in equilibrium?

5) An aq. solution of 0.5M KMnO4 is divided into two parts. One part of it requires 125 ml of 1.5M
aq. solution of oxalate ions in acidic medium, while another part requires 270 ml of 0.5M aq. solution
of iodide ions in neutral medium which are converted into I2 only. Calculate total volume (mL) of the
initial KMnO4 solution.

6) 2.0 moles of an ideal diatomic gas undergoes adiabatic reversible compression from
20L to 4L, at an initial temperature of 27ºC. The change in entropy of gas, is: (in cal/mole)

7) A gas behaves ideally over a range of pressure at 270 K. Find the critial temperature of the gas (in
K).

8) How many s-electrons are present in Ba2⊕?

9) Find total no. of elements, which has more IE1 than Nitrogen (N) atom.
B, C, O, F, Ne, P, Si

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 10) Number of carbon atom present linearly with sp hybridisation in C2(CN)2:-

PART-3 : MATHEMATICS

SECTION-I

1) The medians of a triangle meet at (0,–3) and its two vertices are at (–1,4) and (5,2). Then the third
vertex is at

(A) (4,15)
(B) (–4,–15)
(C) (–4,15)
(D) (4,–15)

2) Let L denote the line in the xy-plane with x and y intercepts as 3 and 1 respectively. Then the
image of the point (–1, –4) in this line is

(A)

(B)

(C)

(D)

3) The pair of lines represented by

3ax2 + 5xy + (a2 – 2)y2 = 0 are perpendicular to each other for

(A) two values of a

(B) ∀ a
(C) for one value of a
(D) for no values of a

4) If the equation ax2 – 6xy + y2 + 2gx + 2fy + c = 0 represents a pair of lines whose slopes are m
and m2, then sum of all possible values of a is

(A) 17
(B) –19
(C) 19
(D) –17

5) The circle passing through (1, – 2) and touching the axis of x at (3, 0) also passes through the
point

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 (A) (–5, 2)
(B) (2, –5)
(C) (5, –2)
(D) (–2, 5)

6) y – 1 = m1(x – 3) and y – 3 = m2(x – 1) are two family of straight lines, at right angled to each
other. The locus of their point of intersection is

(A) x2 + y2 – 2x – 6y + 10 = 0
(B) x2 + y2 – 4x – 4y + 6 = 0
(C) x2 + y2 – 2x – 6y + 6 = 0
(D) x2 + y2 – 4x – 4y – 6 = 0

7) The smallest distance between the circle

(x – 5)2 + (y + 3)2 = 1 and the line 5x + 12y – 4 = 0, is

(A) 1/13
(B) 2/13
(C) 3/15
(D) 4/15

8) The equation of the image of the circle

x2 + y2 + 16x – 24y + 183 = 0
by the line mirror 4x + 7y + 13 = 0 is

(A) x2 + y2 + 32x – 4y + 235 = 0

(B) x2 + y2 + 32x + 4y – 235 = 0
(C) x2 + y2 + 32x – 4y – 235 = 0
(D) x2 + y2 + 32x + 4y + 235 = 0

9) Combined equation to the pair of tangents drawn from the origin to the circle x2 + y2 + 4x + 6y +
9 = 0 is

(A) 3(x2 + y2) = (x + 2y)2

(B) 2(x2 + y2) = (3x + y)2
(C) 9(x2 + y2) = (2x + 3y)2
(D) x2 + y2 = (2x + 3y)2

10) If a circle C passing through the point (4,0) touches the circle x2 + y2 + 4x – 6y = 12 externally at
the point (1, –1), then the radius of C is

(A)
(B) 4
(C)
(D) 5

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 11) The common tangent to the circles x2 + y2 = 4 and x2 + y2 + 6x + 8y – 24 = 0 also passes through
the point

(A) (–4, 6)
(B) (6, –2)
(C) (–6, 4)
(D) (4, –2)

12) Locus of the image of the point (2, 3) in the line , k ∈ R, is a

(A) circle of radius

(B) circle of radius
(C) straight line parallel to x-axis
(D) straight line parallel to y--axis

13) If α2 = 5α – 3, β2 = 5β – 3 (where α β) then the value of + is

(A) 19/3
(B) 25/3
(C) –19/3
(D) none of these

14) If the roots of equation (4p – p2 – 5)x2 – (2p – 1)x + 3p = 0 lie on either side of unity then the
number of integral values of p is

(A) 4
(B) 2
(C) 3
(D) 1

15)

Let a, b, c are roots of equation x3 + 8x + 1 = 0,

then the value of

is equal to

(A) 0
(B) –8
(C) –16
(D) 16

16) In triangle ABC, If then angle C is equal to [Note: All symbols used
have usual meaning in triangle ABC.]

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 (A) 30°
(B) 45°
(C) 60°
(D) 90°

17) If sum of all the solutions of the equation

8 cos x =1
in [0, π] is kπ, then k is equal to

(A)

(B)

(C)

(D)

18) Let a1, a2, a3, ... be an A.P. such that

; p ≠ q.

Then is equal to

(A)

(B)

(C)

(D)

19) The sum upto 11-terms is

(A)

(B)

(C)

(D)

20) If ,

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 (x ≠ 0), then is equal to

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-II

1) If x, y, z ∈ R and 121x2 + 4y2 + 9z2 – 22x + 4y + 6z + 3 = 0 then value of x–1 – y–1 – z–1 is equal to

2)

If 9x + 6x = 2.4x then the value of .

3) If n(A) = 10, n(B) = 15, n(A ∪ B) = 23 then n ( A ∩ B) is equals to

4)

The value of tan6°.tan42°.tan66°.tan78° is

5) Value of if n is the number of solution of cosx = |x| + 1

6) If the sum of n terms of an A.P. is 3n2 + 5n,

then which of its terms is 164

7) If α, β are roots of equation 6x2 – 5x + 1 = 0 then value of is

8) If two perpendicular tangents can be drawn from the origin to the circle x2 – 6x + y2 – 2py + 17 =
0 then the value of p2 is

9) From the origin, chords are drawn to the circle

(x – 1)2 + y2 = 1. The equation of the locus of the midpoints of these chords is x2 + y2 – λx = 0,
then the value of λ is

10) The value of λ for which the equation

2x2 – 10xy + 2y2 + 11x – 5y + λ = 0 represents a pair of straight lines, must be

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 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A D A A B D A D B C A C D C B C D B B

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 2.00 5.00 0.60 5.00 2.82 2.00 16.00 200.00 2.00 6.00

PART-2 : CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. D B C B C D D C A A A C B B A B D A B C

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 64.28 11.3 6.00 6.00 240.00 0.00 80.00 10.00 2.00 4.00

PART-3 : MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. B C A B C B B D C D B A A B C C A B D B

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 16.00 12.80 2.00 1.00 0.25 27.00 3.50 25.00 1.00 2.00

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 SOLUTIONS

PART-1 : PHYSICS

1)

4I = ;I=

2)
Let mass and side of cube be M' and a a = 2R

M' =

Moment of Inertia of cube =

3)

From the conservation of energy

loss in KE of body = Gain in potential energy

mv2 + I = mg
on solving

I=
∴ The body is a disc

4)

L=Iω ...(i)

K= Iω2 ...(ii)
On replacing I from eq. (i) we get

= ⇒

5)

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 N = mg +

and

6)

7)

mg – T = ma

T×R=

⇒a=

8)

fR = (MR2) (α)
f = M(Rα) = Ma
Mg sinθ = Ma
a = g sinθ

9)

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 10)

After all collisions vm =

11)

Applying Linear momentum conservation

mv = (m + M)vc

vc =
applying work energy theorem

–mgh = (m + M)vc2 – mv2

solve, h =

12)

13)

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 14)

θ = ωt = =

15)

16)

fL = 2.5 × 4 = 10N
No slipping
Wstatic friction = Fs × d

17)

fx = –ky

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 fy = –kx

W = 0 + 0 + 0 – ka2 ⇒ –ka2

18)

N1 = (N2 + Mg) cos θ ....(1)

(N2 + Mg) sin θ = Ma1 ....(2)
N2 + Ma1 sin θ = Mg ....(3)
Ma1 cos θ = Ma2 ....(4)
N2 = Mg – Ma1 sin θ
(2mg – ma1 sin θ) × sin θ = ma1
(2g – a1 sin θ) sin θ = a1
2g sin θ = (1 + sin2 θ) a1

t = 1;

19)

20) µ1 = µ2 =

f2 = µmg cos 60 f1 =

f2 =

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 f2 = 4

21)

22)

= 5 kg m2

23)

F1 = 3F and F0 = 2F1 = 6F = 60 N

24)

=
Put M = 5kg, m = 2kg, L = 3m
α=5

25)
y=x+2
L=1×2× = 2 × 1.41 = 2.82 kg m2/sec

26)

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 Since collision is elastic ball rebound with same speed, after collision motion is projectile on incline
plane
Let t - time of flight

As velocity along the plane is increasing linearly so R1, R2, R3 are in A.M.

a=2

27) When particle reach at bottom.

From momentum conservation :
mv1 = 4mv2
(v1 = 4v2)
From energy conservation :

v1 = 16 m/s.

28) Relative velocity VA/B must be along line of joining A and B

tan θ =
⇒ D = 200 M

29)

In this case minimum drifting = 0

so sin 30° =

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 30)

Vω = 10.39 km/hr

PART-2 : CHEMISTRY

31) As we can add 50 g of liquid

∴ 2L = 2 dm3

32) Dalton's law of partial pressure is applicable on mixture of non reacting gases.
– NH3 + HCl → NH4Cl
– O2 & N2 Non reating at normal temperature
– He & N2 Non reacting at normal temperature

33)

More is the 'a' value, more compressible is the gas. Intermolecular force when molecular weight .
So, C5H12 is most probable.

34)

For KCN, Normality = Molarity.

Kh =

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 h=
= 2.5 × 10–2

35)

Let V ml of NH4 Cl added into NH4 OH solution

[NH4 Cl] in resultant solution =

[NH4 OH] in resultant solution =

pOH = + log
5.3 = 4.7 + log

∴4= ⇒ V = 200 ml

36)

pH = 1, Volume = 1 Litre
[H⊕] = 10–1 M moles = 10–1 mol
New volume = 1 + V
New [H⨁]=10–2 M

= 10–2
10 = 1 + V
V = 9L

37) Kp = ; Kc = [H2O]2 ;
Kp = Kc(RT)2 Δs (Δng = 0)

38) from Q

39) Kp = =1

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 40) (A)
there is no change in oxidation number of any element, so this is not a redox reacton

(B)

(C)

(D)

41) 1gm of base gives: 0.04 mole OH– ions.

No. of eq. of OH– = moles of OH– × n-factor
No. of eq. of OH– = 0.04 × 1 = 0.04
No. of eq. of OH– = No. of eq. of acid
0.04 = 0.1 × V(litre)

42) Disproportionate reaction is one in which 1 atom of a given compound oxidises & Reduces
both in a redox reaction.

(1) only reduction of Mn & oxidation of oxygen.

(2)
Reduction of Mn & oxidation of Iodine
+1 +2

(3)
Both oxidation & reduction of copper hence disproportionate

(4)
oxidation of Br & Reduction of chlorine

43) Hardness of H2O is expressed as equivalent amount of CaCO3 as compared to actual

hardening compound present in 106 gm of H2O
So 1 mole Ca(HCO2) ≡ 1 mole CaCO3
1 mole Mg(HCO3)2 ≡ 1 mole CaCO3

So = 0.005

= 0.005
So nTotal of equivalent CaCO3
= 0.005 + 0.005 = 0.01

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 Hence wt of CaCO3 = 0.01 × 100 = 1 gm in (100 ml ≡ 100 gm H2O)

So in 106 gm H2O wt CaCO3 = = 104 = 1000 ppm

44)

2 C(s) + 3 H2(g) → CH3CH3(g)

1 mole of C2H6 is formed from elements in their stable standard state.

45)

2H2O2(l) ⇌ 2H2O(l) + O2(g)

w = – Pext(ΔV) =
∵ 100 mole H2O2 on decomposition give 50 mole O2.
∴ w = –(50) (8.3) (300) = –124500 J = –124.5 kJ.

46)

E = nhn

ng = no. of photons (green)

⇒ ng ng = nr nr nr = no. of red photons

v → frequency vg > vr ⇒ nr > ng

47) No. of C-atoms in 35 gm C5H10

= × 5 × 6.022 × 1023

49) An ionic bond between A and B is most likely to be formed when:

(i) Ionization energy of A is low, because A+ will formed easily
(ii) Electron gain enthalpy of B is high, because B– will formed easily

50)

51)

Rigid vessel so volume is constant.

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 P2 = 64.28 cm Hg

52)

HCl (pH = 2)
[H⨁] = 10–2 M
200 ml of HCl gives → 10–2 × 200 ⇒ 2 mmoles of H⊕
NaOH (pH = 12)
[OH⊝] = 10–2 M
300 ml of NaOH gives → 10–2 × 300 = 3 mmoles
HCl + NaOH → NaCl + H2O
2 m mole 3 m mole 2
× 1 m mole

[OH⊝] = → 2 × 10–3
∴ pH = 14 – 2.7 →11.3

53) 3A(g) 2B(g)

At eq. a(1–α)
(moles)

Kp =
Kp = 2 bar–1
solving P = 6.00 bar

54)

KC =

⇒9=
⇒V=6L

55)

Let V1 & V2 are volumes of KMnO4 in 1st part & 2nd part
Reaction (1) KMnO4 + C2O42– CO2 + Mn2+
⇒ 0.5 × V1 × 5 = 1.5 × 125 × 2
⇒ V1 = 150 mL
Reaction (1) KMnO4 + I– I2 + MnO2

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 ⇒ 0.5 × V2 × 3 = 0.5 × 270 × 1
⇒ V2 = 90 mL
So initial volume = 150 + 90 = 240 mL

56)

For reversible adiabatic process =0

57) TB = 270 K =

TC =

58)

10 s-electrons are present in Ba2⊕.

59)

F, Ne have more IE1 than nitrogen

60)

SP hybridised carbon → linear

PART-3 : MATHEMATICS

61)

⇒ a = –4

⇒ b = -15
∴ (α, β) = (–4, –15).

62)

Ans. (C)

x + 3y – 3 = 0
image of point (–1, –4) is :

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 63)

Ans. (A)
3ax2 + 5xy + a2 – 2y2 = 0 represent pair of two perpendicular lines
⇒ (3a) + (a2 – 2) = 0
⇒ a2 + 3a – 2 = 0

64)

m + m2 = 6, m3 = a
⇒ m3 + m6 + 3m3 (m + m2) = 216
2
⇒ a + a + 3a (6) = 216
⇒ a2 + 19a – 216 = 0
sum = –19

65) Let equation of circle be (x – 3)2 + (y + r)2 = r2

∵ it passes through (1, –2)
⇒r=2
⇒ circle is (x – 3)2 + (y + 2)2 = 4
⇒ (5, –2)
Aliter :
(x – 3)2 + y2 + λy = 0 ....(1)
Putting (1, –2) in (1)
⇒λ=4
Required circle is x2 + y2 – 6x + 4y + 9 = 0 point (5, –2) satisfies the equation the equation.

66)

First family passes through (3,1)

and second family passes through (1,3)
Let point of intersection is P(h,k)
so, mAP.mBP = –1 (for locus)

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 ⇒ (k – 1)(k – 3) = –(h –3 )(h – 1)
⇒ k2 – 4k + 3 = –(h2 – 4h + 3)
⇒ h2 + k2 – 4h – 4k + 6 = 0
⇒ x2 + y2 – 4x – 4y + 6 = 0

67)

ℓ = |d – r| = minimum distance between line & circle

68)

Image of a circle in a line is a circle with same radius and centre as the reflection of centre of the
given circle.
Let image is (x0, y0) of (–8,12) in line L : 4x + 7y + 13 = 0

so,

and radius,
∴ equation of the circle is
(x + 16)2 + (y + 2)2 = 52
⇒ x2 + y2 + 32x + 4y + 235 = 0

69)

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 SS1 = T2 is formula for pair of tangents.
where S = x2 + y2 + 4x + 6y + 9
S1 = 9

= 2x + 3y + 9
so, (x2 + y2 + 4x + 6y + 9) (9) = (2x + 3y + 9)2
⇒ 9(x2 + y2) + 18(2x + 3y) + 81 = (2x + 3y)2 + 18(2x + 3y) + 81
⇒ 9(x2 + y2) = (2x + 3y)2

70)

x2 + y2 + 4x – 6y – 12 = 0
Equation of tangent at (1, –1)
x – y + 2(x + 1) – 3(y – 1) – 12 = 0
3x – 4y – 7 = 0
∴ Equation of circle is
(x2 + y2 + 4x – 6y – 12) + λ(3x – 4y – 7) = 0
It passes through (4, 0):
(16 + 16 – 12) + λ(12 – 7) = 0
⇒ 20 + λ(5) = 0
⇒ λ = –4
∴ (x2 + y2 + 4x – 6y – 12) – 4(3x – 4y – 7) = 0
or x2 + y2 – 8x + 10y + 16 = 0
Radius =

71)

Circle touches internally

C1(0, 0); r1 = 2
C2 : (–3, –4); r2 = 7
C1C2 = |r1 – r2|
S1 – S2 = 0 ⇒ eqn. of common tangent
6x + 8y – 20 = 0
3x + 4y = 10
(6, –2) satisfy it

72)

P is the fixed point for given family of line

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 ⇒ (α – 1)2 + (β – 2)2 = 1 + 1

∴ locus is a circle of radius .

73)

Since, α2 = 5α – 3 ⇒ α2 – 5α + 3 = 0
and β2 = 5β – 3 ⇒ β2 – 5β + 3 = 0
These two equations shows that a and b are the roots of the equation
x2 – 5x + 3 = 0
∴ α + β = 5 and αβ = 3

Now

74) Let ƒ(x) = (4p – p2 – 5)x2 – (2p – 1)x + 3p ...(1)

∴ a.ƒ(1) < 0
⇒ (4p – p2 – 5).[4p – p2 – 5 – 2p + 1 + 3p] < 0

⇒ (p – 4)(p – 1) < 0
∴ p ∈ (1, 4)
∴ Number of integral value(s) of p is (2)

75) ∵ a, b, c are roots of x3 + 8x + 1 = 0

∴ a3 + 8a + 1 = 0
⇒ 8a + 1 = –a3
same as 8b + 1 = –b3
& 8c + 1 = –c3

find

76)

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 b(b + c) + a(a + c) = (a + c)(b + c)
b2 + bc + a2 + ac = ab + ac + bc + c2
b2 + a2 = ab + c2

or (By transforming)

or ∠C = 60°

77)

⇒ 8cosx =1

⇒ 8cosx =1

⇒ 2cos3x = 1 ⇒ cos3x =

∴ 3x + 2nπ ± ,n∈I

In x ∈ [0, π] : x = only

sum =

78)

a1, a2, a3…. AP

⇒ ..…(i)

(an = a1 + (n – 1)d)
From equation (i)

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 and
p = 11 q = 41
put p = 11 and q = 41 in equation (i)

79)

80)

Let &

81)

(11x)2 + (2y)2 + (3z)2 – 22x + 4y + 6z + 3 = 0

⇒ (11x–1)2 + (2y + 1)2 + (3z + 1)2 = 0
⇒ 11x – 1 = 2y + 1 = 3z + 1 =0

⇒
⇒ x–1 –y–1 – z–1 = 11 + 2 + 3 = 16.

82)

9x + 6x = 2 × 4x

Let
so, t2 + t – 2 = 0
⇒ t = 1 or t = –2 (rejected)

83)

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 use n (A ∪ B) = n(A) + n(B) – n(A ∩ B)

84)

Multiply and divide by tan 54º

w.r.t.
tanθ.tan(60 + θ) tan(60 – θ) = tan3θ
so if θ = 6º, then

(Now of θ = 18º)

85)

No. of solution = n =1

86)

So,
n = 27

87)

1 + α + α2 + ... ∞ + 1 + β + β2 + ... ∞

= 3.50

88)

origin lie on dir. circle

(x – 3)2 + (y – p)2 = 2(p2 – 8)
⇒ 9 + p2 = 2p2 – 16

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 89)

OP = PA
∴ A(2h, 2k)
∵ Point A lies on the circle,
Hence, (2h – 1)2 + (2k)2 = 1
⇒ x2 + y2 – x = 0
∴λ=1

90)

For represent a pair of straight line

⇒ abc + 2fgh – af2 – bg2 – ch2 = 0

On solving

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