1.

Select all sets of quantum numbers that can exist in the following sets of quantum numbers:
1) n = 3, l = 3, m l = +3. 2) n = 3, l = 2, m l = +2.
3) n = 4, l = 1, m l = +2. 4) n = 0, l = 0, m l = 0.
A. Only 1,4 B. All C. Only 2 D. Only 2,4

2. Subclass 4s has quantum numbers n, l and maximum number of electrons respectively:

A. n = 4; l = 1 and 6e B. n = 4; l = 0 and 2e
C. n = 4; l = 2 and 10e D. n = 4; l = 3 and 14e

3. The molecule CH3 – CH2 – CH3 has:

A. The 3 C atoms all hybridize sp.
B. 2 sp2 hybrid C atoms, 1 sp hybrid C atom.
C. The 3 C atoms all hybridize sp2.
D. The 3 C atoms are all sp3 hybridized.

4. In the periodic system table, with all periods:

1) The periods is the sequence of elements, beginning with element s, ending with element p.
2) A periods is a sequence of elements, beginning with an alkali metal and ending with a noble gas.
3) The nth periods contains n2 chemical elements.
4) During one periods the nuclear charge of the elements increases steadily from left to right.

A. Only 1,2,3 B. All C. Only 4 D. Only 1,2

5. According to VB theory we have:

1) The s-valence orbitals are only capable of overlaping to form bonds .
2) p-valent orbitals are only capable of overlaping to form bonds  and .
3) d-valent orbitals are only capable of overlaping to form bonds  and .
4) Hybridized orbitals are only capable of overlaping to create bonds .
5) Orbitals that do not participate in hybridization have the ability to overlaping to form bonds .

A. Only 1,2,4 B. All C. Only 4, 5 D. Only 1,2,3

6. The electron formula of 30Zn2+ in the ground state is:

A. 1s22s22p63s23p63d84s2 B. 1s22s22p63s23p63d94s1
C. 1s22s22p63s23p63d9 D. 1s22s22p63s23p63d10

7. Choose the correct statement.

1) The HCN molecule has the central atom C in the sp2 hybridization state, so the molecular geometry
should be angular.
2) The ion has the central atom S in the sp3 hybridization state, so the molecular geometry should
be trigonal pyramidal
3) The POCl3 molecule has the central atom P in the sp3 hybridization state, so the molecular geometry
should be distorted tetrahedral (tứ diện lệch)
4) The SOBr2 molecule has the central atom S in the sp2 hybridization state, so the molecular geometry
should be trigonal planar
A. 1.2 B. 1,3,4 C. 2.3 D. Only 3

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8. The atom with a valence electron configuration (n–1)d7ns2 has the smallest ordinal number in the
chemical system:
A. 27 B. Unidentified C. 30 D. 26

9. Atom A has 4 quantum numbers of the last electron: n = 3; ℓ = 2; mℓ = 0; ms = +½ (In the same
sublayer, the electron convention fills in the orbitals in the order of ml from –l to +l and fills positive
spin first, negative after). Atom A has:
A. Z = 23 and is metallic. B. Z = 22 and is nonmetallic.
C. Z = 20 and is nonmetallic. D. Z = 21 and is metallic.

9. According to VB theory, H3O+ ion has properties:

1) sp2 hybrid, trigonal planar and nonpolar.
2) sp3 hybrid and tetrahedral geometry, 109,5o
3) O atom has 2 covalent bonds with H atom by sharing mechanism and 1 covalent bond with H by
acceptor-donor mechanism.
4) sp3 hybrid and pyramidal geometry, polar.

A. 3, 4
B. 1, 2, 3, 4
C. 1, 3
D. 2, 3, 4

10. In the ground state, the last electron of atom 53I has a set of quantum numbers (in the same subclass,
the electron convention fills in the orbitals in the order of ml from –l to +l and fills in positive spin first,
negative after):
A. n = 4, l = 2, ml = 0, ms = −1/2 B. n = 5, l = 2, ml = 1, ms = +1/2
C. n = 4, l = 1, ml = −1, ms = 1−/2 D. n = 5, l = 1, ml = 0, ms = −1/2

11. Choose the correct statement.

1) The process of forming stable covalent bonds from atoms is the process of heat generation.
2) On the potential energy curve of the hydrogen molecule, to form a covalent bond, two hydrogen
atoms with opposite spin (in the gas phase) are infinitely close to each other, the initial predominant
interaction is the attraction interaction.
3) All chemical bonds are electrical in nature.
4) The larger the size of the atom participating in a covalent bond, the more the bond length increases,
so the stronger the bond.
A. Only 1,2,3. B. All. C. Only 2.4. D. Only 1.3.

12. Choose the right case. Names of quantum subclasses corresponding to n = 7 and l = 5; n = 6 and l =
4; n = 4 and l = 3 are:
A. 7d, 6p, 4s B. 7g, 6f, 4d C. 7f, 6d, 4p D. 7h, 6g, 4f

13. The maximum possible number of orbitals corresponding to the symbol: 2px, , 4d, 3d x 2 − y 2 n = 2
and n = 5 have values of respectively:
A. 2, 3, 4, 2, 5 B. 1, 1, 5, 4, 25 C. 3, 1, 5, 4, 16 D. 3, 5, 1, 11, 9

14.The number of single electrons in the 26Fe atom in the ground state is:
A. 5 B. 4 C. 3 D. 2

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15. Three sp2 hybridization orbitals of the BF3 molecule have characteristics:
A. Equal energy, different shapes and spatial orientations.
B. The shape is the same, the energy is equal and the distribution is symmetrical in space with a
hybridization angle of 120o.
C. The shape is the same but the energy and spatial orientation are different.
D. Different shapes, energies and spatial orientations.

16. The X3+ ion has the outermost shell of 3d3. In the ground state, the outermost electron of X is
characterized by a set of 4 quantum numbers (in the same subshell, the electron convention fills the
orbitals in the order of ml from +l to –l and fills positive spin first, negative after):
A. n = 3, l = 2, ml = –2, ms = +1/2 B. n = 4, l = 0, ml = 0, ms = ±1/2
C. n = 4, l = 0, ml = 0, ms = +1/2 D. n = 3, l = 2, ml = +2, ms = –1/2

17. Does the molecule have a different dipole moment:

1) OF2 2) IF 3) COS 4) cis–C2H2Cl2

A. Only 1,2,4 B. All C. Only 1,2,3 D. Only 2.4

18. Atomic orbitals are:

1) The wave function describes the state of electrons in an atom determined by a triplet of quantum numbers: n,
l and ml.
2) The surface has an equal electron density of the electron cloud.
3) The orbital of electron motion in the atom.
4) The wave function describes the spatial motion of electrons around the atomic nucleus.
5) The region of space around the nucleus where the probability of electrons being present is 100%.

A. 1, 2, 3, 4. B. Only 2, 3, 4. C. Only 1, 4. D. Only 1, 5.

19. The CFCl3 molecule has bonding characteristics:

1) Bond length: C–Cl > C–F. 2) Bonding energy: E(C–F) > E(C–Cl).
3) The molecule has a distorted tetrahedral, polar 4) ClCCl angle > 1200.

A. All B. Only 1, 3 C. Only 1,2,3 D. Only 1, 2

20. According to quantum mechanics, the probability density of the distribution of electrons across
orbitals:
1) 3d z 2 along the Z-axis is the largest.
2) 3dxy along the Z-axis is the largest.
3) 3d x 2 − y 2 along the bisector between the x and y axes is the largest.
4) 3dyz following the bisector between the y and z axes is the largest.
A. 1,2 B. 1, 4 C. 3,4 D. 2.3

21. The electron in atom X has four quantum numbers: n = 2, l = 1, ml = 0, ms = −1/2. So in atom X
there cannot be an additional electron with four quantum numbers:
A. n = 2, l = 0, ml = 0, ms = +1/2. B. n = 2, l = 1, ml = 0, ms = −1/2
C. n = 2, l = 1, ml = 0, ms = +1/2. D. n = 2, l = 0, ml = 0, ms = −1/2.
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22. In an atom:
1) Orbital 2s are larger than orbital 1s.
2) The energy of the electron on AO 2s is greater than the energy of the electron on AO 1s.
3) AO 3dxz consists of 4 deformed spheres located on the x and z axes in contact at the base of the
coordinates.
4) The energy of the electron on AO 2pz is greater than the electron energy on AO 2px.
A. 1,2,3,4 B. Only 1,2,3 C. Only 3.4 D. Only 1.2

23. The elements containing unbound valence electron pairs at the central atom are:
1) SO2 2) PH 3 3) SO3 4) CS2 5) NH +4
A. 1.4 B. 1.2 C. 3.4 D. 2,3,5

24. The bond strength increases in the following series:

1) (2s-2s) < (2s-2p) < (2p-2p) 2) (1s-2p) < (1s-3p) < (1s-4p)
3) C–O < C=O < C≡O 4) (2p-2p) < (2p-3p) < (3p-3p)
A. (1) and (3) only
B. (2) and (4) only
C. (1), (3) and (4)
D. All of the above

24. In a major subgroup of the periodic system table, the metallicity of elements in a top-down
direction tends to:
A. No change B. Transformations without rules
C. Ascending D. Descending

25. The correct alignment angle of the elements: NH +4 (1), H2O (2) and H3O+(3).
A. (2) < (3) < (1) B. ( 1) < (2) < (3) C. ( 1) < (3) < (2) D. (3) < (1) < (2)

26. Which of the following values is the nuclear charge of element p:

1) Z = 33 2) Z = 42 3) Z = 38 4) Z = 52 5) Z = 56

A. 1,4 B. 1,5 C. 2,3 D. 3,5

27. Choose the correct option in terms of the spatial configuration and polarity of ions (17Cl is the
central atom) as follows:
1) – angle, non-polar 2) ) – trigonal pyramidal, polar 3) – tetrahedral, with
polar
A. Only 3 B. Only 2 C. 1 D. 2.3

28. According to the VB method, molecule have covalent bonds according to the electron donor-
acceptor mechanism: 1) O3 2) SO2 3) CO 4) NO2
A. Only 1,2 B. All C. Only 2,4 D. Only 1,3,4

29: Dipole moment of substances ascending in series:

A. CH4 = CO2 < OF2 < H2O B. CH4 < CO2 < OF2 < H2O
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 C. CH4 < CO2 < H2O < OF2 D. H2O < OF2 < CH4 < CO2

30. Arrange the following covalent compounds in order increasing bond angle:
1) CH4 2) NH3 3) H2O

A. (1) < (2) < (3) B. (2) < (1) < 3)

C. (3) < (2) < (1) D. (3) < (2) < (1)

31. Which quantum number(s) must be the same for the orbitals that they designate to be degenerate in a
multi-electron system?
A. n and l only
B. n, l, ml, and ms
C. n only
D. n, l, and ml

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