Periodic Table & Periodicity

@ Marked Questions may have for Revision Questions.

ONLY ONE OPTION CORRECT TYPE

* Marked Questions may have more than one correct option.

Section (A) : Development of Periodic Table, Period, Group and Block

1.@ How many periods and vertical columns are there in the long form of the periodic table?
(1) 8, 12 (2) 6, 8 (3) 7, 18 (4) 6, 18

2.@ The period number in the long form of the periodic table is equal to :
(1) magnetic quantum number of any element of the period.
(2) atomic number of any element of the period.
(3) maximum Principal quantum number of any element of the period.
(4) maximum Azimuthal quantum number of any element of the period.

3. Which one of the following statements related to the modern periodic table is incorrect :
(1) The p-block has 6 columns, because a maximum of 6 electrons can occupy all the orbitals in a
p-subshell.
(2) The d-block has 8 columns, because a maximum of 8 electrons can occupy all the orbitals in a
d-subshell.
(3) Each block contains a number of columns equal to the number of electrons that can occupy that
subshell.
(4) The block indicates value of Azimuthal quantum number () for the last subshell that received
electrons in building up the electronic configuration.

4. The elements in which electrons are progressively filled in 4f-orbital are called :
(1) actinoid (2) transition element (3) lanthanoid (4) halogen

5. Which of the following electronic configuration represent noble gas ?

(1) ns2np6 (2) ns2np5 (3) ns2np4 (4) ns2np3

6. Which of the following group of transition metals is called coinage metals ?

(1) Cu, Ag, Au (2) Ru, Rn, Pd (3) Fe, Co, Ni (4) Os, IR, Pt

7.@ What is the characteristic valence shell electron configuration of 11th group metals ?
(1) ns2 np6 (2) (n – 1)d2 ns2 (3) nd9 ns2 (4) (n – 1)d10 ns1

8. Pt, Ni, Au and Ti belongs to :

(1) f-block (2) d-block (3) p-block (4) s-block

9. Which of the following element is a metalloid ?

(1) Bi (2) Sn (3) Ge (4) C

10.@ An element has atomic number 37. The block and group of this element are respectively :
(1) s and 1st (2) p and 17th (3) s and 2nd (4) p and 13th
Periodic Table & Periodicity

11. In modern periodic table, the element with atomic number Z = 118 will be :
(1) Uuo ; Ununoctium ; alkaline earth metal (2) Uno ; Unniloctium ; transition metal
(3) Uno ; Unniloctium ; alkali metal (4) Uuo ; Ununoctium ; noble gas

Section (B) : Shielding Effect & Zeff

1. The order of screening effect of electrons of s, p, d and f orbitals of a given shell of an atom on its outer
shell electrons is :
(1) s > p > d > f (2) f > d > p > s (3) p < d < s > f (4) f > p > s > d

2. Which of the following is generally true regarding effective nuclear charge (Zeff) :
(1) It increases on moving left to right in a period.
(2) It remains almost constant on moving top to bottom in a group.
(3) For isoelectronic species, as Z increases, Zeff decreases.
(4) Both (1) and (2).

3. From the given set of species, point out the species from each set having highest Zeff
(a) O2–, F–, Na+ (b) Li, Be, C (c) He, Li+, H–
a b c a b c
(1) Na +
C Li+ (2) O2– Li H–
(3) F –
Na He (4) Na+ Be He

Section (C) : Atomic and Ionic Radius

1.@ Select correct statement about radius of an atom :
(1) Values of Vander waal's radii is larger than those of covalent radii because the Vander waal's forces
are much weaker than the forces operating between atoms in a covalently bonded molecule.
(2) The metallic radii is smaller than the Vander waal's radii, since the bonding forces in the metallic
crystal lattice are much stronger than the Vander waal's forces.
(3) Both (1) & (2)
(4) None of these

2. The atom larger in size as compared to oxygen is :

(1) F (2) He (3) Ne (4) none of these

3.@ Which of the following has the largest ionic radius ?

(1) Na+ (2) Cs+ (3) Ca+ (4) Mg+

4.@ Which one of the following is the smallest in size ?

(1) N 3 - (2) O 2 - (3) F - (4) Na +

5. Which has smallest size ?

(1) Na+ (2) Mg2+ (3) Ne (4) O2–

6. In which pair, the second atom is larger than first :

(1) Br, Cl (2) Na, Mg (3) Sr, Ca (4) N,P

7.@ Which of the following order of radii is correct ?

(1) Li < Be < Mg (2) O+ < O2– < N3– (3) O < F < Ne (4) Na+ > F– > O2–

8.@ Among Cl–, F– Br– and I– the correct order of increasing atomic radii is :
(1) I– > F– > Cl– > Br– (2) I– > Br– > Cl– > F– (3) F– > Br– > Cl– > I– (4) F– > Cl– > Br– > I–
Periodic Table & Periodicity

9. The size of isoelectronic species O-2 , F– and Na+ is affected by :

(1) nuclear charge (Z)
(2) valence principal quantum number (n)
(3) electron-electron interaction in the outer orbitals
(4) none of the factors because their size is the same.

10. Atomic radii of F & Ne in Angstrom are respectively given by :

(1) 0.72, 1.60 (2) 1.60, 1.60 (3) 0.72, 0.72 (4) 1.60, 0.72.

11. Match the correct atomic radius with the element :

S.No. Element Code Atomic radius (pm)
(i) Be (p) 74
(ii) C (q) 88
(iii) O (r) 111
(iv) B (s) 77
(v) N (t) 66
(1) (i) – r, (ii) – q, (iii) – t, (iv) – s, (v) – p (2) (i) – t, (ii) – s, (iii) – r, (iv) – p, (v) – q
(3) (i) – r, (ii) – s, (iii) – t, (iv) – q, (v) – p (4) (i) – t, (ii) – p, (iii) – r, (iv) – s, (v) – q

12.@ Match list – I with list – II and select the correct answer using the codes given below –
List – I List – II
Ion Radius
(I) Li+
(1) 216
(II) Na+ (2) 195
(III) Br –
(3) 60
(IV) I –
(4) 95
Codes :
I II III IV I II III IV
(1) a b d c (2) b c a d
(3) c d b a (4) d c b a

13.@ Which of the following order of atomic / ionic radius is not correct ?
(1) F < Cl < Br < I (2) Mg2+ > Li+ (3) Nb » Ta (4) Li > Be > B

Section (D) : Ionisation Energy

1.@ Which one of the following statements is incorrect in relation to ionisation enthalpy ?
(1) Ionization enthalpy increases for each successive electron.
(2) The greatest increase in ionization enthalpy is experienced on removal of electron from core of
noble gas configuration.
(3) End of valence electrons is marked by a big jump in ionization enthalpy.
(4) Removal of electron from orbitals bearing lower n value is easier than from orbitals having higher n
value.

2. The first ionisation enthalpies (in eV) of N & O are respectively given by :
(1) 14.6, 13.6 (2) 13.6, 14.6 (3) 13.6, 13.6 (4) 14.6, 14.6

3. The set representing the correct order for first ionisation potential is :
(1) K > Na > Li (2) Be > Mg > Ca (3) B > C > N (4) Ge > Si > C
Periodic Table & Periodicity

4. The first ionisation enthalpies of Na, Mg, Al and Si are in the order :
(1) Na < Mg > Al < Si (2) Na > Mg > Al > Si (3) Na < Mg < Al < Si (4) Na > Mg > Al < Si

5. Which electronic configuration of neutral atoms will have the highest first ionisation energy ?
(1) 1s2 2s2 2p4 (2) 1s2 2s2 2p3 (3) 1s2 2s2 2p2 (4) 1s2 2s2 2p1

6. The first ionization energy is smallest for the atom with electronic configuration :
(1) ns2 np6 (2) ns2 np4 (3) ns2 np5 (4) ns2 np3

7.@ The first ionisation energy will be maximum for :

(1) Be (2) He (3) Li (4) Fe

8. Which of the following has maximum ionization enthalpy.

(1) P (2) N (3) As (4) ,Sb

9. Which among the following elements have lowest value of IE1 ?

(1) Pb (2) Sn (3) Si (4) C

10.@ The second ionization energies of elements are always higher than their first ionization energies
because :
(1) the cation is smaller than its parent atom.
(2) it is easier to remove electron from cation.
(3) ionization is an endothermic process.
(4) cation formed always have stable half filled or completely filled valence shell electron configuration.

11. Which of the following orders are correct for the ionization energies ?
(i) Ba < Sr < Ca (ii) S2– < S < S2+ (iii) C < O < N (iv) Mg < Al < Si
(1) i, ii and iv (2) i, iii and iv (3) i, ii and iii (4) i, ii, iii and iv

12.@ Which represents alkali metals (i.e. 1st group metals) based on (IE)1 and (IE)2 values (in kJ/mol) ?
(IE)1 (IE)2 (IE)1 (IE)2
(1) X 500 1000 (2) Y 600 2000
(3) Z 550 7500 (4) M 700 1400

13.@ Which of the following relation is correct with respect to first (I) and second (II) ionization enthalpies of
potassium and calcium ?
(1) ICa > IIK (2) IK > ICa (3) IICa > IIK (4) IIK > IICa

14. Strongest reducing agent is :

(1) CS (2) Mg (3) Al (4) K

Section (E) : Electron gain enthalpy (Electron affinity)

1.@ Electron affinity is a :
(1) Relative strength to attract the shared electron pair
(2) Necessary energy required to remove the electron from the ultimate orbit
(3) Energy released when an electron is added to the outermost shell
(4) Energy released when an electron is added to the inner shell
2. Second electron effinity of an element is :
(1) Always exothermic (2) Endothermic for few elements
(3) Exothermic for few elements (4) Always endothermic

3.@ The correct order of electron affinity is :

Periodic Table & Periodicity

(1) Be < B < C < N (2) Be < N < B < C (3) N < Be < C < B (4) N < C < B < Be

4.@ For electron affinity of halogens which of the following is correct ?

(1) Br > F (2) F > Cl (3) Br < Cl (4) F– > I

5. In which case the energy released is minimum?

(1) Cl ® Cl– (2) P ® P– (3) N ® N– (4) C ® C–

6.@ Which of the following will have the most negative electron gain enthalpy and which the least negative ?
(1) F, Cl (2) Cl, F (3) S, Cl (4) Cl, P

7. Element having maximum electron affinity is :

(1) Fluorine (2) Chlorine (3) Bromine (4) Iodine

8. Among halogens, the correct order of amount of energy released in electron gain (electron gain
enthalpy) is:
(1) F > Cl > Br > I (2) F < Cl < Br < I (3) F < Cl > Br > I (4) Cl > Br > F > I

9.@ Which of the following will have the most negative electron gain enthalpy and which the least negative ?
F, P, S, Cl.
(1) P, Cl (2) Cl, F (3) Cl, S (4) Cl, P

10.@ The order of electron gain enthalpy (magnitude) of O, S and Se is :

(1) O > S > Se (2) S > Se > O (3) Se > S > O (4) S > O > Se

11. Electronic configurations of four elements A, B, C and D are given below :

(i) 1s22s22p6 (ii) 1s22s22p4 (iii) 1s22s22p63s1 (iv) 1s22s22p5
Which of the following is the correct order of increasing tendency to gain electron :
(1) (i) < (iii) < (ii) < (iv) (2) (i) < (ii) < (iii) < (iv) (3) (iv) < (ii) < (iii) < (i) (4) (iv) < (i) < (ii) < (iii)

12. Which of the following statement is correct ?

(1) Electron gain enthalpy may be positive for some elements.
(2) Second electron gain enthalpy always remains positive for all the elements.
(3) DegH(K+) = – IE (K)
(4) All of these

Section (F) : Electronegativity

1.@ Following the Mulliken scale, what parameters are required to evaluate electronegativity ?
(1) Only electronegativity (2) Only electron affinity
(3) Electron affinity and ionization energy (4) Ionic potential and electronegativity

2.@ The electronegativity values of C,N,O and F :

(1) increase from carbon to fluorine.
(2) decrease from carbon to fluorine.
(3) increase up to oxygen and is minimum at fluorine.
(4) is minimum at nitrogen and then increase continuously.

3.@ The electronegativity of the following elements increases in the order :

(1) C < N < Si < P (2) N < Si, < C < P (3) Si < P < C < N (4) P < Si < N < C

4. The correct set of decreasing order of electronegativity is :

(1) Li, H, Na (2) Na, H, Li (3) H, Li, Na (4) Li, Na, H
Periodic Table & Periodicity

5.@ Increasing order of electronegativity left to right is :

(1) Bi < P < S < Cl (2) P < Bi < S < Cl (3) C > F > N > O (4) F > N > O > C

6.@ The outer most electronic configuration of the most electronegative atom is :
(1) ns2 np5 (2) ns2np6 (3) ns2np4 (4) ns2np3

7. Which of the following is affected by the stable electronic configuration of an atom ?

(1) Electronegativity (2) Ionisation enthalpy (3) Electron gain enthalpy
Correct answer is :
(1) only electronegativity (2) only ionisation enthalpy
(3) both electron gain enthalpy and ionisation enthalpy (4) all of the above

8. The electronegativity values of Li,Be,B and C on Pauling scale :

(1) decrease from Li to C
(2) increase from Li to C
(3) increase upto Boron and then decrease upto carbon
(4) decrease from Li to B and then increase carbon

9. Correct order of electronegativity of N, P, C and Si on Pauling scale is :

(1) N > P > C > Si (2) C > Si > N > P (3) N < P < C < Si (4) N > C > P > Si

10. The correct order of electronegativity on Pauling scale is :

(1) F > Cl > O > S (2) Li > Na > K > Rb > Cs
(3) Be < B < N < C (4) Both (1) and (2)

11.@ Which of the following is most electronegative element.

(1) Li (2) Mg (3) H (4) Na

Section (G) : Inert pair effect

1._ Correct order of stability of +2 oxidation state is :
(1) Si+2 > Ge+2 > Sn+2 > Pb+2 (2) Si+2 < Ge+2 < Sn+2 < Pb+2
(3) Si+2 = Ge+2 = Sn+2 = Pb+2 (4) None

2._ Correct order of stability of Sn+2 and Sn+4 is

(1) Sn+2 > Sn+4 (2) Sn+2 = Sn+4 (3) Sn+4 > Sn+2 (4) All are correct

3._ PbCl2 is a stable compound but PbCl4 is unstable due to

(1) Ionisation potential of Pb2+ and Pb4+ are almost same
(2) Stability of Pb4+ is greater Pb2+
(3) both (1) and (2)
(4) due to inert pair effect

4._ Correct order of stability is

(1) Bi+5 > Br+3 (2) Bi+3 < Br+5 (3) Tl+3 > Tl+1 (4) Pb+4 > Pb+2

5. Electrons of which subshell do not participate in bonding due to inert pair effect ?
(1) 6s (2) 6p (3) 5d (4) 4f

6. Thallium shows different oxidation states because :

(1) of its high reactivity (2) of inert pair of electrons
(3) of its amphoteric nature (4) its is a transition metal
Periodic Table & Periodicity

7. In which of the following elements, + 3 oxidation state is more stable than + 5 ?

(1) P (2) As (3) N (4) Bi

8._ Which of the following is correct order of stability :

(1) Tl3+ > Bi3+ (2) PbO2 > PbO (3) Tl+1 < Tl+3 (4) Sn2+ = Ge2+

@ Marked Questions may have for Revision Questions.

ONLY ONE OPTION CORRECT TYPE

1. The statement that is not correct for periodic classification of elements in Modern periodic table is :
(1) The properties of elements are periodic function of their atomic numbers.
(2) Non-metallic elements are less in number than metallic elements.
(3) For transition elements, the 3d-orbitals are filled with electrons after 3p-orbitals and before 4s-
orbitals.
(4) The first ionisation enthalpies of elements generally increase with increase in atomic number as we
go along a period.

2. Which of the following is true about the element 33As according to Modern periodic table :
(1) It is a 5th period element. (2) It is a p-block element.
(3) It belongs to 16th group. (4) It is one among typical elements.

3.@ Which of the following contains atomic number of only s-block

(1) 55,12,18,53 (2) 13,33,54,83 (3) 3, 20,55,87 (4) 22,33,55,66

4.@ Screening effect is not observed in :

(1) He+ (2) Li2+ (3) Be3+ (4) In all cases

5.@ When the following five anions are arranged in order of decreasing ionic radius, the correct sequence is
(1) Se2–, I–, Br–, O2–, F– (2) I– , Se2–, Br– , F–, O2–
(3) Se , I , Br , F , O
2– – – – 2–
(4) I–, Se2–, Br–, O2–, F–

6. The correct order of size of ions Li+, Mg2+, K+, Al3+ :

(1) Al3+ < Mg2+ < Li+ < K+ (2) Mg2+ < Al3+ < Li+ < K+
(3) Al < Mg < K < Li
3+ 2+ + +
(4) Al3+ < Li+ < Mg2+ < K+

7. The correct order of Ionic radius is :

(1) Ti4+ < Mn7+ (2) 35Cl– < 37Cl– (3) K+ > Cl– (4) P3+ > P5+

8. The correct order of radii is :

(1) N < Be < B (2) F– < O2– < N3– (3) Na < Li < K (4) Fe3+ < Fe2+ < Fe+4

9.@ Which of the following is the correct order of ionisation enthalpy ?

(1) Be+ > Be (2) Be > Be+ (3) C > Be (4) B > Be
(1) 2, 3 (2) 3, 4 (3) 1, 3 (4) 1, 4
10.@ Considering the elements B, Al, Mg, and K, the correct order of their metallic character is :
(1) B > Al > Mg > K (2) Al > Mg > B > K
(3) Mg > Al > K > B (4) K > Mg > Al > B
11. The incorrect statement among the following is :
(1) the first ionization energy of Al is less than first ionization energy of Mg.
Periodic Table & Periodicity

(2) the second ionization energy of Mg is greater than second ionization energy of Na.
(3) the first ionization energy of Na is less than first ionization energy of Mg.
(4) the third ionization energy of Mg is greater than third ionization energy of Al.
12. Fluorine has the highest electronegativity among the ns2 np5 group on the Pauling scale, but the
electron affinity of fluorine is less than that of chlorine because :
(1) the atomic number of fluorine is less than that of chlorine.
(2) fluorine being the first member of the family behaves in an unusual manner.
(3) chlorine can accommodate an electron better than fluorine by utilising its vacant 3d–orbital.
(4) small size, high electron density and an increased electron repulsion makes addition of an electron
to fluorine less favourable than that in the case of chlorine in isolated stage.
13.@ Which of the following statement is incorrect ?
(1) The tendency to attract bonded pair of electron in case of hybrid orbitals follow the order : sp > sp2 > sp3
(2) Alkali metals generally have negative value of electron gain enthalpy.
(3) Cs+(g) releases more energy upon gain of an electron than Cl(g).
(4) The electronegativity values for 2p-series elements is less than that for 3p-series elements on
account of small size and high inter electronic repulsions.
14. Identify the least stable ion amongst the following :
(1) Li– (2) Be– (3) B– (4) C–
15. The correct order of stability of Al+3, Ga+3, In+3, Tl+3
(1) Al+3 > Ga+3 > In+3 > Tl+3
(2) Al+3 < Ga+3 < In+3 < Tl+3
(3) Al+3 > Tl+3 > Ga+3 > In+3
(4) Al+3 = Tl+3 = Ga+3 = In+3
16.@ Which of following does not exist :
(1) TlI3 (2) PbF4 (3) Both (1) and (2) (4) None of these

17. Elements of which period show maximum inert pair effect :

(1) 3 (2) 4 (3) 5 (4) 6
Periodic Table & Periodicity

EXERCISE - 1
SECTION (A)

1. (3) 2. (3) 3. (2) 4. (3) 5. (1) 6. (1) 7. (4)

8. (2) 9. (3) 10. (1) 11. (4)

SECTION (B)

1. (1) 2. (4) 3. (1)

SECTION (C)

1. (3) 2. (3) 3. (2) 4. (4) 5. (2) 6. (4) 7. (2)

8. (2) 9. (1) 10. (1) 11. (3) 12. (3) 13. (2)

SECTION (D)

1. (4) 2. (1) 3. (2) 4. (1) 5. (2) 6. (2) 7. (2)

8. (2) 9. (2) 10. (1) 11. (3) 12. (3) 13. (4) 14. (1)

SECTION (E)

1. (3) 2. (4) 3. (2) 4. (3) 5. (3) 6. (4) 7. (2)

8. (3) 9. (4) 10. (2) 11. (1) 12. (4)

SECTION (F)
1. (3) 2. (1) 3. (3) 4. (3) 5. (1) 6. (1) 7. (3)

8. (2) 9. (4) 10. (2) 11. (3)

SECTION (G)
1._ (2) 2._ (3) 3._ (4) 4._ (2) 5. (1) 6. (2) 7. (4)

8._ (3)

EXERCISE - 2
1. (3) 2. (2) 3. (3) 4. (4) 5. (4) 6. (1) 7. (4)

8. (2) 9. (3) 10. (4) 11. (2) 12. (4) 13. (4) 14. (2)

15. (1) 16. (4) 17. (4)