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The document contains a series of chemistry questions and answers related to solutions, including calculations of mole fraction, properties of ideal solutions, and effects of solutes on boiling points and osmotic pressure. Key concepts discussed include molality, molarity, van’t Hoff factor, and the behavior of azeotropic mixtures. Each question is followed by the correct answer, providing a concise review of solution chemistry principles.

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Subhankar Nath
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5 views2 pages

Selfstudys Com File

The document contains a series of chemistry questions and answers related to solutions, including calculations of mole fraction, properties of ideal solutions, and effects of solutes on boiling points and osmotic pressure. Key concepts discussed include molality, molarity, van’t Hoff factor, and the behavior of azeotropic mixtures. Each question is followed by the correct answer, providing a concise review of solution chemistry principles.

Uploaded by

Subhankar Nath
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Solutions

1. Mole fraction of glycerine C3H5(OH)3 in solution containing 36 g of water and 46 g of glycerine is


(a) 0.46
(b) 0.40
(c) 0.20
(d) 0.36

Answer

Answer: c

2. Out of molality (m), molarity (M), formality (F) and mole fraction (x), those which are independent of temperature are
(a) M, m
(b) F, x
(c) m, x
(d) M, x

Answer

Answer: c

3. Which of the following condition is not satisfied by an ideal solution?


(a) ΔHmixing = 0
(b) ΔVmixing = 0
(c) Raoult’s Law is obeyed
(d) Formation of an azeotropic mixture

Answer

Answer: d

4. The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows
(a) no deviation from Raoult’s Law.
(b) positive deviation from Raoult’s Law.
(c) negative deviation from Raoult’s Law.
(d) that the solution is unsaturated.

Answer

Answer: b

5. Which has the lowest boiling point at 1 atm pressure?


(a) 0.1 M KCl
(b) 0.1 M Urea

(c) 0.1 M CaCl2


(d) 0.1 M A1Cl3

Answer

Answer: b
6. Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be
(a) 0.33
(b) 0.666
(c) 0.3 × 10-2
(d) 3

Answer

Answer: c

7. People add sodium chloride to water while boiling eggs. This is to


(a) decrease the boiling point.
(b) increase the boiling point.
(c) prevent the breaking of eggs.
(d) make eggs tasty.

Answer

Answer: b

8. The van’t Hoff factor (i) accounts for


(a) degree of solubilisation of solute.
(b) the extent of dissociation of solute.
(c) the extent of dissolution of solute.
(d) the degree of decomposition of solution.

Answer

Answer: b

9. Which relationship is not correct?

Answer

Answer: b

10. The molal elevation constant depends upon


(a) nature of solute.
(b) nature of the solvent.
(c) vapour pressure of the solution.
(d) enthalpy change.

Answer

Answer: b

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