S Block
S Block
03 s-Block
Introduction
The s-block elements of the Periodic Table are those in which the last electron enters in the outermost s-
orbital. As the s-orbital can accommodate only two electrons, two groups (1 & 2) belong to the s-block of
the Periodic Table. Group 1 of the Periodic table consists of the elements: lithium, sodium, potassium,
rubidium, cesium and francium. They are collectively known as the alkali metals. They are so called because
they form hydroxides on reaction with water which are strongly alkaline in nature. The elements of Group
2 include Beryllium, Magnesium, Calcium, Strontium, Barium and Radium. These elements with the
exception of beryllium are commonly known as the alkaline earth metals. They are so called because their
oxides and hydroxides are alkaline in nature and these metal oxides are found in the earth's crust.
Physical properties of s-Block Elements
The atomic, physical and chemical properties of alkali metals are discussed below.
Atomic and Physical Properties of the Alkaline Metals
Physical properties of s-Block Elements
ALKALI METALS ALKALINE EARTH METALS
Physical state
• One electron in outermost shell & General • Two electrons in outer most shell &
formula ns1. General formula ns2.
• Francium is radioactive element. • Radium is radioactive element.
• All are silvery white • All are silvery white.
• Light soft, malleable and ductile metals with • These metals are harder than alkali metals.
metallic lustre.
ALKALI METALS ALKALINE EARTH METALS
Atomic size
• Largest in their respective period (except • Smaller than IA group elements, since extra
noble gas element) charge on nucleus attracts the electron
• Size increases from Li to Cs due to addition of cloud.
an extra shell. • Size increases gradually from Be to Ba
Li < Na < K < Rb < Cs Be < Mg < Ca < Sr < Ba
IA IIA
Li Be In s-block elements
Na Mg Be has smallest size, while Cs has largest
K Ca size.
↓ ↓
Rb Sr
↓ ↓
Cs Ba
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Melting point & Boiling point Strength of metallic bond Number of valence shell e–
ALKALI METALS ALKALINE EARTH METALS
Ionisation energy (I.E.)
• First ionisation energy (I.E.) is very less • First ionisation energy is higher than IA
because of larger atomic size and only one group because of smaller atomic size and
electron in outer most shell. completely filled s-orbital (stable electronic
• Decreasing order of ionisation energy- configuration)
Li > Na > K > Rb > Cs • Decreasing order of ionisation energy–
• Second ionisation energy of alkali metals is Be > Mg > Ca > Sr > Ba
very high because by loosing one electron they • Second ionisation energy is lesser than IA
achieve inert gas configuration. group.
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Halides
• Alkali metals reacts directly with halogen to • Alkaline metals reacts with X (Halogen) to
form MX form MX2.
(M – alkalimetal, X – Halide ion) • Order of Ionic nature
• Ionic nature of MX increases from LiCl to CsCl BeCl2 < MgCl2 < CaCl2 < SrCl2 < BaCl2
• LiCl is covalent in nature (due to polarisation • Hydrolysis tendency of these halides
of Cl– ion by small Li+ ion). hence its tendency decreases from BeCl2 to BaCl2 due to
of hydrolysis is more. decrease in covalent nature.
• K, Rb and Cs halides reacts with more • BeCl2 and MgCl2 are covalent in nature.
halogens to gives polyhalides. BeO + C + Cl2 ⎯⎯
→ BeCl2 + CO
KI + I2 → KI3
CsBr + Br2 → CsBr3
Nitrides
• Only Li reacts directly with N2 to form nitride • All elements of II A burns in N2 to give M3N2
which gives NH3 on reacting with water. (nitrides)
6Li + N2 → 2Li3N For example :
Li3N + 3H2O → 3LiOH + NH3 Be3N2 + 6H2O → 3Be(OH)2 + 2NH3
Mg3N2 + 6H2O → 3Mg(OH)2 + 2NH3
Formation of amalgam
• Alkali metals gives amalgam with Hg. • Shows same properties.
• These metals reacts with other metals to give
mixed metals (alloys)
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BEGINNER’S BOX-1
1. Which of the following is soluble in organic solvents like ethanol?
(1) LiCl (2) NaCl (3) KCl (4) RbCl
2. Which of the following is the correct order of hydrated radii?
(1) Li+< Na+< K+< Rb+ < Cs+ (2) Rb+< Na+< Li+< Cs+ < K+
(3) Cs+< Rb+< K+< Na+ < Li+ (4) Li+< K+< Na+< Rb+ < Cs+
3. As compared to potassium, sodium has
(1) Lower electronegativity (2) Higher ionization potential
(3) Larger atomic radius (4) Lower melting point
4. Which of the following statement is correct regarding alkali metals
(1) All are black in colour (2) Cation is smaller in size than the parent atom
(3) Size of cation and parent atom is the same (4) Cation is greater in size than the parent atom
5. Which shows golden yellow colour in flame test ?
(1) Li (2) Ca (3) Na (4) Cs
6. Which of the following halides are ionic in nature ?
(1) BaX2 (2) CaX2 (3) SrX2 (4) All of these
7. Which of the following carbonates is the most thermally stable ?
(1) BeCO3 (2) MgCO3 (3) CaCO3 (4) BaCO3
8. Correct order of Hf of alkali metal fluorides
(1) LiF < NaF (2) KF < CsF (3) RbF < CsF (4) LiF > CsF
9. White metal is
(1) Li + Na (2) Li + Pb (3) Li + Mg (4) Na + K
() ()
10. LiNO3 ⎯⎯→ NaNO3 ⎯⎯→
Common paramagnetic gas in the above reactions
(1) O2 (2) N2 (3) NO2 (4) NO
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At cathode (Perforated steel) : 2H+ + 2e– → H2(g) At anode (Carbon) : 2Cl–(aq.) → Cl2(g) + 2e–
(b) Castner – Kellner Cell : (Hg – Cathode Process)
Electrolyte (Brine) NaCl Na+ + Cl -
On electrolysis –
At Cathode (Hg)
Na+ + e– → Na and Na + Hg → Na.Hg (amalgam)
At anode (Graphite)
2Cl– → Cl2(g) + 2e– and 2Na.Hg + 2H2O → 2NaOH + H2 + 2Hg
Properties :
i. It is deliquescent white crystalline solid.
ii. It absorbs CO2 from air forming Na2CO3.
iii. NaOH is strong base
SiO2
Na2SiO3 + H2O
NaOH
2NaAlO2 + H2O
Al2O3
iv. Reaction with non metals : No reaction with H2, N2 and C
B
Na3BO3 (sodium borate)
NaOH
Na2SiO3 (sodium silicate)
Si
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vi. The hydroxides of aluminium, zinc, lead and tin, however, dissolve in excess of sodium hydroxide
giving clear solution which can also be obtained when these metals are acted upon by the
concentrated solution of sodium hydroxide.
Uses (i) In the manufacture of soap, rayon, dyes, paper and drugs.
(ii) In petroleum refining.
Note: Potassium bicarbonate (KHCO3) cannot be prepared by Solvay process as it is more soluble in water
as compared to NaHCO3.
Properties of NaHCO3 :
(i) Hydrolysis NaHCO3 + H O 2 NaOH + H2CO3
(ii) Effect of heat (temp. > 100°C) 2NaHCO3 ⎯⎯→ Na2CO3 + H2O + CO2
(iii) Reaction with acids – gives CO2 NaHCO3 + HCl ⎯⎯→ NaCl + H2O + CO2
(iv) Reaction with bases NaHCO3 + NaOH ⎯⎯→Na2CO3 + H2O
Note: Reaction (iii) and (iv) explain amphoteric behaviour of NaHCO . 3
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(Calcium phosphate)
(iii) Reaction with carbon :
Uses of CaO :
(i) In the manufacture of bleaching powder, cement, glass, calcium carbide etc.
(ii) In the purification of sugar
(iii) As a drying agent for NH3 and C2H5OH
(iv) As basic lining in furnaces
(v) For making Soda lime [NaOH + CaO]
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CaCO3
⎯⎯ → CaCO3
Uses of Ca(OH)2
(i) For softening of hard water.
(ii) For purification of sugar and Coal gas.
(iii) In the manufacture of bleaching powder, Caustic soda and soda lime
(iv) In preparation of mortar, plaster and white washing.
Calcium Sulphate [Gypsum CaSO4.2H2O]
Preparation : CaSO4.2H2O is naturally occuring calcium sulphate. It can be obtained by the action of
dil.H2SO4 on a soluble calcium salt below 600C.
Properties of Gypsum
(i) Action of heat :
Properties of POP
(i) It is a white powder.
(ii) It has the property of setting to a hard mass when a paste with water is allowed to stand aside for
sometime.
(iii) When it is heated at 2000C, anhydrous CaSO4 is formed.
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Fe2O3(2.O%) Al2O3(7.5%)
Cement
KO2(1.5%) 100% MgO(2.5%)
SO3(1.5%) Na2O(1.5%)
(ii) Raw Materials
• Lime Stone – It provides CaO
• Clay – It provides Al2O3 and silica (SiO2)
• Gypsum – CaSO4·2H2O
(iii) Setting of cement : When water is mixed to cement and the mixture is left it becomes very hard.
This property of cement is called setting.
(iv) Mortar : It is a mixture of cement, sand and water to give a proper consistency.
(v) Concrete : A mixture of cement, Sand gravel and water is known as concrete.
(vi) Reinforced concrete cement (RCC) : When concrete is filled in beams made of iron bars, it is
called RCC. Iron imparts extra strength to the structure.
Biological role of sodium, potassium, magnesium and calcium
(From Biology portion)
Normally % of abundance in human body – K > Na > Fe > Cu
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BEGINNER’S BOX-2
Que. 1 2 3 4 5 6 7 8 9 10
BEGINNER'S BOX-2
Ans. 2 2 3 2 2 2 1 3 4 2
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