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Model Question Module 2

The document contains a series of questions related to spectroscopy techniques, covering topics such as UV-visible spectra, NMR, IR spectra, and molecular characterization. It includes inquiries about specific molecules, spectral properties, and calculations related to spectroscopy. The questions aim to assess understanding of fundamental concepts and applications in spectroscopy.

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ece2023011
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5 views2 pages

Model Question Module 2

The document contains a series of questions related to spectroscopy techniques, covering topics such as UV-visible spectra, NMR, IR spectra, and molecular characterization. It includes inquiries about specific molecules, spectral properties, and calculations related to spectroscopy. The questions aim to assess understanding of fundamental concepts and applications in spectroscopy.

Uploaded by

ece2023011
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Model Question

Module 2: Spectroscopy technique

1. Most of the absorption band in UV-visible spectra are very broad. Give reason.
2. Why 1,3- Butadiene possess higher max value than that of ethane?
3. Why sky color is blue?
4. Predict the proton NMR spectra of CH4.
5. What kind of molecules shows IR spectra? “IR spectra are often characterized as molecular
finger prints”. Justify statement.
6. Intensity of spectral line depends on which factor? What is Lambert – Beer Law?
7. What do you mean by shielding and deshielding effects involved in NMR spectroscopy?
8. Give that the spacing of the lines in microwave spectrum of 27Al 1H is constant at 12.604 cm-1.
Calculate the moment of inertia and bond length of the molecule. (Mass of 27Al is 26.981 amu).
9. Predict the kind of electronic transition in Cl2 and carbonyl group. Also give their intensity.
10. Name of any four surface characterization technique.
11. How do you account for the effect of polar solvents on (i)  and (ii) n transitions?
12. How many kinds of 1H are present in the following molecules? (i) C6H5-CH3 (ii) CH3-
CH=CH2 (iii) Ethanol.
13. What is fingerprint region range in IR spectra?
14. How many methyl peaks would you expect to observe in the 1H NMR spectrum of cis-1,4-
dimethylcyclohexane?
15. What does MRI stands for?
16. A strong signal at 1700 cm–1 in an IR spectrum indicates the presence of________________.
17. IR spectra can detects_____________.
18. Whether molecule B will have higher or lower carbonyl stretching frequency compared to molecule
A? Justify your answer.

19. What do you mean by shielding and deshielding effects involved in NMR spectroscopy?
20. Calculate the force constant for the bond in HCl from the fact that fundamental vibrational
frequency is 8.667×1013 s-1.
21. Write the principle and applications of NMR and MRI.
22. Explain trans-stillbene absorbs at a longer wavelength than cis-stillbene.
23. IR spectra detects---------
24. Explain vibrational and rotational spectroscopy for diatomic molecules.

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