24-07-2024

6201CJM11SCHOOL124006 JM

PHYSICS

SECTION-I

1) The angle between two vectors

(A) is acute angle

(B) is obtuse angle
(C) lies between 60° and 120°
(D) depends on x

2) A vector of magnitude units makes equal angles 53° each with X and Y axes. Its component
along z axis :

(A) 1.2 units

(B) 1.4 units
(C) 1.6 units
(D) 1.8 units

3) Find the ratio of average speed and magnitude of average velocity of tip of minute hand in 20
minutes :

(A)

(B)

(C)

(D) None of these

4) A particle is moving towards east with velocity 8 m/s and acceleration 4 m/s2 directed towards
west. Find the distance travelled in 6 seconds.

(A) 40 m
(B) 24 m
(C) 32 m
(D) 16 m

5) Which car is ahead just after they leave the starting point?
(A) P
(B) Q
(C) Both P and Q move simultaneous
(D) Data insufficient

6) At what time both the cars are at the same point again?

(A) 2 seconds
(B) 3 seconds
(C) 2 or 3 seconds
(D) Never

7) At what instants the distance between P and Q neither increasing nor decreasing?

(A) 2 seconds
(B) 3 seconds
(C) 2 and 3 seconds
(D) Never

8) If and then find the angle between the vectors

in degrees.

(A) 0°
(B) 45°
(C) 120°
(D) 90°

9) Two force = 500 N due east and = 250 N due north are acting on a body. The magnitude of
is :-

(A) 250 N
(B) 500 N
(C) N
(D) 750 N

10) Find the angle between the vectors and :

(A) 0°
(B) 120°
(C) 90°
(D) 60°

11) If x = at2 and y = 2at, then

(A) t
(B) 1

(C)

(D) 0

12) Evaluate the

(A)

(B)

(C)

(D)

13) Velocity of a particle varies with time as v = 4t. The displacement of particle between t = 2 to t
= 4 sec, is

(A) 12 m
(B) 36 m
(C) 24 m
(D) 6 m

14) Slope of given straight line is :-

(A)

(B)

(C)
(D) –1

15) =?

(A)

(B)
(C)

(D)

16) A particle moving in a straight line covers half the distance with a speed of 3 m/s. The other half
of the distance is covered in two equal time intervals with speeds of 4.5 m/s and 7.5 m/s respectively.
The average speed of the particle during this motion is :

(A) 4.0 m/s

(B) 5.0 m/s
(C) 4.8 m/s
(D) 5.5 m/s

17)

Area of shaded region of graph is :

(A) 3a2
(B) a3
(C) 3a3
(D) 4a3

18) a = 2, b = 5 and then is equal to:

(A) 6
(B) 4
(C) 3
(D) 5

19) A person pushes a box kept on a horizontal surface with force of 100 N. In unit vector notation

force can be expressed as :

(A) 100

(B) 100
(C)
(D)

20) The vector has components +5 and +7 along the x-axes and y-axes, respectively. Along a set
of axes rotated 90° counterclockwise relative to the original axes, the vector’s components are :

(A) –7 ; –5
(B) 7 ; –5
(C) –7 ; 5
(D) 7 ; 5

SECTION-II

1) The speed versus time graph for a particle is shown in figure. The distance travelled (in m) by the

particle during the time interval t = 0 to t = 5 will be ___.

2) If the velocity of a body related to displacement x is given by then the

acceleration of the body is ___ m/s2.

3) The sum of two unit vectors and is also equal to a unit vector. Then the magnitude of the
vector is . The value of x is

4) Angle between the two vectors and is . Find the value of n :-

5) If y = x3 then = nx. Find n?

6) A force of 30 N is inclined at an angle θ to the horizontal. If the vertical component is 18 N. Then

the horizontal component is ___.

7) The radius of a circular plate increases at the rate of 0.1 cm per second. At what rate does the
area increase when the radius of plate is (in cm2/s)

8) . Find 10A.

9) Find the value of x for which the function y = x3 – 3x2 + 2 is maximum?

10) Area bounded the curve y = sin x and x-axis on the interval [0, π] is ___.

CHEMISTRY

SECTION-I

1) In the sixth period, the orbitals that are filled are

(A) 6s, 5f, 6d, 6p

(B) 6s, 4f, 5d, 6p
(C) 6s, 5d, 5f, 6p
(D) 6s, 6p, 6d, 6f

2) Similarity in chemical properties of the atoms of elements in a group of the periodic table is most
closely related to :

(A) number of principal energy levels

(B) atomic numbers
(C) number of valence electrons
(D) atomic masses

3) In which of the following pairs, the outermost electronic configuration will be the same?

(A) Cr+ and Mn2+

(B) Ni2+ and Cu+
(C) Fe2+ and Co+
(D) V2+ and Cr+

4) The IUPAC group number, number of valence electrons and valency of an element with atomic
number 15, respectively, are

(A) 16, 5 and 2

(B) 15, 5 and 3
(C) 16, 6 and 3
(D) 15, 6 and 2

5) The electronic configuration of transition elements is exhibited by :

(A) ns0–2(n–1)d1–10
(B) ns2(n–1)d10
(C) (n–1)d10s2
(D) ns2np5

6) The electronic configuration of two neutral elements A and B are A = 1s22s22p63s1 and B =
1s22s22p5. The type of compound formed by the element is

(A) A+B–
(B) A–B+
(C) A – B
2+ –
(D) A (B )2

7) Match List-I with List-II :

List-I
List-II
Electronic configuration
IE1 in kJ/mol
of elements

(a) 1s22s2 (i) 801

(b) 1s22s22p4 (ii) 899

(c) 1s22s22p3 (iii) 1314

(d) 1s22s22p1 (iv) 1402

Choose the most appropriate answer from the options given below :
(A) (a) → (ii), (b) → (iii), (c) → (iv), (d) → (i)
(B) (a) → (i), (b) → (iv), (c) → (iii), (d) → (ii)
(C) (a) → (i), (b) → (iii), (c) → (iv), (d) → (ii)
(D) (a) → (iv), (b) → (i), (c) → (ii), (d) → (iii)

8) The group having iso-electronic species is :

(A) O2–, F–, Na+, Mg2+

(B) O–, F–, Na, Mg+
(C) O2–, F–, Na, Mg2+
(D) O–, F–, Na+, Mg2+

9) The set of elements that differ in mutual relationship from those of the other sets is :

(A) Li-Mg
(B) B-Si
(C) Be-Al
(D) Li-Na

10) The electron gain enthalpy (in kJ/mol) of fluorine, chlorine, bromine and iodine respectively, are :

(A) –333, –325, –349 and –296

(B) –296, –325, –333 and –349
(C) –333, –349, –325 and –296
(D) –349, –333, –325 and –296

11) The electron affinity of fluorine is less than that of chlorine because :

(A) The incoming electron enters the 3p orbital in fluorine.

(B) The incoming electron enters the 2p orbitals in fluorine and 3p orbital in chlorine.
(C) The electron density in fluorine is higher.
(D) Fluorine has lower ionisation potential than chlorine.

2– – + 2+
12) The ionic radii of O , F , Na and Mg are in the order

(A) O2– > F– > Mg2+ > Na+

(B) Mg2+ > Na+ > F– > O2–
(C) O2– > F– > Na+ > Mg2+
(D) F– > O2– > Na+ > Mg2+

13) The IP1, IP2, IP3, IP4 and IP5 of an element are 7.1, 14.3, 34.5, 46.8, 162.2 eV respectively. The
element is likely to be :

(A) Na
(B) Si
(C) F
(D) Ca

14) Second electron affinity of an element is

(A) always exothermic

(B) endothermic for few elements
(C) exothermic for few elements
(D) always endothermic

15) Hybridisation of carbon * marked is

(A) sp
(B) sp2
(C) sp3
(D) sp3d

16) The hybridization of nitrogen atom in are

(A) sp, sp3 and sp2 respectively

(B) sp, sp2 and sp3 respectively
(C) sp2, sp and sp3 respectively
(D) sp2, sp3 and sp respectively

17) Which of the following T-shape

(A) XeO3
(B) CℓF3
(C) XeOF4
(D) XeF2

18)

An ionic bond can be formed between two atoms when

(A) One of them has a low ionization energy and the other a high electron affinity
(B) Both the atoms have low values of ionization energy
(C) Both the atoms have high values of ionization energy
(D) Both the atoms have low values of electron affinity

19) The structure of PCl5 in the solid state is :

(A) Square pyramidal

⊕ ⊝
(B) Tetrahedral [PCl4] and octahedral [PCl6]
⊕ ⊝
(C) Square planar [PCl4] and octahedral [PCl6]
(D) Trigonal bipyramidal

20) Sum of σ and π-bonds in NH4+ cation is

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-II

1) If the effective nuclear charge on the valence electron in carbon be x, then the value of 100x is
___.
2) Total number of gaseous elements in the long form of periodic table is ___.

3) Calculate E.N of chlorine atom on Pauling scale if I.E of Cl– is 4eV and of E.A of Cl+ is +13.0 eV?
(Nearest Integer)

4) Write the total number of elements (upto atomic number = 10), which have positive electron gain
enthalpy (EGE1)?

5) The electronic configuration of an element [X] is 1s2 2s2 2p6 3s2 3p4. The difference in atomic
number (Z) and the IUPAC group number (N) of the element [Y], which is just below the element [X]
in the periodic table i.e., (Z – N) is ___.

6) If each orbital can hold a maximum of three electrons, the number of elements in 9th period of
periodic table (long form) is ___.

7) Total number of acidic oxides among N2O3, NO2, N2O, Cl2O7, SO2, CO, CaO, Na2O and NO is ____.

8) The atomic number of the element unnilennium is ___.

9) The electronegativities of X and Y are 4.0 and 2.0 respectively. The percent ionic character
rounded off to nearest integer in X – Y bond is ___.

10) Find the number of atoms are lying in the same plane of C2(CN)4.

MATHEMATICS

SECTION-I

1) The number of real roots of the equation |x|2 + 8|x| + 15 = 0 is :

(A) 0
(B) 3
(C) 2
(D) 1

2) Number of real solutions of the equation is

(A) 4
(B) exactly 2
(C) exactly 1
(D) None of these
3) For defined values of a, b, c expression has the value equal
to :

(A) 1/2
(B) 1
(C) 2
(D) 4

4) where is

(A) a negative integer

(B) a prime integer
(C) a positive integer
(D) an even-natural number

5) The number when simplified reduces to :

(A) a real number which is more than log2e

(B) a real number which is less than log3π
(C) a real number which is less than logπ3
(D) None of these

6) Identify the correct order :

(A) log26 < log38 < log36 < log46

(B) log26 > log38 > log36 > log46
(C) log38 > log26 > log36 > log46
(D) log38 > log46 > log36 > log26

7) The square root of the product of the roots of the equation 9x2 – 18|x| + 5 = 0 is

(A)

(B)

(C)

(D)

8) The sum of squares of all the real solutions of the equation, x2 – |x| – 12 = 0 is :

(A) 21
(B) 23
(C) 25
(D) 27

9) The solution set of the inequality is

(A) (2, 6)
(B) (2, 6) U (8 ,10)
(C) (–1, 0) U (2, 6)
(D) (0, 6)

10) The solution set of the inequality is

(A) (–∞, –2)U(1, ∞)

(B) (1, ∞)
(C) (–∞, –2)
(D) (–2, 1)

11) The solution set of the inequality is

(A) (–1, 2)
(B) (–1, 0)U(1, 2)
(C) (3, 2)
(D) (0, 2)

12) The solution set of the inequality log1/2(2x – 1) < 2, is

(A)

(B)

(C)

(D)

13) Total number of integer satisfying the inequality log2(2x – 5) < 3, is

(A) 2
(B) 3
(C) 4
(D) None of these
14) Find the value of x, log4(x + 3) – log4(x – 1) = log48 – 2.

(A) 0
(B) 1
(C) 2
(D) No values

15) The total number of values of x and y satisfying the equation log10x + log10y = log106, such that x
and y are positive integers.

(A) 3
(B) 6
(C) 4
(D) 8

16) The value of 'a' for which the sum of the squares of the roots of x2 – 2(a – 2)x – a – 1 = 0 is least

(A) 7

(B)

(C)

(D)

17) Graph of y = ax2 + bx + c, is given adjacently. What conclusions can be drawn from this graph?

(A) a = 0
(B) b > 0
(C) c < 0
(D) None of these

18) The adjoining figure shows the graph of y = ax2 + bx + c, then

(A) a > 0
(B) b > 0
(C) b2 < 4ac
(D) None of these

19) The number of integral values of m for which the quadratic expression
(1+2m)x2–2(1+3m)x+4(1+m), has imaginary roots.

(A) 3
(B) 6
(C) 7
(D) 8

20) If α and β are the roots of the equation 7x2 – 3x – 2 = 0, then the value of is equal to

(A)

(B)

(C)

(D)

SECTION-II

1) Let the sum of all the solution of the equation, be 'm', then the
value of 4m is equal to ___.

2) The expression has the value equal to ___.

3) The value of x satisfying the equation is x1, then the value of is ___.

4) Let x and y be the solution of the equation Then the

value of y – x is ___. (where x < 0 and y > 0)

5) The number of solutions of the equation log(x+1)(2x2 + 7x + 5)+log(2x+5)(x+1)2 – 4 = 0, x > 0 is ___.

6) If log2 log2 log5x = 0, then the value of x is ___.

7) If Then the value of x is ___.

8) The number of the real roots of the equation is ___.

9) The sum of the solution of the equation is ___.

10) The least positive value of 'a' for which the equation has real roots is
___.
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C B A A A D C D C C C B C B B A B A C B

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 25 50 3 6 6 24 1 5 0 2

CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. B C A B A A A A D C C C B D A B B A B D

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 325 11 3 4 18 75 4 109 46 10

MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. A B B C B B A C A C B C C D C B C B C B

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 1 3 3 30 1 25 3 2 1 8
 SOLUTIONS

PHYSICS

1)

2)

3)

Distance = Rθ = R.2π/3
Displacement

4)

v = u + at
v = 0 at t = 2 sec
t = 0 to t = 2
S = ut + 1/2 at2
= 8(2) + 1/2 (–4)(2)2 = 8 m
t = 0 to t = 6
S = ut + 1/2 at2
= 0 + 1/2 (4) (4)2 = 32 m.

5)

vP = 40 + 6t2
vQ = 4 + 30t
At, t = 0, vP > vQ

6)

xP = xQ
40t + 2t3 = 4t + 15t2
2t2 – 15t + 36 = 0
No real roots for the quadratic equation.

7)

Distance between the cars

D = xP – xQ
= 36t + 2t3 – 15t2

0 = t2 – 5t + 6
t = 2, 3

8)

Let and

Angle between is given by

9) ,
=
=
= = 250 N

10)

Since
So angle between and is 90°

11)

12)

13)
 14)

Slope = m = tan θ = tan 30° =

15)

16)

Let the total distance be S. The time taken to travel the first half, i.e., S/2 is .
Let t2 be the time taken to cover a distance S1 with speed 4.5 m/s and t3 that to cover distance S2
with speed 7.5 m/s.
Total time taken

18)

19)

20)
A vector rotated in counter clockwise by 90°. So, components also rotated by 90°.

21)

Area under speed-time graph gives distance.

Distance = 1/2 × 5 × 10 = 25 m

22)

23)

∴ Angle between and is 120°.

24)

cosθ = = θ = 30º

25)

y = x3

= 3x2 ⇒ = 6x

26)

30 sinθ = 18

Horizontal component

27)
 28)

Let

29) = 3x2 – 6x = 0
⇒ 3x(x – 2) = 0
∴ x = 0 or x = 2

= 6x – 6

for x = 0; = – 6 = –ve
Hence y is maximum at x = 0

for x = 2; = 6 = +ve
Hence y is minimum at x = 2

30)

CHEMISTRY

31)

Filling of electrons in orbitals in any period takes place as :

ns(n – 2)f(n –1)d np if possible.
Therefore, as per (n + ) rule for sixth period n = 6, orbitals that are filled are 6s, 4f, 5d, 6p.

32)

Chemical properties of the atoms of elements in a group depends on number of valence electrons.

33)

Iso-electronics have same electronic configuration.

34)

The group number, number of valence electrons and valency of an element with atomic number 15
are 15, 5 and 3 respectively. Modern periodic table is based on the atomic number.
Number of valence electrons present in an atom decides the group number.
Electronic configuration of element having atomic number
15 =1s2 2s2 3s2 3p3 (Valence electrons)
As five electrons are present in valence shell, its group number is 15.
Valency of element having atomic number 15 is +3 (8 – 5 =3).

35)

Conceptual

36)

a/c to octet rule,

A = 1s2 2s2 2p6 3s1 (stable)
A+ = 1s2 2s2 2p6 (stable)
B = 1s2 2s2 2p5 (unstable)
B– = 1s2 2s2 2p6 (stable)

37)

1s2 2s2 → Be
1s2 2s2 2p4 → O
1s2 2s2 2p3 → N
1s2 2s2 2p1 → B
The IE1 order of above 4 element is Be (899) > B(801) < N(1402) > O(1314)

38)

Iso-electronic species are those which contains same number of electrons.

Species Atomic Number Number of electrons

O2– 8 10

F– 9 10

Na+ 11 10

Mg2+ 12 10

O– 8 9

Na 11 11

Mg+ 12 11

39)

Li → Mg, B → Si and Be → Al show diagonal relationship.

40)

Order of electron gain enthalpy (magnitude) is F < Cl > Br > I.

41)
Conceptual

42)

O2–, F–, Na+ and Mg2+ are iso-electronic species.

Ionic O2– F– Na+ Mg2+

Number of e– 10 10 10 10
For iso-electronic species,

43)

Suddenly jump in IP values from IP4 and IP5, indicates it contains four valence electrons.

44)

In the process of adding further electron, the second electron will be added to gaseous anion against
the electrostatic repulsion between the electron being added and the gaseous anion.
Energy instead of being released is supplied for the addition of an electron to an anion.

49)

50)

Conceptual

51)

Z* = Z – σ
σ = 1s2, 2s2, 2p2
(1s)2 (2s, 2p)4
σ = (3 × 0.35) + (2 × 0.85)
= 1.05 + 1.70 = 2.75
Z* = Z – σ
= 6 – 2.75
= 3.25

52)

The 11 gaseous elements are H2, N2, O2, F2, Cl2, He, Ne, Ar, Kr, Xe and Rn.

53)
 54)

He, Be, N and Ne have +ve EGE1.

55)

1s2 2s2 2p6 3s2 3p4

[X] = S
[Y] = Se
[Z] = 34
[N] = 16
Atomic number – Group number
(Z – N) = 34 – 16 = 18

56)

In 9th period, the sub-shells filled with e– are s, p, d, f, g

–
9s → 3e
9p → 9e–
8d → 15e–
7f → 21e–
6g → 27e–

57)

Acidic oxides Basic oxides Neutral oxide

N2O3 Na2O N2O

NO2 CaO NO

Cl2O7 CO

SO2

58)

Theoretical

59)

% ionic character = 16(4.0 – 2.0) + 3.5(4.0 – 2.0)2 = 46

60)
MATHEMATICS

61) (Reference to B.B-03) Moderate

Case-1:
x≥0
x2 + 8x + 15 = 0
(x + 5) (x + 3) = 0
x = –5, –3
Case-2:
x<0
x2 – 8x + 15 = 0
(x – 3) (x – 5) = 0
x = 3, 5
Hence, the equation consists no solutions.

62) (Reference to Ex.1 ,Q.7)Tough

as x can only take negative values |x| = –x

Squaring both sides

Either, log10(–x) = 0
–x = 1
x = –1
(or)
log10(–x) = 1
–x = 10
x = –10

63) (Reference to Ex.1 ,Q.10) Easy

Hence, the expression can be rewritten as

logabcabc = 1

64) (Reference to Ex.1 ,Q.14) Moderate

Therefore, A = B

65) (Reference to Ex.1, Q.8) Moderate

Hence N can be rewritten as

66) (Reference to Ex.01, Q.8) Moderate

log38 > log36 (strong base)

Hence, 2m = 3t
m>t
log26 > log36
log33 < log38 < log39
1 < log38 < 2
and
log24 < log26 < log28
2 < log26 < 3
1 < log38 < 2 < log26 < 3
The correct order is
log26 > log38 > log36 > log46.

67)
(Reference to Ex.4a/b, Q.02) Easy
9|x|2 – 15|x| – 3|x| + 5 = 0 (since, x2 = |x|2)

Product of roots =25/81, Square root = 5/9

68) (Reference to Ex.4a/b, Q.5) Easy

Case-1:
x≥0
x2 – x – 12 = 0
(x – 4) (x + 3) = 0
x = 4, x = –3
Therefore, x = 4
Case-2:
x<0
x2 + x – 12 = 0
(x + 4) (x – 3) = 0
x = –4, x = 3
Therefore, x = –4
Sum of squares (4)2 + (–4)2 = 32

69) (Reference to B.B-03) Tough

Case-1:
x≥0

Therefore, x ϵ (2, 6)
Case-2:
–2 ≤ x < 0

Therefore, no solution
Case-3:
x < –2

Therefore, no solution
 70) (Reference to B.B-08) Easy

(as strong base)

Also,

On taking intersection solutions (–∞, –2)

71) (Reference to B.B-05) Easy

2–x>0
x<2

Solving overall inequality

(Weak base)

(–1, 0)U(1, ∞)
Taking intersection of all the three sets x < 2 and x > –1 and (–1, 0) and (1, ∞).

72)

(Reference to illustration) Easy

.... (i)

Also,

.... (ii)
By (i) and (ii)

73)
(Reference to illustration) Easy
2x – 5 > 0 and 2x – 5 < 8

x = 3, 4, 5, 6

74)

(Reference to illustration) Easy

log4(x + 3) – log4(x – 1) = log48 – 2 .... (i)

2x + 6 = x + 1
x = –5
Since, x = –5 does not satisfy the equation (i).
Hence, there is not value of x
x ϵ Φ.

75)

(Reference to Ex.01, Q8) Easy

log10x.y = log106
xy = 6
either x = 1, y = 6
x = 2, y = 3
x = 3, y = 2
x = 6, y = 1

76) (Reference to Ex.01, Q.17) Moderate

Let the roots are α and β.
Sum of square of roots are

(2(a–2))2 – 2(–a–1)
2(2(a–2)2 + a + 1)
2(2a2 + 8 – 8a + a + 1)
2(2a2 – 7a + 9)

77) (Reference to Ex.01, Q.4) Easy

From the graph a > 0.
c → y intercept which is negative.

78) (Reference to Ex.01, Q.6) Easy

a<0

Real and distinct roots means b2 – 4ac > 0.

b2 > 4ac

79) (Reference to Ex.01, Q.16) Tough

All integral values of m.

m = {0, 1, 2, 3, 4, 5, 6}

80) (Reference to Ex.01, Q.24) Tough

7x2 – 3x – 2 = 0

81) (Reference to Ex.03, Q.2) Easy

Let log10x = t

then,

Either,

(or)
 4m = 1

82) (Reference to Ex.03, Q.3) Easy

83) (Reference to Ex.03, Q.10) Moderate

84) (Reference to Ex.03, Q.13) Tough

y = 2|x|
|x + 2|x|| = 0
Case-1:
x≥0
|x + 2x| = 10
3x = 10

Case-1:
|x| = –x
|x – 2x| = 10
|–x| = 10 = –x
x = –10 and y = 20
y – x = 20 + 10 = 30

85)

(Reference to Jee-Main 2021) Tough

 86)

(Reference to illustration 39) Easy

log2 log2 log5x = 0
log2 log5x = 1
log5x = 2
x = 52 = 25

87)

(Reference to illustration-40) Easy

2log3[1+log2(1+3log3x)] = 2
1 + log2(1+3log3x) = 3
log2(1+3log3x) = 2
1 + 3log3x = 4
3log3x = 3
log3x = 1
x=3

88)

(Reference to illustration-43) Moderate

 89)

(Reference to Jee-Main 2021) Moderate

x2 – x – 6 = 0
(x – 3) (x + 2) = 0
x = 3, –2

90)

(Reference to Jee-Main 2020) Moderate

D≥0