Bohr's model

1. The energy of an electron in the first Bohr orbit of hydrogen atom is

-2.18×10-18 J Its energy in the third Bohr orbit is____
A. 1/9 th of the value
B. 1/27 of this value
C. Three times of this value
D. One third of this value

2. The electron in the nth orbit of LI2+ is excited to (n + 1) orbit using the radiation
of energy 1.47 × 10-17 J (as shown in the diagram). The value of n is ___.

Given : RH = 2.18 × 10-18 J

3.
If the radius of the first orbit of H atom is a0, then the de Broglie’s wavelength
of electron in third orbit is
𝜋𝑎0
A. 6
𝜋𝑎0
B. 3
C. 6𝜋𝑎0
D. 3𝜋𝑎0
4. Maximum number of electrons that can be accommodated in shell with n =
4 are:
A. 16
B. 32
C. 50
D. 72

5. The energy of one mole of photons of radiation of frequency

2 × 1012 Hz in Jmol−1 is _____ .
(Nearest integer)
(Given: h=6.626 × 10−34 JsNA = 6.022 × 1023 mol−1

6. Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6Å. The
radius of the third Bohr orbit of He+ is _____ picometer. (Nearest Integer)

7. The radius of the 2nd orbit of Li2+ is x. The expected radius of the 3nd orbit
of Be3+ is
9
A. 4 𝑥
4
B. 9 𝑥
27
C. 16 𝑥
16
D. 27 𝑥

8. If wavelength of the first line of the Paschen series of hydrogen atom

is 720 nm, then the wavelength of the second line of this series is
_______nm. (Nearest integer)
Dual Behaviour of Matter and Heisenberg Uncertainty Principle

9. Values of work function (W0) for a few metals are given below
Metal Li Na K Mg Cu Ag
𝑊0
2.42 2.3 2.25 3.7 4.8 4.3
𝑒𝑉

The number of metals which will show photoelectric effect when light of
wavelength 400 nm falls on it is _____
Given : h = 6.6 × 10-34 J s
c = 3 × 108 ms-1
e = 1.6 × 10-19 C

10. Given below are two statements : one is labelled as Assertion A and the other
is labelled as Reason R :
Assertion A: In the photoelectric effect, the electrons are ejected from the
metal surface as soon as the beam of light of frequency greater than
threshold frequency strikes the surface.
Reason R : When the photon of any energy strikes an electron in the atom,
transfer of energy from the photon to the electron takes place. In the light of
the above statements, choose the most appropriate answer from the options
given below :
A. Both A and R are correct and R is the correct explanation of A

B. A is correct but R is not correct

C. Both A and R are correct but R is NOT the correct explanation of A

D. A is not correct but R is correct

11. The wavelength of an electron of kinetic energy 4.50 × 0−29 J is __×10–5 m.
(Nearest integer) Given: mass of electron is
9 × 10–31 kg, h = 6.6×10–34 Js

12. Electrons in a cathode ray tube have been emitted with a velocity of 1000
ms−1. The number of following statements which is/are true about the emitted
radiation is
Given: h = 6 × 10−34Js, me = 9 × 10−31 kg
(A) The de Broglie wavelength of the electron emitted is 666.67 nm
(B) The characteristic of electrons emitted depend upon the material of the
electrodes of the cathode ray tube.
(C) The cathode rays start from cathode and move towards anode.
(D) The nature of the emitted electrons depends on the nature of the gas
present in cathode ray tube.

Quantum mechanical model

13. Given below are two statements Statement I : According to Bohr’s model of
hydrogen atom, the angular momentum of an electron in a given stationary
state is quantised. Statement II : The concept of electron in Bohr’s orbit,
violates the Heisenberg uncertainty principle. In the light of the above
statements, choose the most appropriate answer from the options given
below
A. Statement II is incorrect but Statement II is correct
B. Both Statement II and Statement II are correct
C. Both Statement II and Statement II are incorrect
D. Statement II is correct but Statement II is incorrect
14. The orbital angular momentum of an electron in 3 s orbital is xh/2π. The value
of x is (nearest integer)

15. The number of correct statements from the following is ...........

A. For 1s orbital, the probability density is maximum at the nucleus
B. For 2s orbital, the probability density first increases to maximum and then
decreases sharply to zero.
C. Boundary surface diagrams of the orbitals encloses a region of 100%
probability of finding the electron.
D. p and d -orbitals have 1 and 2 angular nodes respectively
E. probability density of p -orbital is zero at the nucleus

16. For a metal ion, the calculated magnetic moment is 4.90 BM. This metal ion
has _______ number of unpaired electrons

17. The number of atomic orbitals from the following having 5 radial nodes is
7s, 7p, 6s, 8p, 8d
18. Arrange the following orbitals in decreasing order of energy.
A. n = 3, l = 0, m = 0
B. n = 4, l = 0, m = 0
C. n = 3, l = 1, m = 0
D. n = 3, l = 2, m = 1
The correct option for the order is:
A. D > B > C >A
B. B>D>C>A
C. A>C>B>D
D. D>B>A>C

19. The wave function (Ψ) of 2 s is given by

1
1 1 2 𝑟
𝛹2𝑠 = ( ) (2 − 𝑎 ) 𝑒 −𝑟/2𝑎0
2√2𝜋 𝑎0 0

At r = r0, radial node is formed. Thus, r0 in terms of a0

A. r0 = a0
B. r0 = 4a0
𝑎
C. 𝑟0 = 20
D. R0 = 2a0

20. The number of given orbitals which have electron density along the axis is
px, py, pz, dxy, dyz, dxz, 𝑑𝑧2 , 𝑑𝑥 2−𝑦 2

Atomic Mass and Atomic Size

21. The total number of isoelectronic species from the given set is ________.
O2−, F–, Al, Mg2+, Na+, O+, Mg, Al3+, F
22. Which of the following sets of ions represents a collection of isoelectronic
species?
(Given : Atomic Number : F : 9, C1 : 17, Na = 11
Mg = 12, A1 = 13, K = 19, Ca = 20, Sc = 21)

A. Li+, Na+, Mg2+, Ca2+

B. Ba2+, Sr2+, K+, Ca2+
C. N3-, O2-, F-, S2-
D. K+, Cl-, Ca2+, Sc3+

Hydrogen spectrum

23. The number of following statement/s which is/are incorrect is ______

A. Line emission spectra are used to study the electronic structure
B. The emission spectra of atoms in the gas phase show a continuous spread
of wavelength from red to violet.
C. An absorption spectrum is like the photographic negative of an emission
spectrum
D. The element helium was discovered in the sun by spectroscopic method

24. Which transition in the hydrogen spectrum would have the same wavelength
as the Balmer type transition from n = 4 to n = 2 of He+ spectrum

A. n = 2 to n = 1
B. n = 1 to n = 3
C. n = 1 to n = 2
D. n = 3 to n = 4

25. The shortest wavelength of hydrogen atom in Lyman series is λ. The longest
wavelength in Balmer series of He+ is
5
A. 9𝜆
9𝜆
B. 5
36𝜆
C. 5
5𝜆
D. 9
26. It is observed that characteristic X-ray spectra of elements show regularity.
When frequency to the power 'n' i.e. vn of X-rays emitted is plotted against
atomic number Z , the following graph is obtained.

The value of ‘n’ is

A. 1
B. 2
C. 1/2
D. 3

Electronic configuration

27. Given below are two statement : one is labelled as Assertion A and the other
is labelled as Reason R Assertion A : 5f electron can participate in bonding to
a far greater extent than 4f electrons
Reason R : 5f orbitals are not as buried as 4f orbitals
In the light of the above statements, choose the correct answer from the
options given below
A. A is false but R is true
B. Both A and R are true and R is the correct explanation of A
C. A is true but R is false
D. Both A and R are true but R is NOT the correct explanation of A
 Solution
1. 1. (A)
2. 2. (1)
3. 3. (C)
4. 4. (B)
5. 5. (798)
6. 6. (270)
7. 7. (C)
8. 8. (492)
9. 9. (3)
10. 10. (B)
11. 11. (7)
12. 12. (2)
13. 13. (B)
14. 14. (0)
15. 15. (3)
16. 16. (4)
17. 17. (3)
18. 18. (A)
19. 19. (D)
20. 20. (5)
21. 21. (5)
22. 22. (D)
23. 23. (1)
24. 24. (A)
25. 25. (B)
26. 26. (C)
27. 27. (B)
28.