Agilent 7800 Manual
Agilent 7800 Manual
General Precautions 28
General Precautions
The Agilent ICP-MS is a very safe instrument with many built-in protective
C AU T I O N features:
• A safety interlock shuts off the plasma if either of the top covers is opened
during operation.
• A plasma viewing window provides eye protection.
• Sensors monitor the water and argon flow rate and pressure. If the water
flow is too low to sufficiently cool the ICP-MS, or if the argon supply is
insufficient, the plasma is turned off automatically.
• There are fans to help ensure that the instrument's internal temperature
stays within the preset limits. The plasma is turned off automatically if any
of these fans, except the QP fan, fail.
• Temperature sensors on the exhaust vent, instrument inside, and intake
water line stop the plasma if overheating occurs.
• A manual switch shuts down the instrument immediately, even if the
MassHunter Workstation is inoperable.
In case of uncertainty about a specific fluid, that fluid should not be used until
C AU T I O N confirmation by the manufacturer that it will not present a Hazard.
The bundled power supply cable and foreline pump power supply cable are for
C AU T I O N use exclusively with the ICP-MS. Do not use them for other devices or
instruments.
To shut down the instrument quickly, turn OFF the main switch located on the
NOTE lower center of the front panel. To switch the instrument to Standby mode and/or
Shutdown mode without using MassHunter Workstation, a “Vacuum ON/OFF
Switch” is available on the front panel inside. For positioning of the Vacuum
ON/OFF Switch, refer to Figure 1 on page 13.
• A sensor monitors the radio frequency (RF) generator and shuts it down if it
C AU T I O N is improperly matched to the RF coil.
• A fiber-optic sensor shuts off the RF high voltage power whenever the
plasma is not present or is turned off manually.
The ICP-MS MassHunter Workstation displays warning messages when the
sensors first detect a problem, enabling you to stop work before the
shutdown limits are reached.
• The parameters displayed in the instrument control window change from
green to yellow/red as the shutdown limits are approached/reached.
In addition to the above safety features, the following precautions should
always be taken during operation or maintenance:
• Check acid concentration. Continuous aspiration of a highly concentrated
acid might attack the inside of the instrument.
• Close the instrument covers and panels before operation.
• Check the exhaust system for a positive extraction at the exhaust duct.
• Handle solvents correctly.
• Check the drain vessel frequently.
• Check the condition of the pipes, replace as needed.
Pay close attention to the cautions and warnings within this manual and the
MassHunter Workstation online Help.
Protective Earth
Close the instrument top covers before starting the plasma. Because the
instrument can be optimized entirely via MassHunter Workstation, there is no
need to open the front and side panels or cover after the plasma is ignited. In
addition, a safety interlock shuts off the plasma if the cover is lifted.
The external covers of the instrument protect the operator from internal
WAR NING hazards while the instrument is in operation. Exposure to high voltage and
radio frequency radiation from the RF power supply is present and can be very
dangerous.
Eye Hazard
WAR NING
Always wear appropriate safety glasses when handling sample solutions and
other chemicals, or when the plasma is on, in order to minimize the risk of eye
damage by hazardous liquids and exposure to ultraviolet rays.
Asphyxiation Hazard
WAR NING
Laboratory must be equipped with ventilation system to supply continuous and
sufficient fresh air from outside to prevent user from asphyxiation.
Health Hazard
WAR NING
If the exhaust system stops for any reason, immediately shut off all gas
supplies at the source.
• Do not turn off the exhaust system while gas supplies are on.
• Do not cover the holes for air intake on the ICP-MS.
• If the exhaust fan is inoperable or there is insufficient air flow, do not start
the ICP-MS until the appropriate maintenance personnel have repaired the
problem.
The exhaust system must remain on at all times while the ICP-MS is on: in
NOTE Analysis mode, Standby mode and Shutdown mode.
Noxious Gases
WAR NING
If the exhaust system stops for any reason while the vacuum pump or ICP-MS
are still running, immediately turn on the exhaust system or turn off the pump
and instrument. If inadequate ventilation occurs, vaporized pump fluid, ozone,
and other toxic combustion products will accumulate in the laboratory.
Hydrofluoric acid (HF) fumes, if inhaled, cause extensive burning of lung
tissue.
Explosion Hazard
WAR NING
The laboratory exhaust system must always be operational and connected to
the instrument exhaust vent. Potential health hazards and the risk of
explosions may occur if exhaust gases are incorrectly ventilated.
Toxic Gases
WAR NING
Immediately turn off the gas supplies at the source in the event the exhaust
system is stopped for any reason. Refer to “Appendix H. Hydrogen Safety
Guide” on page 165 and “Appendix I. Ammonia Safety Guide” on page 167.
These, and other gases which may be used with the ICP-MS present a variety
of risks.
Condensation
C AU T I O N
Ensure that the exhaust system is working correctly at all times. Instrument
damage from condensation may occur due to reverse flow through the exhaust
system.
Exhaust venting must comply with all local environmental and safety codes.
IMPORTANT Contact your Environmental Health & Safety (EHS) specialist.
When using Organic solvents, extra caution should be observed. If the spray
WAR NING chamber drain is not pumped properly, the excess flammable solvents in the
spray chamber may ignite and/or become explosive. If the torch injector clogs,
the increased pressure in the spray chamber may cause the end cap to blow off
exposing the solvent to ignition.
The drain vessel contains the spray chamber effluent, which can be toxic.
WAR NING Improper handling of the vessel can result in a serious explosion or fire if
incompatible substances accumulate. Corrosion of the vessel and connecting
tube can result in leaks that may damage the instrument or cause bodily harm.
If the effluent collected in the drain vessel contains toxic materials or solvents,
follow approved laboratory procedures to safely dispose of this hazardous
waste.
Ensure that the drain bottle is adequately ventilated (by the lab ventilation
system, the same as for the ICP-MS mainframe) to deal with vapors from the
bottle.
Clean the drain vessel every time you empty it by thoroughly flushing it with
water. If it contained organic solvents, wash the drain vessel in acetone and
allow it to dry.
Follow the procedures below to avoid exposure to the contents of the drain
vessel:
• When using organic solvent, please use a suitably sized waste container of
appropriately resistant material for the collection of organic solvent.
• Place the drain vessel on the instrument table, where it is easy to check the
liquid level.
• Tightly connect the drainage tubing from the spray chamber around the
peristaltic pump to the drain vessel. Do not crimp the tubing.
• Check the drain vessel frequently. Empty it before you ignite the plasma.
• Be aware of the nature of the vessel contents. If the contents are toxic,
dispose of them as hazardous waste. Also, always empty the vessel when
switching from aqueous to organic sample solutions.
• Check the tubing and vessel for deterioration. If the tubing becomes brittle
or cracked, replace it. Organic solvents generally cause more rapid
deterioration than aqueous solutions.
Do not set the cell gas supply pressure higher than the specification of the
WAR NING ICP-MS instrument.
Compressed gas tanks must be handled with care. The contents of the
WAR NING cylinders also may be hazardous, depending on the gases you choose to use.
All compressed gases (other than air) can create a hazard if they leak into the
atmosphere. Even small leaks in gas supply systems can be dangerous. Any
leak can create an explosion hazard, a fire hazard, or can result in an
oxygen-deficient atmosphere. Such hazards can cause death, serious injury,
asphyxiation, anesthetic effects, and serious damage to equipment and
property.
Consult the cylinder, regulator and/or gas supplier for additional safety
WAR NING measures and ensure all staff are fully familiarized with all safety precautions.
Cell Gas
Health Hazard
WAR NING
The exhaust gas tubing from foreline pump must be always connected to the
rear port of the ICP-MS instrument to ensure that the cell gas evacuated by the
foreline pump is exhausted via the external duct. Health hazards include the
possibility of flammable, toxic or asphyxiating gas entering the room air.
Health Hazard
WAR NING
Close all gas supply valves to the ICP-MS instrument before turning off the
vacuum system. Health hazards include the possibility of flammable, toxic or
asphyxiating gas accumulating in the vacuum chamber or instrument
enclosure.
Individual stop valves must be installed for all gas lines for each individual
ICP-MS instrument.
Fully and strictly adhere to all local and national regulations and guidelines for
WAR NING the proper storage, handling and transport of all gases.
Other Gas
The torch and interface remain hot after the plasma is turned OFF. Do not
WAR NING touch the torch box or interface cones for 10 minutes after turning off the
plasma to let them cool.
Always re-attach the torch box cover after maintenance. This cover reduces
C AU T I O N the emission noise from the plasma.
Peristaltic Pump
Take care when you open and close the clamp of the peristaltic pump.
WAR NING Otherwise, you could get your finger caught between the stator and the rotator,
or between the stator and the stopper.
Foreline Pump
The pump oil may be very hot. Direct skin contact may cause burns.
WAR NING
If foreline pump oil is accidentally spilled on skin, in mouth, or eyes; wash
immediately and thoroughly and seek expert medical attention.
The surface of the Foreline Pump may be HOT, do not touch the pump until it
WAR NING has cooled.
Air Intake
The ICP-MS is heavy (about 100 kg), so if you need to lift the instrument, it
WAR NING should be lifted by at least 4 people or with a mechanical lifter.
If the exhaust fan is inoperable or there is insufficient air flow, do not start the
WAR NING plasma until the appropriate maintenance personnel have rectified the
problem.
Do not cover the holes for air intake on the ICP-MS.
Environmental Conditions
“Pollution level” describes the degree to which a solid, liquid, or gas which
NOTE deteriorates dielectric strength is adhering. “2” applies to a normal indoor
atmosphere.
“Installation category” implies the regulation for impulse withstand voltage. It is
also called the “Over voltage category”. “II” applies to electrical equipment
This equipment requires the following space for ventilation, maintenance access,
and easy access to the Main Power Breaker Switch. There must be a clear space
of at least 60 cm (24 in) on all sides of the equipment. The bench in your
laboratory must be able to support the entire ICP-MS system and other
laboratory equipment.
Electromagnetic Compatibility
EN55011/CISPR11
Group 1 ISM equipment: group 1 contains all ISM equipment in which there is
intentionally generated and/or used conductively coupled radio-frequency energy
which is necessary for the internal functioning of the equipment itself.
Class A equipment is equipment suitable for use in all establishments other than
domestic and those directly connected to a low voltage power supply network
which supplies buildings used for domestic purposes.
ICES/NMB-001
This ISM device complies with Canadian ICES-001.
Cet appareil ISM est conforme à la norme NMB-001 du Canada.
Sound pressure
Sound pressure Lp < 70 dB(A) according to DIN EN ISO 7779.
Schalldruckpegel
Schalldruckpegel LP < 70 dB(A) nach DIN EN ISO 7779.
Cooling Water
Inlet Temperature: 15 to 40 °C
Inlet Pressure: 230 to 400 kPa
Minimum Flow Rate: 5.0 L/min
Exhaust Duct
Extraction Flow Rate: 5 to 7 m3/min
Foreline Pump
Current Rating: 5 A
Do not use any foreline pump except those specified by Agilent for use with the
C AU T I O N Agilent ICP-MS.
The rated current of foreline pumps (for use other than with the Agilent ICP-MS):
NOTE 6.0 A for MS40+; 6.8 A for DS402; 7.0 A for Dry pump (NeoDry36E), but the above
listed rating of 5 A is applicable for use with the Agilent ICP-MS.