contact with equimolar solution of benzene and

SUPER 50 COACHING CLASSES tol

CHAPTER – SOLUTIONS
TOPIC – Raoult’s Law
Q.1 What phenomenon occurs when a solution’s Contact with equimolar solution of Toluene is-
equilibrium vapour pressure equals the a) 0.5 b) 0.6
surrounding atmospheric pressure? c) 0.27 d) 0.73
a) Boiling b) Melting 8. The vapour pressure of two pure liquids A and
c) Condensation d) Sublimation B are 100 torr and 80 torr respectively. The total
Q.2 “Total pressure of gas mixture is the sum of pressure of solution obtained by mixing 2 moles
individual pressures.” Which law is reflected in of A and 3 moles of B are:
this statement? a) 120 torr b) 36 torr
a) Amagat’s law b) Raoult’s law c) 88 torr d) 180 torr
c) Henry’s law d) Dalton’s law 9. PA and PB are the vapour pressure of pure liquid
3. If ethanol and chloroform are present in a components A and B respectively of an ideal
molar ratio of 2:3 then what is the vapour binary solution. If XA represents the mole fraction
pressure of this mixture at 200 C if vapour of component A, the total pressure of the
pressures of pure liquids are 5.95 kPa and 21.17 solution will be:
kPa respectively? a) PB + XA ( PA – PB)
a) 16.692 kPa b) 15.082 kPa b) PA + XA ( PB – PA)
c) 8.731 kPa d) 12.038 kPa c) PA + XA ( PA – PB)
4. The factor which affect vapour pressure is: d) PB + XA ( PB – PA)
a) temperature 10. A mixture of ethyl alcohol and propyl alcohol
b) pressure has a vapour pressure of 290 mm Hg at 300 K.
c) forces between liquid molecules The vapour pressure of propyl alcohol is 200 mm
d)all of these Hg. If the mole fraction of ethyl alcohol is 0.6, its
5. At vapour pressure vapour pressure (in mm Hg) at the same temp.
a) evaporation is favoured will be:
b) condensation is favoured a) 350 b) 700
c) both evaporation and condensation is favoured c) 360 d) 300
but at a equal rate 11. The correct option for the value of vapour
d) none of these pressure of a solution at 450 C with benzene to
6. Vapour pressure is achieved in octane in molar ratio 3 : 2 is:
a) closed vessel ( At 450 C vapour pressure of benzene in 280 mm
b)open vessel Hg and that of octane is 420 mm Hg)
c) both a and b a) 168 b) 336
d) none of these c) 350 d) 160
7. The vapour pressure of pure benzene and 12. For a binary liquid solution of A and B, the
toluene are 160 torr and 60 torr respectively. The mole fraction of A in liquid and vapour phase are
mole fraction of toluene in vapour phase in 0.6 and 0.35 respectively at 400 torr. What are
the vapour pressure of pure liquid A and B?
a) 233.3 torr, 650 torr 18. The correct expression for vapour pressure of
b) 400 torr, 650 torr a solution containing volatile solute A and solvent
c) 233.3 torr, 450 torr B is
d) 346.2 torr, 456 torr a) P = PA0XA - PB0XB
13. The vapour pressure in mm Hg of a methanol b) P = PA0 + (PA0 – PB0) XA
– ethanol solution is represented by the equation c) P = PB0 + (PA0 – PB0) XB
P = 120 XA + 140, where XA is the mole fraction of d) P = PA0 + (PB0 – PA0) XB
methanol. Calculate pure vapour pressure of 19. Mole fraction of the toluene in the vapour
methanol and ethanol. phase which is in equilibrium with a solution of
a) 260, 160 b) 140, 260 benzene (P0 = 120 torr ) and toluene ( P0 = 80
c) 260, 140 d) 300, 180 torr) having 2.0 mol of each is:
14. Vapour pressure of chloroform ( CHCl3) and a) 0.5 b) 0.25
dichloromethane ( CH2Cl2) at 250 C are 200 mm c) 0.6 d) 0.4
Hg and 41.5 mm Hg respectively. Vapour pressure 20. At 298 K, vapour pressure in torr of ethanol
of the solution obtained by mixing 25.5 g of and propanol solution is P = 119x + 135, where x
chloroform and 40 g of dichloromethane at the is the mole fraction of ethanol. Hence:
same temp. will be: a) vapour pressure of pure ethanol is 119 torr
( Molecular mass of CHCl3 = 119.5 u and b) vapour pressure of pure propanol is 135 torr
molecular mass of CH2Cl2 = 85 u) c) vapour pressure of equimmolar mixture of
a) 285.5 mm Hg b) 173.9 mm Hg each is 127 torr
c) 615 mm Hg d) 90.3 mm Hg d) mixture is completely immiscible.
15. Which one is not correct mathematical
equation for Dalton’s Law of partial pressure?
Here p = total pressure of gaseous mixture
Xi = mole fraction of ith gas in gaseous mixture
Pio = pressure of ith gas in pure state
Pi = partial pressure of ith gas
a) pi = xi pi0
b) p = p1 + p2 + p3
c) pi = xi p
d) p = n1 RT/ V + n2 RT/V + n3 RT/V
16. At a given temperature, total vapour pressure
in Torr of a mixture of volatile components A and
B is given by P = 120 – 75 XB. Hence, vapour
pressure of pure A and B respectively (in torr)
are:
a) 120, 75 b) 120, 195
c) 120, 45 d) 75, 45
17. At 298 K, the vapour pressure of pure liquid A
( mol mass = 40) is 100 torr, while that of pure
liquid B is 40 torr, ( mol mass = 80). The vapour
pressure at 298K of a solution containing 20g of
each A and B is
a) 80 torr b) 59.8 torr
c) 68 torr d) 48 torr