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The document contains a series of physics and chemistry problems, including calculations related to angular momentum, electromagnetic waves, electrical circuits, and thermodynamics. It also includes questions about chemical reactions, properties of substances, and stoichiometry. The problems require knowledge of various scientific principles and mathematical skills to solve.

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0% found this document useful (0 votes)
335 views33 pages

Solution

The document contains a series of physics and chemistry problems, including calculations related to angular momentum, electromagnetic waves, electrical circuits, and thermodynamics. It also includes questions about chemical reactions, properties of substances, and stoichiometry. The problems require knowledge of various scientific principles and mathematical skills to solve.

Uploaded by

jaffrinjugal123
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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You are on page 1/ 33

27-04-2025

1001CJA101021240060 JA

PART-1 : PHYSICS

SECTION-I

1) The expression for the angular momentum of a point mass about origin is given by

where α is a certain constant and ‘t’ is time in seconds.

(A)
The torque acting on the mass as a function of time is .
(B) The mass can pass through the point (0, 0, 4).
If the position of the particle at t = 1s is (0, 2, 0), the x component of its momentum at t = 1 s is
(C)
.
If the position of the particle at t = 1s is (0, 2, 0), the z component of its momentum at t = 1 s is
(D)
.

2) A plane electromagnetic wave of the radiation field from a distant wire antenna travels toward
the plane of the paper (which is in the -z direction). At time t = 0 s, the wave strikes the paper at
normal incidence. The magnetic field vector at point O in the figure points in the -y direction and has
a magnitude of 4.0 × 10–8 T at that moment. This magnitude is maximum. The frequency of the wave

is 1.0 × 1016 Hz.

(A) The associated electric field E at time t = 0 s at the point O is V/m.


–17
(B) The associated electric field E at time t = 2.5 × 10 s at z = 0.75 × 10–8 m is V/m.
–17 –8
(C) The associated electric field E at time t = 5 × 10 s at z = 1.5 × 10 m is V/m.
–17 –8
(D) The associated electric field E at time t = 7.5 × 10 s at z = 2.25 × 10 m is V/m.

3) To an ideal battery with EMF 1.3 V we connected a bridge circuit assembled from three identical
voltmeters and two identical milliammeters (see figure). It is known that the reading of one of the
milliammeters is three times the other. Resistance of voltmeters are more than milliammeters.
(A) Reading of Voltmeter A is 1.0 V.
(B) Reading of Voltmeter B is approx 0.62 V.
(C) Reading of Voltmeter C is 0.4 V.
(D) Reading of Voltmeter C is approx 0.68 V.

4) Consider a specially designed vernier calliper in which Vernier divisions are not equi spaced and
main scale divisions are equispaced. 1 main scale division is equal to 1mm. Vernier scale has 8
divisions. When zero of the vernier scale is matched with zero of main scale, these 8 divisions of
vernier scale coincide with 6 division of main scale division as shown.

When nothing is put between the jaws,


zero of the main scale lies between zero and 1 division of Vernier scale and 4th Vernier scale division
exactly coincide with one of the main scale division. To measure the diameter of a cylindrical wire it
is put between the jaws. Zero of vernier scale lies between 4th& 5th of main scale division and 6th
division of Vernier scale division coincide with one of the main scale division. Diameter of the wire
is:

(A) Zero error is 0.2mm


(B) Zero error is –0.2mm
(C) Diameter is 4.3 mm
(D) Diameter is 4.1 mm

SECTION-II (i)

Common Content for Question No. 1 to 2

A charged particle enters a region in which there is a frictional force proportional to the particle’s
velocity , and the particle stops 10 cm from its entry point. If the particle repeats its motion
when a homogeneous magnetic field of magnitude B, perpendicular to the plane of its trajectory, is
also present, then the particle comes to rest at a displacement of 6 cm from its entry point (see
figure).
(velocity with which particle enters the region is to be taken same in all cases)
1) If the magnetic field were twice as large the particle would stop at a displacement of cm from
entry point, where N is:

2) The magnitude of the magnetic field for which the particle would stop at a displacement

of cm from entry point is , where n is:

Common Content for Question No. 3 to 4


Consider an adiabatic chamber, divided in three equal parts as shown. Pistons are massless and can
slide freely inside the chamber, without any leakage of gas. Area of cross section of each piston is A.
Piston-1 is conducting and piston-2 is adiabatic. Piston 1 and 2 are connected by a rigid massless rod
whose thermal coefficient of linear expansion and heat capacity is negligible. Each part contains
same gas, each at temperature T0, pressure P0 and volume V0. Adiabatic exponent of gas is γ = 2.
Now using an electrical arrangement gas in part B is heated slowly so that its temperature becomes

2T .

3) Final temperature of gas in chamber A is nT0 where n is:

4) Final pressure of gas in chamber A is , where N is :-

Common Content for Question No. 5 to 6

A small container (1) of height 2ℓ0 and cross-section area ‘A’ is kept in a big container (2) of height
3ℓ0 and cross-section area 2A. The bottom of container (1) is welded with the bottom of container
(2). A massless piston is put on the container (1). The container (2) is completely filled with water
and initially the length of air column in container (1) is ℓ0. Now a small orifice is made at the bottom
of the container (2). Assume the temperature of water and air remains constant in all the following
processes.
5) When the height of water level in container (2) becomes 2ℓ0, the piston reaches the topmost
portion in container (1). The atmospheric pressure is Nρwgℓ0, where N is: (density of water is ρw)

6) Now the piston is held (fixed) at that position. The orifice is closed and another orifice is made at
the lowest position of container (1). The height up to which the water will rise in the container (1) at

equilibrium is then (N + M) is :

SECTION-II (ii)

1) Four identical condensers are connected as shown in figure, and joined to a battery E. Switch II is
open to start with, and switch I closed. Switch I is then opened and switch II is closed.
List-I List-II

ratio of energy stored in condenser ‘1’ before and after closing switch
(P) (1) 1:1
II

ratio of energy stored in condenser ‘2’ before and after closing switch
(Q) (2) 1:4
II

(R) ratio of charge on condenser ‘2’ before and after closing switch II (3) 4:1

ratio of potential difference across condenser ‘3’ before and after


(S) (4) 2:1
closing switch II

2) Two infinite perpendicular planes were charged uniformly with surface densities of the charges
being σ and 2σ respectively. A long hollow cylinder of radius R, whose axis coincides with the line of
intersection of the planes, is given a surface charge –3σ, as shown in figure.

List-I List-II

(P) x-component of electric field at a point (x,y,z) inside cylinder (1)

(Q) z-component of electric field at a point (x,y,z) inside cylinder (2)

(R) x-component of electric field at a point (x,y,z) outside cylinder (3)

(S) z-component of electric field at a point (x,y,z) outside cylinder (4)

SECTION-III

1) Very thin non-conducting rod of length L is uniformly charged along the length with total charge
of Q. A small conducting ring of radius R is made of very thin wire, its center coincides with one of
the ends of the rod, and the plane of the ring is perpendicular to the rod. Ring has uniform charge q.
With what net force F does the rod act on the ring? If the tension in ring due to charge on rod is T,
find F/T. Round off to nearest integer. (Take )

2) In an interference experiment as shown in the figure, the source plane and screen are separated

by a distance 1m. At a certain position of source, fringe width is and by moving the source

away from mirror along the line AB by 0.6 mm, the fringe width changed to , then wavelength

of light used is (N × 1000) Å, where N is:

3) A narrow beam of light is incident on a 30° – 60° – 90° prism kept in air as shown figure. The

refractive index of the prism is μ = 2.1. The total clockwise deviation of the beam is radians,

where N (≠ 2) is:

4) A snap shot, of a vibrating string at t = 0, is shown in the figure. A particle at point P is observed

moving up with velocity cm/s and the tangent at the point P makes an angle

with the positive x-axis.

The equation of the wave is

(L → smallest positive integer). Find (N + M + L).

5) At low temperatures, the molar heat capacity of solids at constant pressure depends on

the absolute temperature T according to the law . One mole (40 g) of solid argon at
temperature 9 K is brought into thermal contact with 600 gm of solid argon at a temperature of 1 K
in an insulated chamber. What will be the temperature (in K) of the system when thermal
equilibrium is established? The heat capacity of chamber is negligible. Round off to the nearest
integer if necessary

6) In the photoelectric experiment, if we use a monochromatic light, the I-V curve is as shown. The
work function of the metal is 2eV (Assume percentage efficiency of photo emission = 10–3 %, i.e.
number of photoelectrons emitted are (10–3) % of number of photons incident on metal.) The power

of light used in Watts is:

PART-2 : CHEMISTRY

SECTION-I

1) In the following chemical reaction sequence which is/are correct.


(A) ‘P’ gives yellow ppt. with I2/OH .
(B) ‘P’ on treatment with NaBH4 / EtOH will form a diol.
(C) If 1 mole of ‘P’ is treated with Sodium metal then 22.4 L of H2(g) is released at 0°C, 1 atm.
(D) ‘P’ is an aldehyde.

2) During the preparation of K2Cr2O7, Chromite ore is fused with Na2CO3 in free excess of air. Then
which is are correct?

(A) Chromite ore has iron in +2 oxidation state.


(B) Oxidation number of Cr in fusion product is +6.
(C) In the fusion product all ‘Cr–O’ bond length are equal.
(D) In the product Cr has no unpaired electron but still it is coloured.
3)
Which is/are correct about above reaction sequence?

(A) ‘C’ is a 2° alcohol.


(B) ‘E’ can’t decolorize Br2 + H2O.
(C) ‘C’ to ‘D’ conversion is nucleophilic substitution reaction.
(D) Formation of ‘B’ from ‘A’ is dehydration reaction.

4)

Which is/are correct?

(A) Cr2O3(s) is reduced by Al(s) in given standard condition.


(B) Al2O3(s) is reduced by Cr(s) in given standard condition.
º
(C) ΔrH for the reduction of Cr2O3 by Al is –500 kJ.
(D) Reduction of Cr2O3 by Al is spontaneous at all temperature.

SECTION-II (i)

Common Content for Question No. 1 to 2


Sulphate salt of an element ‘A’ of 3-d series is (X). On heating ‘X’ produces mixture of two gases.
Both the gaseous product contains S–atom. Addition of few drops of HNO3 to the solution of ‘X’,
followed by addition of KSCN produces blood red colour. Red colour disappears upon addition of
excess of sodium oxalate, due to the formation of (Y). Then answer the following questions.

1) How many statement is/are true?


(i) Element ‘A’ on treatment with dilute HCl forms salt in +3 oxidation state and releases H2(g).
(ii) Decomposition of Sulphate salt (X) produces an oxide in +3 oxidation state of element.
(iii) Gases are SO2 and SO3.
(iv) Element is diamagnetic.
(v) ‘Y’ is paramagnetic complex.

2) Find P + Q + R for compuond (Y)


(P) Number of unpaired electron(s)
(Q) Number of stereoisomers
(R) Number of oxygen atoms

Common Content for Question No. 3 to 4

The vapour pressure of two miscible liquids A and B are 300 and 500 mm Hg respectively. In a flask,
10 mole of A is mixed with 12 mole of B. However, as soon as 'B' is added, 'A' starts polymerizing
into a completely insoluble solid. The polymerisation follows first order kinetics. After 100 min, 1
mole of a non–volatile solute is dissolved, which arrests the polymerisation completely. The final
vapour pressure of the solution is 400 mm of Hg.
Assume negligible volume change on mixing and polymerisation and ideal behaviour for the final
solution. [log2 = 0.3, loge10 = 2.3]

3) If rate constant for the first order is ‘K’ min–1, then find the value of is:

4) If initially mixed A and B has non–ideal behaviour with negative deviation from Raoult's law and
there is no polymerisation, then how many of the following are true:
(i) Attraction between A and B is more than individual attraction of A.....A and B.....B.
(ii) Potential energy of the system decreases on mixing.
(iii) ΔSSystem > 0
(iv) ΔSSurrounding < 0
(v) ΔGMixing < 0

Common Content for Question No. 5 to 6


Amino acids are connected by peptide bonds. A decapeptide (Mol. wt. 796) on complete hydrolysis
gives glycine (Mol. wt. 75), alanine and phenylalanine. Glycine contributes 39.14% to the total
weight of the hydrolysed products. Then answer the following questions.

5) Find the total number of Glycine units present in the decapeptide.

6) This decapeptide consists of an octapeptide part with the following properties -


(i) All the glycine units are used in this octapeptide part & it is single specific sequence
(ii) This octapeptide chain is fixed with an ordered linkage
(iii) The remaining two amino acids apart from this octapeptide are alanine and phenylalanine.
Then how many such decapeptides are possible

SECTION-II (ii)

1) Match the Lists.

List-I List-II
(P) (1)

(Q) (2)

(R) (3)

(S) (4)

2) Match the Lists.

List-I List-II (pH)

(P) 10 ml of 0.1 M Na2HPO4 + 10 ml of 0.1 M HCl (1)

(Q) 10 ml of 0.1 M Na3PO4 + 15 ml 0.2 M HCl (2)

(R) 10 ml of 0.1 M H3PO4 + 15 ml 0.1 M NaOH (3) H3PO4 is the product

(S) 15 ml of 0.1 M Na3PO4 + 40 ml of 0.1 M HCl (4)

SECTION-III

1) To form a complete monolayer of acetic acid on 1g of charcoal, 100 mL of 0.5 M acetic acid was
used. Some of the acetic acid remained unabsorbed. To neutralize the unabsorbed acetic acid, 40 mL
of 1 M NaOH solution was required. If each molecule of acetic acid occupies P × 10–21 m2 surface

area on charcoal, the value of is ______.


[Use given data: Surface area of charcoal = 1.5 × 102 m2g–1; Avogadro's number (NA) = 6.0 × 1023
mol–1]

2) Given:

Molar conductivity of 0.038 M ‘HA’ solution is 20 Scm2mol–1 at 298 K. What is the pH of 0.01 M NaA
salt solution. (Express your answer to nearest integer).

3) An organic compound (A) having molecular formula C5H10O responds +ve to Baeyers reagent as
well as Lucas reagent. It shows geometrical isomerism as well as optical isomerism. (A) on heating
with MnO2 followed by treatment with Cl2/NaOH forms (B) (organic product containing one carbon
less than (A)). (B) when heated with NaOH/CaO forms organic compound (C). What is number of
H–atoms in (C).

4) Find the number of combination(s) of reagents in which pink coloured solution or precipitate or
product(s) is/are formed.
(i) MnCl2 + H2S(g) + HCl (ii) Mn2+ + S2O82–
(iii) Mn2+ + NaBiO3 + HNO3 (iv) Mn2+ + PbO2 + HNO3
(v) K2MnO4 + Cl2 (vi) ZnCl2 + H2S + NH4OH(aq.)

5) Suppose de–Broglie equation is valid in Bohr model. In H–like sample, all electrons are in that
orbit which has path length of the orbit equal to 3 times of de-Broglie wavelength of electrons in that
orbit. This orbit of H–like sample has total energy equal to the ground state energy of H–atom. Now
we have same H-like sample having all electrons in the ground state. If photons of energy 126.566
eV are given to this ground state sample and de-Broglie wavelength of the emitted electron is (P ×
10–10) metres then find nearest integer value of (P) ?

6) Consider the following reaction sequence.

Find the sum of number of stereoisomers of complexes P, Q and R.

PART-3 : MATHEMATICS

SECTION-I

1) Which of the following is/are true :

(A)
In any ΔABC, minimum value of is 3
If sec A tan B + tan A sec B = 30 then
(B)

If sec A tan B + tan A sec B = 30 then


(C)

Three lines y – z –1 = 0 = x, z +x +1 = 0 = y, x – z –1 = 0 =y intersect the xy plane at U, M, R


(D)
then orthocenter of triangle UMR is (0, 1, 0)

2) If A and B are respectively a symmetric and skew symmetric matrix such that AB = BA then :

(A) is orthogonal matrix when A – B is non-singular


(B) is orthogonal matrix when A + B is non-singular

(C) and

(D) and

3) Let y = ƒ(x) be a differentiable function passing through M(1,–1) and has a property that the chord
joining any two points A(x1,ƒ(x1)) and B(x2, ƒ(x2)) always intersects y-axis at N(0,2x1x2). Then

(A)

(B)

area bounded by ƒ(x) and x-axis is equal to


(C)

area bounded by ƒ(x) and x-axis is equal to


(D)

4) If a,b,c,d ∈ R such that , then equation ax3 + bx2 + cx + d = 0 has

(A) at least one root in (–1,0)


(B) at least one root in (–1,1)
(C) at least one root in (0,1)
(D) no root in (–1,1)

SECTION-II (i)

Common Content for Question No. 1 to 2


Let , then consider the function y = h(x)
and
h(x) = then answer the following questions

1) is equal to :

2) Range of the function is then a + b is equal to :

Common Content for Question No. 3 to 4


Let be a polynomial such that and

3) If , then λ equals

4) If the constant term in is where p and m ∈ N, then p + m is equal to :

Common Content for Question No. 5 to 6

If , then

5) is -

6) I(3) – I(–3) is -

SECTION-II (ii)

1) Consider a triangle having vertices at the points A(z1) ≡ B(z2)

≡ and C(z3) ≡ . A circle is inscribed in triangle ABC touching the side AB, BC and
CA at D(z4), E(z5), F(z6) respectively, consider point P(z) on incircle of ΔABC then

List-I List -II

(P) Value of is (1) 4

(Q) (2) 1

(R) is equal to (3) 5


(S) is equal to (4) 2

2) Match the following List-I with List-II

List-I List-II

(P) Trace B is (1) 256

(Q) 4 det(adj B) is (2) –10

(R) Det(adj(adj (2B))) is (3) 1

(S) Sum of element of B is (4) –8

SECTION-III

1) Let E1 and E2 two ellipses. The area of ellipse E2 is one-third the area of quadrilateral formed by
tangents at the ends of latus rectum of ellipse . E1, E2 and E3 are similar
and concentric. E1 is inscribed in E2 in such a way that both E1, E2 touches each other and minor axis
of E2 coincides with major axis of E1. If length of major axis of E1 is equal to length of minor axis of
E2, then area of ellipse E2 outside the ellipse E1 is equal to :

2) f(x) is a fifth order polynomial in x with every root of f(x) = 0 is real and distinct. The number of
real roots of is :

3) In an organization number of women are μ times that of men. If α things are to be distributed
among them then the probability that the number of things received by men are odd is

. Then find the value of μ :

4) Let be three vectors having magnitude 1, 2, 3 units respectively such


that . If is unit vector coplanar with and and , then the value of
is equal to :

5) On the side AC of an acute angled triangle ABC, a point D is taken such that AD = 1, DC = 2 and
BD is an altitude of ΔABC. A circle of radius 2 which passes through points A and D and touch a
circle at the point D circumscribed about the ΔBDC. The area of ΔABC is (p → prime number
and q is natural number.) The value of is :

6) let then the value of is (where [.] denotes greatest integer function) :
ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4
A. A,C,D A,D A,C B,C

SECTION-II (i)

Q. 5 6 7 8 9 10
A. 73 3 2 9 2 4

SECTION-II (ii)

Q. 11 12
A. 1341 2413

SECTION-III

Q. 13 14 15 16 17 18
A. 4 6 6 4 5 7

PART-2 : CHEMISTRY

SECTION-I

Q. 19 20 21 22
A. A,B A,B,C,D A,C A,C

SECTION-II (i)

Q. 23 24 25 26 27 28
A. 3 19 10 4 5 6

SECTION-II (ii)

Q. 29 30
A. 3421 4321

SECTION-III

Q. 31 32 33 34 35 36
A. 5 8 6 4 6 6

PART-3 : MATHEMATICS
SECTION-I

Q. 37 38 39 40
A. A,B,D A,B B,C B,C

SECTION-II (i)

Q. 41 42 43 44 45 46
A. 2 0 210 145 4 0

SECTION-II (ii)

Q. 47 48
A. 2134 4312

SECTION-III

Q. 49 50 51 52 53 54
A. 4 0 3 9 6 9
SOLUTIONS

PART-1 : PHYSICS

1)

Particle can never be found at point (0, 0, 4) m

At t = 1s, ;

2)

(B)
=0

(C)
=

(D)
=–

3)
y>x
4)

1 VSD → 0.6 → 0.4


2 VSD → 0.1 → 0.9
3 VSD → 0.5 → 0.5
4 VSD → 0.8 → 0.2
5 VSD → 0 → 0
6 VSD → 0.1 → 0.9
7 VSD → 0.1 → 0.9
8 VSD → 0 → 0
Zero error = 0 – 0.2 mm = – 0.2 mm
Reading = 4 + 0.1 mm = + 4.1 mm
Diameter = (4.1 + 0.2) mm = 4.3 mm

5)

(a) when
(b) when
(c)

6)

(a) when
(b) when

(c)
7)
γ=2

In part C

T= = constant ⇒ = constant ⇒ =

Let =x

8) γ=2

In part C

T= = constant ⇒ = constant ⇒ =

Let =x
9)

(p0 + ρg × 2ℓ0) × ℓ0 = p0 × 2ℓ0


p0 = 2ρgℓ0

10)

p0 × 2ℓ0 = (p0 + ρg(h – ℓ)) (2ℓ0 – ℓ)


ℓ = 2ℓ0 – h
h = 2ℓ0 – ℓ

11)

12)

Along the X-axis:


Along the Y-axis: 0.

Along the Z-axis:


13)

14)

Let AS = h

...(i)

...(ii)
h = 1.2 mm
λ = 0.6 × 10–6 m = 6000 Å

15)

As seen from figure, for normal incidence at the bottom face the angle of incidence at B is 30°,
and that at C is 60°, both of which are larger than the critical angle of the prism,

Hence the ray is totally reflected at B and C. Also, the ray is partially reflected back at the
bottom and the right-hand faces. Therefore, the entire beam emerges either from the right-
hand face, or back along the incident path.
16)

vp = –slope × vw

vw = 10 cm/s in negative x-direction


λ = 2 cm; f = 5 Hz
Y = (4 cm) sin (10πt + πx + π/4)
N = 5, M = –2, L = 1

17) nCdt + n'C'dT' = 0

T4 – 94 + 15(T4 – 14) = 0
16T4 = 6562
T4 = 410.0625
T = 4.5 K ≈ 5 K

18)

The energy of incident photons is given by


hv = eVs + f0 = 2 + 5 = 7 eV
(Vs is stopping potential and ϕ0 is work function)

Saturation current = 10–5 A =


(h is photo emission efficiency)
P = 7 W.

PART-2 : CHEMISTRY
19)

20)

21) (A) (B) (C) (D) (E)

22) Cr2O3 + 2Al → Al2O3 + 2Cr


ΔrGº = (–827 + 527) = –300 kJ
ΔrHº = –1600 + 1100 = –500 kJ

23) (ii), (iii) and (v) are correct statements.


24)

P=5
Q=2
R = 12

25)

Initial moles of A = 10
Let the number of moles of A when polymerization is arrested = n
Moles of B = 12
Moles of solute added = 1
Total moles = (n + 12 + 1) = (n + 13)

400 n + 5200 = 300 n + 6000


100 n = 800
n=8

For 1st order K =

27) Total wt. of amino acid after addition of 9 mole of H2O = 796 + 9 × 18 = 958.
Now 39.14% is glycine, then total mass of glycine = 958 × 0.3914 = 375

Therefore number glycine units =

28) Octapeptide chain is fixed (8 amino acids involved in this can be taken as one unit). Since
two more amino acids are present, hence 3! = 6 decapeptides are possible.

30) [P-4, Q-3, R-2, S-1]


(P) Final solution will be of NaH2PO4
1 mm of Na2HPO4 + 1 mm of HCl
∴ Amphoteric

Hence

(R) 1 mm of H3PO4 & 1.5 mm of NaOH


∴ Final solution will have
NaH2PO4 + Na2HPO4
0.5 mm 0.5 mm
Handerson equation

Hence
(S) 1.5 mm Na3PO4 + 4 mm HCl
∴ Final solution will have
NaH2PO4 + H3PO4
0.5 mm 1 mm

31)

Millimole of acid taken = 100 × 0.5 = 50


Millimole of NaOH used = 40 × 1 = 40
Millimole of acid adsorbed = 50 – 40 = 10
Molecules of acid adsorbed = 10 × 10–3 × 6 × 1023 = 6 × 1021

Surface area occupied per molecule = = 0.25 × 10–19 = 2500 × 10–23

32)

pH = [14 + 4 – 2] = 8

33) (A) (B) (C) CH3–CH=CH2

34) MnCl2 + H2S → No ppt.


Since MnS is obtained in basic medium.

35)
T.E. in the orbit = –13.6 eV

, Sample is Li2+.
Ground state energy = –13.6 × 9 eV
Energy of ejected e– = 126.566 – 122.4 = 4.166

36) P = [Pt(Py)2Cl2] Q = [Pt(Py)2(NH3)Cl]+


cis + trans cis + trans
R = [Pt(NH3)2(Py)Cl]+
cis + trans

PART-3 : MATHEMATICS

37) (A) a = k sin A

let

(B,C) (sec A sec B + tan A tan B)2 – (sec A tan B + tan A sec B)2 = 1
(D) U(0, 1, 0), M(–1, 0, 0), R(1, 0, 0) orthocenter is (0, 1, 0)

38)

∴ is orthogonal matrix
∴ is orthogonal
Det
∴ Determinant of both will be 1 or –1

39) ƒ(x) = x – 2x2


and area =

40)
3a + 4b + 6c + 12d = 0

⇒ Option B and C are right

41)

42)

43)

:
:

For constant term put x = 0

, p+m = 145
44)

:
:

For constant term put x = 0

, p+m = 145

45) ...(1)

...(2)

I(m) = I(–m)
adding (1) and (2)

I(m) + I(–m)
I(m) + I(–m) = I(m2) I(9) = 2I3
2I(m) = I(m2) I(81) = 2I5

46) ...(1) ...(2)

I(m) = I(–m)
adding (1) and (2)

I(m) + I(–m)
I(m) + I(–m) = I(m2) I(9) = 2I3
2I(m) = I(m2) I(81) = 2I5

47) Clearly point A, B, C lie on circle


ΔABC is equilateral Ar(ΔABC)

Area ΔDEF =

Let P(z) be any point on incircle

AP2 + BP2 + CP2 =5


DP2 + EP2 + FP2
=

=2

48)

AB = I

|adj (B)| = |B|2 =

49)
Equation of tangent at is 2x + 3y = 9
Area of quadrilateral = 27

Let

Required area = πb(a – c)

Area =

50)
Take log and differentiable

Differentiate again

51) Let p and q denote probability of things going to man and woman respectively Therefore

and

probability of men receiving r things is given by


So required probability is given by P1 + P3 + P5 + …..
i.e.

By comparison, we have Thus μ = 3

52)
are mutually perpendicular vectors
53)

BD =

Area of ΔABC =
P = 3, q = 15

54)

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