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REDOX

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Rajat Majumder
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11 views2 pages

REDOX

Best book pef

Uploaded by

Rajat Majumder
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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D-25/06/2024

1. Assign oxidation numbers to the underlined elements in each of the following species:

(a) NaH2PO4 (b) NaHSO4 (c) H4P2O7 (d) K2MnO4 (e) CaO2 (f) NaBH4 (g) H2S2O7 (h) KAl(SO4)2.12 H2O

(i) KI3 (j) H2S4O6 (k) Fe3O4 (l) CH3CH2OH (m) CH3COOH

2. Justify that the following reactions are redox reactions:

(a) CuO(s) + H2(g) → Cu(s) + H2O(g)

(b) Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g)

(c) 4BCl3(g) + 3LiAlH4(s) → 2B2H6(g) + 3LiCl(s) + 3 AlCl3 (s)

(d) 2K(s) + F2(g) → 2KF (s)

(e) 4 NH3(g) + 5 O2 → 4NO(g) + 6H2O(g)

3. Fluorine reacts with ice and results in the change:

H2O(s) + F2(g) → HF(g) + HOF(g) Justify that this reaction is a redox reaction.

4. Calculate the oxidation number of sulphur, chromium and nitrogen in H 2SO5,CO2O7 2- , NO3 - . Suggest
structure of these compounds.

5. Write the formulae for the following compounds: (a) Mercury(II) chloride (b) Nickel(II) sulphate

(c) Tin(IV) oxide (d) Thallium(I) sulphate (e) Iron(III) sulphate (f) Chromium(III) oxide.

6. While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their
reactions but nitric acid act only as oxidants. Why?

7. Identify the substance oxidised, reduced, oxidising agent and reducing agent for each of the following
reactions:

(a) 2AgBr (s) + C6H6O2(aq) → 2Ag(s) + 2HBr (aq) + C6H4O2(aq)

(b) HCHO(l) + 2[Ag (NH3)2] (aq) + 3OH– (aq) → 2Ag(s) + HCOO– (aq) + 4NH3(aq) + 2H2O(l)

(c) HCHO (l) + 2Cu2+(aq) + 5 OH– (aq) → Cu2O(s) + HCOO– (aq) + 3H2O(l)

(d) N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)

(e) Pb(s) + PbO2(s) + 2H2SO4(aq) → 2PbSO4(s) + 2H2O(l)

8. Balance the following redox reactions by ion-electron method:

(a) MnO4 - (aq) + I – (aq) → MnO2 (s) + I2(s) (in basic medium)

(b) MnO4 - (aq) + SO2 (g) → Mn2+ (aq) + HSO4 - (aq) (in acidic solution)

(c) H2O2 (aq) + Fe2+ (aq) → Fe3+ (aq) + H2O (l) (in acidic solution)
(d)Cr2O7 2- + SO2(g) → Cr3+ (aq) + SO4 2- (aq) (in acidic solution)

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