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Questions For Practice Real Gas

The document discusses the behavior of real gases compared to ideal gases, including deviations, the van der Waals equation, and the significance of constants a and b. It covers various concepts such as Boyle temperature, compressibility factor, and the principles of continuity of state, along with numerical problems and experimental observations. Additionally, it explores intermolecular forces, critical constants, and the Lennard-Jones potential.

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shitakshay17
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47 views2 pages

Questions For Practice Real Gas

The document discusses the behavior of real gases compared to ideal gases, including deviations, the van der Waals equation, and the significance of constants a and b. It covers various concepts such as Boyle temperature, compressibility factor, and the principles of continuity of state, along with numerical problems and experimental observations. Additionally, it explores intermolecular forces, critical constants, and the Lennard-Jones potential.

Uploaded by

shitakshay17
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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GASEOUS STATE

• Discuss the causes of deviation of real gas from ideal gas behaviour.

• Derive van der Waals equation for n mole real gas and explain the significance of a and b.

• Numerical value of excluded volume is 4 times the actual volume. Explain.

 The plot of PV vs P for H2 and He shows a continuous increase at room temperature-why?


 Why pressure correction term in the van der Waals equation proportional to a/v2?

• Define Boyle temperature. Derive an expression for Tb for v d w gas .

 The plot of PV vs P for H2 and He shows a continues increase at room tempr-why?


 At the Tb the real gas obeys ideal gas equation. So the v.d.W constants a and b become
zero? Comment.
 Find the unit and dimension of ‘a’ and ‘b’
 If V is the volume of a gas and Vid its volume in ideal condition then what does V/Vid mean?

• What do you mean by compressibility factor Z. Explain why the initial slope of Z Vs P curve is
i) +ve above Tb and ii) –ve below Tb.

 For what factor the compressibility factor of a gas is less than unity?

 Calculate the compressibility factor for a vdw gas at 1 atm and 300K. Given, a= 1.39
atm.lit2mol-2 and b=0.039lit.mol-1
 Calculate the pressure of one mole NH3 gas, which is in a 100 ml vessel, at 500 K, given the
second and third virial coefficients are B= -68.3 cc.mol-1 and C=2397cm6.mol-2 respectively.
 Give an account of Andrews experiment with CO2 and its important conclusions. Draw it in
different temperature and identify Tc and Vc in the diagram.
 Draw the Andrews plot for a real gas below its Tc and compare this with VDW theoretical plot.
 Ideal gas cannot be liquefied. Explain.
 The Tc and Pc for a gas A are 521K and 2.26 atm and those for gas B are 304.2 K and 72.7 atm
respectively.i) Calculate the Boyle’s temp of both the gases. And ii) which of the gases can be
liquefied more easily?
 Setup an expression Z= 1+ (b-a/RT) P/RT+ …. And find the initial slope of Z Vs P curve of real
gas and obtain an expression for Tb.

• State and explain the principle of continuity of state.

• Derive virial equation of of v d W gas in power series of pressure.

• Show that for a v d w gas RTc/PcVc = 8/3

• For a real gas its Tb value is always greater than Tc.

• Two separate bulbs are filled with an ideal gas A and non ideal gas B respectively in such a
way that PV remain same. B is below its Tb. Which gas has greater temperature? Give reason.
 What are the necessary conditions that are applied on v d w equation to obtain the
expression i) Tc ii)Tb
 For a van der Wall’s gas critical temperature is 150 K, critical pressure is 5x106 Pa. Calculate
the volume occupied by each molecule of the gas.
 What is the value of compressibility factor of a van der Waals gas at its critical point?
 For a van der Waals gas find the reduced pressure and the pressure exerted by one mole of
the gas taken ina 0.09 lit. vessel at 37.50C. [Given Pc=48 atm, Tc = 305K and Vc =0.148 lit.mol-
1

 Deduce reduce equation of state of n mole v d W gas equation using proper expression for
critical constants.
 State law of corresponding states and what is its significance.
 Express values of a, b, R in terms of Pc, Vc. and Tc.
 Express compressibility factor in terms of π. ,φ and ѳ, what conclusion may be drawn from
the result.
 What are different type intermolecular forces are present in NH3 , HCl and Ar molecules.
Which are temperature dependent and how? Which forces size dependent and how?
 I2 is solid and F2 is gas at room temperature. Explain.
 Which of Ne and Ar has the larger van der Walls parameter ‘a’. Explain your answer.
 What is Lennard Jones 6-12 Potential? Draw the L-J potential against the internuclear
distance.
 The P.E of attraction between polar molecules is given U(r) = A/rn

Remark on the sign of A and its dependence on the properties of the molecules.

 What is orientation polarisation?


 Calculate Tb for a gas obeying vdw eqn . a=2.44 atm.litr2.mole-2, and b=29.4 ml.mol-1
 For a vdw gas Pc= 112.2 atm and b= 0.037 lit.mol-1. find the reduced tempr of the gas at 27
0
C.
 For a van der Waals gas find the reduced pressure and the pressure exerted by one mole of
the gas taken in a 0.09 lit. vessel at 37.50C. [Given Pc=48 atm, Tc = 305K and Vc =0.148
lit.mol-1.
 Second virial co-efficient of a gas is 13.7 lit.mol-1. Calculate its molar volume at NTP.
 Tc of CO2 =304.2 K, Pc = 72.9 atm. What is the radius of CO2 molecule. [1.6190A].
 Calculate the volume occupied by 2.0 mole of nitrogen gas at 200K and 8.21 atm. Pressure if
PcVc/RTc=3/8 and PrVr/Tr=2.4.

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