Solution (232425)
Solution (232425)
1001CJA101021240056 JA
PART-1 : PHYSICS
SECTION-I (i)
1) A region in the form of an equilateral triangle (in x-y plane) of height L has a uniform magnetic
field pointing in the +z-direction. A conducting loop PQR, in the form of an equilateral triangle of
the same height L, is placed in the x-y plane with its vertex P at x = 0 in the orientation shown in the
figure. At t = 0, the loop starts entering the region of the magnetic field with a uniform velocity
along the +x-direction. The plane of the loop and its orientation remain unchanged throughout its
(A)
(B)
(C)
(D)
2) A particle of mass m is under the influence of the gravitational field of a body of mass M (>> m).
The particle is moving in a circular orbit of radius r0 with time period T0 around the mass M. Then,
the particle is subjected to an additional central force, corresponding to the potential energy Vc(r) =
mα/r3, where α is a positive constant of suitable dimensions and r is the distance from the center of
the orbit. If the particle moves in the same circular orbit of radius r0 in the combined gravitational
potential due to M and Vc (r), but with a new time period T1, then is given by :- [G is the
gravitational constant]
(A)
(B)
(C)
(D)
3) A metal target with atomic number Z = 91 is bombarded with a high energy electron beam. The
emission of X-rays from the target is analyzed. The ratio r of the wavelengths of the Kα-line and the
cut-off is found to be r = 8. If the same electron beam bombards another metal target with Z = 41,
the value of r will be
(A) 12.64
(B) 40.5
(C) 0.63
(D) 1.58
4) A thin stiff insulated metal wire is bent into a circular loop with its two ends extending
tangentially from the same point of the loop. The wire loop has mass m and radius r and it is in a
uniform vertical magnetic field B0, as shown in the figure. Initially, it hangs vertically downwards,
because of acceleration due to gravity g, on two conducting supports at P and Q. When a current I is
passed through the loop, the loop turns about the line PQ by maximum angle given by :-
(A)
(B)
(C)
(D)
SECTION-I (ii)
1) A small electric dipole , having a moment of inertia I about its center, is kept at a distance r
from the center of a spherical shell of radius R. The surface charge density σ is uniformly distributed
on the spherical shell. The dipole is initially oriented at a small angle θ as shown in the figure. While
staying at a distance r, the dipole is free to rotate about its center. If released from rest, then which
of the following statement(s) is(are) correct? [ε0 is the permittivity of free space.]
(A) The dipole will undergo small oscillations at any finite value of r.
(B) The dipole will undergo small oscillations at any finite value of r > R.
(C)
The dipole will undergo small oscillations with an angular frequency of at r = 2R.
(D)
The dipole will undergo small oscillations with an angular frequency of at r = 10R.
2) A table tennis ball has radius (3/2) × 10−2 m and mass (22/7) × 10−3 kg. It is slowly pushed down
into a swimming pool to a depth of d = 0.7 m below the water surface and then released from rest. It
emerges from the water surface at speed v, without getting wet, and rises up to a height H. Which of
the following option(s) is(are) correct? [Given: π = 22/7, g = 10 ms−2, density of water = 1 × 103 kg
m−3, viscosity of water = 1 × 10−3 Pa-s.]
(A) The work done in pushing the ball to the depth d is 0.077 J.
(B) If we neglect the viscous force in water, then the speed v = 7 m/s.
(C) If we neglect the viscous force in water, then the height H = 1.4 m.
The ratio of the magnitudes of the net force excluding the viscous force to the maximum viscous
(D)
force in water is 250.
3) A positive, singly ionized atom of mass number AM is accelerated from rest by the voltage 192 V.
Thereafter, it enters a rectangular region of width w with magnetic field Tesla, as shown
in the figure. The ion finally hits a detector at the distance x below its starting trajectory. Which of
the following option(s) is(are) correct? [Given: Mass of neutron/proton = (5/3) × 10−27 kg, charge of
the electron = 1.6 × 10−19 C.]
SECTION-II (i)
1) The 8th bright fringe above the point O oscillates with time between two extreme positions. The
separation between these two extreme positions, in micrometer (μm), is ______.
2) The maximum speed in μ m/s at which the 8th bright fringe will move is __________.
4) If the collision occurs at time t0 = 0, then the value of 4b2/a2 will be ________.
SECTION-II (ii)
1) The dimensions of a cone are measured using a scale with a least count of 1 mm. The diameter of
the base and the height are both measured to be 10.0 cm. The maximum percentage error in the
determination of the volume is ______.
2) A ball is thrown from the location (x0, y0) = (0,0) of a horizontal playground with an initial speed v
at an angle θ0 from the +x-direction. The ball is to be hit by a stone, which is thrown at the same
time from the location (x1, y1) = (L, 0). The stone is thrown at an angle (180 – θ1) from the +x-
direction with a suitable initial speed. For a fixed v0, when (θ0, θ1) = (45°, 45°), the stone hits the ball
after time T1, and when (θ0, θ1) = (60°, 30°), it hits the ball after time T2. In such a case, (T1/T2)4 is
______.
3) A charge is kept at the central point P of a cylindrical region. The two edges subtend a half-angle
θ at P, as shown in the figure. When θ = 60º, then the electric flux through the curved surface of the
cylinder is Φ. If θ = 30º, then the electric flux through the curved surface becomes , where the
value of n is ______.
4) Two equilateral-triangular prisms P1 and P2 are kept with their sides parallel to each other and
very close in vacuum, as shown in the figure. A light ray enters prism P1 at an angle of incidence θ
such that the outgoing ray undergoes maximum deviation in prism P2. If the respective refractive
indices of P1 and P2 are and 2, then , where the value of β (in degree) is ______.
5) An infinitely long thin wire, having a uniform charge density per unit length of 5 nC/m, is passing
through a spherical shell of radius 1 m, as shown in the figure. A 2 nC charge is distributed
uniformly over the spherical shell. If the configuration of the charges remains static, the magnitude
of the potential difference between points P and R, in Volt, is ______. [Given: In SI units =9×
6) A spherical soap bubble inside an air chamber at pressure P0 = 105 Pa has a certain radius so that
the excess pressure inside the bubble is ΔP = 36 Pa. Now, the chamber pressure is reduced to
8P0/27 so that the bubble radius and its excess pressure change. In this process, all the
temperatures remain unchanged. Assume air to be an ideal gas and the excess pressure ΔP in both
the cases to be much smaller than the chamber pressure. The new excess pressure ΔP in Pa is
______.
PART-2 : CHEMISTRY
SECTION-I (i)
1) According to Bohr's model, the lowest kinetic energy is associated with the electron in the :
2) In a metal deficient oxide sample, MxY2O4 (M and Y are metals), M is present in both +2 and +3
oxidation states and Y is in +3 oxidation state. If the fraction of M2+ ions present in M is , the
value of X is _______.
(A) 0.25
(B) 0.89
(C) 0.67
(D) 0.75
(A)
(B)
(C)
(D)
SECTION-I (ii)
OH– ions react with N2H4 at the anode to form N2(g) and water, releasing 4 electrons to the
(A)
anode.
At the cathode, N2H4 breaks to N2(g) and nascent hydrogen released at the electrode reacts with
(B)
oxygen to form water.
(C) At the cathode, molecular oxygen gets converted to OH–.
(D) Oxides of nitrogen are major by-products of the electrochemical process.
2) The option(s) with correct sequence of reagents for the conversion of P to Q is(are) :
+
(A) i) NaBH4 ; ii) SnCl2/HCl ; iii) H3O ; iv) Lindlar's catalyst, H2
+
(B) i) Lindlar's catalyst, H2 ; ii) H3O ; iii) SnCl2/HCl ; iv) NaBH4
+
(C) i) Lindlar's catalyst, H2 ; ii) SnCl2/HCl ; iii) NaBH4 ; iv) H3O
+
(D) i) Lindlar's catalyst, H2 ; ii) NaBH4 ; iii) SnCl2/HCl ; iv) H3O
3) Among the following options, select the option(s) in which each complex in Set-I shows
geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.
en = H2NCH2CH2NH2 ;
SECTION-II (i)
3) If 3 moles of potassium iodide are taken then X moles of P and Y moles of iodine is formed. Find
the value of (X+4Y).
SECTION-II (ii)
1) To form a complete monolayer of acetic acid on 1g of charcoal, 100 mL of 0.6 M acetic acid was
used. Some of the acetic acid ramained unadsorbed. To neutralize the unadsorbed acetic acid, 40 mL
of 1 M NaOH solution was required. If each molecule of acetic acid occupies P × 10–23 m2 surface
area on charcoal, the value of P is ______.
[Use given data : Surface area of charcoal = 1.5 × 102 m2g–1; Avogadro's number (NA) = 6.0 × 1023
mol–1]
4) A sample initially contains only U-238 isotope of uranium. With time, some of the U-238
radioactively decays into Pb-206 while the rest of it remains undisintegrated.
When the age of the sample is P × 108 years, the ratio of moles of Pb-206 to that of U-238 in the
sample is found to be 15. The value of P is _______.
[Given : Half-life of U-238 is 4.5 × 109 years]
5) Among [Co(CN)4]4–, [Co(CO)3(NO)], XeF4, [PCl4]+, SF4 , [ICl4]–, [Cu(CN)4]3– , [Ni(CO)4] , [CdCl4]2– ,
C2H4 and P4 the total number of species with tetrahedral geometry is ______.
6) An organic compound P having molecular formula C6H6O3 gives ferric chloride test and does not
have intramolecular hydrogen bond. The compound P reacts with 3 equivalents of NH2OH to
produce oxime Q. Treatment of P with excess methyl iodide in the presence of KOH produces
compound R as the major product. Reaction of R with excess methylmagnesium bromide followed by
treatment with H3O+ gives compound S as the major product.
The total number of methyl (–CH3) group(s) in compound S is ________.
PART-3 : MATHEMATICS
SECTION-I (i)
1) Considering only the principal values of the inverse trigonometric functions, the value of
is
(A)
(B)
(C)
(D) 0
(A)
(B)
(C)
(D)
(A) 1
(B) 2
(C) 3
(D) 4
(A)
f(x) = 0 has finitely many solutions in the interval
(B)
f(x) = 0 has no solutions in the interval
(C)
The set of solutions of f(x) = 0 in the interval is finite
(D)
f(x) = 0 has no solutions in the interval
SECTION-I (ii)
(A) (–1, 3) ∈ S
(B) (–1, 1) ∈ S
(C) (1, –1) ∈ S
(D) (1, –2) ∈ S
2) A straight line drawn from the point P(1, 3, 2), parallel to the line , intersects
the plane L1 : x – y + 3z = 6 at the point Q. Another straight line which passes through Q and is
perpendicular to the plane L1 intersects the plane L2 : 2x – y + z = –4 at the point R. Then which of
the following statements is (are) TRUE ?
(C)
The centroid of the triangle PQR is
(D) The coordinates of R are (1, 6, 3)
3) Let A1, B1, C1 be three points in the xy-plane. Suppose that the lines A1C1 and B1C1 are tangents to
the curve y2 = 8x at A1 and B1, respectively. If O = (0, 0) and C1 = (–8, 0), then which of the following
statements is (are) TRUE ?
(A) The length of the line segment OA1 is
(B) The length of the line segment A1B1 is 16
(C) The orthocentre of the triangle A1B1C1 is (0, 0)
(D) The orthocentre of the triangle A1B1C1 is (–8, 0)
SECTION-II (i)
4) The value of is
SECTION-II (ii)
1) Let f : be a function such that f(x + y) = f(x) + f(y) for all x, y ∈ and g : → (0, ∞) be a
function such that g(x + y) = g(x) g(y) for all x, y ∈ . If f = 12 and g = 2, then the value
of is
2) A bag contains N balls out of which 3 balls are white, 6 balls are green and the remaining balls
are blue. Assume that the balls are identical otherwise. Three balls are drawn randomly one after
the other without replacement. For i = 1, 2, 3, let Wi, Gi and Bi denote the events that the ball drawn
in the ith draw is a white ball, green ball and blue ball, respectively. If the probability
.
Then the number of solutions of f(x) = 0 in is
5) A normal with slope is drawn from the point (0, –α) to the parabola x2 = –4ay, where a > 0. Let
L be the line passing through (0, –α) and parallel to the directrix of the parabola. Suppose that L
intersects the parabola at two points A and B. Let r denote the length of the latus rectum and s
denote the square of the length of the line segment AB. If r : s = 1 : 32, then the value of 24a is
f(t) =
Define g(x) = , x ∈ (1, ∞). Let α denote the number of solutions of the equation g(x) = 0 in
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4
A. C D B C
SECTION-I (ii)
Q. 5 6 7
A. B,C A,B A,B,C,D
SECTION-II (i)
Q. 8 9 10 11
A. 501.25 20.00 0.25 0.25
SECTION-II (ii)
Q. 12 13 14 15 16 17
A. 3 4 3 23 135 24
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 18 19 20 21
A. C B B D
SECTION-I (ii)
Q. 22 23 24
A. A,C A,D A,C,D
SECTION-II (i)
Q. 25 26 27 28
A. 5.00 5271.00 9.00 7.00
SECTION-II (ii)
Q. 29 30 31 32 33 34
A. 1250 200 48 180 7 9
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 35 36 37 38
A. D C B A
SECTION-I (ii)
Q. 39 40 41
A. A,B,C,D A,B,C A,B
SECTION-II (i)
Q. 42 43 44 45
A. 34.00 6.00 2.00 1.00
SECTION-II (ii)
Q. 46 47 48 49 50 51
A. 50 10 1 26 24 6
SOLUTIONS
PART-1 : PHYSICS
1) 0 to L
L to 2L
at x =
emf = 0
2)
3)
5) The electric field inside sphere is zero. So dipole will oscillate when r > R.
For r > R; E =
ω=
when r = 2R
when r = 10 R
6)
(A) wall = kf – ki = 0
wg + wB + wv + wext = 0
mgd –
(slowly v = 0)
v = 7 m/s
(C) H =
7) x = 2R
For H+ → m =
∴x= = 4 cm
Option B
For Am = 144
x= = 48 cm
Option C
for Am = 1
x = 4 cm & for Am = 196
x = 56 cm.
so x0 = 4 cm & x1 = 56 cm
∴ x1 – x0 = 52 cm.
Option D
Minimum width = R
for AM = 196
wmin = R = = 28 cm
8)
for 8th fringe
y=
ymax =
ymin =
ymax – ymin =
λ = 5000Å
D = 1m
dmax = 0.34 mm
dmin = 0.76 mm
= 8 × 5 × 10–4 ×
9) y =
for v → max ⇒
For
cos ωt = 1 ⇒ sin ωt = 0
⇒ d = 0.8 mm vmax =
10) At T t0 = 0
Before collision
11) Particles at mean
w.r.t. to cm
12)
V=
∴ % Error in V = 2(% error in D) + % error in H.
∵ Least count is 2mm.
∴ % error in D = = 1%
& % error in H = = 1%
So % error in V = 2 × 1% + 1% = 3%
For collision
∴ v = v0
So T1 =
∴ T1 = .....(1)
For case II,
arel = 0
For collision,
∴v=
So, T2 =
T2 =
∴ T2 = ........(2)
so, ⇒
14)
Solid angle made by plane surfaces Ω = 2 × 2π(1 – cos θ)
⇒ Ω = 4π – 4πcos θ
So solid angle made by curved surface = 4π – Ω
= 4π – (4π – 4π cos θ) = 4π cos θ
ϕ30° = ϕ =
⇒n=3
16)
due to wire
dV =
vR – vP = =
= –9V
vR – vP = –126 – 9 = – 135V
vP – vR = 135 V
17)
Case–1
P – P = ΔP =
0
Case–2
→ (Neglected)
R= ⇒ R1 =
ΔP1 = =
PART-2 : CHEMISTRY
18)
(A)
(B)
(C)
(D)
19)
Charge balance
8= ×3+ ×2+6
x = 0.89
20)
21)
26)
Value of =
Answer is ⇒ 5271
27)
30) Vessel – I :
(ΔTb)1 = i1 × Kb ×
Vessel – 2 :
(ΔTb)2 = i2 × Kb ×
31) A = T 2 H-bond
G≡C 3 H-bond
Number of A=T pair = 6
Number of G ≡ C pair = 8
Number of H-bond involve in A = T = 6 × 2 = 12
Number of H-bond involve in G ≡ C = 8 × 3 = 24
Energy required for A = T = 12 × 1 = 12
Energy required for G ≡ C = 24 × 1.5 = 36
Total energy required 12 + 36 = 48
0
6 –1β
238
32) 92U → Pb206
82 + 8 2He4 +
t = 0 N0 = 1 + 15 = 16 0
t=t Nt = 1 15
As per 1st order kinetics :
f = age = 4 × f1/2
= 4 × 4.5 × 109 yrs.
= 18 × 109 yrs.
= 180 × 108 yrs.
34)
No. of –CH3 group (methyl group) in S is → 9
PART-3 : MATHEMATICS
35)
36)
Area = =
37)
= (1∞ form)
⇒ k2 – 1 = 3 ⇒ k = 2
38)
n ∈ I+
(A)
→ finite solutions
(B)
→ 9 solutions
(D)
39)
Now, if αβ + 3 > 0,
∴ limit = 0 if αβ + 3 > 0
40)
Line passing through 'P' is
C1 (λ + 1, 2λ + 3, λ + 2)
put C1 in L → (λ + 1) – (2λ + 3) + 3(λ + 2) = 6
⇒ λ = 1 ⇒ Q(2, 5, 3)
41)
42)
Number of elements in S × S = 36
Number of possible ordered pairs which satisfy given condition = 36 – 16 = 20
n(X) = 20C6
m = 20
43)
44)
Let ...(1)
...(2)
2I1 – I2 = 0
45)
– (0 + 0) =
46)
f(0) = 0
⇒
f(2x) = 2f(x)
f(3x) = f(2x) + f(x) = 3f(x)
f(4x) = 4f(x)
f(5x) = 5f(x)
f(nx) = nf(x)
n = 4, x = f(1) = 4f ⇒ –20 = 4f ⇒
g(x + y) = g(x) g(y)
g(0) = g2(0) ⇒ g(0) = 1
g(nx) = gn(x)
n = 6, x = – g(–2) = g6 = (2)6 = 64
g(0)
(–5 + 64 – 9) × 1 = 50
47)
P(W1 ∩ G2 ∩ B3) =
⇒ N = 65, 10
Also
⇒
⇒ N = 10
48)
49)
= (1 + 3) – (2 – 3) + (–2, –1) =
Given equation
=
50)
x2 = –4ay
2x = –4ay'
⇒
equation of normal
y + 6a = –2a
y = –2a – 6a = –8a
α = 8a
Equation of line L
y = –8a
x2 = –4ay
x2 = +32a2 ⇒
S = 128a2
r = 4a
⇒a=1
51)
Graph of f(t)
Apply L'Hospital
α+β=4+2=6