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G.C 2-7 Lab

The document discusses how various substances affect chemical equilibria in solutions, detailing shifts in equilibrium when NaC₂H₃O₂, HCl, NaOH, and other compounds are added. It explains the resulting changes in ion concentrations, pH levels, and the colors of the solutions, indicating whether the shifts are endothermic or exothermic. The document also includes specific equilibrium equations related to the reactions described.

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5 views3 pages

G.C 2-7 Lab

The document discusses how various substances affect chemical equilibria in solutions, detailing shifts in equilibrium when NaC₂H₃O₂, HCl, NaOH, and other compounds are added. It explains the resulting changes in ion concentrations, pH levels, and the colors of the solutions, indicating whether the shifts are endothermic or exothermic. The document also includes specific equilibrium equations related to the reactions described.

Uploaded by

64x4t2zdhq
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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G.C.

2-7: Equilibrium shifts Maddox


Anderson
1. Did the equilibrium shift and in which direction? -> Adding NaC₂H₃O₂
introduces C₂H₃O₂⁻ ions, increasing its concentration, reaction shifts
left to reduce added acetate ions, H+ decreases.
2. How did the pH of the solution after adding NaC 2H3O2 to it? (Identify
which ion is being added to the solution and how it affects the
concentration of other ions present in the solution.) -> pH will increase
because H+ concentration decreases.
3. Explain how the equilibrium shifted when you added HCl to the
solution? -> HCl increases H+ ions, equilibrium shifts right to produce
more dichromate.
4. Which chromium ion is orange, and which is yellow? How did you
know? -> chromate is yellow, dichromate is orange. I know this
because adding H+ from HCl shifts right, producing dichromate.
5. How did the equilibrium shift when you added NaOH to the solution
(think about what NaOH will react with and how will that result will
affect the other components present in the solution.) -> NaOH
neutralizes H+, decreasing its concentration, shifting the reaction to
the left.
6. Explain how the equilibrium shifted when you dissolved the BiCL 3 in
excess water. -> adding water decreases H+ and Cl- ions, shifting the
reaction to the right.
7. Explain how the equilibrium sifted after the addition of HCl. -> HCl
increases the concentration of H+ and Cl-, shifting the equilibrium to
the left to dissolve the BiOCl.
8. Explain how the equilibrium shifted after dilution. -> Dilution reduces
all ions concentrations, shifting the reaction to the right side which has
more ions present.
9. According to the equilibrium equation, which ions do you have after the
solid was diluted? Explain how you know the identity of the ions
present. -> Dilution favors the side with more particles (left), meaning
there will be mostly Co(H2O)62+.
10. Explain what happened when HCl was added to the solution. ->
HCl increases Cl-, shifting equilibrium to the right to form more CoCl4 2-.
11. Explain what happened when the solution was heated. Was the
shift in equilibrium exothermic or endothermic? -> Heating favors the
endothermic side (takes in heat), and because it turns blue the shift to
the right is endothermic.
12. Explain what happened when the solution was cooled. Was the
shift in equilibrium endothermic or exothermic? -> Cooling favors the
exothermic side, since it turns the solution pink, the shift to the left is
exothermic.
13. When the test tube was placed in the hot water bath, was the
shift in equilibrium endothermic or exothermic? Explain. -> heating
made the solution more red, meaning the reaction shifts right, and that
it is endothermic.
14. Explain what happened when you added more Fe(NO 3)3 and
KSCN. -> The reaction shifts right and solution becomes more red.
15. Explain what happened after you added AgNO3. Hint: determine
the potential products being formed when adding AgNO3 to the solution.
-> The solid AgSCN is formed, decreasing SCN- concentration, shifting
the reaction left which causes a lighter solution color.
16. Explain what happened after you added NaOH. Hint: determine
the potential product being formed from adding NaOH the solution. ->
Fe(OH)3 is formed, reducing Fe3+ concentration, shifting the solution
left, reducing the redness of the solution.

System #’s:

1. HC2H3O2 <-> H+ + C2H3O2-


2. 2CrO42- + 2H+ <-> Cr2O72- + H2O
3. BiCl3 + H2O <-> 2H+ + BiOCl + 2Cl-
4. [Co(H2O)6]2+ +4Cl- <-> [CoCl4]2- + 6H2O
5. Fe3+ +SCN- <-> [Fe(SCN)]2+

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