Thermal Unit Operation L7 Corrected
Thermal Unit Operation L7 Corrected
➢ Consider a double pipe heat exchanger in which the hot fluid flows
through the inner pipe and the cold fluid flows through the outer pipe.
➢Heat is first transferred from the hot fluid to the wall by convection,
through the wall by conduction, and from the wall to the cold fluid
again by convection. The thermal resistance network associated with
this heat transfer process involves two convection and one conduction
resistances, as shown in Figure
Overall heat transfer coefficient (U)
➢
𝑇ℎ −𝑇1
➢ 𝑄ሶ from hot fluid to wall 𝑄ሶ = ℎ𝑖 𝐴𝑖 𝑇ℎ − 𝑇1 , 𝑄ሶ = 1 ……1
ℎ𝑖 𝐴𝑖
(𝑇1−𝑇2) (𝑇1−𝑇2)
ሶ ሶ ሶ
➢ 𝑄 through the wall 𝑄=2𝜋KL 𝐷𝑜 , 𝑄 = 𝐷𝑜 ………….2
ln( 𝐷 ) ln( 𝐷 )
𝑖 𝑖
2𝜋KL
𝑇2−𝑇𝑐
➢ 𝑄ሶ from the wall to cold fluid 𝑄ሶ = ℎ𝑜 𝐴𝑜 𝑇2 − 𝑇𝐶 , 𝑄ሶ = 1 ……….3
ℎ𝑜𝐴
𝑜
Overall heat transfer coefficient (U)
➢ Addition of the numerator and denominator of equn 1, 2 and 3 become
𝑇ℎ − 𝑇1 + 𝑇1 − 𝑇2 + 𝑇2 − 𝑇𝑐
𝑄ሶ =
𝐷𝑜
ln( )
1 𝐷𝑖 1
+ +
ℎ𝑖 𝐴𝑖 2𝜋KL ℎ𝑜𝐴𝑜
𝑇ℎ −𝑇𝐶 ∆𝑇
ሶ
𝑄= 𝐷 = =UA∆𝑇
ln( 𝐷𝑜 ) 𝑅
1 𝑖 + 1
+
ℎ𝑖 𝐴𝑖 2𝜋 KL ℎ𝑜𝐴
𝑜
1 1
Where U = = 𝐷 𝑖𝑠 𝑡ℎ𝑒 𝑜𝑣𝑒𝑟𝑎𝑙𝑙 ℎ𝑒𝑎𝑡 𝑡𝑟𝑎𝑛𝑠𝑓𝑒𝑟 𝑐𝑜𝑒𝑓𝑓𝑖𝑐𝑖𝑒𝑛𝑡
𝑅 ln( 𝑜 )
1 𝐷𝑖 1
+ +
ℎ𝑖 𝐴𝑖 2𝜋 KL ℎ𝑜𝐴
𝑜
Fouling of heat exchangers
➢ During heat exchanger operation; dirt materials (scale or corrosion)
deposits on the heat exchanger surface as a result of fluid impurities,
rust formation, or reactions between the fluid and the wall material.
➢ The deposition/accumulation of dirt material (scale or corrosion) on
heat exchanger surface is known as fouling of heat exchangers.
❖Fouling can be caused by the following sources:
1) Scaling or precipitating fouling: Caused by the crystallization of
dissolved substance. Example CaCO3, CaSO4, Ca3(PO4)2, CaSiO3,
Ca(OH)2, Mg(OH)2, MgSiO3, Na2SO4, LiSO4, and Li2CO3.
2) Corrosion fouling is caused by chemical reaction of some fluid
constituents with the heat exchanger tube material.
Fouling of heat exchangers (Cont’d…)
3) Chemical reaction fouling as a result of chemical reactions in
process stream.
✓ Fouling will reduce the overall heat transfer coefficient and heat
transfer rate.
✓ Fluid temperature and velocity at any inlet or outlet remain the same.
d𝑄ሶ
d𝑄ሶ =- 𝑚ሶ ℎ 𝐶𝑝ℎ d𝑇ℎ , d𝑇ℎ =− …….4
𝑚ሶ ℎ 𝐶𝑝ℎ
d𝑄ሶ
d𝑄ሶ =𝑚ሶ 𝑐 𝐶𝑝𝑐 d𝑇𝑐 , d𝑇𝑐 = …….5
𝑚ሶ 𝑐 𝐶𝑝𝑐 subtraction of equn 5
from equn 4 becomes
d𝑄ሶ d𝑄ሶ
d𝑇ℎ - d𝑇𝑐 = − -
𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
ሶ 1 1
d(𝑇ℎ - 𝑇𝑐 ) = −d𝑄( ሶ + ) …….6
𝑚ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
Log mean temperature difference (LMTD) method…..
➢ The rate of heat transfer in small differential area of heat exchanger
can also be expressed as;
1 1
d(𝑇ℎ - 𝑇𝑐 ) = −U(𝑇ℎ − 𝑇𝑐 )d𝐴𝑠 ( + ), and rearrange this to
𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
d(𝑇ℎ − 𝑇𝑐) 1 1
= −U ( + )d𝐴𝑠 , Let 𝑇ℎ − 𝑇𝑐 =∆𝑇,then
𝑇ℎ −𝑇𝑐 𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
d∆𝑇 1 1
= −U ( + )d𝐴𝑠 … … … … … .8
∆𝑇 𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
Log mean temperature difference (LMTD) method…..
➢ Integrate equation 8 from heat exchanger inlet (1) up to its outlet (2)
∆𝑇1 −∆𝑇2
ln∆𝑇1 − 𝑙𝑛∆𝑇2 = U𝐴𝑠 ( ),
𝑄ሶ
∆𝑇1 −∆𝑇2
ሶ U𝐴𝑠
𝑄=
ln∆𝑇1 −𝑙𝑛∆𝑇2
∆𝑇1 −∆𝑇2
ሶ U𝐴𝑠
𝑄= ∆𝑇
ln(∆𝑇1 )
2
ሶ U𝐴𝑠 ∆𝑇𝑙𝑚 ……heat transfer rate for parallel flow heat exchanger
𝑄=
∆𝑇1 −∆𝑇2
∆𝑇𝑙𝑚 = ∆𝑇 …. Logarithmic mean temperature difference for parallel heat
ln(∆𝑇1 )
2
exchanger
Log mean temperature difference (LMTD) method…..
Ⅱ) Counter flow heat exchanger
➢ The heat transfer rate equation and the log mean temperature
difference expression for counter flow heat exchanger is determined in
similar way as for parallel flow heat exchanger.
∆𝐓𝟏
T
∆𝑇1 = 𝑇ℎ,𝑖𝑛 − 𝑇𝑐,𝑜𝑢𝑡 ∆𝐓𝟐
∆𝑇2 = 𝑇ℎ,𝑜𝑢𝑡 − 𝑇𝑐,𝑖𝑛
✓ Fluid temperature and velocity at any inlet or outlet remain the same.
d𝑄ሶ
d𝑄ሶ =- 𝑚ሶ ℎ 𝐶𝑝ℎ d𝑇ℎ , d𝑇ℎ =− …….3a
𝑚ሶ ℎ 𝐶𝑝ℎ
d𝑄ሶ
d𝑄ሶ =−𝑚
ሶ 𝑐 𝐶𝑝𝑐 d𝑇𝑐 , d𝑇𝑐 =- …….4a
𝑚ሶ 𝑐 𝐶𝑝𝑐 subtraction of equn 4a
from equn 3a becomes
d𝑄ሶ d𝑄ሶ
d𝑇ℎ - d𝑇𝑐 = − -(- )
𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
ሶ 1 1
d(𝑇ℎ - 𝑇𝑐 ) = −d𝑄( ሶ − ) …….5a
𝑚ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
Log mean temperature difference (LMTD) method…..
➢ The rate of heat transfer in small differential area of heat exchanger
can also be expressed as;
1 1
d(𝑇ℎ - 𝑇𝑐 ) = −U(𝑇ℎ − 𝑇𝑐 )d𝐴𝑠 ( − ), and rearrange this to
𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
d(𝑇ℎ − 𝑇𝑐) 1 1
= −U ( − )d𝐴𝑠 , Let 𝑇ℎ − 𝑇𝑐 =∆𝑇,then
𝑇ℎ −𝑇𝑐 𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
d∆𝑇 1 1
= −U ( − )d𝐴𝑠 … … … … … .7a
∆𝑇 𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
Log mean temperature difference (LMTD) method…..
➢ Integrate equation 7a from heat exchanger inlet (1) up to its outlet (2)
∆𝑇1 −∆𝑇2
ln∆𝑇1 − 𝑙𝑛∆𝑇2 = U𝐴𝑠 ( ),
𝑄ሶ
∆𝐓𝟏
∆𝑇1 −∆𝑇2
ሶ U𝐴𝑠
𝑄=
ln∆𝑇1 −𝑙𝑛∆𝑇2 ∆𝐓𝟐
∆𝑇1 −∆𝑇2
ሶ U𝐴𝑠
𝑄= ∆𝑇
ln(∆𝑇1 )
2
ሶ U𝐴𝑠 ∆𝑇𝑙𝑚 ……heat transfer rate for counter flow heat exchanger
𝑄=
∆𝑇1 −∆𝑇2
∆𝑇𝑙𝑚𝐶𝐹 = ∆𝑇 …. Logarithmic mean temperature difference for counter
ln(∆𝑇1 )
2
flow heat exchanger
Log mean temperature difference (LMTD) method…..
Ⅲ) Cross flow heat exchanger
➢ For cross-flow heat exchangers having mixed and unmixed flow, the
derivation of expression for logarithmic mean temperature difference
becomes quite complex. The simple method is to modify the simple
LMTD by correction factors (F), which is given in chart form.
➢ The easy method to solve the unknown heat transfer rate and out let
temperature of hot and cold fluid is the effectiveness-NTU method.
2) Effectiveness–NTU method (Cont’d....)
➢The effectiveness-NTU method is based on a dimensionless parameter
called effectiveness of heat exchanger (∈).
Where 𝐶ℎ =𝑚ሶ ℎ 𝐶𝑝ℎ and 𝐶𝑐 =𝑚ሶ 𝑐 𝐶𝑝𝑐 is the heat capacity rate of hot and cold
fluid respectively
2) Effectiveness–NTU method (Cont’d....)
➢The maximum possible heat transfer rate in a heat exchanger occurs at
maximum temperature difference between the inlet temperatures of
the hot and cold fluids.
where 𝐶𝑚𝑖𝑛 is the heat capacity rate of fluid with the smaller heat
capacity rate
2) Effectiveness–NTU method (Cont’d....)
❖ The effectiveness–NTU equation for parallel flow heat exchanger
𝑇ℎ,𝑜𝑢𝑡 −𝑇𝑐,𝑜𝑢𝑡 1 1
For parallel flow ln = −U𝐴𝑠 ( + ) …….3
𝑇ℎ,𝑖𝑛 −𝑇𝑐,𝑖𝑛 𝑚ሶ ℎ 𝐶𝑝ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐
1 1 1 1
but = and = substitute into equation 3
𝑚ሶ ℎ 𝐶𝑝ℎ 𝐶ℎ 𝑚ሶ 𝑐 𝐶𝑝𝑐 𝐶𝑐
𝑇ℎ,𝑜𝑢𝑡 −𝑇𝑐,𝑜𝑢𝑡 1 1 1
ln = −U𝐴𝑠 ( + ) rearranging this by taking as factor
𝑇ℎ,𝑖𝑛 −𝑇𝑐,𝑖𝑛 𝐶ℎ 𝐶𝑐 𝐶𝑐
𝐶𝑐
𝑇ℎ,𝑜𝑢𝑡 = 𝑇ℎ,𝑖𝑛 − (𝑇 − 𝑇𝑐,𝑖𝑛 )………..5
𝐶ℎ 𝑐,𝑜𝑢𝑡
2) Effectiveness–NTU method (Cont’d....)
subtracting and adding Tc,in in equation 5 gives
𝐶𝑐
𝑇ℎ,𝑜𝑢𝑡 = 𝑇ℎ,𝑖𝑛 − Tc,in + Tc,in − (𝑇 − 𝑇𝑐,𝑖𝑛 )…….6
𝐶ℎ 𝑐,𝑜𝑢𝑡
𝐶
𝑇ℎ,𝑖𝑛 −Tc,in +Tc,in −𝑇𝑐,𝑜𝑢𝑡 − 𝐶 𝑐 (𝑇𝑐,𝑜𝑢𝑡 −𝑇𝑐,𝑖𝑛 )
ℎ −U𝐴𝑠 𝐶𝑐
ln = (1+ )
𝑇ℎ,𝑖𝑛 −𝑇𝑐,𝑖𝑛 𝐶𝑐 𝐶ℎ
[
ln 1 − (1 +
𝐶𝑐 𝑇𝑐,𝑜𝑢𝑡 −Tc,𝑖𝑛
)
𝐶ℎ 𝑇ℎ,𝑖𝑛 −Tc,in
) ]= −U𝐶 𝐴 (1+ 𝐶𝐶 )……..7
𝑐
𝑠 𝑐
ℎ
2) Effectiveness–NTU method (Cont’d....)
From definition of effectiveness, we have
𝑄ሶ 𝐶𝑐 (𝑇𝑐,𝑜𝑢𝑡 −𝑇𝑐,𝑖𝑛 )
∈ = ሶ =
𝑄𝑚𝑎𝑥 𝐶𝑚𝑖𝑛 (𝑇ℎ,𝑖𝑛 −𝑇𝑐,𝑖𝑛 )
[
ln 1 − (1 +
𝐶𝑐
𝐶ℎ
) ∈
𝐶𝑚𝑖𝑛
𝑪𝒄
) ]= −U𝐶 𝐴 (1+ 𝐶𝐶 )…….8
𝑐
𝑠 𝑐
ℎ
− 𝐴U (1+ 𝐶𝑐 )]
[ 𝐶 𝑠
1−𝑒 𝑐 𝐶ℎ
∈𝑝𝑎𝑟𝑎𝑙𝑙𝑒𝑙 flow = 𝐶 𝐶 ……….9
(1+𝐶 𝑐 ) 𝑚𝑖𝑛
ℎ 𝑪𝒄
2) Effectiveness–NTU method (Cont’d....)
➢ Taking either 𝐶𝑐 or 𝐶ℎ to be 𝐶𝑚𝑖𝑛 (both give the same result), so let’s
take 𝐶𝑐 = 𝐶𝑚𝑖𝑛 and Ch = Cmax then equation 9 is simplified to;
[
− U𝐴𝑠(1+ 𝐶𝑐 )]
1−𝑒 𝐶𝑐 𝐶ℎ
∈𝑝𝑎𝑟𝑎𝑙𝑙𝑒𝑙 flow = 𝐶 𝐶 ………….….9
(1+ 𝑐 ) 𝑚𝑖𝑛
𝐶ℎ 𝑪𝒄
U𝐴𝑠(1+ 𝐶𝑚𝑖𝑛 )]
−
[𝐶
1−𝑒 𝑚𝑖𝑛 𝐶𝑚𝑎𝑥
∈𝑝𝑎𝑟𝑎𝑙𝑙𝑒𝑙 flow = 𝐶 𝐶
(1+ 𝑚𝑖𝑛 ) 𝑚𝑖𝑛
𝐶𝑚𝑎𝑥 Cmin
[
− 𝐴𝑠U (1+ 𝐶𝑚𝑖𝑛 )]
1−𝑒 𝐶𝑚𝑖𝑛 𝐶𝑚𝑎𝑥
∈𝑝𝑎𝑟𝑎𝑙𝑙𝑒𝑙 flow = 𝐶 ……………10
(1+𝐶 𝑚𝑖𝑛 )
𝑚𝑎𝑥
2) Effectiveness–NTU method (Cont’d....)
U 𝐴𝑠
➢ The parameter in equation 10 is called number of transfer unit (NTU)
𝐶𝑚𝑖𝑛
U𝐴𝑠
NTU=
𝐶𝑚𝑖𝑛
𝐶𝑚𝑖𝑛
let =C where c is a capacity ratio
𝐶𝑚𝑎𝑥