| aga 4 = i i a ~~~ amet a lan j 1 | | M.G KASHI VIDYAPITH UNIVERSITY, VARANASI i M.Sc. | (SEMESTER) . ) CHEMISTRY ~~ GED0] M.G. KASHI VIDYAPITH UNIVERSITY, VARANASI SVLtapus*, M.Sc. | Sem. CHEMISTRY (PAPER-FIRST), (INORGANIC CHEMISTRY - 1) UNIT-T: Symmetry and Group Theory In Chemistry Symmetry elements and symmetry operation, definitions of groups, subgroups, relation between orders of a finite group and its subgroup. Conjugacy relation and classes. Point symmetry group. Schontlies symbols, representation of groups by matrics (representation of the Cn, Cnv, Cnh, Dnh etc groups to be worked out explicitly). Character of a representation. Character tables and their use ii Spectroscopy. UNIT-II : Stereochemistry and Bonding in Main Group Compounds VSEEPR, Walsh diagrams (tri and penta-atomic Molecules), dr-px bonds, bent rule and energetics of hybridization, some simple reactions of covalently bonded molecules. UNIT-IIl: Metal-Ligand Equilibria in Solution Stepwise and overall formation constants and their interaction, trends in stepwise constants, factors affecting the. stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, determination of binary formation constants by pH metry and spectrophotometry. UNIT — IV: Metal-Ligand Bonding . Limitation of crystal field theory, molecular orbital theory. Octahedral, tetrahedral and square planar complexes, _-bonding and molecular orbital theory. M.G. KASHI VIDYAPITH UNIVERSITY, VARANASI SYLLABUS", M.Sc. | Sem. CHEMISTRY (PAPER-SECOND) (ORGANIC CHEMISTRY - I) UNIT-1: Nature of bonding in Organic Molecules Delocalized chemical bonding-conjugation, cross conjugation, resonance, hyperconjuation, bonding in fullerenes. Aromaticity in benzenoid and non-benzenoid Compounds, Huckel's -rule, energy level of pi-molecular orbitals, annulenes, antiaromaticity. UNIT-II A- Stereochemistry Conformational analysis of cycloalkanes, decalines, effect of conformation of reactivity Elements of symmetry; chirality, molecule with more than one chiral center, threo and erythro isomers, stereospecific and stereoselective synthesis.Asymmetric s i \s ynthesis. biphenyls, allenes and B- Reaction mi of determining mect Stability and reactivity Spiranes echanism, Structure and hanism, reactivi anism, isotope ettect. Generation’ stactoss ' of benzynes, carbenes and nitrenes, Effect of 'y resonance and field effect, steric effect, rf ‘substitution and SN>, the neighbor ing group paricpation by Pi ang Sigma vende, Terie assistance Classical and non classical carbocations.” aliphate gions Mechanism nucleophilic substitution at an al sree takin a b carhon. Reactivity effects of substrate ambideni nucleopile, regieselectvty PS “easton medium, A- Aromatic electrophilic substit stitution protie Me, arenium ion mechanism, orientation and reactivity, ene Profile diagrams. The Ortho/Para’ ratio, ipso attack, oriental 7” her ring systems. Vilsmeir reaction, Gaitemann-Koch reaction. ‘The SNe; Morale nucleophilic substitution A stfect of substrate structure, isaving group and atacring nace wing group and att ‘The Von Richter, Sommelet Hauser, and Smiles rearrangements, M.G. KASHI VIDYAPITH UNIVERSITY, ‘SYLLABUS’, M.S¢ SareHeuey ( 3", M.Sc. | Sem. CHEMISTRY. 1 (PHYSICAL CHEMISTRYS) ed le. UNIT A-Unifying Principles radiate momagnatic radiation, interaction “of electromagnetic radia ‘matter-absorption, emission, transmission, reflection, ction, “dispersion, polarization and’ scattering. Uncertainty relation and natural line width and natural line broadening, sel substation’ on thet ano frequencies intensities, non ric or avon of not hares SrestaseoMy Shel ar a ath; anharmonicity; P.O.R. branches, r ules, Selection rules, normal modes of vibration, octing. the band positions and intensities.) 'B. Flaman Spectro’ Classical and quantum theories of Raman effect Piro tational, vibrational ‘and. vibrational-rotational Raman | Sher ion rules, mutual exclusion princi a ‘Quantum Chemistry ‘A. Fundamental Background Operators, Postulates of Quantum Mechanics, Hamiltonian for ular momentum. ferent systems Moto Exact quantum Mechanical Results: B Inteoductinger equation, discussion of solutions, of 18 schrouhger equation to some model system viz,partice in a Box athe ae rnie osellator, the rigid rotar, the hydrogen atom. C. Approximate Methods: “The Variation theorem, linear variation principlo. Perturbation theory(rest order and. nondegenerate) \ Application of variation ane hod and perturbation theory to the Helium atom. 'D. Electronic structures of Atoms: AusselSaunders terms and coupling schemes, term symbols for the band 4" configurations Spin orbit coupling ane Zeeman Mey "introdustion to the methods of self-consistent field, Slaters tions of polyatomic anos pe factors E, Molecular orbital theory: Huckel theory of conjugated systems, bond order and charged density. calculations.” Application ‘to ethylene, butadiene, ¢yclobutadiene and Benzene molecules, 'UNIT- IV : Chemical Dynamics : Methods of determining rate law, collision theory of reaction rates steric factors Activated complex theory, Arrehenius equation tS the activated complex theory, lonic reactions kinetic salt effect, Steady state kinetics. Dynamic chain (hydrogen-bromine reaction - wrolysis of acetaldehyde), photochemical _(hydrogenbromine itttion hydrogen-chloride reactions) and oscillatory | reactions (Belousay Zhabotinsky reaction) homogeneous catalysis.kinetics of Snzyme reaction General features of fast reaction study of fast faction by relaxation method flash photolysis and the nuclear magnetic resonance method. Dynamics of unimolecular reactions (undemann Hinshelwood and Rice ~Rampsperger-kassel, -marcus (ARKM) theories of unimolecular reactions).Asymmetric syithests. Optical act biphenyls, allenes and spi , iranes 8. Reaction mechanism, Of determining mechanism, Stability and react ‘Structure on reacti Qvanttative treatment. “onanee and UNIT-I Aliphatic nucleophilic substitution The SNa SNj, mixed SN; and SNz2, the neighborin, mechanism, neighboring group participation by Pi and Sigma bord: anchimeric assistance Classical and non classical carbocation, The SN; mechanism nucleophilic substitution at an all sphatie iigoral and a vinylic carbon. Reacti structure, attacking nucleophile. leaving group and reactior ambident nucleophile, regioselectivit) 9 group ne UNIT-N a A- Aromatic electrophilic substitution The arenium ion mechanism, orientation and reactivity, profile diagrams. The Ortho/Para ratio, ipso attack, orientatior ‘other ring systems. Vilsmeir reaction, Gattemann-Koch reaction. B- Aromatic nucleophilic substitution fF The SNAr. SN;, benzyne and SRN; mechanism. React effect of substrate structure, leaving group and attacking nucleophi The Von Richter, Sommelet Hauser, and Smiles. rearrangements. M.G. KASHI VIDYAPITH UNIVERSITY, VARANASI SYLLABUS", M.Sc. | Sem. CHEMISTRY (PAPER-THIRD) (PHYSICAL CHEMISTRY - |) UNIT: “Electromagnetic _ radiation, radiation with matter-absorption, emission, transmission, reflection, Unifying Principles: interaction of lectromagnetic refraction, dispersion, polarization and’ scattering. Uncertainty relation and natural line idth and natural line broadening, selection rules, intensity of spectral lines, Born Oppenheimer approximation, rotational, vibrational and electronic energy levels. B-Microwave Spectroscopy Classification of molecules, rigid rotor model, Etfect of isotopic substitution on the transition frequencies. intensities, non rigid rotor. Stark effect. Applicatio UNIT-iI: Vibrational Spectroscopy A. Infrared Spectroscopy »,___ Review of linear harmonic oscillator, ‘vibrational energies of diatomic molecules, zero point energy, force constant and bond tivity In the absence of chiral carbon Structure and reactivity Moth sotope effect. Generation’ gvosies Of benzynes, carbenes and nitrenes, Effect of Id effect, steric effect, 19 group ty effects of substrate energy =" ae a aa (iii) e “ale ngth; anharmonicity, P.O.R. ranches, rations of POM ets cules, Selection rules, norms t tions and intensities. ena eben Pe Raman pect —P' naman afl Pe Clacsal and, ava gionakoltgnal aman spac jon tules, mutual exclusion principle. Appli een UNIT- Hh: ate creed cat Bae Operators, postulates ‘of Quantum Mechanics, Hamiltonian for 1 ee Ree morn. The. Schrodinger equation, Giscussion Odie theorem, near var inciple. Perturbation ont akin rar ase) Agen fan pest Suins fr ar SP coun and, ura ” ” uration type orbitals. E. Molecular orbital theory: nd order and charged 1 theory of conjugated systems, bo! density calculations. Application 10” ethylene, butadiene, jiene and Benzene molecules. oyctobutaciene 2nd ir IV : Chemical Dynamics sho Methods of determining rate law, collision theory of reaction rates steric factors Activated complex theory, Arrehenlus equeten tnd the activated complex theory, lonic reactions Kinetic salt effect, kinetics: Dynamic chain (hydrogen-bromin fon seat et Mietaldehyae) photochemical (hydrogenbromine Teabtion hydroger-chloride reactions) and oscillatory | reactions (Belousav Zhabotinsky reaction) homogeneous catalysis kinetics of enzyme reaction General features of fast reaction study of fast Feaction by relaxation method flash photolysis and the nuclear ignetic resonance method. Dynamics of unimolecular reactions (Lindemann Hinshelwood and Rice -Rampsperger-kassel, marcus (RRKM) theories of unimolecular reactions).(lv) M.G. KASHI VIDYAPITH UNIVERSITY a - VARANASI , YLLABUS", M.Sc. | Sem, CHEMISTRY (PAPER-FOURTH) (COMPUTER FOR CHEMISTS) (COMPULSORY FOR ALL STUDENT) UNIT-T: Introduction to Computer and Computing: Basic structure and lunctoning of computers wit @ BC ag example Memory, VO devices, Secondary storage Computer languages. Operating systems with DOS as an example OWS Data Processing principles o Introduction to UNIX’ and Programming. algorithms and flowcharts. ‘Computer Programming in FORTRANIC/BASIC: The language features are here with reference FORTRAN. The instructor my choose another language such a} BASIC or C and the features may be replaced appropriately, Elements of the computer language. Co! Operations and symbols, expressions. Arithmat statement. Input, and Outpt, Form ment. Termi tatements. Branching statements such as IF or GO TO LOGIGAL variables. Double’ precision variables. Subsea I: Programming in Chemistry: of small computer codes formulae in chemistry such as van der W: inetics. ye decay. Evaluation of lattice energy-and i ‘adi tom expermenta al Linear smutancous equates sone sory. Elementary stuctural features such as bond lengths. bond angles, dihedral angles etc. of ‘molecules extracted from a database such as Cambridge data base. 3e of Computer Programmes: Developm Ex (daF Give the reasons ‘n PCI ere me more tolrahed wget 3. see M.G. KASHI VIDYAPITH UNIVERSITY: VR AN cR-FIRST. 2015 M.Sc, 1 Sem. CHEMISTRY (F “INORGANIC CHEMISTRY ~ a guaras 100 lon No. 7 Answer type Quest! Sham Arsraner One. question (410240) 35°) > NO3(115°) > AsCh(98-4") ‘equatorial bonds. than. other Nox(180°) > NOz! As Is(101%) > As Bs the axial bonds ‘complexes ms in PFs but it is “AF Col transition metal ions. mhere is rapid exchange of hibited in (CHs)2 PF jorine ator iJo_ is trigonal planar with 120° ‘expected to have trigonal pyramidas shape. Explain. AIF Wie the point group of the fo 5,BrFy,NHy- he following molecules and ions has (a) centre of Wich of t 2s inversion. (b) an S¢ axis? CO2, CzH2, BFs, SOz Unit-l meant by isomorphic group? Explain with molecular der three and four and. construct the point group multiplication table from each element. ss Or Give the character table of water, each point group is C2V. Give ‘one example each for the point group Coov. Dah and Cav.q 2 a en 2 _ Kashi Vidyapith (Chemistry) 3 “2 nied 1 i Vidyapith (Chemisty) IVERSITY 4. Explain bonding and shapes of any four of the following SHI VIDYAPITH UN t aes one basic of VSEPR theory #IFs, Se XiFe script MUG KASI" “Vy aRaNasl sc a oO a Msc. 1Sem. CHEMISTRY (paren SECON?) at x Sc. " CHEMIS A L 5. Explain the following : 5x 3e15 fi kone A No. \ Thr jours ty ui al _" {@) Why do GCl,, NHs and H,0 have different shape, pe rower ro questions inal si Ans ewer One question S ; (b) Discuss the molecular structure of SF, and ICI and justity i marl the positions of lone pair of electrons. 4 carrying 40 Samrying 15 marks from each Unit. (©) BeF is tinear while SF2 is nat. car ger 1 SIO ag cage of Bs 2 al Unita Sve sit the more stable SOE se. t@isingian between Ve ayramic and Kinetc stably, Crane 1 2MeIY Ts rated ing evs 229° ‘Arrange the following complex species in increasing order of ces whan do you understand Im AOA exambles. stability: 75x 2015 Wat ohead carbons. Exalan ON iy nbiphenys? JAUF.T, (AUCH, [Au Bro and [AU LT . co naar ro essonalconatons Croats), ne do (mg te novo, SOAS fan) have (i) react tosyate Fey compared 10 (). Explain dS thS> 2 (b) Discuss the mechanism of ati i (Discuss, th m of aquation -of .cisandtrans Or . Provide suitable explanation for the following: (6 x3 = 15) {a) The rate of water exchange for [Mo(H0)]"* Is very slow. {b) The log B value for (Fe F]* is 6 and that for (F, Cll’? is 1.3. What do these values indicate about these species? (©) Complexes containing chelate rings are more stable than these containing similar but unidentate ligand? UnitVv 8. What is crystal field theory? What are the theory and how are they overcome by legal fi Or 9. What are the basic postulates of MO theory of coordination complexes. Discuss ¢ and x metal ligand bonding in transition ‘metal complexes with reference to octahedral complexes. on {e)Discuse the outcome of, the, reaction of, singlet and triplet methylene species with cis-2-butene. (y How many symmetry elements/operations can describe the symmetry of a molecule? (@ How HNMR spectroscopy can be used to study aromatic and antinomatic compounds? is (when HBr adds to 1, S-butadiene at low tempertire WeSSoy 1, ‘2-adduct fs 1Srmed as the major product while ot ‘4-adduct that oo) @ CONNECT YOURSELF WITH. Physics, Chemistry> EXAM. NOTES jfath, zootozy. Botany |) _ figher” temperature (40°C), it is 1, predominates. Explain. ( in what type of solvents tho relative order of reactivity of the halide ton will be observed and why? FecrsBror() Teprsor>F (i) pve?ae () Draw: Newmann __ Show how the anti fo 5 Vidyapith (Chemistry) Hy M.G: KASHI VIDYAPITH UNIVERSITY, VARANASI 6 M.Sc. | Sem. CHEMISTRY (PAPER-THIRD), 2015 1 ICAL CHEMISTRY - !) a ree Hours: a ‘Maximum Marks : 100, U Question No. io uestions In all. Short Answer type N (@)Explain aromaticity in bentenoid and on-benzenoid oarvig 40 Srarks. Is compulsory. ‘Answer One question Deere from ear Ini Unital =) Define operators in Quantum Chemistry. {a) Discuss stereospecific and stere (©) Discuss the conformation of di (€) Explain the optical activity in biphenyls? Or (a) Whatis isotope ettect? 5 (b) Discuss the structure and reactivity of benzynes? (c) Discuss the optical activi ns. Uni - \tef Ditterentiate between SN, and SN reaction? \ydiscuss SNi mechanism? What do you understand by anharmonicity? ‘At higher temperature antistokes lines are more intense than jokes lines. Explain. ; i (@) What do you understand by ‘Selection Rule’ in spectroscopy. Define linear variation principle. Explain Stark effect. : What is meant by kinetic salt effect? Define a rigid rotar. What do you understand by self consistent field method? () Explain Zeeman splitting. lective synthesis? 5 aa i ; Unita (What are non-classical Soe 5 Wate classiication of molecules. Discuss rotational spectra of ‘wipe noms dn: osburs) diatomic molecule. or a eos om Participation by pi-bond, (a) Explain uncertainty relation and natural line width. 7 UD he oN Ee ont aca (0) Sat and discuss Bom Oppenheimer approximation. Unit-V i Define the necessary condition for IR spectroscopy. Find out the pascre the following reaction: expression for vibrational motion of a diatomic molecule. filsmeir reaction s Explain the zero point energy. 18 Von-Richter reaction 5 ~ Or Ag Ortho-Para ratio 5 What is Raman effect? Explain it by the help of classical theory , ior of Raman effect. Give a brief account of mutual exclusion rule. ). 46) What is ipso attack? Expl 5 . 15 44 Discuss the uranium ion mechanism. 5 Unit-ttt Discuss the react fect of substrate, leaving group and attacking mucleophile in aromatic nucleophilic substitution?S ca: Discuss the solution of: Schrodinger’s wave equation for one dimensional simple harmonic oscillator.6 a - ey yapith (c Explain Huckel Molecular orbital theory o como mein saiculate bond order and show. Huckel Moleculai system, diagram of butadiene on the basis of his theory.” tal Unit-lV 7] 5 eal ‘ASHI VIDYAPITH UNIVERSITY, VARANASI Se, | Sem, CHEMISTRY (PAPER-FOURTH), 2015 Discuss the Kinetcs of thermal combination of hycrogen ang computer FOR CHEMISTS) 2 ( + Or 15) (COMPULSORY FOR ALL STUDENTS) 0 tes ‘ ! wo Serious ‘Maximum Marks : 60 short notes on the following : ir Short Answer type Question No- bte : Answer five questions i a 1 carrying 20 marks is compulsory. Answer ‘One question ‘camying 10 marks from each Unit ein cay Paper is compulsory for all students, which Coes Fourth (A) th (8) Paper is to be attempted only by swaers 60 marie Toay background and fourth (C) Paper by students having etpomatics background only. Each of these papers carry 40 marks. Sarivate answer books willbe used for 1V (A) and IV (8)/ 1V(C) paper. us Give short answers of the following questions : 2x10=20 {@) Wy is t necessary to provide secondary storage in a digital computer system? " (p) State three features of Assembly language. {(@) Write the names of any two operating systems. ‘2 function? Give an example.of a function in any computer programming language. (@) What isthe task performed by a scanner? Is it an input or an output device? how we can save a file in MS-WORD. ite the formula for Van Der Waals equation and convert It (0 équivalent FORTRAN or C representation (n) What is an array in a computer program? How {() What do you mean by flowchart? Give an example. () What do you mean by Assignment Statement? Give an example, {a) Study of fast reaction by relaxation method (0) Osci (©) Steady state approximation. @ CONNECT YOURSELF WI uP! -, Chemistry, anveExam, NOTES ,USisem soa att ‘ a Units Jain with clear diagram 645 (a) Dot Matrix Printer ‘ u (i) oval Dept uit Or8 Kash! Vidyaplth (Che. 1 Unitst (Chomi 4, Write a program (in Basic ORTRAN() to rod an 9 ‘then to compute and pr ye square, cube and the same, with suitable messages. oe IVERSITY, VARANASI 1.Sc. 1 Sem. CHEMISTRY (PAPER-FOURTH), 2015 (Section ~ 8) Or |ATICS FOR CHEMISTS) B.Sc.) 5. Explain with examples : MATHEM rene, cousin ASS yy (ii) WHILE-DO statement 4 short Answer type ‘Question No. fe quarks. is compulsory. Answer One question Sand tic 110=10 (Nested loop Unitall 6. Write the programming code segmé radii from experimental data. Or Write the programming code segment for solv ‘simultaneous equations. Unit-lV & Write about the main features of a word processing softy package such as MS-WORD, with the help of examples, Or ‘4 .. Explain the applications and use of a software package ¢ MATLAB or LOTUS. jent for evaluation p_!anX_ ete Inearate feces tank ‘2 sample space and let E be an event. Then oth pal > CONNECT YOURSELF WT Oe, eo of the differential equation PE XA iC on) oy An Mm. NOTES i225 -@] -< wl | (i) Find r, if 7p, = 6840. @ Write Rodrigue’s formula. i cf : ax Birrg me ae i Prove that div grad (P) = Find the inverse of the matrix, 1 As]o 1 oo Unit-tt . Examine the continuity of the function : 75 4“uy serey u 10 Kashi Vidyapith (Chong : : : peeaentit =D Shite si Vidyapith (Chemistry) AN faa = x)= 41 oex ko gn R oF S configuration to the folowing ‘structures = 8. Give the important features of MOT € ntiguia of metal ligand bonding i von re Gomplex, compound. Draw molecular orbital ener 4 oe t agram for (CO(HO)<)”* and [COF.]”. leva seo = a i Hs 9. {a)Discuss the sigma and pi bonding in square plang eee complexes with the hi gemplexes wih. the help of molecular orbital enoray (©) Why is molecular orbital theory preferred over crystal Teen 4 sal theory in explaining metal-igand bending in transition m {¢) Diferentiate between Age a9 Bact? e) A el y the products (A) and (B) and give the mechanism of the for their formation. aman, @ © ad mechanism for bromination of te the major product. (q Draw all the isomers of 4-tertiary butylcyciohexanel and Srrange the conformers in decreasing order of their stability. (t)With the help of suitable structures explain why 3: hyéroxybenzolc acid is stronger than 4-hydroxybenzoic acid Nhereas 4-nitrobenzoic acid is stronger than 3-nitrobenzoic © CONNECT YOURSELF WITH Anve"E yan, NOTES nieces ‘Math, Zoology, Bota ach () Differentiate between compound | and compound Il on the ieir symmetry elements. pee << Sene-ee "Kashi Vidyapith (Chemist () Arrange the following compounds in the decreasing order their reactivity to-wards an. electrophile. Give gyi teasons for your answer. na a Benzene, Aniline, Acetanilide and Nitrobenzene. Define Hickel's rule. What are the necessary conditions fq anti-aromatic non-aromat aromatic, anti-aromatic and non-aromatic systems ‘of ty molecules having cycles of three (C,) and five (Cs) Carta atoms. q (0) Describe the stability of isomeric forms of [10] annulene. 05 iscuss the different energy levels of pi molecular orbitals q 1,3-Butadiene and Benzene. 1 Give example of two molecules showing cross conjugatio Write down their conjugal (b) Draw the conform: ‘and give the reasons for the most stable conformer. or Give suitable mechanism for any five of the following r (a) CICH,CH,SCH,CH,Cl —°/"_, CICH,CH,SCH; z 1 () [A aa! =a z oes ac 4 vidyapith (Chemistr”) -cH=cl (c) CaHsCHOH + SOCK 1 1 CHs CHs poe exon >—cHLOH* Os OH i “gH, VW (e) CHy eahon (0 CHy-CH- CH= CHe ee bi Bene = CH-CH2 (CH = CH: + CH3— CH 1 OC2Hs echanisms for aroma a jitfer from "SN and SN’ reactions?) x b. \\gf Discuss tne eneray profile diagram for aromatic electrophilic substitution reactions. Explain why = : in Naphthalene nitration reaction occurs at alpha (a) position Hone sulphonation reaction prefers beta (B) position. Chiorobenzene is less reactive than electrophilic substitution reactions although chlorine and nitrogen have almost the same electronegativity. aay 18 BOE Kashi Vidyapith ( M.G. KASHI VIDYAPITH UNIV! pu VARANASI ERSITy ni vidyapith (Chemisty), . 19 MSc. 1 Sem. CHEMISTRY (PAPER-THIRD), 2015, teyHow is force constant related with IR absorption (PHYSICAL CHEMISTRY - I) frequencies? (o) How many fundam bending modes of vit CO, molecules? ‘Time : Three Hours : odes of vibrations, stretchirg af | modes of gpserved in HO ang ‘Maximum May ‘Note : Answer five questions in all. Short Answer tyne Gs jestins 1 canying 40 marks is compulsory. Answer Or carrying 15 marks from each Unit. rs ‘Answer All. questions : {a) Explain stokes and antistokes lines. ‘ (©) What is stark effect in microwave spectra? (c) What are selection rules f : (6) How do the IR spectra unit-ill (@) Explain the term operery ‘and derive the operator form of EProdinger equation from its igeneral form. cater “ne energy of a particle in one dimensional box potential walls. sea or A in the postulates of Huckel molecular Orbital o ‘ational spectroscopy? theory. for studying inorganic neoretical resonance energy of benzene 5 ganic systems. Ex (ey prove that the theoretical (9 What is Hamittonian operator? Whi Prove ules 2(-8), where 19 is the resonance integral. 38 in quantum mechanics? Uunit-IV (9) Explain bond-order and bond-length. i it Discuss Mention general characteristics of CAT reactions. Wy mechs aan terre (ay Mention gersfpyroly sis of acetaldehVOe. ects i () What are steric factors in Collisi (b) Give an account of primary and secondary salt et in ols e Oe eee solution. 3 8 2 Unit r 2. (@) Write down the mechanist ‘of Belousov-Zhabotinsky Wte sory reaction and explain the oscillatory nature of reaction. 7 vee Wea oy oan ge ames secre ie (o)Mention diferent_methods to study the Kinetics of fast 2) the rigid rotor model of a Veactions. Discuss one method in detail. 8 lof diatomic fave spectra. Mi reo What co, you understand by Bom ao ui ie. Wee ee the, tase or dia ae pve @ CONNECT YOURSELF WITH Spectroscopy? Differentiate ie and Physics, Chemistry: real etbn test esde ing KAM, NOTES sfaihzscion Boryon eo oot ne a . ox alate 20 Kashi Vidyapi + M.G. KASHI VIDYAPITH UNIVERS ith (Chemistry) VARANAS| Dae M.Sc. 1 Sem. CHEMISTRY. (PAPER-FOURTH), 20; ‘What is moant Funeti (Section — A) i ‘oxample. (COMPUTER FOR CHEMISTS) (COMPULSORY FOR ALL STUDENTS) Time : Three Hours 2 Ht in FORTRAN? Give a Subroutine a FORTRAN? Sie io Explain constants & varaniey in a computer language. What is ts & variable ference between them? 10 7 Maximum Man, or btaining the Vander Wa Note : Answer five questions inal, Shon Anwer type Gueatig Write a computer ee wot carrying 10 marks om sack Un ey ATSWET- One ai awe « program {2 obtaining the pH tiation curve cf having mathematics bac en having mathem ground only. Each of these Separate answer books wil Paper. Give short answers of the five features & sin kage? List any a viniis aworporentng RISERS hela moment 6 used for V (A) and IV (B) /1y preparation? or 10 jing matrix? il you create the following lowing questions 2ero.aff. In MATLAB. How will you create (3) Who is known as the father of modern digital computer? : (b)What is the value of What is the base/radix for binary nu (c) Writ teers (c) Write the file extension of Microsoft word documer a Rea SE Tee iz (qd) What is machine language? ference to an element in the 2 row and 5 (@) Wie the ful fom of FONTAN & BASIC Soa eneed ()Whatie meantoy oak et ee AS ee (9) What is a comment statement? How a comment statem: ee corer rat (h)What happens when a ni oa What wmber is divided by zero in (@ Name two peripheral devices and i © CONNECT YOURSELF WITH input, output or Vo in nat anu?"EX aM, NoTES ‘physics, Chemistry Math, Zoology, Botany Write short notes on : (i) Bar-Code reader (i) Optical mark readeriis SS —_— Kashi Vidyapith, 7 M.G.KASHI VIDYAPITH UNIVER chomistt”) cats, VARANASI 2 jr vidya (EMT ysl get os MSc. 1 Sem. CHEMISTRY (PAPER-FOURTH), -0,x=0 (Section - B) x) axe (MATHEMATICS FOR CHEMISTS) ‘Test the continu Or. Is (For STUDENTS WITHOUT MATHEMATICS IN B.Sc, | ‘wing integr’l Maxima ie Evaluate the follo nexsZ rs fxtoax® Sane 7% 78 ul 1 ial equation = 1. Give short answers of the following questions : solve the aitorontat sya + (1 0, : (a) Define cross product of two vectors. OF gitterenti equations in ) Define solencidal vector or irrotational vector. 5 at of the application of the value of div F . te an accoul Chemisty. unitsV 75 (WA p=? ‘|c-[7 ! : “le -1\ > l2 4) o of it ne value of Mi Find thes, = 12. "Pe a je and a ina simultaneous 1085 oad x (t= (yah, B ¢ Find AB. z Find differential coetticient of in x + log x +x), Evaluate (sec? x +seextanx)dx. ) Find the value of C$. ist the sample space Coin. aa Find the value of "P,. ) A coinis tossed once. Find the probabiliy of getting a Unit \i 2, Find the value of grad’, where 7 =xi+yj+zk. Or Find the inverse of the matrix. CONNECT YOURSELF iT Hey, e sicS> of pov?™"Exam. NOTES aimee Bota | 4. Afunetionfs Kashi Vidyapith (Q .G. KASHI VIDYAPITH UNIVERS, i VARANASI De -HEMISTRY (PAPER-FOURTH) sas of ANAS = MSc. | Sem. Ct \gecton-0) i 2 pina tne (BIOLOGY FOR CHEMISTS) (For STUDENTS WITHOUT BIOLOGY IN B.Sc.) Time : Three Hours Maximum hy in all, Short Answer type Que: Answer five questions ee 10 marks is compulsory. Answer One ‘q 25 ITH F WI eo CONNECT Yours creat, Lw?™"Exam, NOTES sian. zocterr Glycerophospholipids Liposomes Oxytocin : ‘Amino acid metabolism Purine () Hydrolysis of nucleic acid @ Genetic code Unit 2. (Distinguish between DNA and RNA. Describe intracellular organelles in brief 4. Discuss the role of fatty acid synthetase complex in synthesis. Or 5. Outline the pathway of Beta oxidation of fatty aci molecules of ATP are produced by complete oxi ‘molecule of palmitic acid. y u 5. Describe bret the physical nd chemical properties Or 7. Describe alpha helix and Beta structure of proteins.26 Kashi Vidyapith (Che 2 M.G. KASHI VIDYAPITH UNIVERSITy. 7 VARANASI e M.Sc. | Sem. CHEMISTRY (PAPER-FIRST), 2017 (0) Explain the appl (INORGANIC CHEMISTRY - 1) 10 thermodynamic -& Time : Three Hours Maximum: eral formation of complexes. ity, and stepwise & etic stability, and Sor hip Note : Answer five questions in all. Short Answer type Qi between Ba and Ko x 5 ing 4% marks is compulsory. Answer One q {b) Write a'short note on "Chelate Erect carrying 15 marks from each Unit. % es ‘of Note : The answers to short questions should not exceed (a) Explain 10 fare ta answers to long questions should not ey wo ene experimental determination of-stability constant * stric method. it Eenan sare the following in briet : ¥ by spectephotometic meth : 1 ‘Symmetry of elements with examples. OT for @ bounded [Co(NHs)]"" S and sketch MOT for “OY Groups which are the subgroups of De. > © Oe ee. 2 ASS’ Shapes and structures of NHy and HzO. . (0) Why LFT is also called ACFT- “ASN Trace out the hybridization of CIF, and XeOF, mo or (@) Calculate CFSE for d° and d? octahedral comp (@Write the similarities and differences be strong and weak field ligand. 4 MOT. (f) Sketch the MOT diagram for [CoFe]” complex. (b) Explain the John Teller t! tween CFT and theorem regarding distortion of (9) Explain the Irvin-William order regarding st complexes. 3 xes. 2 {c) Explain d-p transition. the colour concept in complexes. : ac ()_Iceis less denser than water. 2 @) Show that Z, Y & x are a degenerate set of 5, function of the tetrahedral group. > CONNECT YOURSELF WITH Physics, ChemIsteYs Unit oe y 2. (a) Explain various symmetry operations with examples. pave EXAM. NOTES. sian, zootoey Boon (b) Draw a square planer molecular MX, and indicate the and two fold rotational axis and reflection plar Or limitations. a (b) Arrange in decreasing order of bond length amot Ch & Pla and Justity it. or 5. (a) Explain the Bent rule in det~ 29 28 ‘idyapin $ M.G. KASHI VIDYAPITH UNIVERS os VARANASI M.Sc. | Sem. CHEMISTRY (PAPER-SECONp), (ORGANIC CHEMISTRY - 1) Time : Three Hours Maximum er type Qi A pulsory. Answer o, : ) Explain ipso attack. Note : Answer five questions in all. Short Answ 1 carrying 40 marks is ct carrying 15 marks from each Ur Note : The answers to short Unitt jing alkenes aS tic 7 ye. following | ions : questions should not exceed 209 4 -Nathan effect, Arrange following arene Se and the answers to long questions should not axe a) Describe Bast rol the stables wi Prop ate words, 0+ 1. Answer the fol (@)Cyclopentacione shows acidic behaviour. Why? (©) Why ‘-bromocyctohepta-2,4,6-trene exists in salt fom? | smma isomer of benzene hexact Bi 4x10m4 ity of vinyl, alkyl and allyl he leophilic substitution reactions, tic different aromatic and anti-aromat ‘our and six x electrons with the help off ‘lecular orbi 1045 why azulene is blue while naphthalene is white ‘though both are isomeric bicyclic aromatic compounds. Unit (@)Neomerthy! chloride upon B-climination reacts 200 times lbenzene is less reactive than toluene toward Substitution reactions. Why? haviour off 1-Bromotryptycene towards reaction conditions. (h) Explain inert SN! and SN* (Assign followings in to FYS system :examples. Or 5. (a) Describe the following methods of mechanism with suitable exampl () Crossover experiments d Sterecctencal oat reaction : (w)Energy Profile Diagram 5 ‘short note on orientation in electrophilic substitution {b) Describe quantitative A 7 Relationship. oo (a) What is anchimeric group participation by « and x bonds with examples. 2 (b) Discuss non-classical carbocations. Or 7. - (a) Give plausible mechanism for the followings : o me we Se S oO, ON need oe ee @ CONNECT YOURSELF WITH Chemistry, proP™"EXam, NOTES Zens 5ore 32 Kashi Vidyapith (Chem M.G.KASHI VIDYAPITH UNIVERSITY, 7 VARANASI ‘ unit-itl tom ation for Hydrogen a TI A CH MSTE Ee eet7 cowie gow ne sodran wave inthe postulates. of Huckel Mole lar Orbital theory c tulate’ | Mol 7 plait and tne Pits application to determine ond order ang ‘Gensity in butadiene molecue- 8 the ication to (@Discuss Perturbation theory ‘and its’ appl jiumation for. De the allowed 33 i vidyapith (Chemisty) AON ‘Time : Three Hours Maximum Marks: wes Note : Answer five questions in all. Short Answer type Ques and de No.1 carrying 40 marks is compulsory. Answer One charge carrying 15 marks from each Unit. ‘ Note : The answers to short questions should not exceed 200 wo and the answers to long question should not exceed 500,wordg in erm symbols for an atom containg figuration. 8 ae (4x 10zig 0) Dede raent electrons in ts pz econ conto Ls iswer All questions : 7 Unit- " iscuss the (2) Discuss the wave theory of Electromagnetic Radiation. » Describe the characteristics of chain reactions. Discuss the {Wie a torreon Bam appesteterApprosmaton. reso poh acetatonyee. lain Mutual Exclusion principle. alt effects in (6) What are selection Rules for vibrational spectroscopy? » ve an account of primary and secondary S 7 (e)Wi short-not Stark- pe een rite a short-note on Stark-Etfect. ‘Senet jon based on rive uation for the rat a reactiol 9 Oa tor ‘and discuss about its applicabity- () Define energy of activation. () Write short-note on kinetics of enzyme reaction, Unit 2. (a) How can we determine the intensity of spectral lines? {b) Derive the Rigid Rotator Model of diatomic molecuk microwave spectra. @ CONNECT:-YOURSELF WITH, i Physics Boo?" EXam, NOTES. jintezsooss natn Or Be (a) Discuss the phenomenon of Electromagnetic Radiat What are basic principles of microwave spectra Discuss the effect of isotopic substitution on the Ory 5. (a) Discuss the classical and Quantum mechanical Raman Effect. ‘down the applications of Raman spect