4.solutions and Colligative PropertiesExercise
4.solutions and Colligative PropertiesExercise
Q.15 Two liquids X and Y form an ideal Q.17 At 80°C , the vapour pressure of pure
solution. At 300K, vapour pressure of the liquid ‘A’ is 520 mm Hg and that of pure liquid
solution containing 1 mol of X and 3 moles of ‘B’ is 1000 mm Hg. If a mixture solution of ‘A’
Y is 550 mm Hg. At the same temperature, if and ‘B’ boils at 80°C and 1 atm pressure, the
1 mol of Y is further added to this solution, amount of ‘A’ in the mixture is (1 atm = 760
vapour pressure of the solution increases by mm Hg) (2008)
10 mm Hg. Vapour pressure (in mm Hg) of X
and Y in their pure states will be respectively (A) 52 mol percent (B) 34 mol percent
(2009) (C) 48 mol percent (D) 50 mol percent
(A) 200 and 300 (B) 300 and
(C) 400 and 600 400 Q.18 At a given temperature, total vapour pressure in
Torr of a mixture of volatile components A and B is
given by PTotal = 120 – 75XB hence, vapour pressure of
Q.16 A mixture of ethyl alcohol and propyl pure A and B respectively (in Torr) are
alcohol has a vapour pressure of 290 mm at A) 120, 75 (B) 120, 95
300K. The vapour pressure of propyl alcohol (C) 120, 45 (D) 75, 45
is 200 mm. If the mole fraction of ethyl
alcohol is 0.6, its vapour pressure (in mm) at Q.19 The mole fraction of a solute in a
the same temperature will be solution is 0.1. At 298 K, molarity of this
(2007) solution is the same as its molality. Density of
this solution at 298 K is 2.0 g cm-3. The ratio
(A) 350 (B) 300 (C) 700 (D) 360 of the molecular weights of the solute and
solvent (2016)
2 2
v (10)
(B) tan θ = Rg= (10)
=1
(10)
(D) =a
(D) All of
Q.17 Which of the following is/are true?
(A) For the same solution, elevation in boiling
point = depression in freezing point
(B) The Van’t Hoff factor for a dilute solution of
BaCl2. (C) The elevation in boiling point is due
to increase in vapour pressure.
(D) The depression in freezing point is due to
decrease in vapour pressure.
Q.22 Correction factor for 0.1M ideal solution is (C) Al2(SO4)3, Na3 PO4, (r) 1 : 1 : 1
K3r[Fe(CN)6]
(A) 0.1 (B) 1 (C) 0.01 (D) 2 > (s) 2 : 3 : 3
1 (D) Glucose, NaCl, CaCl2
Q.2 Which of the following 0.1M aqueous Molecular weight of ethanol = 46 g mol–1
solution will have the lowest freezing point?
(1989)
(A) Potassium sulphate (B) Sodium chloride
(C) Urea (D) Glucose
Paragraph 3
Properties such as boiling point, freezing
point and vapour pressure of a pure solvent
change when solute molecules are added to
get homogeneous solution. These are called
colligative properties. Applications of
colligative properties are very useful in day-to-
day life. One of its examples is the use of
ethylene glycol and water mixture as anti–
freezing liquid in the radiator of automobiles.
A solution M is prepared by mixing ethanol
and water. The mole fraction of ethanol in the
mixture is 0.9.
Given, freezing point depression constant
of water (kfwater) = 1.86 K kg mol–1
freezing point depression constant of ethanol
(kfethanol) = 2.0 K kg mol–1
Boiling point elevation constant of water
(kbwater) = 0.52 K kg mol–1
Boiling point elevation constant of water
(kfethanol) = 1.2 K kg mol–1
Standard freezing point of water = 273 K
Standard freezing point of ethanol =
155.7 K Standard boiling point of
water = 373 K
Standard boiling point of ethanol =
351.5 K Vapour pressure of pure
water = 32.8 mm Hg Vapour pressure
of pure ethanol = 40 mm Hg Molecular
weight of water = 18 g mol–1
In answering the following questions, consider
the solution to be ideal dilute solution and
solute to be non–volatile and non–dissociative.
(2008)
Q.12 The degree of dissociation of Ca (NO3)2 in Properties such as boiling point, freezing
a dilute aqueous solution, containing 7.0g of point and vapor pressure of a pure solvent
the salt per 100g of water at 100ºC is 70%. change when solute molecules are added
If the vapour–pressure of water at 100ºC is to get homogeneous solution.
760 mm, calculate the vapour pressure of the
solution.
(1991)
Z 283ºC 0.53
= 0.52 K kg mol−1
Boiling point
elevation = 1.2 K kg constant of ethanol (K
mol−1
In answering the following questions, consider
the solutions to be ideal dilute solutions and
solutes to be non-volatile and non- dissociative.
(2008)
MASTERJEE Essential
Questions
JEE Main/Boards JEE Advanced/Boards
Exercise 1 Exercise 1
Q.2 Q.4 Q.9 Q.6 Q.10 Q.16
Q.14 Q.29 Q.20 Q.21 Q.25
Exercise 2 Exercise 2
Q.2 Q.4 Q.14 Q.6 Q.7 Q.12
Q.17 Q.15 Q.17 Q.25
Q.28
Previous Years' Questions
Q.6 Q.9 Q.11 Previous Years' Questions
Q.16 Q.17 Q.1 Q.13
Chemistry | 20.45
Answer Key
JEE Main/Boards
Exercise 1
Q.1 4.9 gm Q.2 0.89 Q.3 (i) 0.52m, (ii)
0.99
Q.6 0.2121 m Q.7 53.06g mol–1 Q.8 23.44 mm Hg
Q.9 0.988; 0.156 m Q.121.35 mol/litre; 1.52 Q.13 0.283 mol/L
mol/kg
Q.14 0.099 mol L–1 Q.15 0.23 K
Q.16 158.9 mL of 0.1 M HCl Q.17 57.5 g mol–1 Q.18 256 g mol–1
Q.19 10 g Q.21 (b) 7.389 atm
Q.22 Degree of dissociation = 90% Q.23 18.6 × 10–4
Q.24 Atomic mass of A = 25.59; B = Q.25 1.0753; 30.68 × 10–4 Q.28 (b) 92%
42.64
Exercise 2
Single Correct Choice Type
JEE Advanced/Boards
Exercise 1
Q.1 0.24 Q.2 0.25 Q.3 24.5 torr
Q.4 57.24 g/mol Q.5 111.1 g, 18.52 molal Q.6 106 g/molal
Q.7 64.0 g/mol Q.8 100.079ºC Q.9 –0.62ºC
Q.10 T = -2.28ºC Q.11 0.741m, 0.013 Q.12 0.162 m
Q.13. 65.25 Q.14 17.38 Q.15 0.964
Exercise 2
Single Correct Choice Type
Q.7 D
Assertion Reasoning
Type Q.19 C
Q.20 D
Comprehension Type
Q.21 A Q.22 B Q.23 B Q.24 C Q.25 B
Q.26 A → p, r; B → q, t; C → q, t; D → p, s Q.27 A → r; B → s; C → p; D →
q
Q.28 A → s; B → r; C → q; D → p
Q.7 B Q.8 Condition Q.9 C5 Q.10 0.657 Q.11 65.25 Q.12 746.32
H10O11
Q.13 168 Q.14 1.005 × 10–4 min–1 Q.15 Q.16 A Q.17 D
Subjective
Q.18 B Q.19 B Q.20 A Q.21 A Q.22 A Q.23 3