Devres-1994-Psychrometric Properties of Humid
Devres-1994-Psychrometric Properties of Humid
Y. O. Devres
T U B I T A K M a r m a r a Research Centre,
F o o d a n d R e f r i g e r a t i o n Technology D e p a r t m e n t ,
P.O.Box 21, 41470 Gebze-Kocaeli,Turkey
A BSTRA CT
NOTATION
INTRODUCTION
In the study of the processes of air conditioning, cold storage and drying,
a knowledge of the psychrometric properties of the working fluid, that is
humid air, is essential. In general, the psychrometric properties of a
medium can be predicted either analytically by recourse to the laws for
gases or by consulting specially prepared charts and tables. Using these
charts, if the atmospheric pressure or altitude is known, it is easy to find
the psychrometric properties using two other known properties. However,
during the designing, for instance, of a cold store, in most cases its
altitude is different from sea level. And yet, most of the charts available
in the references are based on sea level properties. Therefore, finding
psychrometric properties from zero-altitude charts can create errors.
Although the best method for finding these properties is to calculate
them analytically using the perfect gas relationships, in many situations,
it is often neither convenient nor practical. A realistic solution for these
problems is to employ a computer for the numerical solution of the
relevant equations: the psychrometric properties being defined in the
software.
There are seven main different properties in the psychrometric charts,
namely dry-bulb, wet-bulb and dew-point temperatures, atmospheric
pressure, humidity ratio, relative humidity and enthalpy. ~ According to
the Gibbs Phase Rule, there are four degrees of freedom for a system
consisting of humid air, assuming it to be a mixture of nitrogen, oxygen,
and water vapour. For all practical purposes the ratio of the masses of
oxygen and nitrogen in air is constant, hence the degrees of freedom are
reduced to three. Thus any three intensive properties will be sufficient to
evaluate the remaining properties. 2 Therefore the combination of three
out of seven properties gives a total of 35 different sets. These are shown
TABLE 1
C o m b i n a t i o n Sets o f Seven Psychrometric Properties, Each Set Comprising Three Properties
1 T T* TD 2 T TD P 3 T P W 4 T W ¢ 15IT + hi
6 T T* P 7 T TD W 8 T P ¢ 9 T W h
10 T T* W 11 T TD ¢ 12 T P h
13 T T* ¢ 14 T TD h
15 T T* h '5
16 T* TD P 17 T* P W 18 T* W 1'9IT" + hi
20 T* TD W 21 T* P ¢ 22 T* W
23 T* TD 24 T* P h
25 T* TD h
26 TD P W 27 TD W ¢ 28 TD ¢ h ]
29 TD P ¢ 30 TD W h T Dry-bulb temperature
31 TD P h T* Wet-bulb temperature
TD Dew-point temperature
32 P W ¢ 33 P + hi P Pressure
34 P W h W Humidity ratio
¢ Relative humidity
1351w + hi h Enthalpy
4 Y . o . Devres
METHOD
Psychrometric equations
R E S U L T S A N D DISCUSSION
Temperature ( K )
213.15 < T < 273-15 273.15 _< T < 322-15 322.15 < T < 373.15 373.15 <_ T < 423-15 423.15 < T < 473-15
e~
TABLE 3
C a l c u l a t i o n o f T e m p e r a t u r e w h i c h is D e p e n d e n t on W a t e r V a p o u r S a t u r a t i o n P r e s s u r e w i t h i n V a r i o u s T e m p e r a t u r e R a n g e s
T- E .134 + F . ~3 + G . ~2 + H . fi + K, T in K
13 - In ( p , J , p,~ in P a
-W
Pres,~ure ( P a /
1 _<p<611 61t _<p < 12 350 12 3 5 0 _ < p < 101420 101420_<p<476207 476 207 <-p < 1 555 0 9 9
1 Pws T a= A . T2 + B . T + C + D . •l Pws = 1 0 0 0 . e x p ( a )
T in K, Pws in Pa
for c o n s t a n t s see T a b l e 2
2 T Pw~ T=E. /34+F. /33+ G . /32 + H . / 3 + K /3=ln(Pw~)
T in K, Pws in Pa
for c o n s t a n t s see T a b l e 3
3 Pw To a=A. Tt~+ B . T o + C + D . To I Pw = 1 0 0 0 . e x p ( a )
T O in K, Pw in Pa
for c o n s t a n t s see T a b l e 2
4 TO Pw TD=E./34+F./33+G./32+H./3+K /3 = In (pw)
TD i n K , p w i n P a e~
for c o n s t a n t s see T a b l e 3
5 p*s T* o t = A . T . 2 + B . T* + C + D . T* i P*s = 1 0 0 0 . e x p ( a )
T* in K, P*s in Pa
for c o n s t a n t s see T a b l e 2
6 h T, W h = T+ W . (2501 + 1-805. T) T i n °C, h i n kJ/kg
h - 2501. W
7 T h,W T- T in °C, h in kJ/kg
1 + 1-805. W
h-T
8 W h, T W = T in °C, h in kJ/kg
2501 + 1-805. T
9 W P, Pw W = 0.621 98 - Pw P a n d Pw in Pa
P - Pw
10 P Pw, H/ P = 0.621 98 • ~ " + p,, P a n d p,~ in Pa
W
P.W Pandp~in Pa
11 p~ P, W Pw
W + 0.621 98
e P a n d p,,,~ in P a
14 Pw~ P, W~ p,,~ = 0.621 98 • ca
W~ + 0.621 98
7
p*~
147 = 0-621 98 • - - - - P a n d p{~ in Pa
15 ~7 P, P*~ p - p*
P. W*
17 p~ P, W~ p*~- P a n d p*~ in Pa
W * + 0.621 98
/ 7 " : T* + (2501 + 1 . 8 0 5 . T * ) . W*
w,*= h * - h + W h * = 4 . 1 8 6 . T*
18 W* h, W, T*
h* h, h* h * in k J / k g , T* in °C
T A B L E 4---contd
h * = T * + (2 501 + 1 . 8 0 5 . T * ) . IV*
19 W W.*,h, T* W- h-h*+ W*
hw* -- 4 . 1 8 6 . T*
h*
h, h*s, hw* in k J / k g , T * in ° C
21 T* W~, W, T T * = 2 5 0 1 . (Ws* - W ) - T . (1 + 1 - 8 0 5 . W )
T a n d T * in ° C
2.381. W* -4.186. W- 1
Ra . T R a -- 287-055 J / k g . K
28 v T,P, W Y z _ _
- (1 + 1 - 6 0 7 8 . W) v in m3/kg, T in K , P in P a
P
Psychrometric properties 0["humid air 9
TABLE 5
Recommended Procedures for the Calculation of Psychrometric Properties
1 T, T*, TD 1 Pws 1
2 p*s 5
3 Pw 3
4 P 9, 15, 18 Replace eqns (9) and (15) in eqn (18), then solve
the resulting equation using numerical analysis
5 W 9
6 Ws 12
7 w* 15
8 h 6
9 ~b 24
2 T, TD, P 1 Pws 1
2 Pw 3
3 W 9
4 WS 12
5 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
6 P*s 5
7 Ws* 15
8 h 6
9 ~ 24
3 T,W,P 1 Pw~ 1
2 Pw 11
3 TD 4
4 Ws 12
5 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
6 P*s 5
7 W* 15
8 h 6
9 4~ 24
4 T,W,d) 1 Pws 1
2 Pw 25
3 P 10
4 TD 4
5 Ws 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 P*s 5
8 ~ 15
9 h 6
I C~mtinued)
10 E O. Devres
TABLE 5--contd
5 T,(o,h 1 Pw~ 1
2 Pw 25
3 W 8
4 P I0
5 TD 4
6 Ws 12
7 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
8 P*s 5
9 W* 15
6 T,T*,P 1 Pws 1
2 P*s 5
3 W* 15
4 W 20
5 W~ 12
6 Pw 11
7 TD 4
8 h 6
9 ~b 24
7 T, TD, W 1 Pw~ 1
2 Pw 3
3 P 10
4 W, 12
5 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
6 p*~ 5
7 W* 15
8 h 6
9 cb 24
8 T,c~,P 1 Pws 1
2 Pw 25
3 W 9
4 W~ 12
5 To 4
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 Pw*~ 5
8 W* 15
9 h 6
Psychrometric properties o f humid air 11
TABLE 5---contd.
9 T, IV, h UNRESOLVABLE
10 T, T*, W 1 p,,, 1
2 p*~ 5
3 w* 22
4 P 16
5 w~ 12
6 p,, 11
7 TD 4
8 h 6
9 4' 24
11 T, TD, 05 UNRESOLVABLE
12 T, h, P 1 p,,~ 1
2 W 8
3 p,,. 11
4 TD 4
5 w~ 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 p*.~ 5
8 W*s 15
9 4' 24
13 T, T*,05 1 p,,,~ 1
2 p,, 25
3 TD 4
4 p*~ 5
5 P 9, 20 Replace eqn (9) in eqn (20), then solve the
resulting quadratic equation
6 W 9
7 w~ 12
8 w~ 15
9 h 6
14 T, tl, T D 1 Pws 1
2 W 8
3 Pw 3
4 P 10
5 w, 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 p*~ 5
8 w~* 15
9 4' 24
{'iOllftllli,d,
12 Y.O. Devres
TABLE ~-contd.
15 T, T*, h 1 Pws 1
2 W 8
3 P*s 5
4 W* 22
5 P 16
6 p~ 11
7 TD 4
8 Ws 12
9 ~ 24
16 T*, TD, P 1 Pw 3
2 p*~ 5
3 W* 15
4 W 9
5 T 23
6 P,,,s 1
7 Ws 12
8 h 6
9 ~b 24
17 T*, P, W 1 Pw 11
2 TD 4
3 p*s 5
4 W* 15
5 T 23
6 Pw~ 1
7 Ws 12
8 h 6
9 ~b 24
18 T*, W, 1 p*~ 5
2 7" 1, 10, 20, Replace eqn (25) in eqn (10), then solve the
25 resulting equation with eqns (1) and (25) using
numerical analysis
3 Pws 1
4 P 10, 25
5 ws 12
6 w* 15
7 Pw 11
8 TD 4
9 h 6
Psychrometric properties of humid air 13
TABLE 5---contd.
20 T*, TD, W 1 Pw 3
2 P 10
3 p*~ 5
4 W* 15
5 T 23
6 Pws 1
7 W~ 12
8 h 6
9 4~ 24
22 T*, W, h 1 P*s 5
2 T 7
3 Pws 1
4 W* 22
5 P 16
6 Pw 11
7 TD 4
8 w, 12
9 ¢b 24
;()mlmued)
14 Y.O. Devres
TABLE 5 contd.
23 T*, T D,4~ 1 Pw 3
2 p*s 5
3 Pws 26
4 T 2
5 P 9, 15, 20 Replace eqns (9) and (15) in eqn (20) and solve
the resulting quadratic equation
6 W 9
7 W* 15
8 W~ 12
9 h 6
24 T*, P, h 1 p*~ 5
2 w* 15
3 W 19
4 Pw 11
5 TD 4
6 T 7
7 Pw~ 1
8 W~ 12
9 ~ 24
26 TD, P, W UNRESOLVABLE
27 TD, W , ~ 1 Pw 3
2 Pw~ 26
3 T 2
4 P l0
5 W~ 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 P*s 5
8 w* t5
9 h 6
Psychrometric properties q f humid air 15
TABLE ~ c o n t d
28 T D, oh, h 1 Pw 3
2 Pws 26
3 T
4 W 8
5 P 10
6 W~ 12
7 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
8 p*~ 5
9 W* 15
29 TD, P, c~ 1 Pw 3
2 Pw~ 26
3 T 2
4 W 9
5 w~ 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 P*s 5
8 w* 15
9 h 6
30 T D, W, h 1 Pw 3
2 P 10
3 T 7
4 Pws 1
5 W~ 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 P*s 5
8 W* 15
9 4~ 24
31 TD, P , h 1 Pw 3
2 W 9
3 T 7
4 Pw~ 1
5 w~ 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 P*s 5
8 w* 15
9 ~h 24
r ~oHlitillcd!
16 Y.O. Devres
TABLE 5~contd.
32 P, W, ~h 1 Pw 11
2 TD 4
3 Pws 26
4 T 2
5 Ws 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 P*s 5
8 W* 15
9 h 6
34 P, W , h 1 T 7
2 Pws 1
3 Pw 11
4 TD 4
5 Ws 12
6 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
7 P*s 5
8 w* 15
9 q~ 24
35 w, 4~,h 1 T 7
2 Pws 1
3 Pw 25
4 TD 4
5 P 10
6 Ws 12
7 T* 15, 21 Replace eqn (15) in eqn (21), then solve the
resulting equation using numerical analysis
8 p*~ 5
9 W* 15
TABLE 6
Results of Properties for Different Combination Sets
Property Calculations
* Knowns.
-7,
18 Y.O. Devres
CONCLUSION
REFERENCES