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Solution Test 2

The document outlines a chapter on solutions, including multiple choice questions, assertion and reason questions, and theoretical concepts related to colligative properties, ideal solutions, and osmotic pressure. It includes calculations for molecular weights, freezing point depression, and osmotic pressure, along with definitions and examples of key terms like plasmolysis and azeotropic mixtures. Overall, it serves as a comprehensive assessment of knowledge in the topic of solutions in chemistry.

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arindam saha
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16 views2 pages

Solution Test 2

The document outlines a chapter on solutions, including multiple choice questions, assertion and reason questions, and theoretical concepts related to colligative properties, ideal solutions, and osmotic pressure. It includes calculations for molecular weights, freezing point depression, and osmotic pressure, along with definitions and examples of key terms like plasmolysis and azeotropic mixtures. Overall, it serves as a comprehensive assessment of knowledge in the topic of solutions in chemistry.

Uploaded by

arindam saha
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Chapter: Solution

Total marks: 25 Time: 40 minutes

1. Multiple Choice Questions: (5 x 1 = 5)

(a) A 5% solution of cane sugar (mol. wt. = 342) is isotonic with 1% solution of a
substance X. The molecular weight of X is:
a. 34.2 b. 171.2 c. 68.4 d. 136.8

(b) Which of the following 0.10m aqueous solution will have the lowest freezing
point?
a. Al2(SO4)3 b. C5H10O5 c. KI d. C12H22O11

(c) 3.65 gms of HCl is dissolved in 16.2 gms of water. The mole fraction of HCl in
the resulting solution is:
a. 0.4 b. 0.3 c. 0.2 d. 0.1

(d) On dissolving 1 mole of each of the following acids in 1 litre water, the acid
which does not give a solution of strength 1 N is?
a. HCl b. Perchloric acid c. HNO3 d. phosphorous acid

(e) Calculate the molal depression constant of a solvent which has freezing point
16.6oC and latent heat of fusion 180.75 Jg-1 .
a. 2.68 b. 3.86 c. 4.68 d. 2.86

2. Assertion and Reason based question: (3 x 1=3)


Read the Assertion (A) and Reason (R) carefully to mark the correct option out of the
options given below:
a. If both assertion and reason are true and the reason is the correct explanation of the
assertion.
b. If both assertion and reason are true but reason is not the correct explanation of the
assertion.
c. If assertion is true but reason is false.
d. If the assertion and reason both are false.
e. If assertion is false but reason is true.
(i) Assertion: Out of various colligative properties, osmotic pressure is used for
determination of molecular masses of polymers.
Reason: Polymer solutions do not possess constant boiling point or freezing
point.

(ii) Assertion: Elevation in boiling point is inversely proportional to relative lowering


of vapour pressure for dilute solutions.
Reason: Relative lowering of vapour pressure is directly proportional to mole
fraction of solute.
(iii) Assertion: Van’t Hoff factor is equal to unity if the electrolytic solute undergoes
100% dissociation.
Reason: Van’t Hoff factor for sucrose solution is unity.

3. What is an ideal solution? Draw graph to show its behaviour in case of binary
solution. 3
4. Show that relative lowering of vapour pressure is a colligative property. 2
5. What do you understand by plasmolysis? 1
6. How abnormal mass is related to Van’t Hoff factor? Give examples in each case. 2
7. Two elements A and B form compounds having formula AB2 and AB4. When
dissolved in 20gm of benzene, 1 gm of AB2 lower the freezing point by 2.3oC,
whereas 1 gm of AB4 lowers the freezing point by 1.3oC. The molal depression
constant for benzene is 5.1 K kg mol-1. Calculate the atomic masses of A and B. 3
8. At 27oC, 36 gm of glucose per litre has an osmotic pressure of 4.92 atm. If the
osmotic pressure of another solution of glucose is 1.5 atm at the same temperature,
what would be its concentration? 2
9. Calculate the freezing point of an aqueous solution of a non-electrolyte having an
osmotic pressure of 2 atm at 300K. Kf for water is 1.86 K Kg mol-1. 3
10. Give one example of azeotropic mixture. 1

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