Assignment Mid Physics 2 Theory Final Draft
Assignment Mid Physics 2 Theory Final Draft
UNIVERSITY-BANGLADESH
408/1, Kuratoli, Khilkhet, Dhaka 1229, Bangladesh
* Student(s) must complete all details except the faculty use part.
** Please submit all assignments to your course teacher or the office of the concerned teacher.
Group Name/No.: 02
10
Marks Obtained
Total Marks
Lesson-01
Temperature, heat and the first law of thermodynamics
Problem 2 :A certain substance has a mass per mole of 50.0 g/mol. When 314 J
is added as heat to a 30.0 g sample, the sample’s temperature rises from 25.0°
C to 45.0° C. What are the (a) specific heat and (b) molar specific heat of this
substance? (c) How many moles are in the sample?
Mass, m = 30 g = 30 × 10 ^-3 kg ;
Initial Temperature, Ti = 25°C ;
Final Temperature, Tf = 45°C ;
Change in Temperature, ∆T = (45 + 273)K – (25+273)K = (45 -25 )K = 20 K
Heat energy,Q = 314 J
(a) Specific Heat (capacity), c = 𝑄/ 𝑚 ∆T = 314 /30 × 10 ^−3 ×20 = 523
J/kg-K (Ans)
Solution:
Heat energy, Q = 50.2 kJ = 50.2 ×10^3 J
Latent heat of fusion, Lf = 333 kJ/kg = 333 ×10^3 J/kg
Mass of frozen water (ice), m = ?
(a) The water (of mass m) releases energy in two steps, first by
lowering its
temperature from 20°C to 0°C, and then by freezing into ice. Thus the total
energy
transferred from the water to the surroundings is
(b) Before all the water freezes, the lowest temperature possible is 0°C,
below which the
water must have already turned into ice.
Solution:
Solution:
The work the man has to do to climb to the top of Mt. Everest is given by
Solution1 : The volume increases through the three paths , so the work done
by the gas is always positive.
b) The work done by the gas is the area under the curve
WB= ½ ×(4 - 1)(40 -10) + (4 -1)(10 - 0)
= 75 J
Msam 50
n= = = 25.01 mol
M 1.999
Solution:
a) piVi = nRTi ------------------(1)
𝑝𝑖 𝑉𝑖 1×105 ×2.50
𝑛= = = 106.24 mol
𝑅𝑇𝑖 8.31 ×283.15
Q. 07) Suppose 1.80 mol of an ideal gas is taken from a volume of 3.00 m3
to a volume of 1.50 m3 via an isothermal compression at 30 0C.
(a) How much energy is transferred as heat during the compression,
and
(b) is the transfer to or from the gas?
Solution:
b)As we have got negative amount of heat, the heat is transferred from
the gas.
Problems for Practice
Q. 01)Find the mass in kilograms of 7.50 × 1024 atoms of arsenic, which has
a molar mass of 74.9 g/mol.
Solution:
Given,
Molar mass M = 74.9 g/mol = 74.9 × 10−3 g/mol
Number of atoms N = 7.50 × 1024 atoms
Number of moles = n
Mass = Msam
N 7.50 ×1024
Msam = nM = ×M= × 74.9 × 10−3 = 0.933 kg
N𝐴 6.023×1023
Solution:
a) Given,
M = 197 g/mol
Msam = 2.50 g
Number of moles = n
Msam 2.50
n= = = 0.0127 mol
M 197
b) Number of atoms = N
N= n × NA = 0.0127 × 6.023 × 1023 = 7.64 × 1021 atoms
Q. 03) Oxygen gas having a volume of 1000 cm³ at 40.0°C and 1.01 × 105 Pa
expands until its volume is 1500 cm³ and its pressure is 1.06 × 105 Pa.
Find:
(a) Find the number of moles of oxygen present.
(b) Find the final temperature of the sample.
Solution:
a) Initial volume, V1 = 1000 cm³ = 1.0 × 10-3 m3
Initial pressure, P1 = 1.01 × 105 Pa
Initial Temperature, T1 = 40.0°C = 313.15K
Ideal gas constant, R = 8.314 J.M-1K-1
PV 1.01 × 105 ×1.0 × 10−3
n= = = 0.0388 mol
RT 8.314×313.15
Q. 05) The best laboratory vacuum has a pressure of about 1.00 × 10-18 atm,
or 1.01 × 10-13 Pa. How many gas molecules are there per cubic centimeter in
such a vacuum at 293 K?
Solution:
Pressure, P = 1.0 × 10-18 Pa
Volume, V = 1 cm3 = 1.0 × 10-3 L
Temperature, T = 293 K
R = 0.0821 L.atm.K-1.K-2
NA = 6.022×1023
Number of molecules = N
PV 1.0 × 10−18 × 1.0 × 10−3
n= = = 4.157 × 10−23 mol
RT 0.0821 × 293
Solution:
a) Pressure, P = 100 Pa
Volume, V = 1.00 cm³ = 1.00 × 10⁻⁶ m³
Temperature, T = 220 K
Gas constant, R = 8.314 J.mol-1·K-1
Avogadro’s number, Nₐ = 6.022 × 10²³ mol⁻¹
Number of moles = n
Number of Molecules = N
PV
n=
RT
N = n × Nₐ
= 5.47 × 10⁻⁸ × 6.023 × 10²³
≈ 3.29 × 10¹⁶ molecules
Name: Sabekun Nahar
ID: 24-58349-2
Lesson :4
Chapter 19:The Kinetic Theory of Gases
18.The temperature and pressure in the Sun’s atmosphere are 2.00x106 K and
0.0300 Pa. Calculate the rms speed of free electrons (mass 9.11x10-31 kg)
there, assuming they are an ideal gas.
Solution:
We know ,
𝟑𝑹𝑻
Vrms = √
𝑴
M = m×𝐴
= 9.11x10-31× (6.023X1023)
= 5.49×10−7 kg
3𝑅𝑇
Vrms = √
𝑀
3×8.31×2×106
=√
5⋅49×10−7
3 3 𝑅 3 8⋅314
(b) Kavg per molecule= KT = ( ) 𝑇= × (373) =
2 2 𝑁 𝐴 2 6.022×10^23
7.724×10−21 J
(c) Kavg per mole = Kavg NA = 5 .654 × 10−21 x 6.022 ×1023 = 3405 J
(d) Kavg per mole = Kavg NA = 7.724 J ×10−21 x 6.022 ×1023 = 4651 J
Name: Rafiatul Zannat ID: 24-57184-2
Lesson- 5:
Chapter 19: The Kinetic Theory of Gases
(Fundamental of Physics, 10th edition)
Q. 47) The temperature of 2.00 mol of an ideal monatomic gas is raised 15.0 K
at constant volume. What are
(a) the work W done by the gas
(b) the energy transferred as heat Q
(c) the change ΔEint in the internal energy of the gas, and
(d) the change ΔK in the average kinetic energy per atom?
Solution: Here, ΔT= 15 K
n=2.00mol
ΔV = V - V =0
k = 𝑵𝑹 = 𝟔.𝟎𝟐𝟑
𝟖.𝟑𝟏 𝑱/𝒎𝒐𝒍−𝑲
𝒙 𝟏𝟎𝟐𝟑 /𝒎𝒐𝒍
= 𝟏.𝟑𝟖 𝒙 𝟏𝟎−𝟐𝟑 𝑱/𝑲
𝑨
[ CV = (𝟑𝟐)𝐑 ]
[𝐑 = 8. 𝟑𝟏 𝐉/𝐦𝐨𝐥 − 𝐊]
Q. 48) When 20.9 J was added as heat to a particular ideal gas, the volume of
the gas changed from 50.0 cm3 to 100 cm3 while the pressure remained at
1.00 atm.
(a) By how much did the internal energy of the gas change?
If the quantity of gas present was 2.00x10-3 mol, find
(b) Cp and
(c) CV.
Solution:
Here, Q = 20.9 J
ΔV = (100 – 50) cm3 = 50 cm3 =50(10-2 m)3 = 50x10-6 m3
p = 1.00 atm = 1x105 Pa
n = 2.00x10-3 mol
(a) ΔEint = Q – W = Q – p ΔV = 20.9 – 1x105(50x10-6) = 20.9 – 5.0 = 15.9 J
(b) Ideal gas law, pV = nRT
Δ Δ
(pV) = (nRT)
Δ𝑇 Δ𝑇
ΔV ΔT
p = nR
Δ𝑇 Δ𝑇
ΔV
p = nR
Δ𝑇
pΔV = nR ΔT
pΔ𝑉
= n ΔT
R
Q = nCpΔT
𝑄 𝑄 𝑄𝑅 20.9(8.31) 173.68
Cp = = pΔ𝑉 = = = = 34.74 J/mol-K
𝑛∆𝑇 𝑝∆𝑉 1×105 (50×10−6 ) 5.0
R
(c) Cp – CV = R,
CV = Cp – R = 34.74 – 8.31 = 26.43 J/mol-K
Problems for Practice
Q.42) What is the internal energy of 1.0 mol of an ideal monatomic gas at
273 K?
Solution:
Given,
n = 1.0 mol
T = 273k
R = 8.31 J/mol − K
U = 3/2 nRT
= 3/2 . 1.0⋅8.31⋅273
=1.5⋅8.31⋅273
=3401.6J
Solution: Given,
R = 8.31 J/mol − K
a) Cp=7/2.R
Q=nCpΔT=n(7/2 .R)ΔT
=3.00⋅27⋅8.314⋅40.0=3.00⋅3.5⋅8.314⋅40.0=3.00⋅1163.96=3491.9J
b) Cv= 5/2.R
ΔU=nCvΔT
=3.00⋅5/2⋅8.314⋅40.0=3.00⋅2.5⋅8.314⋅40.0=3.00⋅831.4
=2494.2J
c) Here,
Q =3491.9J
ΔU= 2494.2J
Q=ΔU+W
W=Q−ΔU =3491.9 – 2494.2 = 997.7J
d) Here,
ΔU= 2494.2J
55.A certain gas occupies a volume of 4.3 L at a pressure of 1.2 atm and a
temperature of 310 K. It is compressed adiabatically to a volume of 0.76 L.
Determine (a) the final pressure and (b) the final temperature, assuming the
gas to be an ideal gas for which γ = 1.4.
Solution:
Here, Vi = 4.3 L
pi = 1.2 atm = 1.2x105 Pa
Ti = 310 K
Vf = 0.76 L
𝛾 = 1.4
p𝑣 ɣ = constant
𝛾 𝛾
𝑝𝑖 𝑣𝑖 = 𝑝𝑓 𝑣𝑓
𝑝𝑓 =
54. We know that for an adiabatic process p𝑉 𝛾 = a constant. Evaluate “a
constant” for an
adiabatic process involving exactly 2.0 mol of an ideal gas passing through the
state having
exactly p = 1.0 atm and T = 300 K. Assume a diatomic gas whose molecules
rotate but do not oscillate.
Solution:
Diatomic gas whose molecules rotate but do not oscillate,
f=3+2=5