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UNIQUE WORLD EDUCATION - CHEMISTRY MODEL

[Time allowed: 3 hours] [Maximum Marks: 70]

General Instructions:-
Read the following instructions carefully and strictly follow them.
(i) This question paper is divided into five sections A, B, C, D and E.
(ii) This question paper contains 35 questions. All questions are compulsory.
(iii) In Section A – Question No. 1 to 18 are multiple choice (MCQ) type
questions carrying 1 mark each.
(iv) In Section B – Question No. 19 to 25 are very short answer (VSA) type
questions carrying 2 marks each.
(v) In Section C – Question No. 26 to 30 are short answer (SA) type
questions carrying 3 marks each.
(vi) In Section D – Question No. 31 and 32 are case based questions carrying
4 marks each.
(vii) In Section E – Question No. 33 to 35 are long answer (LA) type questions
carrying 5 marks each.
(viii) There is no overall choice. However an internal choice has been provided
in two questions in Section B, two questions in Section C, two questions
in Section D and two questions in Section E.
(ix) Use of calculators is not allowed.

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SECTION-A
Question No. 1 to 18 are multiple choice (MCQ) type questions, carrying 1
mark each.
(18x1=18)
1. How many significant figures are present in 0.0025
(a) 2 (b) 4 (c) 1 (d) 3
2. How many unpaired electrons are present in chromium
(a) 5 unpaired e- s (b) 6 unpaired e- s
(c) 3 unpaired e- s (d) 1 unpaired e-
3. Among halogens the correct order of amount of energy released during the
gain of electron is.
(a) F > Cl > Br > I (b) F < Cl < Br < I
(c) F < Cl > Br > I (d) F < Cl < Br > I
4. Which among the following are diamagnetic?
(a) N2+ (b) N22- (c) O2 (d) O22-
5. What is the molar mass of glucose in gm/mol
(a) 1 5 0 (b) 180 (c) 170 (d) 60
6. For the process to occur under adiabatic conductions the correct condition is
(a) T = 0 (b) P = 0 (c) q = 0 (d) w = 0
7. Find the oxidation number of iron in K4[Fe(CN)6]
(a) +2 (b) +3 (c) +4 (d) +1
8. An electrophillic reagent is
(a) Electron deficient species (b) Electron rich species
(c) Negatively charged species (d) Lewis base
9. U° of combustion of methane is –X KJ/mol. The value of H is
(a) = U° (b) > U° (c) < U° (d) = 0
10. Arrange the following in the decreasing order of their boiling point.
n-butane, n-pentane, 2-methyl butane
(a) n-pentane > 2-methyl butane > n-butane

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(b) n-butane > 2-methyl butane > n-pentane

(c) 2-methyl butane > n-butane > n-pentane
(d) 2-methyl butane > n-pentane > n-butane
11. Magnetic Quantum number for the valence electron of Potassium is
(a) 0 (b) 1 (c) 2 (d) 7
12. The shape of carbocation is
(a) planar (b) linear (c) pyramidal (d) Tetrahedral
13. How many molecules of water are present in 0.01 mole of it.
(a) 6.022 x 1023 (b) 6.022 x 1021
(c) 6.022 x 1022 (d) 6.022 x 1024
14. How many hydrogen bonded water molecules are associated with
CuSO4.5H2O
(a) 1 (b) 2 (c) 3 (d) 4

For questions 15 to 18, two statements are given one labelled as

Assertion(A) and the other labelled as Reason(R). Select answer to these
questions from the codes (a), (b), (c), (d) as given below.
(a) Both Assertion(A) and Reason(R) are true and Reason(R) is the correct
explanation of the Assertion(A)
(b) Both Assertion(A) and Reason(R) are true but Reason is not the correct
explanation of the Assertion
(c) Assertion(A) is true but Reason(R) is false.
(d) Assertion(A) is false but Reason(R) is true.
15. Assertion : A substance which gets reduced can act as the reducing
agent.
Reason : An oxidizing agent itself get reduced.
16. Assertion : An acidic buffer is a mixture of weak acid and its salt with a
strong base
Reason : Acetate buffer is an example of acidic buffer

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17. Assertion : Acetylene is more acidic than ethane.

Reason : Acetyleve has sp character of carbon and therefore more s-
character.
18. Assertion : Dipole moment of cis Isomer is less than the trans isomer.
Reason : cis and trans are the geometrical isomers.
SECTION-B
19.(a) Write the electronic configuration of Scandium in its most stable oxidation
state
(b) How many electrons in an atom may have the following quantum
numbers?
n = 4, ms = - 1
(2x1=2)
2

20.(a) What will be the effect on equilibrium of the following reaction, when
volume of vessel increases?
2N2O(g) + O2(g) 4NO(g), H > 0
(b) PCl5(g) PCl3 (g) + Cl2(g) rH° = 124 KJ/mol
What will be the value of Kc for the reverse reaction, if Kc for the
decomposition of phosphorus pentachloride is 8.3 x 10-3 (2x1=2)
21. Derive the relation between Cp and Cv (2)

22. Draw the resonance structures for the compound CH2=CH-C=O

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H (2)
23. What do you mean by buffer solution. Explain the types of buffer with
suitable example. (2)
24. Discuss the mechanism of Friedal Craft Acylation of benzene ring. (2)
OR
Draw Newman projections for the conformations of ethane. Which of these
conformations is more stable and why? (2)
25. Arrange the elements N,P,O and S in the order of
(a) Increasing first ionization enthalpy
(b) Increasing Non-metallic character (2)

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OR
Assign the position of the elements having outer electronic configuration.
(a) ns2 np4 for n=3
(b) (n-1) d2ns2 for n=4 (2)
SECTION-C
26. In three moles of ethane (C2H6) calculate the following
(a) Number of moles of carbon.
(b) Number of moles of hydrogen atoms
(c) Number of molecules of ethane (3x1=3)
27. The first IE1 and second IE2 ionisation enthalpies (KJ/mol) of three elements
A, B and C are given below
Element IE1 IE2
A 403 2640
B 549 1060
C 1142 2080
Identify the element which is likely to be
(a) a non metal
(b) An alkali metal
(c) An alkaline earth metal (3x1=3)
28. Enthalpy and entropy changes of a reaction are 40.63 KJ/mol and 108.8
J/K/mol respectively. Predict the feasibility of the reaction at 27°C. (3x1=3)
OR
The standard enthalpies of formation of SO2(g) and SO3(g) are - 296.6 KJ
and -395.6 KJ respectively. Calculate H° for the reaction.
SO2(g) + 1 O2(g) SO3(g) (3)
2

29.(a) 0.3780 gm of an organic compound gave 0.5740 gm of silver chloride in

carius estimation. Calculate the %age of chlorine present in the compound
(b) What is the principle of paper chromatography? (2+1)

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OR
Explain the term Inductive effect and electromeric effect with suitable
examples. (3)
30.(a) Calculate the pH value of 0.01 M NaOH
(b) What will be the conjugate base of HSO- 4 (2+1)
SECTION-D
The following questions are case based questions. Read the case carefully and
answer the questions.
31.In thermodynamics, the energy changes may be measured in the laboratories
under two common conditions: One in which the volume of the system is
kept constant and other in which the pressure applied on the system is kept
constant. The energy change at constant volume is called internal energy
change (U) and energy change at constant pressure is called enthalpy
change (H).
The two quantities are related to each other as H = U + PV. The heat
changes reported are enthalpy changes because most of the processes are
carried out in open vessels i.e. at-constant pressure. The common enthalpy
changes are enthalpy of solution, enthalpy of neutralization, enthalpy of
hydration etc.
Answer the following questions:-
(a) When a reaction is carried out at constant volume, the heat evolved at
298K – 87.425 KJ. Calculate the enthalpy change for this reaction of
ammonia formation.
N2(g)+3H2(g) 2NH3(g) (2)

OR
(a) Under what conditions heat exchange at constant volume becomes equal to
heat exchange at constant pressure. Explain it by taking suitable example. (2)

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(b) For which of the following reaction H<U and H > U

(i) CH4(g) + 2O2(g) CO2(g) + 2H2O(l)
(ii) C(s) + O2(g) CO2(g)
(iii) H2O(l) H2O(g) (2)
32.Organic compounds are vital for sustaining life on earth. We depend on
these compound for our food, clothing medicines etc. For systematic study
of organic compounds, we classify these compounds depending upon their
structural features and chemical behaviour. We have assigned name to these
organic compounds on the basis of certain standard rule as per IUPAC
system of naming. The name of organic compound consist of three parts
word root, suffix and prefix.
Answer the following questions
(a) Write the IUPAC name of the compound
O O

(b) Draw the bond line formula for the compound pent-3-en-1-yne
(c) Draw the structures and write the IUPAC names of first four homologues
members of carboxylic acid series. (1+1+2)
OR
(c) Give IUPAC names of the following compounds
(i) CN

(ii) CH3 - CH - CH - CH3 (2)

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OH Br
SECTION-E
33.(a) A golf ball has a mass of 40gm and a speed of 45 m/s. If the speed can be
measured with accuracy of 2%. Calculate the uncertainly in position.

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(b) Write two difference between orbit and orbital. (3+2)

OR
(a) Two particles A and B are in motion. If the wavelength associated with
the particles A is 5x10-8m, calculate the wavelength of particle B if its
momentum is half of A.
(b) Write two differences between emission and absorption spectrum. (3+2)
34.(a) Describe the hybridization in case of PCl5. Why the axial bonds are
longer than equatorial bonds in PCl5.
(b) Why BeH2 molecule has a zero dipole moment although, the Be-H
bonds are polar. (3+2)
OR
(a) Compare relative stability of the following species and indicate their
magnetic properties i.e. O2, O 2 +, O2 - on the basis of Molecular Orbital
Theory.
(b) Although CO2 and H2O are triatomic molecules, the shape of H2O molecule
is bent while that of CO2 is linear. Explain on the basis of dipole moment.
(3+2)
35.(a) Write a short note on following name reactions
(i) Friedel Craft alkylation
(ii) Decarboxylation
(iii) Wurtz reaction
(b) Write the product and their IUPAC name obtained when hex-1-ene reacts
with HBr in the presence of peroxide. (3+2)
OR
(a) Convert ethane into butane.
(b) What product is formed when vapours of ethyne are passed over red hot
iron tube.
(c) Ozonolysis of an alkene 'x' followed by decomposition with water and a
reducing agent gave a mixture of two isomers of the formula C 3H6O.
Give the structure of the alkene and its IUPAC name. (1+1+3)

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