Organic Chemistry

Alcohol Phenol and Ether

Lecture - 01 By – Rohit Agarwal (RA sir)

Topics
Q Find all the unknowns

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 Draw all major products

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Question

Major product of the following reaction is

A B

C D
Question

The final product is

A B

C D
Question

Which of the following would be the best synthesis of the acid shown below?

D
Question

Choose those reactions that would give the following amine.

SOCl2 AgNO2

A 1+2+3 B 1+2

C 2+3 D 1+3
Question

Identify correct reactivity order for SN1 reaction

A i > ii > iii

B iii > ii > i

C i > iii > ii

D iii > i > ii

Question

A B

C D
Question

A B

C D
Question

Identify final product in following sequence

A B

C D
Question

A B

C D
Question

A B

C D
Question

A B

C D
Question

A B

C D
Question

A B

C D
Question

Identify major product of the following reaction

A B

C D
Question

Identify SN2 reaction which is favourable in a polar protic medium

A

D
Question

Suppose, a sample of an initially pure single enantiomer of tartaric acid

[a]D20 = +12.4° (H2O) underwent a chemical isomerization reaction which
yielded 10 per cent of the other enantiomer and 20 per cent of the meso
isomer, in addition to 70 per cent of the unchanged starting compound.
What is the enantiomeric excess (ee.) of the major enantiomer relative to the
minor enantiomer?
A 70 per cent

B 700 per cent

C 75 per cent

D 87.5 per cent

Question

Suppose, a sample of an initially pure single enantiomer of tartaric acid

[a]D20 = +12.4° (H2O) underwent a chemical isomerization reaction which
yielded 10 per cent of the other enantiomer and 20 per cent of the meso
isomer, in addition to 70 per cent of the unchanged starting compound.
From the total mixture, chromatographic separation on silica gel (a commonly
used achiral solid adsorbent) might be expected to yield one of the three
components in a pure state. Which one?
A the minor enantiomer

B the meso isomer

C the major enantiomer

D the 1 : 1 racemic form of tartaric acid

Question

Column I Column II
(compounds) (rate of solvolysis)

A (p) 0.07

(q) 0.12
B

C (r) 2100

D
(s) 130000
Question

Column I Column II
(compounds) (rate of reaction with NaI acetone)

A (p) 0.02

(q) 100000
B

C (r) 200

D (s) 79
Question

The final product of above reaction is

A B

C D
Question
The product ‘Q’ in the following reaction sequence is

A B

C D
Question
The major product ‘Q’ is

A B

C D
Question
Choose the incorrect option about LiAlH4.

A It is a very strong nucleophilic reducing agent

B It can reduce acid to corresponding alcohol

C It reduces to R – CH2 – NH2

D One mole of LiAlH4 can reduce only one mole of ester

Question
Which of the compound will produce odd number of moles of CO2 gas with
O3/H2O followed by gentle heating?

A B

C D
Question
Major product (P) and (Q) in following reaction is:

A B

C D
Question
Total possible R – X involved in following reaction:

A 1

B 2

C 12

D 8
Question
Final product ‘S’ in following reaction sequence is:

A B

C D
Question
The product ‘Q’ is

A B

C D
Question
Incorrect statement regarding following reaction sequence is:

A S gives yellow crystal with NaOI

B Q gives orange ppt. with 2, 4-DNP

C Product T is

D P is a Grignard reagent
Question
The product R in the above reaction sequence is

A B

C D
Question

The reagents which on reaction with gives product which give

positive Tollen’s test is

A LiAlH4 followed by H2O

B NaBH4 followed by H2O

C Na-EtOH followed by H2O

D DIBAL-H followed by H2O

Question

The number of moles of LiAlH4 required for complete reduction of 1 mole of:

A 7/4

B 5/4

C 3/4

D 1/4
Question
Reaction in which amino acid which can be obtained by hydrolysis of protein is
not obtained in:

i KCN
B CH3 − CH = NH ⎯⎯⎯⎯→
⊕ ii H2 OΤH

( ) 3( )
D Ph − CH 2 − C − COOH ⎯⎯⎯⎯⎯
( ii ) H 2 / Ni →
i CH excess

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O
Question
In the following reaction sequence, product R is

A B

C D
Question
Major product obtained in following reactions is:

A B

C D
Question
The major product obtained in the following reaction is

A CH3 – (CH2)8 – COOH

B HOOC – (CH2)8 – COOH

Br
C

D HOOC – (CH2)7 – COOH

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