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Assignment 2 SSP

The document outlines various concepts in crystallography, including the seven crystal systems, Miller indices, and Bravais lattices. It includes assignments and questions related to crystal structures, interplanar distances, diffraction, and experimental methods for determining crystal structures. Additionally, it covers definitions and derivations relevant to the study of crystalline and amorphous solids.

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Kushal Bhatt
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Download as PDF, TXT or read online on Scribd
13 views

Assignment 2 SSP

The document outlines various concepts in crystallography, including the seven crystal systems, Miller indices, and Bravais lattices. It includes assignments and questions related to crystal structures, interplanar distances, diffraction, and experimental methods for determining crystal structures. Additionally, it covers definitions and derivations relevant to the study of crystalline and amorphous solids.

Uploaded by

Kushal Bhatt
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Refer this concept

Name the seven types of crystal syatems. Explain the seven crystal systems with
Relation between primitives and angles also with their examples.

What are Miller indicies? How will you determine the miller indicies of a given
plane?

What is Bravais lattice?

Draw the (a) (100) (b) (111) (c) (110) plane.

Assignment 2

1. Anisotropic structures have _______________ properties. 01


2. The structures which are not having directional properties are known as
___________ substances. 01
3. ___________ is the fundamental building block of a crystal structure. 01
4. The inter-atomic distance is equal to _____________ 01

𝑎4 𝑎3
(a) 𝑑 = √ℎ2 +𝑘 2 +𝑙2
(b) 𝑑 = √ℎ2 +𝑘 2 +𝑙2
𝑎 𝑎2
(c) 𝑑 = √ℎ2 +𝑘 2 +𝑙2
(d) 𝑑 = √ℎ2 +𝑘 2 +𝑙2
5. Body centered cubic unit cell is not a primitive cell. (True/False) 01
6. Define : (a) Crystallography, (b) Lattice, (c) Basis, (d) Crystal Structure, (e) Unit cell,
(f) Crystallographic axes, (g) Primitives, (h) Interaxial angles, (i) Lattice Parameter,
(j) Primitive cell, (k) Atomic radius (r), (l) Co-ordination number, (m) Density of
Packing. (each definition carry 01 marks)
7. What is Crystalline Solids & Amorphous Solids. 03
8. Derive the relation between the Interplanar distance and the Interatomic distance. 05
OR
How to determine the lattice constants of crystal structure? Explain with example. 05
9. Define Reciprocal Space and Reciprocal lattice vectors. 02
10. Prove that 𝑏⃗⃗⃗𝑖 . ⃗⃗⃗
𝑎𝑗 = 0 𝑖 ≠ 𝑗
⃗⃗⃗
𝑏𝑖 . ⃗⃗⃗
𝑎𝑗 = 1 𝑖 = 𝑗
where b is a Reciprocal lattice vector and a is a Real lattice vector 03
11. Derive the Relationships between Reciprocal Lattice Vectors and Real Vectors. 03
12. Derive the condition for Diffraction in Real Space.
or
Derive the Bragg Law. 03

13. Derive the condition for Diffraction in Reciprocal Space.


or
Derive the Laue’s interpretation of X-ray diffraction by crystals. 05

14. Draw the Ewald Sphere and write the information that we get from Ewald Sphere. 03

15. Using Primitive translational vectors


(a) Represents Simple Cubic in Reciprocal Space. 02
(b) Represents Body Centred Cubic in Reciprocal Space. 03
(c) Represents Face Centred Cubic in Reciprocal Space. 03

16. Explain Wigner-Seitz cell with diagram. 03


17. Define Bragg Plane and Brillouin Zone. 02
st nd rd
18. Explain and draw the 1 , 2 and 3 Brillouin zone 03
st
19. The 1 Brillouin zone for a fcc lattice in real space is the ______________ for a bcc
lattice in reciprocal space. 01
o
20. (a) The Bragg angle for reflection from (111) planes in Al is 19.2 for an X-ray beam
of wavelength 1.54 Å. Calculate (a) the lattice constant of Al and (b) the Interplanar
spacing for these planes. 03

(b) Calculate the interplanar distance for the (321) planes in SCC lattice with inter-
atomic spacing equal to 4.12 Å. 02

21. Powder diffraction patterns of three monoatomic cubic crystals with BCC, FCC and
diamond structures are recorded using a Debye-Scherrer camera. The angles 2𝜃 in
degrees of the first four diffraction lines for the three samples marked as A, B, C are
as under:

A B C
42.2 28.8 42.8
49.2 41.0 73.2
72.0 50.8 89.0
87.3 59.6 115.0

(a) Determine the structure type of each sample.


(b) What is the size of the cubic cell in each case?
Take the wavelength of incident x-rays as 1.5 Å. 05

22. Name the different method for determination of crystal structure. 01

23. Define Constructive & Destructive Interference with formula. 01


24. Explain Experimental method for the generation of X-rays. 03
25. Explain any one Experimental method for determination of crystal structure. 03
26. Explain the Laue method for determination of crystal structure. 03
27. Explain the Rotating crystal method for determination of crystal structure. 03
28. Explain the powder method for determination of crystal structure. 03
29. Name the source or incident beam with wavelength to study crystal structure. 01
30. Define Atomic form factor. 01
31. Derive the Structure factor for SCC Structure. 02
32. Derive the Structure factor for BCC Structure. 03
33. Derive the Structure factor for FCC Structure. 03

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