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14

③Define
Do not write
outside the
0 6 The concentration of dilute hydrochloric acid can be found by titration using a box

standard solution of barium hydroxide.

0 6 . 1 Calculate the mass, in g, of solid barium hydroxide (Mr = 171.3) needed to prepare
250 cm3 of 0.100 mol dm–3 barium hydroxide solution.
[1 mark]

Mass g

0 6 . 2 The mass of barium hydroxide from Question 06.1 is dissolved in a beaker containing
-
150 cm3 of distilled water.

Describe how this solution is used to make 250 cm3 of the

0.100 mol dm–3 barium hydroxide solution.

Fast
[3 marks]

a volemetric

flask
Wash beaker stirred

two/three time with distilled

and add distilled
transfer washing in f v -
.

to make volume to the mark Place cap

and mix .
well
up .

0 6 . 3 Before the first titration, the 25-

cm3 pipette is rinsed with a small volume of the
0.100 mol dm barium hydroxide solution.
–3

-
State why it is good practice to rinse the pipette in this way.
[1 mark]

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15
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outside the
0 6 . 4 Hydrochloric acid is added to the burette using a funnel. box

State why it is good practice to remove the funnel from the burette before the titration.

E
-
[1 mark]

Ba(OH)2 v
0 6 . 5 In a different experiment, 0.952 g of solid barium hydroxide is used to make 250 cm3
---
of standard barium hydroxide solution. -

②
25.0 cm of this barium hydroxide solution reacts with exactly
3

24.50 cm3 of hydrochloric acid.

Calculate the concentration of the hydrochloric acid.

① Bacon) + QUc1 >
- 10
Ba + [3 marks]

55x#
Balon) - /VC
3 V= 24 50 .

V= 0 .
0245

#
56Xion in 25ch3
.
↑
C =1
~
Concentration 0 . 045 mol dm–3

0 6 . 6 The uncertainty in the 25.0 cm3 of solution from the pipette is ±0.05 cm3
-

O
The total uncertainty in the 24.50 cm3 of solution from the burette is ±0.15 cm3

Calculate the total percentage error in using the pipette and burette.
[1 mark]
total
-
value
uncertainity
measured
100
pipette 25

24 50
.

Percentage error 10

o of times read the apparatus X I error

uncertainity : No we

Turn over ►
Value measured
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 2A)(120)s
Aon): 210
1 :
:

2
& 3 .
1 x 103
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18
Do not write
outside the
0 7 . 8 Hydrated aluminium sulfate, Al2(SO4)3.xH2O, is soluble in water. box

The relative formula mass and value of x can be found from a titration experiment.

Aqueous [Al(H2O)6]3+ ions react to form a stable complex when treated with an excess
of EDTA4 – ions.

The excess of EDTA4 – ions is determined by titration with ZnSO4 solution.

Method
-
• DissolveO
1.036 g of Al2(SO4)3.xH2O in distilled water and make up to 250 cm3
-
-n
-
-

cr
• Add 25.0 cm of this solution to 50.0 cm of a solution containing
I
3 3 =

50x15"
-

EDTA4– ions of concentration 0.0100 mol dm–3 = excer

-

• Determine the excess of EDTA4 – ions by titrating with ZnSO4 solution in the
-
presence of an indicator.
-

The excess of EDTA4 – ions requires 18.00 cm3 of 0.0105 mol dm–3 ZnSO4 solution to
react completely. = xv 1 894104 =
.

The equations for the reactions are

&
[Al(H2O)6]3+ + EDTA4– → [AlEDTA]– + 6 H2O
> Pum
- -

-
[Zn(H2O)6]2+
u
+ EDTA4– → [ZnEDTA]2– + 6 H2O

For Al2(SO4)3 Mr = 342.3

89X104
(unused) 1
gEDTA
.
~ =

Given-unused
ngEDTA
used =

104 89x10" 3
11x10
crisx10
5
.

X -
1 .
=

of Shp] in 250

Hz)sou) ;: Al (to)
·
I 2 xio3
=
Mr = =3
-

= 666

son) = 666

x =
10
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19
Do not write
outside the
Use the information given to calculate the Mr of Al2(SO4)3.xH2O box

Calculate x
Give your answer as an integer.
[7 marks]

Mr

x 17

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IB/M/Jun23/7405/1
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- MARK SCHEME – A-LEVEL CHEMISTRY – 7405/1 – JUNE 2023

Question Answers Additional comments/Guidelines Mark

0.100 × 250 × 171.3 = 4.28 g 1

06.1 Allow 4.3 g
1000 (AO2)

Question Answers Additional comments/Guidelines Mark

M1 Transfers the solution to a volumetric/graduated flask
3
M2 Add washings using distilled water and make up to the
06.2 (3 x AO2)
graduation mark/250 cm3
M3 Invert many times / shake to mix

Question Answers Additional comments/Guidelines Mark

So that the titration is done with known concentration of Ba(OH)2
Allow so that water does not dilute the solution 1
06.3
Allow remove water/prevent contamination (AO3)

Question Answers Additional comments/Guidelines Mark

Drops of acid could fall into the burette (so no longer know how Ignore changes the titre 1
much has been added from burette)
Do not accept increases titre (AO1)
06.4
OR
Decreases titre

21
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MARK SCHEME – A-LEVEL CHEMISTRY – 7405/1 – JUNE 2023

Question Answers Additional comments/Guidelines Mark

0.952
M1 n Ba(OH)2 in 25 cm3 = = 5.56 x 10–4 mol
171.3 𝐱𝐱𝐱𝐱𝐱𝐱

M2 n HCl in 24.5 cm3 = 2 x 5.56 x 10–4 = 0.00111 mol 3

06.5 M2 = M1 x 2
(3 x AO2)
0.00111 × 1000
M3 Concentration of HCl = = 0.045 mol dm–3
24.50 M2 × 1000
M3 =
24.50

Question Answers Additional comments/Guidelines Mark

0.15 + 0.05 x 100% = 0.8(1)% 1

06.6
24.50 25.00
(AO2)

22
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MARK SCHEME – A-LEVEL CHEMISTRY – 7405/1 – JUNE 2023

Question Answers Additional comments/Guidelines Mark

M1 n (EDTA4–) added = 5 x 10 – 4 mol alternative methods will be allowed

M2 n (Zn2+) = 1.89 x 10– 4 mol

M3 = M1 – M2
M3 n (EDTA4–) reacted with the 25 cm3 sample of Al3+
= 5 x 10 – 4 – 1.89 x 10– 4 = 3.11 x 10– 4 mol
M3 × 250
M4 n EDTA4– reacted with the 250 cm3 sample of Al3+ M4 =
25
= 3.11 x 10– 4 x 10 = 3.11 x 10– 3 mol
7
07.8 M5 n Al2(SO4)3 xH2O = 3.11 x 10– 3 ÷ 2 = 1.555 x10– 3 mol M5 = M4 ÷ 2
(7 x AO2)

M6 Mr Al2(SO4)3 xH2O = 1.036 ÷ 1.555 x10– 3 = 666.2 M6 = 1.036 ÷ M5

M6 – 342.3
M7 342.3 + 18 x = 666(.2) so x = 18 M7 = and answer as integer
18

25
 -

kMnO4
2

4120-
G
3MnOn +

3
MnOn +
9120
v = 35 . 85cm
c = 0 .

02

n =
Binon + 102
0 3
10

This question is about hydrogen peroxide, H2O2

Do not write
outside the
box

The half-equation for the oxidation of hydrogen peroxide is

H2O2  O2 + 2 H+ + 2e–

Hair bleach solution contains hydrogen peroxide.

A sample of hair bleach solution is diluted with water.

The concentration of hydrogen peroxide in the diluted solution is 5.00% of that in the
=>
original solution.
A 25.0 cm sample of the diluted hair bleach solution is acidified with dilute sulfuric
-
3
- -

acid.
This acidified sample is titrated with 0.0200 mol dm−3 potassium manganate(VII)
-

solution.
The reaction is complete when 35.85 cm3 of the potassium manganate(VII) solution
are added. -

xio
02x003985 =
Mn=
0
(xV
.

3: 4 Upon 9-50X10-
=

0 3 . 1 Give an ionic equation for the reaction between potassium manganate(VII) and
acidified hydrogen peroxide. C =

1.
W -

Calculate the concentration, in mol dm–3, of hydrogen peroxide in the original hair
bleach solution.

(If you were unable to write an equation for the reaction you may assume that the
mole ratio of potassium manganate(VII) to hydrogen peroxide is 3:4
This is not the correct mole ratio.)
[5 marks]

=>
Conce
0 .

465
-

Concentration mol dm–3

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 11
Do not write
outside the
0 3 . 2 State why an indicator is not added in this titration. box

[1 mark]

0 3 . 3 Give the oxidation state of oxygen in hydrogen peroxide.

[1 mark]

0 3 . 4
apamil
Hydrogen peroxide decomposes to form water and oxygen.

Give an equation for this reaction.

Calculate the amount, in moles, of hydrogen peroxide that would be needed to

produce 185 cm3 of oxygen gas at 100 kPa and 298 K

The gas constant, R = 8.31 J K−1 mol−1

[5 marks]

Equation

212
(e)
-
250 +

Amount mol

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outside the
0 3 . 5 Hydrazine (N2H4) is used as a rocket fuel that is oxidised by hydrogen peroxide. box

The equation for this reaction in the gas phase is

The enthalpy change for this reaction, ∆H = –789 kJ mol−1

Table 3 shows some mean bond enthalpy values.

Table 3

N–H N–N N≡N O–H

Mean bond
388 163 944 463
enthalpy / kJ mol−1

Define the term mean bond enthalpy.

Use the equation and the data in Table 3 to calculate a value for the O–O bond
enthalpy in hydrogen peroxide.
[5 marks]

Definition

Bond enthalpy kJ mol–1 17

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0 5 . 7 Table 4 shows the melting points of three substances. box

int Table 4

H-F/
&-
Substance Melting point / K
sodium chloride 1074
Giant Lallis

mo
chlorine ⑤
172
weak hydrogen chloride 158 3 covalent
molecular
simple
Explain why the melting points of these substances are different. sticker .

You should refer to the structure of and bonding in each substance.

[6 marks]
HCl S -
St Permanent &P-DP

2 +
of
um-polar
more
no / higher LDF

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Do not write
outside the
box

15

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outside the
0 4 . 4 Iron reacts with dilute hydrochloric acid to form iron(II) chloride and hydrogen. box

Y Fe(s) + 2 HCl(aq) → FeCl2(aq) + H2(g)

A 0.998 g sample of pure iron is added to 30.0 cm3 of 1.00 mol dm–3 hydrochloric acid.

One of these reagents is in excess and the other reagent limits the amount of
hydrogen produced in the reaction.

Calculate the maximum volume, in m3, of hydrogen gas produced at 30 oC and

100 kPa.

Give your answer to 3 significant figures.

In your answer you should identify the limiting reagent in the reaction.

The gas constant, R = 8.31 J K−1 mol−1

[6 marks]

Volume of hydrogen m3

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IB/M/Jun21/7405/1
S 0 .

9859y .

E250c
25cm3
+
* 2 cuC + Ul >
-
12

25202
-
+
I
&

- #
u
So = 0 . 08x0 009
.

=
7 . 2x104
+
I c =
7 2x10- Y
.

in
250cm = 7 .
2 x 103

m = nX Mr

7 .
2x103x63 :
5

04579
= 0 .

%T X1004 I