Target DPP Test Contact Number: 9667591930 / 8527521718

1. The enthalpy of combustion of cyclohexane, 6. The standard heat of combustion of Al is

cyclohexene and H2 are respectively -3920, -837.8 kJ mol-1 at 25∘ C which of the following
-3800 and -241 kJ mol-1. The heat of releases 250 kcal of heat ?
hydrogenation of cyclohexene is - 1. The reaction of 0.624 mol of Al
1. -121 kJ mol -1 2. The formation of 0.624 mol of Al2O3
2. 121 kJ mol -1 3. The reaction of 0.312 mol of Al
4. The formation of 0.150 mol of Al2O3
3. -242 kJ mol-1
4. 242 kJ mol-1
7. Heat of hydrogenation of ethene is x1 and
2. Bond dissociation enthalpy of H2,Cl2 and HCl that of benzene is x2. Hence resonance energy
is-
are 434,242 and 431kJ mol-1 respectively.
1. x1 − x2
Enthalpy of formation of HCl is
2. x1 + x2
1. 93 kJ mol-1
3. 3x1 − x2
2. -245 kJ mol-1 4. x1 − 3x2
3. -93 kJ mol-1
4. 245 kJ mol-1 8. The intermediate SiH2 is formed in the
thermal decomposition of silicon hydrides.
∘
Calculate ΔHf of SiH2 given the following
reactions
3. The dissociation energy of CH4 and C2H6 are ∘
Si2 H6 (g)+H2 (g)→ 2SiH4 (g); Δ H = −11. 7 kJ /m
respectively 360 and 620 Kcal/mole. The bond ∘
SiH4 (g)→ SiH2 (g)+H2 (g); Δ H = +239. 7 kJ /m
energy of C-C is-
−1
1. 260 Kcal/mole ΔHf , Si2 H6 (g)= +80. 3 kJ mol

2. 180 Kcal/mole 1. 353 kJ/mol

3. 130 Kcal/mole 2. 321 kJ/mol
4. 80 Kcal/mole 3. 198 kJ/mol
4. 274 kJ/mol
4. The bond energies of C=C and C-C at 298 K
are 590 and 331 kJ mol-1 respectively. The 9. The enthalpies of the following reactions are
enthalpy of polymerization per mole of shown alongwith.
1 1
ethylene is 2
H2 (g)+
2
O2 (g)→ OH (g) ; Δ H = 42. 09 kJ mol
−

1. -70 kJ H2 (g)→ 2H (g); Δ H = 435. 89 kJ mol

2. -72 kJ
O2 (g)→ 2O(g); Δ H = 495. 05 kJ mol
3. 72 kJ
4. -68 kJ Calculate the O-H bond energies for the
hydroxyl radical.
-1
5. The C-Cl bond energy can be calculated from 1. 223.18 kJ mol
: 2. 423.38 kJ mol-1
1. ΔH f (CCl4 , l) only 3. 513.28 kJ mol-1
∘

2. Δ f (CCl4 , l) and Δ(Cl2 ) 4. 113.38 kJ mol-1

∘

3. ΔH ∘ f (CCl4 , l) Δ(Cl2 )
4.
∘ ∘ ∘
ΔH f (CCl4 , l) Δ(Cl2 ), Δ H f (C, g) and Δ H vap (CCl4 )

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 Target DPP Test Contact Number: 9667591930 / 8527521718

10. Consider the following reactions: 13. The enthalpy change for the reaction is
H+(aq) + OH-(aq) → H2O(l) called
(i) C2 H4 + 3O2 → 2CO2 + 2H2 O
ΔH = -x1 kJmol-1
1. Enthalpy of formation
H2(g) + 1/2O2(g) → H2O(l) 2. Enthalpy of vaporisation
(ii)
ΔH = -x2 kJmol-1 3. Enthalpy of sublimation
4. Enthalpy of combustion
CO2(g) + H2(g) → CO (g) + H2O(l)
(iii)
ΔH = -x3 kJmol-1 14. If the value of ΔH in a reaction is positive,
C2H2(g) + 5/2O2(g) → 2CO2 + H2O(l) then the reaction is called
(iv) (1) Exothermic
ΔH = -x4 kJmol-1
(2) Endothermic
(3) Polymorphic
(4) Polytropic
Enthalpy of formation of H2O(l) is :
1. −x3 kJ mol
−1
15. On the basis of thermochemical equations
2. −x4
−1
kJ mol (i), (ii), and (iii), find out which of the algebraic
3. −x1 kJ mol
−1
relationships given in options (a) to (d) is
4. −x2 kJ mol
−1 correct:
C(graphite) + O2(g) → CO2 (g) ; ∆rH = x
(i)
kJmol-1
1

11. Consider the following reaction, C(graphite) + O2(g) → CO(g) ; ∆rH = y kJ

(ii) 2

S + O2 → SO2, ΔH = – 298.2 kJ mole–1 mol-1

SO2 + 1/2 O2 → SO3, ΔH = – 98.7kJ mole–1 O2(g) → CO2(g); ∆rH = z kJ mol-1
1
(iii) CO(g) + 2

SO3 + H2O → H2SO4 , ΔH = – 130.2 kJ mole–1

1. z=x+y
H2 + 1/2 O2 → H2O, ΔH = – 287.3 kJ mole–1
2. x=y-z
the enthalpy of formation of H2SO4 at 298 K 3. x=y+z
will be– 4. y=2z-x
1. – 814.4 kJ mole–1 2. + 814.4 kJ mole–1
3. – 650.3 kJ mole–1 4. – 433.7 kJ mole–1
16. Select the correct option based on
statements below:
12. Given that the bond energies of :
Combustion is an exothermic
, H-H is 435 kJ mol , Assertion (A): process.
−1 −1
N ≡ N is 946 kJ mol

N-N is 159 Kj mol-1 and N-H is 389 kJ mol , the

−1

Combustion is a spontaneous
heat of formation of hydrazine in the gas phase Reason (R): process.
−1
in kJ mol is-
1. 833 Both (A) and (R) are true and (R) is the
2. 101 1.
correct explanation of (A).
3. 334
Both (A) and (R) are true but (R) is not the
4. 1268 2.
correct explanation of (A).
3. (A) is true but (R) is false.
4. Both (A) and (R) are false.

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 Target DPP Test Contact Number: 9667591930 / 8527521718

17. Heat of combustion ∆Hº for C(s), H2(g) and 21.

CH4(g) are – 94, – 68 and – 213 Kcal/mol. ∆Hº for Assertion (A): All combustion reactions are exothermic
C(s) + 2H2(g) → CH4 (g) is: For an exothermic reaction, enthalpies o
1. – 17 Kcal 2. – 111 Kcal products are greater than enthalpies of
Reason (R):
reactants (Σvp Δf H (P ) > ΣvR Δf H (R
3. – 170 Kcal 4. – 85 Kcal
.

18. The average S–F bond energy in kJ mol–1 of Both (A) and (R) are true and (R) is the
1.
SF6 is: correct explanation of (A).
[The values of standard enthalpy of formation Both (A) and (R) are true but (R) is not the
2.
of correct explanation of (A).
SF6(g), S(g), and F(g) are –1100, 275, and 80 3. (A) is true but (R) is false.
kJmol–1 respectively.] 4. (A) is false but (R) is true.
1. 309 kJ mol–1 2. 313 kJ mol–1
3. 305 kJ mol–1 4. 318 kJ mol–1
22. Assertion(A): Enthalpy of graphite is lower
than that of a diamond.
19. If at 298 K the bond energies of C-H, C-C, C = Reason(R): Entropy of graphite is greater than
C and H-H bonds are respectively 414, 347, 615, that of a diamond.
and 435 kJ mol–1, the value of enthalpy change 1. Both A and R are true and R is the correct
for the reaction at 298 K will be: explanation of A.
H2 C = CH2 (g) + H2 (g) ⟶ H3 C − CH3 (g) 2. Both A and R are true but R is not the correct
1. +250 kJ explanation of A.
2. –250 kJ 3. A is true and R is false.
3. +125 kJ 4. A and R both are false.
4. –125 kJ

20. Which of the following equation represents 23. Assertion(A): The enthalpy of formation of
a reaction that provides the enthalpy of the gaseous oxygen molecules at 298 K under a
formation of CH3Cl? pressure of one atm is zero.
Reason(R): The entropy of the formation of
1. C(s) + HCl(g) + H2 (g) ⟶ CH3 Cl(g)
gaseous oxygen molecules under the same
2. C(s) + 3H(g) + Cl(g) ⟶ CH3 Cl(g) conditions is zero.
3. C(s) + 3/2H2 (g) + 1/2Cl2 (g) ⟶ CH3 Cl(g)1. Both A and R are true and R is the correct
4. CH4 (g) + Cl2 (g) ⟶ CH3 Cl(g) + HCl(g) explanation of A.
2. Both A and R are true but R is not the correct
explanation of A.
3. A is true and R is false.
4. A and R both are false.

24. The enthalpy of vaporisation of a liquid is

30 kJ mol–1 and entropy of vaporisation is 75 J
mol–1 k–1. What is the boiling point of the liquid
at 1 atm?
1. 50 K 2. 400 K
3. 450 K 4. 600 K

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 Target DPP Test Contact Number: 9667591930 / 8527521718

25. The bond dissociation energies of gaseous 30. Burning 48.0 g of graphite in excess oxygen
H2 , Cl2 and HCl are 104, 58, and 103 kcal under standard conditions releases 1574.0 kJ of
∘
respectively. The enthalpy of the formation of heat. What is ΔHf of CO2(g)?
HCl gas would be: 1. 157 kJ mol-1
1. – 44 kcal
2. –1574 kJ mol-1
2. 44 kcal
3. – 22 kcal 3. –394 kJ mol-1
4. 22 kcal 4. 32.8 kJ mol-1

26. For which reaction enthalpy change will be

equal to the enthalpy of formation? Fill OMR Sheet*
1. H2 (g) + Cl2 (g) → 2H Cl(g)
2. H2 (g) + Br2 (l) → 2H Br(g) *If above link doesn't work, please go to test link
3. H2 (g) + l2 (g) → 2H l(g) from where you got the pdf and fill OMR from
4. C(graphite) + O2 (g) → CO2 (g) there

27. If bond enthalpies of

C − C, C − H , O = O, C = O and O − H

are
a, b, c, d, and e respectively, then the heat of
combustion of ethane will be:
CLICK HERE to get
7
1. 6b + 2 c + a − 2d − 3e FREE ACCESS for 2
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days of ANY
b + c + a − 4d − 3e
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3. 6b +
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c + a − 4d − 6e

4. 6b + 7c + a − 4d − 6e
NEETprep course
28. If the enthalpy of the formation of diamond
and fullerene respectively are 1.90 and 38.1 kJ
mol-1 then the enthalpy change for the
conversion of diamond to fullerene will be:

1. 19 kJ mol-1
2. 36.2 kJ mol-1
3. 40 kJ mol-1
4. 57.1 kJ mol-1

29. Consider a reaction:

A2 + B2 → 2AB

(g) (g) (g)

If ΔH
o

f
of A2 , AB and B2 are in the ratio
1
1 :
2
: 1 and ΔH of the reaction is -200 kJ/mol.
The value of ΔHfo (A2 ) (kJ mol-1) is:
1. 250
2. 200
3. 300
4. 240

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