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Unit - 2 Cristal Structure

The document discusses the structure and properties of crystalline solids, including their atomic arrangement and classification. It covers various types of crystal systems, unit cells, and packing fractions, emphasizing the geometric and spatial relationships within these structures. Additionally, it touches on Miller indices for identifying crystal planes and their significance in crystallography.

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0% found this document useful (0 votes)
63 views22 pages

Unit - 2 Cristal Structure

The document discusses the structure and properties of crystalline solids, including their atomic arrangement and classification. It covers various types of crystal systems, unit cells, and packing fractions, emphasizing the geometric and spatial relationships within these structures. Additionally, it touches on Miller indices for identifying crystal planes and their significance in crystallography.

Uploaded by

nagas2820
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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UONIT- CRYSTAL A i SPRU CTURE Qasee on dhe Arrangement & oem de omedecule,s, the, solide Pe pinky Clamifieg Afr uo Thies, |. CGsballine sobifs a Apatiphas SoPeR. SenTo Grystalline Sotiys Arraphrs Schiys ' Costallne Sebig heve. Prob phos Schidg have. Segue ava perirdic. | {hhegelh aBtrangemnent- asnengement” cs ctoms | 4. stows. These ahe Arnisctiopic m1 sneha . be, These Solids have These. abe, TLaclSpic. in nslore- ine, These Sets ae Sam Siftelorst porettios 41 | papudies M1 AHL Liffevent dive chins Mivestimns Be | Pt tae Ney Shahp These. donot have. sharp walling poets Melby pate 4) Th have Long Semye | De “have. shat rane ode ¢ chiwnic. Scie tin Pde! Pore, — In ectinn Ryu AKOLLT, GIET, RIy y Cotling Gwe F Gyetling The Coting Cutwe- §- Setids has bvtax, Armphiphoas Sebi IS Somat be | Chee brad Lhée-Gua,} Db have High Lebbig. fury, Gravee 4 eas The. Atlemic oshangeomenit a & Copia % Knowrt os an Suche, ch ‘ehwthon Spowe Laltice + Grae Space tallia $- G Lallze t defy os an aay & Lali poke Aa Space Auch that” the emvinemedt alepul each point is thi Same. Rayctona Kell, GiET, RIy THis also defines as, an Imfints 3—Dimensien ¢. clams ot Bay ane. et fin & Oxted Gass tm A f indettial alte, oreygheeules Fe] a agitny & Glle4 05 Gasis. Tg bats achas & building Unit & Siauctival iat fe the Complelc Cryst! Slut. Unt ell = Uraih Gill js a Smallst” geamalnic Rye, Se depetttom hid; Sn B—Drnensimal well gives usc, one ont “we types. \. priwichie ol ) Simple cll 2. Aim prindiall @ Mule all. poienclit all 3- One Lalitie point is onvodeteg WHT enclt primal. call. Ton — Fmnslie, Sell t Dp weit cll Coctaiys orvte. they one Lottie pt 4 dnc ont tha, it & Glleq as en — pomatig ( “uli Lattice -prarnciens e—_— x > > The Gthee is erste up ¢- a repeliton f unit alls. = Ap unital Gade Comeletl, describeg by tine, —furdacmerita SRetoys, 1, Song C Clley Lattice vectas ¥ a Tr aboot, Ka An angle bebresm bh and © Techs Pa Aim angle belie Tow IT vecing wd Vo Am angle befitum Cond T Ved The Angle o% Band ¥ are Korum as rite — pecs angles om orks Gilley os Late. prem > The tae and Shope ge dhe unital] depends taal the Nalux ¢ Lattice Paraconebois, Rajguena Kon, Ger, RTy Qravais Lalllicg AY pace (ellie on oT is pom a Space. auch that the envinermerit” ebysat each pect ame +» Uy Ail He chrome lata prone Teckel, the Lh te Konto Graves tellin Braves Laitiee ore Jn Tate detroit Prmnemsins, 1. Bravois tatiys £4 Q- Dirmewrions | 2. Ghwais Lilligs 4 3—Deeewaiet- (Breiols litins in 2—-Prevein wa tie boas Fabio Sgworyy the B-0 Fug are Clowifeg Anke 4 Systemys ont F Lathie penile ean g yee, Gonertnanal aa tae |Saiban | ee 1. [oblique | ebleque | Patalllegren 04 ay geist 2. Sqyore Layee | Syove, | asa pore 3 Hexggoml | Hexegene) / be, Romboy a. b= wot a mero | pectendy | Rechnele | WFR 5 Grtevet g =e" Rechomgrle’ Lao aba Syue. 3 p= oseibFoy TT. oe \ 4 ae Hone pe ye | _paveonl, ee ey 220° Th] . . ape, b= 40° Groot Rectangle LJ a a, pebs | Pras Lute i 3—Drmematon Tn 142, Gnavals chonted thet they are 14. defetest “ypes Space Lelie fa BHD « romong 4 balls The gemianel Lette 1 Triclaic and ey, 13 ve Specie] Lsithee. ) Callectl, Bley Umit all chenackmstics: a char Ka Bavage = mo. thee =23 peel ate : fT, + El Be RGA KoLuT , GIET, Ray 2o “ebageu Gren > Unitall durackvishies $a = bet R=Bavaqe > Ao 4% tbh i 2 —> Otaevets Ista: P, ak 3. onthogened ete > Uritall chehackwsties $ ashe oe pav> 40° —> No. $+ icties : 4 > Brwois Litivs: PIL, - eo Thigonal $ystere1 3 Uniball Csockvistics : asb=c Aa PavPqe <12d az Ne. Gf Lattice 3 ~> Orbis Lda s | S: Hereginel ester ¢— Umit ell chahachvishes', aaeb=c =p =, Va 120° No. ¢- Lodtiee s | Brevis Laltice + | C 44 @) RajGibas KoLLl, GieT, KTy b. Monoclinic + DniPall chehackvishes: Gt b#C KaV=qoF Bp neg. Lattices 3 2 Prwais Lhe > P, 6 Wf Tr TRislinic. system Uri all cee aphszc Cothdinekion Numb pt + Srmple Cubic sluctog. (5c) = b e Body GAB ned Cubic. Sthucsting = & 2 face Giles Cable Siuechi = 12 > She dislane bettie tue ~essest “elgh brvting Mirae Joy Copet Stinchae (latte) Known as ey tf ti, Ae oly “estes oneighbounng distane pv «SOC nma Beco = NB ow . 7ce ful Prtemic Packing Fvaction 2 a unt all & Neleome Unitell & low ns Artemic, Pactiigg Fraction, Rejeupan KOLLE, GiET, RIy A Gemenally , the -facicing pracling Nomis firm 0.84. te a T4 fh Seffevenst Cogstel Sticke. +, Artvinic pacing fiaction = Volume of echo 84 De Tole f vrtrall Ape = aL ON treiing Haclion of @ Simple OOF Faction ga Simple " etomele. Cube oe (-c) {$e Ao Ey . > Qrople Cubic stamiliy (S-¢ the dirs one presenc! only at te Chmys ge Orit all. 5 Umitell @ Gibic Gude Ke polenta. > Lack, foms 1 SwHounded by b messed” neigh brung chorms, So Cotdtnatann Trev fs b. > let a be eon tig patarnielets 4 oredr ull The Atirnic tydlivs @) = ofp Baw Ragora four, Fer, Rp > Each Cr doen & Shoteg by 8 mag brosing Unik cll. The numbey coms fev rit ell = Sey=l The hadlius t Atom = Yo aa Aw Nelueme £- cach often = am Te Veburne € acho fq ruebcl Va 1K ne The Nelume €- Inifall V= a = {a vie Be Poctuing freching ph — = anf Prenreyg ARoechony is OG. Hense Las ctanctahe is Loosely packed bud M Pacring rvctin ¢ bee has Bigut @ choms at eign Goneys F the Cue ont one actor at Griki, Gf Cube. 5 Game acto i shotes by Gage cet all of thee ane GS ahs ab tGgah Ghmeys. > The Tunky aa forms py rer ell = 8xb a2 —» Untell ¢ &cc clauckive & Nlon— phionitar Cc <— e—> 7p Pe way Tn dk Ape, Aes At ay ce a ae 20” A= Yaa Rayerbra KoLir, GieT, RIy In Ae Ac, Ac = AB Be ve v GD 2 (la) +a¥ Ilan’ = 30% cs A @ Nebuene € eb Gll Via od Nie a ‘Y= can WE rio. atoms pe Unit ell a2. The Nebuene. atoms nq ntti Veo on A S v= 8 wd fee Pyne packing frachne is Kung S = 8a as (64-8) 15) = Ari HE A LF a om = ae —— = 0.62 Apt = bes Recipes KLEE, Get, Ry Packing Fraction — Face Grltheg Cubic Cyst) (Fee) 3 Fee bs 8 atoms at @ Canes $ the unital ard b atoms The Covrdinslioy rembey is 12, becanse each acto as Hhetied 12. “eases ocloms, Tm Ale Agc - Ac’= AB BY ed ay= abo 20 IbAY ag Rajeubes Kon, GET Ke rae Loe a f® = ON a= oh Nefuome. 6 dhe ete unital) V= a> =Qz ny = = INE NJohome ¢ the toms Fy Orit ail Na 4A Arhrnic pacing Freche 2 Vv paseo v JE Tz 4 ‘SY WN Wy ae N32 Ot ir Arh = 147. Pretng Fractim is 0114. and Pang atoms i fee w 14% 5 Db tas posed that tatth pachas thay sc and Bc RapApra Kort, GIET, oa Mille endices _— x ——-A The Nedproays ¢- the intssaals made by & plane, on te Cochdinale ais GD Coysinlle graple aris one. Kono a6 Miller Trdices. > These oe fe pvewenteg bot (hk, £) ant these one. Smallest i vs Precedune for fending nelle Tndiccs Y = — let He tnlchagls 4 desires plane on the Goedina » Ga, Vo, %) > Dovide Wel prtaicties Gr bo), antesepts ne PLY 7 Tene the hei procls ¢ the dxtenegls ttt of > Ring the Lom ¢ Codinctleys Reduce dhe Secpocl, site Stegeys by ~rualteyi cach them welt Lom RayGunma KoLLr, gieT, Ry —7 These inkeeys nelasea ra bhacnels, representa Ue milly andtas (h Ke) f & Given plane. ay ee sae gee Hy Milan Drdics tps the cumin of plans iq @ Coste! af plone poral ts amg one f- Cobrdincle axes will have. a “penile: Ltiympl and Céresponding mélls, — Trdex ts Bede. > A phne Porting tiny the rigin & Aging Ba tse of. o- pabialel plore having “non Jere srtencets. > All plane parallel bore. some mills, indices (h kD. = When an Lnikisest - 2 plane i veqihe, The index 1 Nepveseniteg by a bab ale th NJovieus planes - Cogetod (i 0 ©) plane @! 0) plane x i as x = z Rapelons Kotte, GET, RI (oon plane (110) plane " Sepmidtion befiion Succes. (h KD phones aiken see] Lebus Comside/ a plane Abe maning intense ls on the Gohdinete axes OX, OY) OF distane 0A, 0B, 06 aspectiiely as Show 31 figue. ¥ Z > Crisidey o plane ABC making inkaels on the Cadine axes Ox, of, oF ata dishes OA, OB, OC hespecla 7 — Letus Comide’ any are Posnilel plans wit mele Indies (h K4). a The ple mks babi cet a, 2 bg ond Sp om %, ¥€ axes Meapeclevely. On= 4%, , 08 = bh and ot = Yp > A nfongh ont & Agsein te dhe plow Asc “from the dyin ong distame of the plone _ Ac hom the Aigin ,désrirnce IS Some plana : Ratiana KoLur, GET, Roy ~ famed tnisy play Spacing & (nl). = let te oa id nédrna) welh- Xe % aves be ot, pan Osa = Ot = ; oh coho oo of bk GsY¥= od 24d oc gt Aron odimg te lan of Aveclionel Casings Gas! asp + csV'= | qd w+ at Can +f Steep sl Al ack lw 44 Pe ri+e — The Ex pessint PR raphe Sepvathion % given by 7 Eee) (eee fe wee toe axzb=c a = b KL TRE a Rapeuone Ket , GIET, RI

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