FULL TEST - 03

PART - I : PHYSICS æ m g ö æ 1.5 ö

çè m - 1÷ø çè - 1÷ 1
1. (1) Let fa l 1.25 ø 5 2
7. (3) = = = =
Initial length = l1 fl (m g - 1) 1.5 - 1 1 5
Final length = l2 2
Initial area = A1 5 5
f l = f a = ´ 2 = 5 cm
Final area = A2 2 2
\Volume remains same 8. (2) Dimensional formula of energy
l 1
\ A1 l1 = A2 l2 Þ A1 l1 = A 2 1 E = mv 2
4 2
Þ 4A1 = A2 [E] = [M1 L2 T–2] ...(I)
rl Dimensional formula of gravitational constant
Initial resistance, R1 = 1 = 160W (given)
A1 Fr 2
rl G=
Final resistance, R 2 = 2 m1m2
A2 [G] = [M–1 L3 T–2] ...(II)
R l A l A From eq. (I) & (II)
\ 2= 2 1= 1 1
R1 A 2l1 4 4A1l1
é M1 L2 T -2 ù
E
1 1
Þ R 2 = R1 = ´ 160 = 10W \ = ë û = é M 2 L-1 T 0 ù
16 16 G éM -1 L3 T -2 ù ë û
ë û
W mgh 9. (3) For photoelectric emission, incident light frequency
2. (4) Power, P = =
t t should be greater than threshold frequency.
m1 gh Frequency of incident light is 1.5 times the threshold
P t m t frequency v0.
\ 1 = 1 = 1 2
P2 m2 gh t1 m2 3
t2 v = v0
2
P1 300 ´ 2 12 3 x If frequency is halved,
\ = = =
P2 5 ´ 50 5 x +1 v 3
\v ' = = v0 Qv ' < v0
So, 12 x + 12 = 15 x Þ 3 x = 12 2 4
\ x = 16 \ No photoelectric emission will take place.
3. (2) Diamagnetic materials does not allow magnetic field 10. (2) Centre of mass of system depends upon position
lines to passes through them. and masses of particle. Also, it depends upon relative
Bar B represents diamagnetic materials.
distance between particles.
4. (3) Microwave ® Aircraft navigation
11. (1) Focal length of the combination can be calculated as,
UV rays ® Lasik eye surgery
1 1 1 1 1 1 200
Infra-red ® Physiotherapy = + Þ = + ÞF=- cm
X-rays ® Treatment of cancer F f1 f 2 F ( + 40) ( - 25) 3
5. (2) As no external force is acting on system so, Pi = Pf 100 100
\ P= = Þ -1.5 D
0.2 ´ 10 = 10 ´ v Þ v = 0.2 m/sec F -200 3
1 2 1 2 12. (3) The two springs are in parallel, so the effective spring
Loss in K.E. = ´ (0.2) ´10 - ´10(0.2) constant is
2 2
1 keq = k1 + k2 = k + k = 2k
= ´ 10 ´ (0.2) [10 - 0.2] = 9.8 J
2 The period of oscillation, k
6. (1) Root mean square speed is given by m m
T = 2p = 2p k M
3kT 1 keq 2k
vrms = Þ vrms µ
M M Frequency of oscillation,
( vrms )O2 M H2 (vrms )O2 2 1 1 1 2k
\ = Þ = = f = =
(vrms )H 2 M O2 (vrms )H 2 32 4 T 2p m
13. (3) The energy stored by a capacitor
Þ (vrms )H = 4 ´ (vrms )O
2 2
(Q (v )
rms O2 = 160 m / s ) 1
U = CV 2 ...(i)
= 4 × 160 = 640 m/s 2

SPECTRA ACADEMY | 1
 V is the p.d. between two plates of the capacitor 21. (3) As per the law of conservation of linear momentum,
potential difference V = E.d. the two balls originally at rest along with one from those
already in motion will move with velocity v. Two of the
The capacitance of the parallel plate capacitor three balls originally moving will naturally come to rest.
Ae 0 22. (4) Taking the rope and the block as a system
C=
d we get P = (m + M) a a
Substituting the value of C in equation (i) P M m
\ a= T P
1 Ae 0 1 m+M
U= ( Ed )2 = Ae 0 E 2 d Taking the block as a system,
2 d 2
dx d (12t ) MP
14. (3) vx = = = 12 we get T = Ma \ T=
dt dt m+M
dy d (5t - 8t 2) 23. (1) 12 V, 60W
and vy = = = 5 – 16 t.
dt dt 220V

\ vt=0 = v x2 + v 2y 2
= 12 + 5 = 13 m/s 2

r r As transfer to be ideal and for ideal transformer

15. (1) Clearly angle between B and A is O°
r r Pinput = Poutput
so, f (flux) = B. A = BA cos 0°
= BA = 0.5 × 12 = 0.5 weber \ (VI)in = 60 Þ 220 × I = 60
\ I = 0.27 A
r r r r r r r
24. (2) t = r ´ F Þ r . t = 0 F . t = 0
B r r r
Since, t is perpendicular to the plane of r and F , hence
A r r r
the dot product of t with r and F is zero.
B 25. (4) It has been known that a nucleus of mass number A
has radius
v2 R = R0A1/3,
16. (4) tan q = where R0 = 1.2 × 10–15m and A = mass number
rg
17. (3) For closed organ pipe, resonate frequency is odd mul- In case of 27 let nuclear radius be R1
13 Al,
tiple of fundamental frequency.
and for 125 nuclear radius be R2
\ (2n + 1) f0 £ 20,000 32Te,
(f0 is fundamental frequency = 1.5 kHz) 27 1/ 3
\n=6
For 13 Al , R1 = R0 (27) = 3R0
\ Total number of overtone that can be heared = 7 For 125
32Te, R2 = R0 (125)
1/ 3
= 5R0
18. (2) For long straight wire
R2 5R0 5 5
m0 i r = Þ R2 = R1 = ´ 3.6 = 6fm.
B= Þ B µ r, r < R R1 3R0 3 3
2pR 2 26. (2) Given : Mass m1 = 4 kg and m2 = 6 kg.
m I 1
B= 0 ÞBµ Acceleration of the system,
2 pr r
19. (1) Bohr ’s postulated that electrons in stationary ( m2 - m1 ) g
a=
orbits around the nucleus do not radiate. ( m1 + m2 ) where m2 > m1
This is the one of Bohr’s postulate-According to this the (6 - 4) g g
moving electrons radiates only when they go from one \a = =
6+4 5
orbit to the next lower orbit.
27. (2) Q = DU + W
20. (2) Given,
Amplitude of magnetic field in an electromagnetic wave, or Q = DU – DU = 0; It is an adiabatic process.
B = 6 × 10–7T 28. (2) Let V be the volume of the load and r its relative
Relation between magnetic field (B) and electric field (E) density
of an electromagnetic wave is given by F L V rg L
So, Y = = .....(1)
E Al a Al a
=c
B When the load is immersed in the liquid, then
Þ E = Bc
F ¢ L (V r g - V ´1´ g) L ....(2)
= 6 × 10–7 × 3 × 108 (Q c = 3 × 108 m/s) Y= =
Al w Alw
Þ E = 180 Vm–1 (Q Now net weight = weight – upthrust)

SPECTRA ACADEMY | 2
 From eqs. (1) and (2), we get 37. (1) The terminal potential difference of a cell is given by
r (r - 1) la V + Ir = E
= or r =
la lw (l a - l w ) V = VA – VB
29. (3) or V = E – Ir
Type of gases No. of degrees of freedom
Monoatomic gas 3T dV
Þ = – r, Also for, i = 0 then V = E
Diatomic + rigid 3T + 2R dI

Diatomic + non-rigid 3T + 2R + 1V
\ slope = – r, intercept = E
h
Polyatomic 3T + 3R + More than 1V 38. (4) De Broglie wavelength is l =
mv
T = Translational degree of freedom lp = le Þ h = h
R = Rotational degree of freedom m p vp m e ve
pp 1
V = Vibrational degree of freedom meve = mpvp Þ pe = pv \ =
30. (2) We know that pe 1
V 39. (1) According to prism formula,
Vrms = 0 Þ V0 = 2 Vrms æ A + dm ö
2 sin ç ÷
31. (1) As liquid drop is in equilibrium. m= è 2 ø
Fb + F T
So Fnet = 0 æAö
sin ç ÷
Boyant force + surface tension = mg è2ø
Here, dm = angle of minimum deviation
V
s g + 2pRT = rVg A = angle of prism
2 We have given, d m = A
mg
(2r - s) 4 3 é 4 3ù sin A A -1 æ m ö
Þ 2 pRT = pR g êQ V = pR ú \ m= Þ m = 2 cos Þ A = 2cos ç ÷
2 3 ë 3 û sin A / 2 2 è2ø
3T 3 ´ 7.5 ´10-4 N - m-1 40. (1)
Þ R2 = ÞR= rest
(2r - s) g (2r - s) ´ 10 II
I u III
3 15 u
ÞR= m= cm 24 cm 3
20 (2r - s) 2r - s
1
32. (4) As R µ \ R1 : R2 = 2 : 1
Power
length of segment (x) Using third equation of motion between I and II
33. (3) No. of fringes(n) = v2 – u2 = 2as
fringe width (b)
2
x æuö 2
Þn= Þ ç ÷ = u – 2a ´ 24
b è ø
3
Þ x = nb = cons. 8u 2
Þ 2a (24) = ... (i)
Þ n1b1 = n2b2 9
Using third equation of motion again between II and III
lD l D
Þ n1 1 = n 2 2 2
d d æuö
0 = ç ÷ – 2as
Þ n1l1 = n2l2 Þ 8 × 600 = 400 × n 2 è3ø
Þ n2 = 12 2
u
Þ = 2as ... (ii)
9
34. (4) Frictional force = pseudo force From equation (i) and (ii)
or mmg = ma 2a24 = 8(2as)
dv Þ s = 3 cm
= m = m × 2bt Length of wooden block = 24 + 3 = 27 cm
dt
mg 41. (2) Using, v2 – u2 2as
\ t= .
2b Þ v22 - v12 = 2 gh Þ v2 = v12 + 2 gh
DV 1 Equation of continuity
35. (2) Reverse resistance = = = 2 ´ 106 W
D I 0.5 ´10-6 A1v1 = A2v2
æ 15 ö
dI (0 - 2) 2
Þ (1 cm2) (1 m/s) = (A2) ç (1) + 2 ´ 10 ´ ÷
36. (4) Induced emf, e = -L Þ 20 = -L -3
è 100 ø
dt 10
Hence, inductance of the coil. 10-4
Þ 10–4 × 1 = A2 × 2 Þ A2 = = 5 × 10–5 m2
L = 10 mH 2

SPECTRA ACADEMY | 3
42. (3) Boolean expression for combination of logic gates Wsurface Mg
49. (2) Wh = Þ Mg' =
Output, y = A. B + B. C 3 3
Input Signals Output Signal (y) g g
Þ 2
=
æ hö 3
Time duration A B C AB B.C y = A. B + B.C çè1 + ø÷
R
0 – t1 0 0 1 0 1 1
t1 – t2 1 0 1 0 1 1 æ hö
Þ ç1 + ÷ = 3
è Rø
t2 – t3 0 1 0 0 1 1
t3 – t4 1 1 0 1 1 1 h
Þ = 3 -1
t4 – t5 0 0 1 0 1 1 R
t5 – t6 1 0 1 0 1 1 Þ h = ( 3 - 1) R
t6 – t7 0 0 1 0 1 1 Þ h = 0.732 × 6400 ; 4685 km
50. (4) Let L is the original length of the rubber cord and K is
Output y is high (1) so output at the terminal y, V0 = 5V
the force constant of rubber cord.
43. (1) vP < v
Final length = initial length + elongation
or wA < f l
fl l F
or A < or L' = L +
w 2p K
44. (3) For tension 4N
45. (1) Given : Length of the dipole (2l) = 10cm = 0.1m or l =
0.05 m 4
Charge on the dipole (q) = 500 mC = 500 × 10–6 C and l1 = L + ..... (i)
K
distance of the point on the axis from the mid-point of the
dipole (r) = 20 + 5 = 25 cm = 0.25 m. For tension 6N
We know that the electric field intensity due to dipole on 6
the given point (E) l2 = L + ..... (ii)
K
1 2(q.2l )r = 9 ´ 109 ´ 2(500 ´ 10-6 ´ 0.1) ´ 0.25
= ´ Solving (i) and (ii) we get
4 pe 0 (r 2 - l 2 ) 2 [(0.25) 2 - (0.05) 2 ]2
7 2
= 6.25 ´ 10 N/C L = 3l1 – 2l2 and K =
l 2 - l1
46. (3) Fv = mg – Fb
= rVg – rl Vg = Vg (r – rl) when tension is 9N, then
Fv1 V1 æ r ö3 1 9
length = L + = 2.5l 2 - 1.5l1
V2 çè 2r ÷ø
So, = = =
Fv2 8 K

47. (1) PART - II : CHEMISTRY

51. (3)
OH O
|| O
¾¾¾
®
PCC ; OH ¾¾¾
PCC
®
Ketone
H
52. ˆˆ† Cr 3+ (aq.) + 3OH - (aq.)
(2) Cr(OH)3 (s) ‡ˆˆ
s 3s
(s) (3s)3 = Ksp
Let mass of scale be ‘m’. Then,
27 s 4 = K sp
About ‘P’ tˆ net = 0
1/ 4 1/ 4
Þ 2 × 10–2 g × 30 – mg × 10 = 0 æ K sp ö æ 1.6 ´ 10-30 ö
s=ç =ç ÷
Þ 6 × 10–1 – 10 m = 0 Þ 0.6 = 10 m è 27 ø÷ è 27 ø
0.6 53. (2) For a 4f- orbital, n = 4 and l = 3
Þ m= Þ m = 0.06 kg For a given value of l, there can be (2l + 1) values of ml
10
48. (3) ranging from –l to + l.

SPECTRA ACADEMY | 4
 Thus, ml = +1 is possible.
1 æ 1 1 ö 1 7´ R
= RZ 2 ç - ÷Þ =
1 1 l è3 2
42 ø l 36
ms can be + or -
2 2
1
54. (4) As we move down the group, due to poor shielding R=
effect of intervening d and f orbitals, the increased A
effective nuclear charge holds ns electrons tightly and 1
´7
therefore restricting their participation in bonding. This 1 A 1 7 36 A
= Þ = Þl=
effect is known as inert pair effect. l 36 l 36 A 7
So, the relative stability of +1 O.S increases for heavier
59. (1) Metalloids : B, Sb, As, Ge
elements.
Hence, TlI is more stable than TlI3. Metals = Mn, Cu, Ag, K, Na
55. (4) [Cr(NO) (NH3) (CN)4]2– Non-Metals = Si, F
Let O.S. of NO be +1, if x is the O.S. of Cr. 60. (4) Rate of reaction is quadrupled on doubling the
\ x + (+1) + (0) + 4(–1) = –2 Þ x = +1 concentration. Thus,
But Cr does not exist in +1 O.S. Now, let O.S. of NO be zero. r = R[A]2
\ x + (0) + (0) + 4(–1) = –2 Þ x = +2
61. (1) No. of bonding orbitals should be more than anti-
Cr2+ (d4) ¾® bonding orbitals.
Due to strong field ligands, pairing of e– will take place, i.e., 62. (4)
eg +
O
t2g O O–
No. of unpaired e–, n = 2 Formal charges on terminal oxygens = 0 and –1.
m = n(n + 2) = 2(2 + 2) = 8 » 2.82 BM 63. (1) In lactose, b Linkage is between C1 of galactose
and C4 of glucose.
56. (1) Total number of angular nodes = l, for a given orbital.
For n = 3, there will be three subshells having 3s, 3p and 64. (4) Mass No. of
Element Mole ratio
percentage mole
3d orbitals.
78 6.5
For 3s, l = 0, so zero angular nodes. C 78% = 6.5 =1
12 6.5
For 3p, l = 1, so one angular nodes. 22
22 = 3.38 ; 3
For 3d, l = 2, so two angular nodes. H 22% = 22 6.5
1
Þ Total angular nodes = 0 + 1 + 2 = 3
\ Possible empirical formula is CH3.
57. (2) Sucrose ¾¾¾¾®
Hydrolysis a-D-Glucose
65. (1) (A) - (iii), (B) - (iv), (C) - (i), (D) - (ii)
+ b-D-Fructose 66. (4) Given : nbenzene : noctane = 3 : 2
CH2OH 3 2
So, c benzene = 5 , c octane = 5
O O
H H HOH2C OH
H p s = pobenzene c benzene + pooctane c octane
OH H H HO
HO O
CH2OH 3 2
= 280 ´ + 420 ´ = 168 + 168 = 336 mm of Hg
H OH OH H 5 5
67. (1) BOH ƒ B+ + OH–
a-D-Glucose b-D-Fructose
é B+ ù éOH - ù
Kb = ë û ë û = 1´10-6
58. (4) For Lyman series (shortest wavelength),
n1 = 1, n2 = ¥ [BOH ]
1 æ 1 1 ö
=RZ 2 çç 2 – 2 ÷÷ pH = 10 Þ pOH = 14 – 10 = 4
λ è n1 n2 ø Þ [OH–] = 10–4 M.
1 2 æ1 1 ö 1
Þ =1 Rç - ÷ Þ = R é -ù 2
A è1 ¥ ø A Ca 2 ëOH û a
Now, K b = =
For Paschen series, 1- a 1- a
Longest wavelength = 1st line
n1 = 3, n2 = 4

SPECTRA ACADEMY | 5
 Cu
Kb a2 10-6 R2–OH–OH ¾¾¾® R – C – R + H2
Þ = @ a2 = = 10-2 300°C
éOH - ù 1- a 10-4 2° Alcohol O
ë û Ketone
Þ a = 10–1 or 0.1 or 10% CH3
68. (1) The enthalpy of formation of a substance is the | Cu
R – C – OH ¾¾¾®
300°C
R - C = CH 2 + H2O
amount of energy required to prepare it from its onstituents | |
in their most stable states. CH3 CH 3
Since graphite is the most stable allotrope of carbon, its 3° Alcohol Alkene
enthalpy of formation is zero.
Cu
Thus, both Assertion and Reason are correct statements C 6 H 5 – OH ¾¾¾® No reaction
300°C
and Reason explains Assertion. 78. (1) 1-butene is an unsymmetrical alkene and will follow
69. (1) In acidic medium the reaction for KMnO4 with oxalic Markovnikov's rule to give major product.
acid is CH3 - CH 2 - CH = CH 2 + H - Br ¾¾ ®
I-Butene
MnO4- + 8H + + 5e - ¾¾
® Mn 2 + + 4H 2 O Å
+7 +2 + H – Br ¾® + Å
Change in oxidation state is = 7 – 2 = 5. H
70. (4) In case, nitrogen and sulphur both are present in minor more stable (2°)
organic compound, sodium thiocyanate is formed. It gives product(s) trigonal planar
carbocation
blood red colour and no Prussian blue since there are no

¾¾
free cyanide ions. H H Br Å
+ ¬¾¾
Na + C + N + S ¾® NaSCN
Fe3+ + SCN– ¾® [Fe(SCN)]2+ Br
Br
Blood red
Racemic mixtures
71. (3) –NO2 and –Cl are written as prefixes with – CH3 being (major products)
given the highest preference for numbering (C – 1). NaNO2 + H2O
79. (2) R—NH2 R–N 2 R–OH
HCl
Thus, the name of the compound will be 2-chloro-1-methyl-
80. (1) A-(iv), B-(iii), C-(i), D-(ii)
4-nitrobenzene.
n2
72. (2) RCONH2 + Br2 + 4NaOH ¾¾ ® 81. (4) DTf = m × Kf = m ´ K f
R–NH2 + K2CO3 + 2NaBr + 2H2O 1

73. (3) Oxidation state of Cr in CrO 24- and Cr2 O27- is + 6 i.e. n2 n2
We have, x 2 = n + n » n = 0.01
oxidation states are same. 1 2 1
74. (1) Both statements are true.
Taking 1L of water, mass of water = 1 kg = 1000 g
acetone
75. (2) R-X + NaI ¾¾¾¾
® R -I + NaX ¯
1000 g
Soluble in Þ n (H2O) = n1 = = 55.55 mol
(CH 3OH, Me 2CO) 18 g mol -1

R-X + NaI ¾¾¾¾

® R -I + NaX ¯ Þ n2 = 55.55 × 0.01 = 0.556 mol
Insoluble in n2 0.556 mol
(CH 3OH, Me 2CO) Þ DTf = ´ Kf = ´1.86
m1 1 kg
(where X = Cl or Br)
76. (4) For the reaction = 1.034 K H » 1.043 K.
3A + 2B ¾¾ ® C+D 82. (1) The oxidation number of iron in mohr ’s salt is +2.
From the rate law, Mohr’s salt - FeSO4. (NH4)2 SO4. 6H2O.
83. (1) Both statements are correct.
1 d [A ] d [C ]
= k [A ] [B ]
n m
=- = 84. (2) Enantiomers are non-superimposable mirror images
3 dt dt of each other.
77. (1) When primary (1°) alcohols are treated with copper at In an SN1 reaction, inversion occurs more than
300°C, then aldehydes are obtained by dehydrogenation of retention. Therefore, the ratio of enantiomers is not
alcohols. Similarly secondary (2°) alcohols form ketone and strictly 1 : 1.
alkene is obtained by dehydration of tertiary (3°) - alcohols.
85. (1) The mass and volume depend upon the quantity of
But phenol does not respond to this test.
matter so these are extensive properties while ratio of mass
Cu
R - CH 2 - CH2 - OH ¾¾® R - CH 2 - CHO + H 2 to its volume does not depend upon the quantity of matter
1° Alcohol 300°C Aldehyde so this ratio is an intensive property.

SPECTRA ACADEMY | 6
86. (4) Essential amino acids cannot be synthesized in our 3+ 0 4+
2+
body so we need to take them in our diet. HAsO2 + Sn ¾¾ ® As + Sn + H 2 O
Amino acids are soluble in water but generally insoluble Hence, HAsO2 is acting as oxidising agent.
in organic solvents. 95. (1) Magnetic moment depends upon the no. of unpaired
Due to crystalline nature, they are high melting solids electrons.
because of dipole-dipole interactions. No. of unpaired electrons
They exist as dipolar zwitter ions in aqueous solutions.
H [Cr(CN)6]3– Cr3+ = t 23g e0g = 3
+ | (In strong
H3 N - C - COO- ligand field)
| [Mn(CN)6]3– Mn 3+ = t 24g e0g = 2
R
(In strong
87. (2) Osmotic pressure ( π) = iCRT where C is molar ligand field)
concentration of the solution. [Fe(CN)6]3– Fe3+ = t25g e0g = 1
(In strong
i ´ m ´ 1000 ´ RT
\ p= ligand field)
M´V [Co(CN)6]3– Co3+ = t 26g e0g = Zero
Order of molar mass of solute decreases as Sucrose (In strong
(342) > Glucose (180) > Urea (60) ligand field)
So, correct order of osmotic pressure of solution is 96. (2) L¥HCl = 426.2 ... (i)
P3 < P1 < P2 ¥
L AcONa = 91.0 ... (ii)
88. (2)
(1) Diamond and graphite both are covalent. L¥NaCl = 126.5 ... (iii)
(3) Only graphite can be used as dry Lubricant.
L¥
AcOH = (i) + (ii) - (iii) = [426.2 + 91.0 - 126.5] = 390.7
(4) Both diamond and graphite have 3-Dimensional
structure. 97. (1) ˆˆ† Ca 2 + + 2OH -
Ca(OH) 2 ‡ˆˆ
89. (3) Due to absence of unpaired electrons, Zn has the
lowest enthalpy of atomization. pH = 9, pOH = 14 – 9 = 5
90. (3) I and II structure shown above constitute the [OH–] = 10–5
cannonical structure. III structure represents the structure
of O3 more accurately. This is also called resonance hybrid. 10-5
[Ca 2+ ] =
91. (1) C > B > A 2
92. (3) KMnO4 on heating dissociates as
æ 10-5 ö -5 2
+7 +6 Ksp = [Ca2+] [OH–]2 = ç ÷ ´ (10 ) = 0.5 × 10–15
D ç 2 ÷
2KMnO 4 ¾¾® K 2 MnO4 + MnO2 + O2 è ø
Permanganate Manganate
98. (2) In disproportionation reaction, a compound convert
to the two compounds, one of higher and one of lower
oxidation state.
0 -2 +2 -1 +1- 2
F2 + 2OH - ® OF2 + 2F- + H 2O
Mn+7 Þ 3d04s0 (Diamagnetic)
In both the compounds, F– and OF2, oxidation state of F
Mn+6 Þ 3d14s0 (Paramagnetic)
Both permanganate and manganate are tetrahedral but is –1. Hence, fluorine does not disproportionate. Also
oxygen has –2 oxidation state, but in product its oxidation
only manganate is paramagnetic.
state becomes + 2 in OF2 but – 2 in H2O.
NH2 + 99. (1) For first order reaction
N º NCl– OH
1 æ P0 ö æ P0 ö
93. (3) ¾¾¾¾
NaNO
2®
¾¾
® k= ln ç ÷ Þ In ç ÷ = kt Þ ln æç P ÷ö = –kt
HCl + t çè P ÷ø ç P ÷ è P0 ø
è ø
On comparing with straight line equation y = mx
k = slope = 3.465 × 104
—N = N— — OH. ln 2 0.693
t1/2 = = = 2 × 10–5 s
94. (4) Oxidising agent itself undergoes reduction during a k 3.465 ´ 104
redox reaction.

SPECTRA ACADEMY | 7
100. (1) Due to inert pair effect, the stability of +1 state in
group 13 elements increases down the group.
Opposite trend is observed for +3 state stability.
PART - III : BOTANY
101. (4) Pollen grains can be stored for several years in liquid
nitrogen at -196°C (cryopreservation). Cryopreservation
is the process of cooling and storing cells, tissues, or
organs at very low temperatures; most common -196°C/-
321°F in liquid nitrogen (N2) to maintain their viability.
102. (2) Phosphorus cycle is an example of sedimentary cycle.
Pyramid of biomass of aquatic ecosystem is inverted. If
decomposition leads to the formation of colloidal organic
matter (humus), the process is called humification. Simple
food chains are very rare in nature. This is because each
organism may obtain food from more than one trophic
level.
103. (4) Electron transport system is located in inner Phenotypic Round : Round : Wrinkled :
mitochondrial membrane, where it serves as the site of ratio Wrinked yellow green
oxidative phosphorylation through the action of ATP yellow green
synthase. 9 : 3 : 3 : 1
104. (3) 105. (2) 106. (1) 107. (1) 108. (2) Genotypic 1 : 2 : 2 : 4 : 1
ratio : 2 : 1 : 2 : 1
109. (1) In G2 phase, the number of chromosome will be same
Results of a dihybrid cross where the two parents differed
as at the end of mitosis i.e., 6. in two pairs of contrasting. Rest of the option does no
110. (2) Centriole is a cylindrical organelle that is involved in support the Mendel’s law of segregation.
the cell division and in the formation of flagella and cilia. 119. (3)
In animal cells, the duplication of centriole takes place 120. (1) The the characteristics specific to family Fabaceae
during the S-phase of the cell cycle. but not found in Solanaceae or Liliaceae is Diadelphous
and dithecous anther.
In the G2 phase of the cell cycle, many important organelles
121. (4) In photosynthesis, ATP synthesis is linked to
such as mitochondria, golgi bodies, chloroplast etc are development of proton gradient across a membrane. The
duplicated. only difference is th at in photosynth esis proton
Chromatin starts to condense in prophase and the accumulation is towards the lumen of thylaroids and is
alignation of the chromosomes occurs during metaphase. respiration, proton accumulate in the intermembrane space
111. (2) of the mitochondria.
122. (2) Golgi apparatus is involved in the formation of
112. (4) Both statements are correct. glycoproteins and glycolipids.
113. (2) The sclereids are spherical, oval or cylindrical, highly Lysosomes are membrane enclosed organelle. It contains
thickened dead cells with very narrow cavities (lumen). digestive enzymes, which digest excess or worn out
114. (1) Clostridium butylicum (a bacterium) is used for the organelles, food particles etc.
Vacuoles is a membrane enclosed fluid filled sac which
production of butyric acid. An bioactive molecule,
traps waste and excretory products.
cyclosporin A, that is used as an immunosuppressive agent Ribosomes is a minute particle consisting of RNA and
in organ-transplant patients, is produced by the fungus associated proteins. They bind mRNA and tRNA to
Trichoderma polysporum. Statins produced by the yeast synthesise polypeptides and proteins.
Monascus purpureus have been commercialized as blood- 123. (1)
cholesterol lowering agents. Aspergillus niger (a fungus) 124. (3) Methanogens are archaebacteria that live in marshy
is used for the commercial production of citric acid. area and produce methane as a metabolic byproduct in
anoxic conditions. So, methane is not their preferred carbon
115. (1)
source.
116. (2) Ligase enzyme is not the component. 125. (4) In photorespiration, O2 binds to RubisCo. As a result
117. (1) Ganga Action plan was initiated by ministry of RuBP instead to being converted to 2 molecules of PGA
Environment and forests. bind with O 2 to for m one molecule each of
118. (2) phosphoglycerate (3 carbon compound) and
phosphoglycolate (2 carbon compound).

SPECTRA ACADEMY | 8
126. (4) C4 plants are more efficient in photosynthesis than of zoological and bacteriological nomenclature. The
C3 plants due to photorespiration. Photorespiration is an foundations of ICBN was found in Philosophia Botanica,
inhibitory process that decreases the rate of a book written by C. Linnaeus.
photosynthesis. It is absent in C4 plants and present only 150. (4) Mendelian dihybrid cross
in C3 plants.
127. (1)
128. (3) The pigments that give class Rhodophyceae (red al-
gae) its distinctive red colour is chlorophyll-a, d. These
pigments are photosynthetic in nature and are located in
the chromatophores. The other pigments present are b-
carotene, xanthophylls, phycocyanin (blue in colour) and
biliprotein (r-phycoerythrin-red in colour).
129. (d)
Commensalism ® Sea anemone and clownfish
Mutualism ® Mycorrhizae and legume plants
Parasitism ® Cuscuta on hedge plants
Competition ® Balanus and Chathamalus
130. (1) 131. (1)
132. (3) Half of the total carbon dioxide fixation on earth is
carried out by algae. Laminaria and Sargassum are among
the 70 species of marine algae used as food. Chlorella a
unicellular alga rich in proteins is used as food supplement
even by space travellers.
133. (1)
134. (3) Stellar’s sea cow (from Russia) is a recently extinct
animal.
Parthenium (carrot grass) is an exotic weed, that grows
rapidly and adversly affects the native species.
African catfish is also an alien species. It adversly affects
the growth of indigenous Clarias batrachus - our local
species.
Lantana camara, another alien species, is also strongly
competing with native species. Results of a dihybrid cross where the two parents differed
135. (1) Autogamy occurs in bisexual flowers. in two pairs of contrasting traits : seed colour and seed
Geitonogamous flowers are unisexual but present in the shape
same plant. Dioecious condition is observed when Other combination do not show dihybrid cross ratio of
unisexual male and female flowers are present on different Mendelian inheritance.
plants and it prevents both autogamy and geitonogamy. PART - IV : ZOOLOGY
136. (4) 137. (2)
138. (1) Mendel did not use pod length for his experiment. 151. (1) Platyhelminthes are triploblastic.
139. (4) 140. (3) 152. (3) The spermatids are transformed into spermatozoa
141. (3) Cells of the tapetum possesses dense cytoplasm and (sperms) by the process called spermiogenesis. After
generally have more than one nucleus. spermiogenesis, sperm heads become embedded in the
142. (4) Both the statements are correct. Sertoli cells, and are finally released from the seminiferous
143. (4) XX-XO type of sex determination is found in tubules by the process called spermiation.
roundworms and some insects like tree bugs, grasshoppers 153. (4) Chelone (turtle) is an example of reptile. The heart of
etc. Here, the females have two sex chromosome XX, while reptiles are usually three-chambered except crocodiles.
the males have only one sex chromosome X. There is no 154. (1)
second sex chromosome. Females show homogamety and 155. (4) Transferases catalyze transfer of atom.
produce all X containing eggs while males show 156. (2) Cuboidal epithelium with brush border of microvilli
heterogamety and produce both X containing sperms and is found in proximal convoluted tubule of nephron (PCT).
sperms without sex chromosomes. 157. (4) The lipids in which only single bonds are present are
144. (2) The rate at which organic molecules are formed in a known as saturated fatty acids. Unsaturated fatty acids
green plant is called gross primary productivity. contain atleast one double bond between two carbon
145. (2) Homeostasis is the property of an open system, atoms in the molecule. Lecithin is an important
especially living organisms, to regulate its internal phospholipid that is present in the cell membrane. Palmitic
environment to maintain a stable, constant condition, by acid is a type of saturated fatty acid that contains 16
means of multiple dynamic equilibrium adjustments, carbon atoms in the molecule.
controlled by interrelated regulation mechanisms. 158. (1) Adrenal cortex secretes mineralocorticoids like
146. (3) 147. (3) aldosterone which increase the reabsorption of Na+ and
148. (4) GAG is replaced by GTG. water from renal tubule that prevent diuresis. Diuresis
149. (1) ICBN (International Code of Botanical Nomenclature) is a condition in which the kidneys filter too much body
is one of the code of nomenclature which is independent fluid.

SPECTRA ACADEMY | 9
159. (3) Interferons are released as cytokine barriers under establishment and maintenance of foetus and estrogen
non-specific immunity. promotes parturition by inducing labor and delivery.
160. (4) Foetal ejection reflex triggers release of oxytocin from 181. (1)
the maternal anterior pituitary gland. Oxytocin acts on the 182. (2) This filtration is about 125ml per minute.
uterine muscles and causes stronger uterine contractions. 183. (3)
Relaxin, secreted by the ovary and placenta, causes the 184. (1) Restriction enzymes, also called restriction
cervix to dilate and prepares the uterus for the action of endonucleases, cut double stranded DNA molecules by
oxytocin during labour. Oestrogen, secreted from ovary, cleaving phosphodiester bonds at palindromic sequences.
is responsible for the development and regulation of the This means that the majority of the restriction enzymes
female reproductive system an d secondary sex cut the DNA into a fragments that are characterized by a
characteristics. Prolactin, secreted from anterior pituitary, two fold rotational symmetry. As in the first option, both
stimulates breast development and milk production in the sequence are palindromic, so it will be the correct
women. answer.
161. (1) Multinucleated animal cells are known as syncytium. 185. (3) Cow Rosie was a transgenic animal and was first
162. (4) Gnerally all of the essential nutrients and 70% to 80% transgenic cow. This cow was able to produce human
of electrolytes and water are reabsorbed by this segment. protein enriched milk. This milk contains the human alpha-
Removal of proximal convolnted tubule from the nephron lactalbumin and was a complete product for human infants
will result in dilution of urine. than non-transgenic cow milk.
163. (2) Statement I is correct but statement II is incorrect . 186. (3) A canal called the cerebral aqueduct passess through
164. (4) In pBR322 the midbrain. At electrical synapses, the membranes of pre-
ori-represents site of origin of replication and post synaptic neurons are in very close proximity.
rop-represents those proteins that take part in replication 187. (1) Antibodies are found in the blood; the response is
of plasmid. also called as humoral immune response. The second type
Hind III, EcoRI- Recoginition sites of Restriction is called cell-mediated immune response or cell-mediated
endonucleases immunity (CMI). The T-lymphocytes mediate CMI.
ampR and tetR - They are antibiotic resistant gene part. 188. (4)
165. (4) Muscular dystrophy is a genetic disorder in which 189. (2) The proteins encoded by the genes cry I Ac and cry
there is continuous weakness and breakdown of skeletal II Ab control the cotton bollworms, that of cry I Ab controls
muscles. corn borer.
166. (4) 167. (1) 168. (2) 190. (3) The sliding filament theory states that contraction of
169. (3) Starch can hold iodine (I2) molecules in its helical a muscle fibre takes place by the sliding of the thin
secondary structure but cellulose being non helical, can filaments over the thick filaments. According to this theory,
not hold I2. Thus, cellulose does not shows blue colour during shortening of the muscle, i.e., contraction, the ‘I’
when treated with I2. bands get reduced, whereas the ‘A’ bands retain the length
170. (3) The single-stranded free ends that project from each that means length of A-band does not change.
fragment of DNA duplex are unpaired bases and are known 191. (4) Somatostatin from the hypothalamus inhibits the
as “sticky ends”. Sticky ends can join with similar release of growth hormone from the pituitary.
complementary ends of DNA fragment can be joined 192. (3)
together using DNA ligases. 193. (3) The part starting with the external nostrils up to the
171. (4) Polymerase chain reaction is a technique used to terminal bronchioles constitute the conducting part
replicate a fragment of DNA so as to produce many copies whereas the alveoli and their ducts form the respiratory or
of a particular DNA sequence. A single PCR amplification exchange part of the respiratory system. The conducting
cycle involves three basic steps: denaturation, annealing part transports the atmospheric air to the alveoli, clears it
and extension (polymerisation). from foreign particles, humidifies and also brings the air
172. (4) Diaphragm is present below lung and separates to body temperature. Exchange part is the site of actual
thoracic cavity from abdominal cavity. Its up and down diffusion of O2 and CO2 between blood and atmospheric
movement helps in expiration and inspiration during air.
breathing. 194. (3) 195. (4) 196. (2)
173. (2) Assertion is correct but reason is not correct. 197. (1) Frequency of dominant allele (p) = 60% = 0.6
174. (4) Myelinated nerve fibres are found in spinal and The frequency of recessive allele, according to
cranial nerves. Retina has bipolar neurons with one axon (p + q) = 1, will be 0.4
and one dendrite. Electrical synapses are rarely present in The value of pq = 0.6 × 0.4 = 0.24
human. In a resting neuron, the axonal membrane is high The frequency of heterozygous individuals, therefore, will
permeable to K+ ions as compare to Na+ ions. As a result, be 2pq = 2 × 0.24 = 0.48 or 48%.
it contains low concentration of Na+. 198. (4) Infertility problems cannot be generalised. It is a false
175. (2) 176. (3) 177. (4) statement to say that in India the infertility problems lie in
178. (1) LNG - 20 and progestasert are the hormone producing females more often.
intra uterine Devices (IUDs). 199. (2) Fully developed foetus and the placenta induce foetal
179. (4) Cytokine barrier is interferon. Virus infected cells ejection reflex. Foetal ejection reflex is also called mild
secrete proteins called interferons which protect non- uterine contraction.
infected cells from further viral infection. 200. (2) Before placing DNA into the electrophoretic chamber
180. (1) The level of progestrone and estrogen is essential it must be cut by restriction endonuclease.
during pregnancy. Progesterone is essential for the

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