SECTION-A (CHEMISTRY)

S l. Which of the following compounds is wrongly named?

(I) CHrCH2-CH2-COOCHi(:H1 ethyl bumoate

CH,,...CH--CH,CHO
(2) ·• I 3-Mcthyl butanal
CH3
CH,,...CH--CH-CH,
(3) , I I • 2-Mcthyl-3-butanol
OH CH3
0
(4) CHnH~-<;H5 2-Mcthyl-3-pentanone
I
CH.,
S2. Total number of stercoisomc111 of given compound?
CH 2=CH.CHCI.CHBr.CH=CHCH1

(I) 4 (2) 5 (3) 6 (4) 8

S3. The R/S configuration of these compounds are

respectively :

o><H H,.,~NHz
HS"-./\_
Pb Cf:i COOH
II
(I) R. R (2) R, S

(3) s. S (4) None of these

S4. Most stable carbocation among the following is -

Ell Ell
( I)
0 (2)
0
ss.
(3)
0- (4)
a
Increasing order of stability of following
resonationg structure.

l J_ II
Ell lIll

( I) 1>11>111 (2) 1>111>11

(3) 11>111>1 (4) 111>11>1
 AU.IN®
What are the major products from the following
reaction?

® 0- C H © .! >?
CJ~ Oll
(I) @ rl + @r

(2> @r OH + @r CH ,I

(3) ~
~O CH .O H
&I
+~•

(4)
~O CH ,1
~ + &
~O H

ely
'· Lucas reagent produces cloudiness immediat
with:-

( I) 1-propanol (2) 2-butanol

(3) 2-methyl-2-propanol (4) 2-methyl-1-propanol

!I. A-r icm :- Benzene sulphonic acid on heating

with NaOH gives sodium phenoxide.
R . - :- -~i is a poor leaving group.

(I) Both Assertion and Reason arc correct

(2) Assertion is incorrect but reason is correct

(3) Assertion is correct but reason is incorrect

(4) Both Assertion and Reason arc incorrect

59. Suppose following reaction :

~
1
NC>i
+

NQi
~nitrophcnol p-nitrophenol

p-nitrophenol is less volatile than o-nitrophenol

it is due to presence what kind of bond between
molecule ofp-niuophenol:

(I) Intramolccular H-bonding

(2) Intermolecular H-bonding
(3) Higher molecular mass than o-nitrophenol
(4) p-nitrophcnol is major product ofreaction

IOOICM0303029230166
3 , _ •....,.,
60. Which one is correct statement :

(I) CHrCl > CHrCH2 -CI [Rate ofSN2)

(2)
1.
l_) > (8J
~,-Cl
1
[Rate of SN )

x,-CI CH,-CI

(3) ~ >@ 1
[Rate ofSN ]

NO,

(') ~ > ~,-Cl[R"eofSN'J

CH, NO,

61. Acetaldehyde on reaction with scmicarbazide

gives:-

0
(I) CH,, II
/C = N - C - NH - NH,
H
0
CH,, II
(2) ,,,c=N-C-NH,
H
0
CH,, II
<3) /C = N - NH - C - NH,
H
CH,,
(4) /C = N - NH,
H

62. Which of the following reagents cannot

distinguish between glucose and fructose ?

(I) Tollens' reagent

(2) Fehling's solution

(3) Benedict' solution

(4) Allofthese

63. Which of the following pair have same hybridisation?

(t) c10; & c10; (2) SF4 & CCl4

(3) BF3 & NF3 (4) CO2 & S02

I. London forces are present in -

(I) Polar - polar molecule

(2) Nonpolar - non polar molecule

(3) Polar - nonpolar molecule

(4) Ionic compound

5. Which of the following propeny increases

regularly from carbon to fluorine?

(I) I.P.

(2) E.A.

(3) Shielding constant

(4) All of these

~- Aam1im : Be & Al show's diagonal relationship

due to similar outer most electronic configuration.
1-,o : They have similar value of ionic potential.

(I) Both Assertion and Reason arc correct and

Reason is correct for the Assertion.

(2) Both Assertion and Reason are correct but

Reason is not correct for Assertion.
(3) Assertion is correct but Reason is incorrect.

(4) Assertion is incorrect but Reason is correct.

67. Which of the following cation have pseudo inert

gas configuration ?
2
(I) Sn+◄ (2) Sn•

(3) Ga• (4) Ge•2

68. IUPAC name of a oomplex [Co(l -l~OI Pl/lli i>Ji

(SO.l)is:
(I) Tris (ethane-I, 2-<liamine) cobalt (Ill) sulphate
(2) Tri (ethane-I, 2-diamine)cobaltate(III) sulphate
(3) Tris (ethane-I, 2-<liamine) cobalt (JI) sulphate
(4) Tris (ethane-I, 2-diamine)cobalt (II) disulphate
th
69. Amongs hydrides of 15 group element, which
has least MP & BP.
(I) NH 3 (2) PH3 (3) AsH3 (4) SbH3

1001(M0303029230166
8 , _ •.....,,,
70. Which of the following statements is/are correct.
(i) In 3d-series, all metals form ionic oxides
"MO" except Sc.
(ii) Basic strength order of oxides of vanadium
are V2O 3 > V2O4 > VzO5.
(iii) CrO is basic while Cr2O3 is acidic in nature.
(iv) Mn (VI) shows disproportionation lo Mn
(VII) & Mn (IV) in acidic medium.

(I) (i) only (2) (ii), (iii)

(3) (i). (ii) (4) (i), (ii), (iv)

71. Aam1ioa: Geometrical isomerism is not possible in

tetrahedral complex having two different unidentate
ligands coordinated with central metal ion.
R-.i : Tetrahedral complexes do not show
geometrical isomerism because the relative position
of unidentale ligands attach lo central metal atom
are same w.r.t. each other.

(I) Both Aam1ioa and R-.i are true and

R-.i is the correct explanation ofAam1ioa.
(2) 80lh Aaa1imland ReaJD are true but ReaJD
is NOT the correct explanation of Aaaticin.

(3) A..tioa is t r u e , ~ is false.

(4) A..tioa is false,~ is true.

72. Hypo solution reacts with AgBr to form which

complex ion ?

(I) [Ag(S2O3)z)3- (2) (AgSzOi)- 1

(3) (Ag2(S2Oih)
4
- (4) [Ag2S2Oi)2-

73. Dimethylglyoxime is used for the test of _ __

in alkaline medium.

(I) Co•2 (2) zn•2 (3) Mn• 2 (4) Ni' 2

74. Rate of formation of S03 in the following reaction

2SO2 + 0 2 -+ 2SO3 is 40 g min_,_ Hence rate of
disappearance ofO2 is :

(I) 32 g min- 1 (2) 8 g min- 1

(3) 20gmin- 1 (4) 16 g min- 1

75. The rate ofa first order reaction is 3 x 10-• mol L-I
s- 1 at 25 minutes and 2 x JO~ mol L- 1 s-• at 75
minutes after initiation. Find the half life of the
reaction. [log3 • 0.48, log2 = 0.3)

250 200
(I) min (2) min
3 3
(3) 60 min (4) 90 min

76. Two liquids A and B on mixing form an ideal

solution. At 300 K. the vapour pressure of solution
containing I mole of A and 3 mole of B is 550 mm
of Hg. At the same temperature, if I more mole of
B is funher added to this solution, the vapour
pressure of the solution increases by IO mm of Hg.
The vapour pressure of A and B in their pure state
(in mm of Hg) is respectively:

(I) 400,600 (2) 500,500

(3) 600,400 (4) 400,400

77. The values of conductivity of material A, B and C

at 298.15 Kin Sm-• arc 2.1 x 103, 1.0 x 10-IS and
I x 10-1. Choose the correct answer from the
options given below :
(I) A is conductor, Band C arc insulator
(2) A is conductor, B is insulator and C is
semiconductor
(3) A is insulator, B is conductor and C is
semiconductor
(4) A is semiconductor, Band Care insulator
78. The standard electrode potential (E0 ) values of Na•
3 2
I Na, Al • I Al, Cu • I Cu and Ag• I Ag arc -2.71 V,
-1.66 V, 0.34 V and 0.80 V respectively. The
COITect decreasing order of reducing power of the
metal is:

(I) Ag>Cu>Al>Na(2) Al>Na>Ag>Cu

(3) Cu> Ag> Na> Al (4) Na> Al> Cu> Ag

79. In the discovery of canal rays, the smallest and

lightest positive ion was obtained from -

(I) Helium (2) Hydrogen

(3) Chlorine (4) Oxygen

0 , ............. ,
80. Consider the following graph for the reaction
H2(g) + ll(g) ~ 2Hl(g)

C
.2
e
i:
HI
""C
8

time ➔ ~time
At point A. B and C relation between equilibrium
constant {K) and reaction quotient {Q) respectively is -

(I) K<Q;K>Q;K=Q (2) K=Q;K<Q;K>Q

(3) K<Q;K=Q;K>Q (4) K>Q;K=Q;K<Q

81. A reaction A + B - q -+ C + D occurs in a

system and entropy of system increases. The
reaction will be :

(I) Possible only at high temperature

(2) Possible only at low temperature
(3) Not possible at any temperature
(4) Possible at any temperature
82. Calculate standard enthalpy of formation of
Fe2O 3(,)·
Given : 8H;(H 2, g) = -285 kJ/mol
Fe2O 3(,J + 3H 2(gl -+ 2Fe(,J + 3H 2O< ( J
8H° = -33 kJ/mol

(I) -712kJ/mol (2) -553 kJ/mol

(3) -822 kJ/mol (4) +712 kJ/mol

83. ANstioa (A) : For substance such as sodium

chloride the term formula mass is used instead of
molecular mass.
Rc8lan. (R.) : In the solid state sodium chloride does
not exist as a single entity (discrete molecule).

(I) Both (A) and (R) are correct and (R) is

correct explanation of {A).

(2) Both (A) and (R) are correct but (R) is not
correct explanation of {A).

(3) {A) is correct but (R) is not correct.

(4) {A) is not correct but (R) is correct.

l AU.aN®
84. Which reaction move in forward direction when
following changes are perfonned at equilibriwn ?
Match colwnn-1 with colwnn-11.
Cdamnl Cdamnll
Volwne redJced
(P) (A) PC¼i:l ~ PCl3(g) + Cll(gl
to half
On addition ofHe
rn4(g1+ HiO<sl ~ co(g1
(Q) at (B)
+3H2(g)
ronslant pressure
On addition of
(R) (C) H2(g) + Cl2(g) ~ 2HC'u;1
Cl2
On removal of
(S) (D) N2(gJ + 3H2(g) ~ 2NHJ(g)
H2

(I) P-+D;Q-+A,B;R-+C;S-+B
(2) P -+ C ; Q -+ B ; R -+ A, B ; S -+ D
(3) P-+ D ; Q-+ C ; R-+ A ; S -+ A, B
(4) P-+ A, B; Q-+ C; R-+ D; S-+ A

85. For one mole of an ideal gas, incorrect option is -

(I) Cp-C,=R (2) ~H-~U=R~T

(3) 1-....9!..=R (4 ) C, = y
~T ~T Cp

SECI10N-B (CHEMISTRY)
86. Match the colwnn :
Cdamn-1 Cdamn-D
~drnalcc- by ioouctivc
(A) effect tu docs oot drnalc I (p) --OH
withdraw by rcsonancc

Group withdraws C
-
by inducth~ d1cct bti docs
(B)
no1 donalc / withdraw by
(q) -NOi
n:sonancc

~ withdraws C

(C) by inductive effect & drnalc (r) -CH2-CH3

- by resonance
C

Group wo!Khws C
- by
+
(D) irxtuctivc effect & wmdraw (s)
-NH 3
-
C by resonance.

(I) (A)-+ r; (8) -+ s; (C)-+ p; (D)-+ q

(2) (A)-+ s; (B)-+ r; (C)-+ p; (D)-+ q
(3) (A) -+ p; (B)-+ q ; (C) -+ s ; (D) -+ r
(4) (A) -+ p; (B)-+ q ; (C) -+ r; (D)-+ s

1001CMD303029230166
 I Hindi • Enallh I

87. Ph
)c= CH, Cl,+H,O • Major product is :-
CH,
Ph OH Ph Cl
(I) )< (2) )<
CH, CH,CI CH, CH,-OH
Ph CH,--CI
(3) )< (4)
CH, Cl

c:
88.
HBr A (Major)

~ R,O,
B(Major)

AaudB are

(I) Chain isomer

(2) Enantiomer

(3) Position isomer

(4) Functional group isomer

89. @rNH, NaNO/HCI A Ph-N(CHJ, B

o·-s·c
What is "B"?

CH~H, CHiH,

(I) (2)

OH

CHi• CH~H,
(3) (4)

N=N-@

NH,
90. 0.3780 g ofan organic chloro compound gave 0.5740 g
of silva- chloride in carius estimation. Calculate the %
ofchlorine present in the compound.

(I) 37.57% (2) 43.12%

(3) 57% (4) 85%

91. Select the pair in which both the species have see
saw shape -

(I) XeO2F2, SiF4 (2) Xe02F2, IO2F2-

(3) TeCLt, tel; (4) Br03F, XeOF2

92. Correct order of bond angle is -

(I) so;2 > SO2 > SO3

(2) so) > so;2> so2
(3) SOJ > SO2 > so;2
(4) so2 >so)> so;2
93. Arrange the following species in increasing
order of ionic radius.
N- 3, 0-2, F-, Na•, Mg+2 & Al+3

(I) N-J > 0-2 > F- <Na+< Mg+2 < Al+J

(2) N- 3 = 0-2 = F- =Na+= Mg+2 = Al+J

(3) Al+J < Mg+2 <Na+< F- < 0-2 < N- 3

(4) 0-2 < F- <Na+< Mg+2 < Al+J < N-J

94. Which elements in 3d-series shows highest &

lowest enthalpy of atomization respectively.

(I) V, Zn (2) Cr, Zn

(3) Cr, Mn (4) Mn, Sc

95. When iodine is dissolved in aqueous potassium

iodide, KJ3 is formed. The shape of anionic part is :

(I) Linear (2) Angular

(3) Triangular (4) See-Saw

96. A 0.18% w/v aqueous solution ofa weak monopro1ic

acid (molar mass = 180 g mol- 1) at 300 K has
obsetved osmo1ic pressure of 0.369 atm. What will
be its van't Hoff factor (i).

(I) 1.2 (2) 1.5 (3) I (4) 0.5

1001 CM0303029230166
4 , _ •..,...,

97. Aa«lion : Negatively charged A52S3 colloidal

sol is obtained by double decomposition method

using As203 and H2S.

As20 3 + 3H2S-+ As 2S3 + 3H20

I t . - : Adsorption of AsJ+ ions take place on

As2S3 when As20 3 solution is saturated with H2S.

( I) Both Aamtion and Rt:aan are bUe and

Rt:aan is the correct explanation ofAllcr1ian.

(2) Both Aamtion and Rt:aan are true but Rt:aan

is NOT the correct explanation of Allcr1ian.

(3) Aaatioo is true but Reuon is false.

(4) Both AJlatioo and Reuon are false.

98. Standard cell potential for the following cell is

1.2 V at 298 IC
Fe I Fe2• II FeJ+, Fe2• I Pt
The value of standard gibbs energy change
(liG 0 ) will be:

(I) -347.4 kJ (2) -231.6 kJ

(3) -115.8 kJ (4) -463.2 kJ

99. Base ionization constant for aniline

(C6HsNH 2) is 4 x 10-IO_ Calculate value of
equilibrium constant for following reaction.
C6HsNHioq> + H2O1,> ~ C6HsNHztoq> + H3O<oq>
(I) 2.5 x 10-s

(2) 2.5 X (0
5

(3) 2.5 X 10- )0

(4) 4 X 10-4

100. Choose correct option for following reaction.

4BCIJ(g)+3LiA f ~,)-+2B2H6(g)+3LiC~s)+3A f CIJ(,)

(I) BCl3 is an oxidant

(2) LiA ( H. is an oxidant

(3) It is a disproportionation reaction

(4) It is not a red ox reaction