Chapter 1
Chapter 1
BASIC CONCEPTS
The Study of Chemistry
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Classification of Matter
States of Matter
• Matter can be a gas, a liquid, or a solid.
• These are the three states of matter.
• Gases take the shape and volume of their container.
• Gases can be compressed to form liquids.
• Liquids take the shape of their container, but they do have their
own volume.
• Solids have a definite shape and volume.
Classification of Matter
Pure Substances and Mixtures
• If matter is not uniform throughout, then it is a
heterogeneous mixture.
• If matter is uniform throughout, it is homogeneous.
• If homogeneous matter can be separated by physical
means, then the matter is a mixture.
• If homogeneous matter cannot be separated by physical
means, then the matter is a pure substance.
• If a pure substance can be decomposed into something
else, then the substance is a compound.
Classification of Matter
Pure Substances and Mixtures
• Elements consist of a unique type of atom.
• Molecules can consist of more than one type of element.
– Molecules that have only one type of atom (an element).
– Molecules that have more than one type of atom (a compound).
• If more than one atom, element, or compound are found
together, then the substance is a mixture.
Classification of Matter
Elements
• If a pure substance cannot be decomposed into
something else, then the substance is an element.
• There are 114 atoms (elements) known.
• Each element is given a unique chemical symbol (one or
two letters).
• Elements are building blocks of matter.
• The earth’s crust consists of 5 main elements.
• The human body consists mostly of 3 main elements.
• Pure
Substances
and Mixtures
compound
molecules
an element
atoms
Classification of Matter
Elements
Classification of Matter
Elements
• Chemical symbols with one letter have that letter
capitalized (e.g., H, B, C, N, etc.)
• Chemical symbols with two letters have only the first
letter capitalized (e.g., He, Be).
Classification of Matter
Compounds
• Most elements interact to form compounds.
• Example, H2O
• The proportions of elements in compounds are the same
irrespective of how the compound was formed.
• Law of Constant Composition (or Law of Definite
Proportions):
– The composition of a pure compound is always the
same.
Classification of Matter
Compounds
• If water is decomposed, then there will always be twice
as much hydrogen gas formed as oxygen gas.
• Pure substances that cannot be decomposed are
elements.
Classification of Matter
Mixtures
• Heterogeneous mixtures are not uniform throughout.
• Homogeneous mixtures are uniform throughout.
• Homogeneous mixtures are called solutions.
Physical vs. Chemical Properties
• Physical properties can be measure without changing the
basic identity of the substance (e.g., color, density, odor,
melting point)
• Chemical properties describe how substances react or change
to form different substances (e.g., hydrogen burns in oxygen)
• Intensive physical properties do not depend on how much of
the substance is present.
– Examples: density, temperature, and melting point.
• Extensive physical properties depend on the amount of
substance present.
– Examples: mass, volume, pressure.
Physical and Chemical Changes
• When a substance undergoes a physical change, its physical
appearance changes.
– Ice melts: a solid is converted into a liquid.
• Physical changes do not result in a change of composition.
• When a substance changes its composition, it undergoes a chemical
change:
– When pure hydrogen and pure oxygen react completely, they
form pure water. In the flask containing water, there is no
oxygen or hydrogen left over.
Chemical Symbols