1. The gas pressure in an aerosol can is 1.5 atm at 25 °C.

Assuming that the gas obeys the ideal-gas equation, what is

the pressure when the can is heated to 450 °C?
2. The pressure in a natural-gas tank is maintained at 2.20 atm.
On a day when the temperature is -15 °C, the volume of gas in
the tank is 3.25 * 103 m3. What is the volume of the same
quantity of gas on a day when the temperature is 31 °C?
3. An inflated balloon has a volume of 6.0 L at sea level (1.0 atm)
and is allowed to ascend until the pressure is 0.45 atm. During
ascent, the temperature of the gas falls from 22 °C to -21 °C.
Calculate the volume of the balloon at its final altitude.
4. A 0.50-mol sample of oxygen gas is confined at 0 °C and 1.0
atm in a cylinder with a movable piston. The piston
compresses the gas so that the final volume is half the initial
volume and the final pressure is 2.2 atm. What is the final
temperature of the gas in degrees Celsius.
5. What is the density of methane, CH4, in a vessel where the
pressure is 910 torr and the temperature is 255 K?
6. A large evacuated flask initially has a mass of 134.567 g. When
the flask is filled with a gas of unknown molar mass to a
pressure of 735 torr at 31 °C, its mass is 137.456 g. When the
flask is evacuated again and then filled with water at 31 °C, its
mass is 1067.9 g. (The density of water at this temperature is
0.997 g>mL.) Assuming the ideal-gas equation applies,
calculate the molar mass of the gas.
7. Automobile air bags are inflated by nitrogen gas generated by
the rapid decomposition of sodium azide, NaN3: Na3N  Na +
N2
If an air bag has a volume of 36 L and is to be filled with
nitrogen gas at 1.15 atm and 26 °C, how many grams of NaN3
must be decomposed?
8. In the first step of the industrial process for making nitric acid,
ammonia reacts with oxygen in the presence of a suitable
catalyst to form nitric oxide and water vapor:
NH3 + O2  NO + H2O
How many liters of NH3 at 850 °C and 5.00 atm arerequired to
react with 1.00 mol of O21g2 in this reaction?
9. A 15-L cylinder contains 4.0 g of hydrogen and 28 g of
nitrogen. If the temperature is 27 °C what is the total pressure
of the mixture?
10. What is the total pressure exerted by a mixture of 2.00 g
of H2 and 8.00 g of N2 at 273 K in a 10.0-L vessel?
11. A study of the effects of certain gases on plant growth
requires a synthetic atmosphere composed of 1.5 mol % CO2,
18.0 mol %O2 and 80.5 mol % Ar. (a) Calculate the partial
pressure of O2 in the mixture if the total pressure of the
atmosphere is 745 torr.
(b) If this atmosphere is to be held in a 121-L space at 295 K,
how many moles of O2 are needed?
12. An unknown gas composed of homonuclear diatomic
molecules effuses at a rate that is 0.355 times the rate at
which O2 gas effuses at the same temperature. Calculate the
molar mass of the unknown and identify it.
13. Thể tích của hỗn hợp khí gồm 0,5 mol CO2, và 0,2 mol O2
ở điều kiện tiêu chuẩn là?
14. Thể tích ở đktc của khối lượng các khí được biểu diễn ở 4
dãy sau. Dãy nào có tất cả các kết quả đúng với 2g H2; 5,6g
N2; 7,2g O2; 22g CO2?
15. Lưu huỳnh S cháy trong không khí sinh ra chất khí mùi
hắc, gây ho, đó là khí lưu huỳnh đioxit có công thức hóa học là
SO2. Biết khối lượng lưu huỳnh tham gia phản ứng là 1,6 gam.
Tính khối lượng khí lưu huỳnh đioxit sinh ra.
16. Tính thể tích của oxi (đktc) cần dùng để đốt cháy hết 3,1
gam P, biết phản ứng sinh ra chất rắn P2O5.
17. Đốt cháy hoàn toàn 1,12 lít khí CH4 (đktc) cần dùng V lít
khí O2 (đktc), sau phản ứng thu được sản phẩm là khí cacbonic
(CO2) và nước (H2O). Giá trị của V là?
 18. a) Calculate the number of molecules in a deep breath of air
whose volume is 2.25 L at body temperature, 37 °C, and a pressure
of 735 torr.

(b) The adult blue whale has a lung capacity of 5.0 * 10^3 L.
Calculate the mass of air (assume an average molar mass of 28.98
g/mol) contained in an adult blue whale’s lungs at 0.0 °C and 1.00
atm, assuming the air behaves ideally.

19. A scuba diver’s tank contains 0.29 kg of O2 compressed into a

volume of 2.3 L. (a) Calculate the gas pressure inside the tank at 9
°C. (b) What volume would this oxygen occupy at 26 °C and 0.95
atm?

20. The metabolic oxidation of glucose, C6H12O6, in our bodies

produces CO2, which is expelled from our lungs as a gas:
C6H12O6 + O2  CO2 + H2O
(a) Calculate the volume of dry CO2 produced at body temperature
137 °C and 0.970 atm when 24.5 g of glucose is consumed in this
reaction.
(b) Calculate the volume of oxygen you would need, at 1.00 atm and
298 K, to completely oxidize 50.0 g of glucose.

21. Rank the following gases from least dense to most dense at 1.00
atm and 298 K: CO, N2O, Cl2, HF

22. Magnesium can be used as a “getter” in evacuated enclosures

to react with the last traces of oxygen. (The magnesium is usually
heated by passing an electric current through a wire or ribbon of the
metal.) If an enclosure of 0.452 L has a partial pressure of O2 of 3.5
* 10^-6 torr at 27 °C, what mass of magnesium will react according
to the following equation?
Mg + O2  MgO

23. Consider the apparatus shown in the following drawing.

(a) When the valve between the two containers is opened and the
gases are allowed to mix, how does the volume occupied by the N2
gas change? What is the partial pressure of N2 after mixing?

(b) How does the volume of the O2 gas change when the gases mix?
What is the partial pressure of O2 in the mixture?

(c) What is the total pressure in the container after the gases mix?

24. A mixture containing 0.765 mol He(g), 0.330 mol Ne(g), and
0.110 mol Ar(g) is confined in a 10.00-L vessel at 25 °C.
(a) Calculate the partial pressure of each of the gases in the
mixture.
(b) Calculate the total pressure of the mixture.

25. Determine whether each of the following changes will increase,

decrease, or not affect the rate with which gas molecules collide
with the walls of their container: (a) increasing the volume of the
container, (b) increasing the temperature, (c) increasing the molar
mass of the gas.

26. Which one or more of the following statements are true?

(a) O2 will effuse faster than Cl2.
(b) Effusion and diffusion are different names for the same process.
(c) Perfume molecules travel to your nose by the process of effusion.
(d) The higher the density of a gas, the shorter the mean free path.