All India Test Series (JEE–2024)

AJAM1/07 Test- 7 Arjuna JEE 2024

DURATION ::180
DURATION Minutes
90 Minutes DATE : 03/03/2024 M. MARKS : 300

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (2) 31. (4) 61. (3)
2. (3) 32. (2) 62. (4)
3. (4) 33. (1) 63. (4)
4. (2) 34. (1) 64. (3)
5. (3) 35. (2) 65. (3)
6. (3) 36. (4) 66. (2)
7. (3) 37. (2) 67. (4)
8. (2) 38. (4) 68. (4)
9. (4) 39. (3) 69. (4)
10. (2) 40. (4) 70. (1)
11. (2) 41. (3) 71. (2)
12. (2) 42. (4) 72. (2)
13. (4) 43. (2) 73. (4)
14. (1) 44. (1) 74. (2)
15. (3) 45. (3) 75. (1)
16. (4) 46. (4) 76. (1)
17. (4) 47. (2) 77. (4)
18. (2) 48. (4) 78. (3)
19. (4) 49. (2) 79. (2)
20. (2) 50. (3) 80. (3)
21. (36) 51. (25) 81. (7)
22. (5) 52. (316) 82. (9)
23. (0) 53. (198) 83. (14)
24. (20) 54. (1) 84. (1)
25. (2) 55. (2) 85. (41)
26. (36) 56. (3) 86. (1)
27. (125) 57. (181) 87. (45)
28. (2) 58. (50) 88. (8)
29. (384) 59. (82) 89. (5)
30. (29) 60. (20) 90. (9)

[1]
 SECTION-I (PHYSICS)
1. (2) −GM
Applying conservation of angular momentum at Potential at A due to the ring is VA =
2R
position A and B
−GM
mv A  OA = mvB  OB Potential at B due to the ring is VB =
5R
v OA
Hence, B = =x dU = U f − U f − U i = U B − U A = m0 (VB − VA )
v A OB
−GMm0  1 1 
= − + 
2. (3) R  5 2
T = N sin  and N = mg cos  Wgr = −Wext
mg Wgr = − dU = −Wext
T = mg cos  sin  = sin 2
2
GMm0  −1 1 
Wext = dU = +
R  2 
5

6. (3)
Average velocity
Displacement H 2 + R2 / 4
= =
Time T /2
3. (4)
4 3 4
R = n  r 3 or R 3 = nr 3
3 3
(
Energy evolved = n 4r 2 − 4r 2 T)
Now,
Q Q
= = = ( In C.G.S.system,  = 1 and S = 1) Putting the required values, we get
V S V
v
 n  4r 2 − 4R 2  T vav = 1 + 3cos 2 θ
 =   2
4 3
R
3 7. (3)

=
3T  nr 2 − R 2 
  (
Given V = 10 ms −1 )
3
R V g 10 10
After 2s: Vx = −  2  Vx = − 2
 nr 2 R 2  1 1  2 2 2 2
= 3T  3 − 3  = 3T  − 
r R 10 10
 nr R  Vx = − ms −1and Vy = − ms −1
2 2
4. (2) 100 100 1 1
V= + = 10 + = 10 ms −1
v 10 2 2 2 2
Finally, he will swim along B . tan  = = =2
u 5
8. (2)

  = tan −1 ( 2 ) N of E

5. (3)
Even through the distribution of the mass is 4
So B = A,  = 240 =
unknown, we can find the potential due to the ring 3
on any axial point because from any axial point
the entire mass is at the same distance (whatever 9. (4)
would be the nature of distribution) Mass of disc  area , M A = 4 M B ( as RA = 2 RB )

[2]
 1 1 2
M R2 Wint = Wspring = −U = − kxmax
IA 2 A A 2
=
I B 1 M R2 1 2 1
2
B B  − kxmax = − (4m)v02 − 0
2 2
m
10. (2)  xmax = 2v0
Apparent coefficient of volume expansion k
 app =  L −  s = 7  s −  s = 6 s (given  L = 7  s )
Ratio of absolute and apparent expansion of liquid 16. (4)
L 7 7 If length is doubled, Δl will also become double
= s =
 app 6 s 6 but Y will remain the same as it is the property of
the material, i.e. it changes only when the material
11. (2) changes.
S1 + S2 + S3 + S4 = 16 m, S1 : S2 : S3 : S4 = 1: 3: 5 : 7
Solve to get S1 = 1 m, S2 = 3 m, S3 = 5 m, S4 = 7 m 17. (4)

n=−
D ( n2 − n1 )
T L−1 −2
=
( )
D L−3
x2 − x1 L
T −1L−2  L
D=  D =  M 0 L2T −1 
L −3  

18. (2)
12. (2)
(92.0+2.17) cm = 94.15 cm. Rounding off to first
decimal place, we get 94.2 cm
T1  T2  T3  lengths L1  L2  L3
13. (4)
Decrease in height : h = 14 − 7 = 7 m
Also KE at C = Loss in PE plus initial KE 19. (4)
1 mv 2A
= mgh + mu 2 = 165 J N A + mg cos 60 =
2 R
mv 2A
14. (1) NA = − mg cos 60
1 R
y= at t = 0 = 6 mg − 0.5 mg = 5.5 mg
1 + x2
1 1 2 1
and y = at t = 4 s mv A + mgR (1 + cos 60 ) = mvB2
2 2 2
1 + ( x − 2)
 1
x x − ( x − 2 ) 2 v 2A + 2gR 1 +  = vB2
v= = = = 0.5 m / s  2
t 4−0 4
6gR + 3gR = vB2
15. (3) vB2 + 9 gR  vB = 9gR
At maximum extension in the spring, both the
rings move with same common velocity. mvB2
N B = mg + = 10mg
Applying Work Energy Theorem from the centre R
of mass reference frame, we get

W = Wint + Wext = ( K )cm =  vrel
2
2 2
− vrel ( )
where, μ is reduced mass of system given by

=
( 6m )(12m ) = 4m
6m + 12m
Since no external forces are there, so Wext = 0 and
due to extension of the spring, we have 20. (2)
At position B, x = 2 R − R = R

[3]
 mg As the ratio of velocities of x and y particles are
N = kx = R = mg
R vx 1
= , therefore ratio of their distance covered
1 2 1 2 vy 2
mv = kx
2 2 will be in the ratio of 2 :1 . It means they collide
at point B

k
v= R = gR After first collision at B, velocities of particles get
m interchanged, i.e ., x will move with 2v and
mv 2 particle y with v
( )
2
N1 = =m gR / R = mg
R Second collision will take place at point C. Again
at this point velocities get interchanged and third
21. (36) collision take place at point A
So, after two collision these two particles will
again reach the point A

26. (36)
45 cm= 5(9 cm) and 99 cm=11(9 cm)
So two other lengths between these two values are
7(9 cm) 9(9 cm), i.e., 63 cm and 81 cm
respectively so the fundamental length is 9 cm

T sin  = mL sin 2 9= (for a closed organ pipe)
4
324 = 0.5  0.5  2  = 36 cm
324
 2 =
0.5  0.5 27. (125)
324 Q = nC P T
=
0.5  0.5 3 
= 2  R + R  T
18 2 
= = 36 rad / sec
0.5 3 
= 2  R + R  3
2 
22. (5)
5 5 25
Given  A = 2 = 5 m / s 2   = m / s 2 = 2  3
2 2 3
= 125 J
5
Hence, acceleration of B, aB = 1( a ) = m / s 2
2 28. (2)
At the time of maximum compression, the speeds
23. (0)
of blocks will be the same. Let that speed be v
t = x +3 and maximum compression be x
Differentiating will respect to t , we get Applying conservation of momentum,
1=
1 dx
+ 0 or
dx
=2 x ( m1 + m2 ) v = m1v1 + m2v2
2 x dt dt  v =4m / s
When velocity is zero, 2 x = 0 or x = 0 Applying conservation of mechanical energy
1 2 1 1 1
kx + ( m1 + m2 ) v 2 = m1v12 + m2v22
24. (20) 2 2 2 2
In the condition of weightlessness, water rises to Solving, we get x = 0.02 m
the whole of the available length
29. (384)
25. (2) Least count
Let initially particle x is moving in anticlockwise pitch
L.C. =
direction and y in clockwise direction number of divisions on circular scale

[4]
 1 30. (29)
LC= mm = 0.01mm
100 Since the last five steps covering 5 m land the
As zero is not hidden from circular scale when A drunkard fell into the pit, the displacement prior to
and B touches each other. Hence, the screw gauge this as ( 11 − 5 ) m = 6 m
has positive error. Time taken for first eight steps (displacement in
e = + n (L.C.) = 32 × 0.01 = 0.32 mm first eight steps = 5 − 3 = 2 m) =8 s. Then time
Linear scale reading = 4 × (1 mm) = 4 mm 6
taken to cover first 6 m of journey =  8 = 24 s
Circular scale reading = 16 × (0.01 mm) = 0.16 mm 2
 Measured reading = ( 4 + 0.16 ) mm = 4.16 mm Time taken to cover last 5 m = 5 s
 Absolute reading = Measured reading – e Total time = 24 + 5 = 29 s
 Absolute reading = (4.16 − 0.32) mm = 3.84 mm
Therefore, thickness of the glass plate is 3.84 mm

SECTION-II (CHEMISTRY)
31. (4) One carbon atom of C=C is linked to two similar
Benzyl alcohol. groups, so it does not show geometrical
isomerism. It has one chiral carbon atom, so it
32. (2) shows optical isomerism.
Two type of C – C bond are present which are (1º
- 4º) C – C bond and (2º - 4º) C – C bond 38. (4)
Neopentane (CH3)4C is the acyclic and saturated
33. (1)
Follow conditions of geometrical isomerism.
39. (3)
34. (1) In 1-Chloroethene two groups are same on one
carbon atom so it cannot show geometrical
(a) and isomerism

O 40. (4)
C–Br Last electrons enters in d-orbital.So it belong to
(b) are chain isomers d-block. For d-block elements the group number
CH3 is equal to the number of valence electrons +
number of electrons in (n – 1) d subshell i.e., 2 +
35. (2) 5 = 7th group.

41. (3)
Ionic bond formation is favoured by high lattice
energy.

42. (4)
PCl6− − sp3d 2 − Octahedral
+
−
N = N = N−
36. (4)
O 22− has bond order 1.
Species is diamagnetic and last electron occupies
anti-bonding MO.

37. (2)

[5]
43. (2) 52. (316)
Spin quantum no. is not obtained from FeSO4 + MnO4− + H + → ( Fe )2 ( SO4 )3 + Mn 2+ + H 2O
Schrodinger wave equation.
n=1 n=5
For uni-electronic species: energy varies with
n-only. Equivalents of KMnO4 = Equivalents of FeSO4
0.1  1  10
= = 10−3
44. (1) 1000
10−3
BF3 (sp2) + F– ⎯⎯
→ BF4– (sp3). Moles of KMnO4 in 10 mL = = 2  10−4
5
Moles of KMnO4 in 1 L = 2 × 10–4 × 100 = 0.02
45. (3)
Mass of KMnO4 in 1 L = 158 × 0.02
Reaction I – II
= 316 × 10–2g/L
2N2O5(s) → 2N2O5(g); H = 108 kJ
108
Hsub = = 54 kJ/mol 53. (198)
2
54  1000 2SO2 ( g ) + O2 ( g ) 2SO3 ( g )
 Tsub = = 300 K
180 2
PSO 3
KP = 2
PSO P
2 O2
46. (4)
Ksp of Zn (OH)2 = 4S3 ( 43)2
Ksp of Zn (OH)2 = 4 × 27 × 10–18 =
pH = 12  [OH–] = 10–2
( 0.53)( 42 )2
 S × (10–2)2 = 1.08 × 10–16 = 198 × 10–2 kPa–1
 S = 1.08 × 10–12
54. (1)
47. (2) Ba(OH)2→ Ba2+ + 2OH–
In presence of Zn in polar protic solvent halogen [OH–] = 2 × 0.005 = 0.01 M
atom is substituted by hydrogen atom −14
 H3O +  = K w = 10 = 10−12
   OH −  0.01
 

48. (4) 55. (2)

In all reactions, hydrogen peroxide acts as Let the mass of A2B and AB3 is 1gm and atomic
reducing agent in basic or acidic medium. mass A and B are x and y respectively.
1 1
 0.15 = , and 0.15 = ,
49. (2) 2x + y x + 3y
Fe 2+ + C2 O 24− + MnO −4 → Fe3+ + CO 2 + Mn 2+ On solving we get
Eq. FeC2O4 = eq. of KMnO4 x = 2y
2.88 M  60
 3 = 5
144 1000 56. (3)
 M = 0.2 mol/L Correct expressions are,
V 
50. (3) Wrev = −nRT ln  f 
Species having planar structure and (4n + 2)πe–  Vi 
are aromatic G sys = −TSTotal ( at constant -P )
G  = H − TS
has aromatic character − RT ln K = H − TS
H − TS
ln K =
−RT
TS − H
ln K =
51. (25) RT
The number of orbitals possible in a shell with G  = − RT ln iK
principal quantum number ‘n’ is ‘n 2’.

[6]
 G Q, Heat released = 0.03 × 57.1 kJ = 1.713 kJ
= ln K
−RT Q = m × C × ΔT
G  1.713  1000
− T = = 81.96  10−2 82  10−2
 K=e RT 500  4.18

57. (181) 60. (20)

Ionisation energy of an atom of meta l A = Quantum Br2(l)  Br2(g)
energy of radiation of wavelength 663 nm
At equilibrium Br2 ( l ) + Cl2 ( g ) 2BrCl ( g )
6.63  10−34  3  108 −19
= −9
J = 3  10 J 1− x 2x
663  10 ( PBrCl ) 2
( PBrCl ) 2
Ionisation energy per mol KP = = =1
= 3 × 10–19 × 10–3 × 6.02 × 1023 PCl2 0.01
= 180.6 kJ mol–1 181  PBrCl = 0.1 atm
n BrCl 0.1 2x
58. (50) = = 10 =
n Cl2 0.01 1− x
A2X ⇌ 2A+ + X2–
2S1 S1 10 5
 x= =
Ksp 12 6
Ksp = 4S13  S1 = 3 = 10−4 5
4  Moles of Br2(l) reacted with Cl2 ( g ) =
MX ⇌ M2+ + X2– 6
S2 S2 moles.
Vapour pressure of Br2(l) = Partial pressure
K sp = s 22  s 2 = k sp = 2  10−6
of BrCl(g)
S1 = s(A2x 10
S2 = x(MX)  Moles of Br2(l) converted into vapour =
6
s1 10−4  Minimum moles of Br2(l) required
= = 50
s 2 2  10−6 10 5
= +
6 6
59. (82) 15
HCl + NaOH →NaCl + H2O =
6
Moles0.04 0.03 – – 15
0.01 – 0.03 0.03  Mass =  160
6
= 400 g

SECTION-III (MATHEMATICS)
2 1 
(x ) 1
61. (3)
2
+ y2  2 + 2  = 4a
2

x y 

62. (4)

h
Equation of line PQ is y − k = − ( x − h) 2PQ = PA + PB
k ⇒ PQ – PA = PB – PQ
or hx + ky = h 2 + k 2 ⇒ AQ = QB
⇒ Q is midpoint of AB
 h2 + k 2   h2 + k 2 
 Points Q  , 0  and P  0,  Let Q has coordinates (h, k)
 h   k Then equation of chord AB is given by T = S1
   
or hx + ky – 4 = h2 + k2 – 4
Also 2a = x12 + y12 This variable chord passes through the point P(3, 5)
 x12 + y12 = 4a 2 ⇒ 3h + 5k = h2 + k2
⇒ x2 + y2 – 3x – 5y = 0
Eliminating x1 and y1 we have
Which is required locus

[7]
63. (4) 68. (4)
The equation of rectangular hyperbola is
f(x) = x12 − x9 + x 4 − x + 1
(x – 3) (y – 5) + λ = 0
Case-I: x < 0 Which passes through (7, 8). Hence,
x12 − x9 + x 4 − x + 1  0 4 × 3 + λ ⇒ λ = –12
+ ve + ve ∴ xy – 5x – 3y + 15 – 12 = 0
Case-II: x  [0, 1) ⇒ xy – 3y – 5x + 3 = 0
x12 − x9 + x 4 − x + 1  0
+ ve + ve 69. (4)
Case-III: x  [1, ) a2 − 2a + 3 = |cos x − 2|
(a − 1)2 + 2 = |cos x − 2|
x12 − x9 + x 4 − x + 1  0
+ ve
a = 0, a = 2, a = 1
+ ve
For 3 integral values
 Domain of f (x) is R
70. (1)
64. (3) tan and tan are roots of
The family of lines (x – 2y + 3) + λ(2x – 3y + 4) =
0 are concurrent at point P(1, 2) (k + 1)tan2x – 2 tanx – (1 – k) = 0
If image of point A(2, 3) in the above variable 2
 tan  + tan  =
line is B(h, k), then AP = BP k +1
⇒ (h – 1)2 + (k – 2)2 = (2 – 1)2 + (3 – 2)2 k –1
Hence, locus of point P is x2 + y2 – 2x – 4y + 3 = 0 tan  tan  =
k +1
65. (3) 2
1 1 Now tan( + ) = k + 1 = 2 = 
+ + ...  k –1 2 2
x1 x2 1–  
 k + 1 
 1 1  1 1  1 1 
= 1 + + 2 + ... 1 + + 2 + ... 1 + + 2 + ... 
 3 3  5 5  7 7  2
= 50
35 2
 3   = 10
16

66. (2) 71. (2)

E = (x – α1) (x – α2) (x – α3) ….. (x – αn) where Discriminant of x2 + px + 3p is p2 – 12q  D1
α1 = 1, α2 = 2 etc Discriminant of –x2 + rx + q is r2 + 4q  D2
= xn – (α1) xn – 1 + (α1α2) xn – 2 + …… Discriminant of –x2 + sx – 2q is s2 – 8q  D3
Hence co-efficient of xn – 2 = sum all the products Case 1: If q < 0, then D1 > 0, D3 > 0 and D2 may
of the first 'n' natural numbers taken two at a time or may not be positive.
Case 2: If q > 0, then D2 > 0 and D1, D3 may or
(1 + 2 + 3 + .... + n )2 − (12 + 22 + ..... + n2 ) may not be positive.
=
2 Case 3: If q = 0, then D1  0, D2  0 and D3  0

=
( )
n n − 1 ( 3n + 2 )
2 From case 1, case 2 and case 3 we can say that
the given equation has at least two real roots.
24
72. (2)
67. (4) 18 = 1118 = 129 = 136 = 233

lim
4 sin 4 4 x  (1 + cos 4 x )
2 The signs are + – –, – + –, – – +, + + +
 The desired number = 18 × 4 = 72 = 9P2
x→0 x
4
| sin 4 x |  1 + cos 2 4 x 73. (4)
lim c c
x→0 x OT 2 = OA  OB =  =  OT =
a a
| sin 4(– h) | 4 1 + cos 2 4h
LHL = lim
h→0 –h
= –4  4 2
= –29/4
| sin 4h | 4 1 + cos 2 4h
RHL = lim
h→0 h
4 9/4
= 4 2 = 2

[8]
74. (2) Case-II, Two are same and two are different
Let z = x + iy 4
x2 + (y + 10)2 – [x2 + (y – 10)2] = 20  3 C1  7C2 
2
 (2y)(20) = 20 Case-III, Two same of one kind and two same of
1 other kind
 y=
2 4
Hence locus is a straight line.  3 C2 
2 2
 Total ways = 1680 + 756 + 18 = 2454
75. (1)
80. (3)
Since x = 0 is one of the solutions so the product
will be zero.

81. (7)
2
 
2 2  5 x − 12 y + 17 
Here, ( x − 1) + ( y − 3) = 
Since ellipse and hyperbola intersect  52 + ( −12 )2 
 
orthogonally, they are confocal  the focus = (1,3) and the directrix is
Hence, a = 2 (equating foci) 5 x − 12 y + 17 = 0
Let point of intersection in the first quadrant be
The distance of the focus from the directrix
P(x1, y1). P lies on both the curves. Therefore,
4x12 + 9y12 = 36 and 4x12 – y12 = 4 5  1 − 12  3 + 17 14
Adding these two results, we get = =
52 + ( −12 )
2 13
8(x12 + y12) = 40
⇒ x12 + y12 = 5 ⇒ r = √5
14 28
Hence, equation of the circle is  latus rectum = 2  =
x 2 + y2 = 5 13 13

76. (1) 82. (9)

2 sinα cosα = 2 cos2β 2740 = 3120
sin 2α = 1 + cos2β 3119 = (4 – 1)119 = 119C0 4119 – 119C1 4118 + 119
C2
 cos2β = sin2α – 1 4117 – 119C3 4116 + …. + 119C118 4 – 1
 3119 = 4k – 1
77. (4)  3120 = 12 k – 3 = 12 (k – 1) + 9
Total number of triangles = 20C3 = 1140.  The required remainder is 9
There are 20 triangles with two sides of the
polygon and there are 20  16 = 320 triangles 83. (14)
with one side of polygon.  |z – i| = |z + 2i| is perpendicular bisector of
 Required probability line segment joining (0, 1) and (0, –2) that is
1140 − 20 − 320 40 1
= = y=− ...(i)
1140 57 2
5
z = represents a circle having equation
78. (3) 2
 xi = 200 and  xi2 = 2080 x2 + y 2 =
25
...(ii)
200 + 11 − 9 202 4
Now Actual Mean = = 1
20 20 From (i) and (ii) x =  6, y = −
2 2
2080 − 81 + 121  202 
 Actual variance = −  1
20  20   z= 6− i
2
106 – (10.1)2 = 106 - 102.01 = 3.99 2
5 7
( 6 )
2
So z + 3i = +  =
79. (2) 2 2
EXAMINATION has letter distribution as
follows 84. (1)
8 7 6 5 4 3 2 1
2 A, 2 N, 2 I , E , X, M , T , O  + 
= 
Case-I, When all letters are different  2 
 8C4  4 = 1680 3
cos + cos =
2
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 1 1
sin + sin =   x =
2 2
 +   −  3 5
2cos   cos   = and  from (i) we get = x +1
 2   2  2 2
 +   − 1 3
2sin   cos  =  x = , (one value)
 2   2  2 2
 +  1
 tan  = 87. (45)
 2  3
1
 x2 
 tan  =  x − tan x + .tan x 
3 lim  3 
x →0  4
sin2 + cos2 x tan x 
 
1 1  
2  1 −
2 tan  1 − tan 2  3  −2 1  7
= + =  + 9 x5  +  + x + ...
1 + tan 2  1 + tan 2  1 + 1 1 + 1  15 9  −1
= lim =
9 9 x →0  x2 2 x4  45
x5  1 + + + .... 
2 8  3 15 
+  
14 7
= 3 9 = =
10 10 5 88. (8)
9

85. (41)
For the required number, it must be divisible by 2 There are eight options on first place (except the
as well as 3. digits 0 and 2) and only one option at fourth
Now, only two cases are possible. place (digit ‘2’).
Case I : Number is formed by 1, 2, 3, 4, 5 Remaining three places can be occupied by any
 Required numbers three digits out of 1, 3, 4, 5, 6, 7, 8 and 9.
= 1  2  3  4  2 = 48 Number of such numbers = 8 × 8 × 7 × 6 = 336 k
2/4 k=8
Case II : Number is formed by 0, 1, 2, 4, 5.
Either, 4  3  2  1  1 = 24 89. (5)
0
or 3  3  2  1  2 = 36
2/4
Total number of required numbers = 36 + 24 + 48
= 108
n (S) = 600 Since BCA = 90°
108 9 Points A, O, B, C are concyclic
Required probability = =
600 50 Let AOC = θ
AOC = ABC
86. (1) y 12
 =
5 {x} = x + [x] ….(i) x 5
1 12x – 5y = 0
 x  −  x = ….(ii)
2
 0  {x} < 1 90. (9)
1 Given, 2m – 2n = 56
 0   x −  1 (by (ii) By hit and trial method, we get m = 6 and n = 3
2
 [x] = 1

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