Midsem 2024-2025
Midsem 2024-2025
Instructions.
i) Answer all the questions.
ii) Symbols have their usual
meanings.
iii) Calculator is NOT allowed.
iv) For questions having more than one part,
answers are to be written together
in continuity.
ii) Let un > 0for all n =1,2,3,.. .. T 4n is convergent, then check whether
n=1
n2024 15 Convergent or not. (2)
2x if x¬Q
6)Show that the function f(x) = is continuous at x =1only. Give
3-x ifxER\Q.
an example of afunction g:R’Rwhich is continuous only at three points. (3+2)
C2 Cn
=0where Co, Ci,.. ., Cy are real, show that the equation
n+1
Co + C1x+cx+ + Cnx=0has at least one real root between 0 and 1. (4)
- END
of
Rajiv Gandhi Institute Petroleum TechnoloMid/gy, Semester
B. Tech. CSE/CSD/IT/DD/M&C Eng9 Odd Semester Jais, Amethi
Examination
2024 -25
Subject CS 101
Computer Programming
Time 2 hrs
Full Marks 30
Section A: (3X5=15]
In question 1-4, use only "main"
function to Complete the task No other function should be
used.
Section B:
int j:
j= 64/ SQUARE (4):
printf ("j = %d". j);
Access the "arr" elements: 11, 22, 32. Using pointer p and a.
Questionl(Q-1) contains 10 MCQ type questions (A)and each one carries 1 mark.
Q4A.
Bond order of CO and C0+ is:
(a) 3 & 3.5 (b) 2.5 & 3.0
(c) 3.5 & 3 (d) 3 & 2.5
1B.
Ifcrystal field splitting energy for an octahedral complex (Ao) is greater than pairing energy (P) then
the metal complex formed will be:
(a) Low-Spin (b) High-Spin (c) Both Low-Spin & High- (d) Ao and P are not
Complex Complex Spin Complexes can form related to each other
1C.
Which one is paramagnetic?
(a) CO (b) CN (c) NO
A-1D.
Which of the following complexes shows zero crystal field
stabilization energy?
(a) [Co(H,0),³+ (b) [Fe(H;0).P: (c) [Co(H;0)%|P* (d) [Mn(H;0)6|
QE.
Which of the following d orbitals take part in the octahedral complex with d'sp³
hybridisation?
(a) dyy, dyz (b) dz, d,?y² (d) d,z, dz
Q-1F.
How many unpaired electrons are present in (CoFG* complex?
4 (b) zero (c) 2 (d) 3
Q1G.
What does LCAO stand for in molecular bonding ?
Limited Combination (c) Light Combination ( Linear Combination
(a) Laborious Cuisine (b) of Atomic Orbital of Acute Orbital
of Atomic Orbital of Atomic Orbital
Q1H.
Which hybridization schemeis most appropriate Tor the central atom in SO:?
(b) sp
(c) sp'd (d) spd
stretching
What is the order of carbonyl
(ii) [Ir(Co)6|}* and (iv) Free
CO. frequencies in the species- () [Mn(CO)6|*, (i) (Os(CO).|t,
i>ii> ii> iv (b) ii > ii>i>iy (c) i>ii>ii> iv
(a) (d) i>ii= ii> iv
Q4J.
Predict the hybridization of Fe(CO)s ?
(a dsp' (b) sp' (c) d'sp (d) dsp
() There are three possible structures of CI3. Which one is correct and why?
-THANK YoU--
Institute of Petroleum Jais, Amethi
Rajiv Gandhi Technology,
B. Tech. Mid Semester (odd Semester) Examination 2024-25
Subject: Classical Physics (PYI11) FullMarks: 30
Time: 2 hours
Allquestions are compulsory.
their usual meanings.
Unless specified, symbols have
Use of scientific calculators is allowed. L6x 10" C; k¡ = kg
x 10:34 J.s; m= 9.l x 10-3 kg; e =] 1.38 x102551J/K; m, = 1.67 x10"
h=6.63
|1|
oxi.show that w=x¼ where IS aconstant vector. r is a position vector.
Oor) Show that r"; = (n+3)r7
|21
in a cylindrical
which are the unit vectors along the o. o and z-axis. respectively,
Determine ep, e and ¬, point P in the
shown in Figure 1. Then show that the nposition vector () of any |2+1|
coordinate system (p, o, z) as
system can be expressed as r= pe, +z¬,.
cylindrical coordinate
Figure I
their coordinates (x,
spherical coordinate system withspherical
cartesian coordinate and conditions/
A three-dimensional rectangular Figure 2. Describe/draw the surface with the given
in
y, z) and (r, 0, ) are shown
restrictions:
ranges of (r, 0, 6)] (2]
[draw single surface which satisfies all these
-/4 & 4<r <9 & =0 to 4
Figure 2
coordinate system)
S'-frame (x' y' z' coordinate system) is rotating with respect to a fixed S-frame (X Y Z system)
A system). The angular velocity of the S'-frame (x' y'e'
having the same origin (i.e., S-frame is an inertial
-tj' + (2t + 4)k. The position vector ofa moving
relative to the S-frame (XYZ system) is given by =2tT of
by Y= (t² + 1)1- 6t + 4K. Find out velocity
particle at time e" as observed in the xyz system is giVen 1. (1,'and k are the unit vectors in the S'-frame
time t=
the particle relative to the XYZ coordinate system at (21
(x'y' z' coordinate system)).
5. A block of mass m' is sliding on the wedge of mass (Figure 3). The wedge alsoslides along a horizontal
surface. Neglect friction.
W Find the Degrees of freedom of the system
[1|
( Find the generalized coordinates |1|
1
Ai)Meñtion the type of constraints |1|
(iy Write the constraints equations |1|
Figure 3
6 Alever ABC has weights WËand W2 at distances 'aj' and 'a:' from the fixed support B(Figure 4). Find out the
necessary and sufficient conditions for the equilibrium us ing the PRINCIPLE OF VIRTUAL WORK. (21
W, W,
B
A C
a
Figure 4
Z A particle of mass m" is projected with initial velocity *u" at angle "a" with the horizontal. Write down the
Lagrangian equation of motion. Using Lagrange's equations of motion shows that the path followed by the
projectile can be expressed by the equation: |3|
1
y=* tan a-2iu cos a)²b
8. Aparticle of mass "m' isconfined to the cylindrical surface as shown in the Figure 5subject to a force F= -kY.
The distance of the particle from the center "0 is 'r and k' is a constant number. The radius of the cylinder is
"p".Consider acylindrical coordinate (p, ¢. z) centered at origin "0.
(i) Find out the potential and express the Lagrangian (L) in terms of (p. $,.z) [2|
(ii) Find out the momentum conjugate and express the Hamiltonian |2
p=R
Figure 5 m,
Figure 6
OR
CPwo masses mand m are suspended over a frictionless pulley of radius " and connected by an inextensible
string of constant length f° (Figure 6).
Express the Hamiltonian 121
Obtain the equation of motion. (21
2
Briefly explain what are the cyclic coordinates. Then prove that the generalized momentum corresponding to a
cyclic coordinate is conserved. |21
10/The energy (e) distribution of the identical gas that follows the classical Maxwell-Boltzmann distribution, is
(TkpT)3/2
2N ¬[/e-e/kgTde where n(a)de is the number of molecules between energy [ and
expressed as, n([)d[ =
etd[
From the above expression of n(e)de in this classical system, describe the expression of velocity (v)
distribution n(v)dv of these gas molecules between the velocity range vto v+dv. [1|
Calculate the most probable velocity (") fromthe obtained equation. (2]
Find out the most probable velocity ("p) and RMS (the root-mean-square) velocity (Prms) of hydrogen
molecules (consider atomic mass) at 100°C. (2|
Useful formulas
Spherical coordinate system
10T 1
Gradient:
r sin -e
1 1dvg
Divergence: ¼:i=(rv,) +rsin 0 Oe (sin vg)+ rsin 8d
1
Curl: xi= r sin lo (sin v) - +L r lsin 0
1
Laplacian: sin 6) (r sin 6)2 a¢2
r² sin 0 00
+
Gradient: 1 ßT
ôp dz
Divergence: 7-=1
pôp
(pv,) + pôRe.+
Curl:
Txi=(-),+
( ) e +1(oug) -
Laplacian: 1 8²T
+
dz2
Jais, Amethi- Uttarol
Rajiv Gandhi Institute Petroleum Technology
Pradesh-229 304, India
Biology
[BY101]
Date: 04.10.2024
Duration: 2 hr
10 20 30 40 50
OH oH
p NH, NH, VNaOH (mL)
Fig.1
OH OH
NH Give the answer tofollowing question based on
NH,
R above figure