R3.2 Practice
R3.2 Practice
2 Organic redox
reactions
Use the following practice questions to check your knowledge and understanding of this sub-topic. You will
need access to the IB data booklet. You have direct access to these questions so you will not be assessed on
them by your teacher.
If you get an answer wrong, read through the explanation carefully to learn from your mistakes.
What is the sum of coefficients when the complete combustion of butan-1-ol is balanced using the smallest possible
whole numbers?
A. 33
B. 24
C. 15
D. 16
What are the oxidation states of carbon in carbon dioxide, CO2, and methane, CH4, respectively?
A. +2 and +4
B. +2 and 0
C. +4 and −4
D. +4 and +4
3
A. propanoic acid
B. propanone
D. propanal
What is the major organic product when ethanol, CH3CH2OH, is reacted with acidified potassium dichromate(VI)
and the product is distilled off immediately?
A. CH3CO2H
B. CH3CHO
C. CH3COCH3
D. CH2OHCH2OH
I. CH3CH2CH2CH2OH
II. C(CH3)3OH
III. CH3CHOHCH2CH3
A. I, II and III
D. I and II only
Which compounds could be reduced by reaction with lithium aluminium hydride and acid?
I. CH3CH2CH2OH
II. CH3COCH3
III. CH3CH2CO2H
A. I, II and III
D. I and II only
I. CH3CH2CO2H → CH3CH2CHO
C. I, II and III
D. I and II only
Methanal, CH2O, is oxidised to product Y by reflux with acidified potassium dichromate(VI). Product Y is isolated
and reacted with a strong reducing agent, lithium aluminium hydride in dry ether, and acid, to produce product Z.
A. 0 and −2
B. +2 and +2
C. +2 and −2
D. 0 and +2
I. Buta-1,3-diene
II. Cyclohexene
III. Ethyne
C. I, II and III
D. I and II only
10
What is the change in the degree of unsaturation of the organic compounds if benzene, C6H6, is converted to
cyclohexane, C6H12?
A. from 3 to 1
B. from 4 to 0
C. from 3 to 0
D. from 4 to 1