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TITRATION AChem

The document provides an overview of titration in analytical chemistry, detailing important terms such as titrant, analyte, equivalence point, and end point. It includes instructions for preparing standard solutions, treating titration data, and calculating the quantity of analyte from titration results. Additionally, it covers various types of titrations, including argentometric and acid-base titrations, with examples and calculations.

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9 views17 pages

TITRATION AChem

The document provides an overview of titration in analytical chemistry, detailing important terms such as titrant, analyte, equivalence point, and end point. It includes instructions for preparing standard solutions, treating titration data, and calculating the quantity of analyte from titration results. Additionally, it covers various types of titrations, including argentometric and acid-base titrations, with examples and calculations.

Uploaded by

jekjekdalisay1130
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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01 CHE 401

ANALYTICAL
CHEMISTRY
TITRATION
02 TITRATION
IMPORTANT TERMS

TITRANT - reagent of known concentration that is added to determine the


analyte's concentration
ANALYTE - substance whose concentration is to be determined
EQUIVALENCE POINT - theoretical point in which the amount of added titrant
is chemically equivalent to the amount of analyte in the sample
END POINT - observable physical change associated with the condition of
equivalence
03 VOLUMETRIC CALCULATIONS
04 TITRATION
MOLARITY OF STANDARD SOLUTIONS

A standard 0.0100 M solution of Na+ is required to calibrate a flame photometric


method to determine the element. Describe how 500 mL of this solution can be
prepared from primary standard Na₂CO₃ (105.99 g/mol).
05 TITRATION
MOLARITY OF STANDARD SOLUTIONS

How would you prepare 50.0 mL portions of standard solutions that are 0.00500 M,
0.00200 M, and 0.00100 M in Na+ from the previous example.
06 TITRATION
TREATING TITRATION DATA

A 50.00 mL portion of an HCI solution required 29.71 mL of 0.01963 M Ba(OH)₂ to


reach an end point with bromocresol green indicator. Calculate the molarity of the
HCl.
07 TITRATION
TREATING TITRATION DATA

Titration of 0.2121 g of pure Na₂C₂O₄ (134.00 g/mol) required 43.31 mL of KMnO₄.


What is the molarity of the KMnO₄ solution. The chemical reaction is:
08 TITRATION
QUANTITY OF ANALYTE FROM TITRATION DATA

A 0.8040-g sample of an iron ore is dissolved in acid. The iron is then reduced to
Fe²+ and titrated with 47.22 mL of 0.02242 M KMnO₄ solution. Calculate the results
of this analysis in terms of (a) % Fe (55.847 g/mol) and (b) % Fe₃O₄ (231.54 g/mol). The
reaction is described by the equation:
09 TITRATION
QUANTITY OF ANALYTE FROM TITRATION DATA

The phosphorus in a 4.258-g sample of a plant food was converted to PO₄³- and
precipitated as Ag₃PO₄ through the addition of 50.00 mL of 0.0820 M AgNO₃. The
excess AgNO₃ was back-titrated with 4.86 mL of 0.0625 M KSCN. Express the results
of the analysis in terms of % P₂O₅.
10 TITRATION
QUANTITY OF ANALYTE FROM TITRATION DATA
11 TITRATION
QUANTITY OF ANALYTE FROM TITRATION DATA

The CO in a 20.3-L sample of gas was converted to CO₂ by passing the gas over
iodine pentoxide heated to 150 ℃ , and I₂ was distilled and collected to 8.25 mL of
0.01101 M Na₂S₂O₃, then back titrated with 2.16 mL of 0.00947 M I₂ solution.
Calculate the mg of CO (28.01 g/mol) per liter of sample.
12 TITRATION
QUANTITY OF ANALYTE FROM TITRATION DATA
13 TITRATION
ARGENTOMETRIC TITRATION

Perform calculations needed to generate a titration curve for 50.00 mL of 0.0500 M


NaCl with 0.1000 M AgNO₃.
14 TITRATION
ARGENTOMETRIC TITRATION
15 TITRATION
STRONG ACID-STRONG BASE TITRATION

Prepare a titration curve for 50 mL of 0.15 M NaOH with 0.20 M HCl.

WEAK ACID-STRONG BASE TITRATION

Prepare a titration curve of 60mL of 0.15M acetic acid with titrant 0.08M sodium
hydroxide.

STRONG ACID-WEAK BASE TITRATION

Prepare a titration curve for 60mL of 0.15M ammonia with titrant 0.08M hydrochloric
acid.
16 TITRATION
STRONG ACID-STRONG BASE TITRATION

Prepare a titration curve for 50 mL of 0.15 M NaOH with 0.20 M HCl.

At equivalence point:
17

THANK
YOU!

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