Inhod sheabosay

dis also Called an Vibraknd sheclroscog

('nvolves the transiting hetwe
tte vibrati ona cnuy lavels of a moleeule om
the assoplin of Aadiatins fny
- Yo Cm

Prinik IR Sþecho sce

an Valuable tool n
IR Shecto s-t) venitcalin
deferniaien and
Compaund suctue wave numna
(IR) hadiain wth
Jnta
bwecn yoD - yoo Cm bastcaw
olecue vibrati at a
The bonda in Hu
chemical bonds n ditt
uyeny abseo rali'ain ¢ Vatiabe
Cnvionmuts wl
Cnten sitis at vatiable freqwy
Javelves colleclihg alial's
The IR shecioscapY
absttin c'nfermalin t molela and analyst
absorloms IR
Tu tuewnin at wtuch he a
moltuls tovde cofmaln abnt
radialn by th molecule
bonds wttn e
vibsatind tueny cebends ubon te moleeule
Presemt u e
He alims
2 Strength of te bonds
3 Tne ashangemeut alms wtHutn Hue maleule

bend m a mole
vibalima frezuny o e bond
Can be Cateulat by Hook's Law

V= Wave numnb
k fosce Constant
Saduce man

mAtmß
Force conslank) o Huee easw
a bono
Ghcali He vale k, slnga
calulali
stretdling thequmg co bod
Solulini
|6
No No

mc =
No Avo jaoo's mumbw
|2 xl6 No
Rduced NoXNo X(|2+l6 )
(metma) mo
-23
G023x03
28
ce 3XCm sec

1138xD-23
a314 X3x10
X 2·09S9Y

|884
 TR active molecului Moleculs wteh wndngo

mt change tn disole momunt oluning vibrat.n

HE, Hl Ho

TR ('nactve moleutsi Any melecule tich eitar

do not have ermanunt dibole moment os then

change n dibole momen
vibralon

Selestin Rud for IR shechresety

moment molceue shuld b nner
Ihe mut cipole
dung vi bralina moltim
Hommomucean diateno'e slecules 0,,N d
IR Cnacte
nerà
specham not AuCored b'cay dipale momud
o=c=(Tn asygmmfical shretzing)
IR acte Net diþole awy 0
’Hult ucdem moleculw HR H HCN, Co
H-B
2-
Fingujrint agin
3 Law tyuny gin
Functinal mat ugini(4toro- 1yoocon)
u ths uin, iwa
Ihe Presene o band
Jnfermalim
molecule

shtelm
band cn the
to 4So Cm
34soc -)
36e0 Cn

stretihiny
vibain

3o
|CH)
Fingaint ugio 0o Com
The ban ds n t's

bout sesence o c'sos n Sample

and esa blisk
Thse band
Hl (dn tity mole cles twt like su
6stablish sus
Can c'denaty srctay
Tie bands
Csms we! os sereo C'so mes

Cm

(Aromale igin)
presne bancb thii ein giies
arenalE
Cnfomaln abut Presne
He bando au
Cumpourda hample
and abpeaw blu
inlensy
sheclsum
Aes o fundamntal A, vibralina
(AB t e molecuti)

steetehing Nochane
Bendingvibalan
vibyalin
(borl angt)
(Bnd angle
chang
Asymmetc
Symmeic shteint
vibralom
streting
vibyalion

Netclipoleto
(IR ace)
Net oi bole =O
IR Cnaclve)

In plans bendiny
þending
Tnstiny
Rocking seitdering H

H H
ctetehnt Vibaim In tis tyte vib»atin, the dis ame
between two atm in Creakts dicx AWS but th alins
Semun u samu bond axis
shcleuing vbalim an

om
a molecule is the sam diredi¡n

2 bsymmlsie
Aspomkie sheteking vibralin ii- Sn is atom
pþoachn te Cens atom wule tu otrmes

Bending vibaioni Positions of the atom chanj wr

hustet to tu on'gina bond axis but He dislane
betwen te atom umm Consa

Bendig vibraions

I: In tlane bending vibns

a

a) Rockng opfoa each othr

b) Suiksoring - Both the
He atons apfaul
2- Out tane bending vibaiaa i
meves ub nl belns the lan
a) wating' Both the atoms
Cenbal atom

b) Tisting Gne atern mve u and other mves odoy

the planu with Apeet to the centd atin
 No vibyatim:
uinear mol eeules (3n-)
mo

Examblis: 3
3x3-s 4
Co =

2 Non l'nan molecutes (3m-6)

xamln = 9
CHy 3 3X56
3x3 -k 3
Ho

hudam Rolleig
molecles! Co - , Ho,
 (t)

?-(ou)-
(i-)a mpuny

(sz).
 Sswe st iatin

Beam
\attemutor

Sampe Referene

-|beector
|Amblifor

Computes IR
Sheefruo
IR Saeialin Sousee i
EAcical
Nermst
thenidc
lawr ( 1soo'c)
Disperbing Elemnta Rock Aoalt prism

Detector - [hermocle
 bmel and Kungth
molecude f
tusrenth S)
delesmine
tue thelbs
to
bordmomt diþole
molecule
boring
H
bond
dabs a 3)
teConsank Porce e mine cleles
delermine tolos 2)
mole.cule t
stopy twoshec IRAtplicains
 agut ens Toll wrth ust (-)ve
CH3
(aceloe) Propanie
mst
be R
klone.
Comounal Iaus
ldehye must So
an be not gi and
oth lot (-)ve veses Compound
Tolens
mean
Cmbamd
than Cm720
at|um sþec LK
IR band
and 2q8o
Cm 7s
shs CaHe0 Compand soluimii
abspin
miale givenConand 14e
eagt Tolen's t
iita sfueline
cm
I720 shechem
cm &o29 and
RIcnbandh tollauwing Shnds CzHe0
tnmudo moleulan Hue Compound A
Numicalsi
 Delermune ue suctune tw curnmpund cGHyor
IR
wich Shs tollog absoplimn bands in
shechum 24c0 -24s0 cnm') CHste eteln)
2.

(-OH )

NarCoz
soluln -cH3 CHa -c-oH
Aceie a d
(Ethanste auid)
 Aand B ue noleula foma
gtgo river IR abselin at 16socna and
|7l0 cm
to
A and B ises
solulo!
lhe peak at l6so cm Correstonda be

CHh CHe CHO

shulad formala (A )Proþiraldiayde

formuda H,c-c-cH3
(B)
Acelne
 sleteh
egldnatly Consi
bmd s hn
cz0 sreteh
of bnd ST
bond
s
Can Caln-
Gelain bnd
sfretding dueabsenpin
hetbing ony Canbs
to
hcrean
tuysfretcluing ete and
cclCz C-C bond
ona!roporti
to
cy die
l68l6Qo- cm
|20
C C-
c
Creas c os
bonds
stveteing and
Anaies CC- Quatin eneies Short ihe
 IR Shecta ain chaacten'sed as maleudan
inge forint Commet eu it
IR sheha
becaw we Can 2]

Different dtiniti osiCons

foue ucgnisasl feaka at
IR Soecta

Can be asignud du to
cul
do t s mole
tsbeetd tu
pais one dn
wticd,
: Out followi'ng for stetehing vibl
biglur uueng
absub at and C-C b) o-H and C-c
a) c=c
absob at tuiyl
is exfeetd to
a) c =C
=c C-c stetclwng becaist
Hhan as
dube bond
bond skengt o
tigh bondl
Combaed t single
absob at lui valne
expecd to hn dmalw
o-H
fesueg becase
because C-C
Combanelto
mas an
reduceal
 ace IR
change shaw shetehiny Asymmliehsymm
Co
c'naive IR
onsy ding momut olhole
chang st not moleclu
do andd N, M,
Conet aclve IR e
vibyaimal
mode somed molecule Co,
molerals inaclve IR au Molecs
ite 9:
6029 2850-
60In |6fo
}cz0
b
tuquenda
(Cm) Absorlin23440 3610-
c-o bSoluiom.
gnapi? unlionad follaaing -OH
 tras dictloro ethylne hs no c zc
ab Soon wile Ci's 'some strekeing
t s Hus bond
bondl dn
brans i'sonw nem bola art
Y oihole momewt on stretcing Tie dibola momend
dsts no change anl lene no absoolion f IR
Saslialon es lace h Cis -LsoTw hs
oibole momut, e maynitude Snereaa on
and hnee
wnce is - Ii
mw shs C c
absp band . Heve botts Lsoms streteling
Shaw' band fur C-H amd c-d streteiny

I
H H

Cis , 2 dicloro eten Tams ,2 dichethe

Dipolemomt 2A5 Dipole moto
 Lmg answe uesns
A what b
Finge þriat fusin
egion and Functimal
IR faP
Define Speche scoty. Describe the Vaicns
mole cula vibahons ttae lecniue amnd waili T-9

9 Dis cus about

9 wthat do y undar stand lbt force Consla Ha

it
tue force Cont t a molecule latd t
fresut
oo ys undslond by mdes o vibabns?
9 what
Erplan Lotth Silatse eaaade

dtet yt malecul vibnatis

(atuing tace
butwen Funclina gio An and inge prt
Augin