Advanced Revision Assignment - Inorganic

Topic : s-Block Elements, p-Block Elements (Gr 13-18), d- Block Elements, Coordination ompounds,
Qualitative Analysis, Extractive Metallurgy, Chemical Bonding and Molecular Structure

1. Mixture of MgCl2 and MgO is called

(A) Portland cement (B) Sorrel’s cement
(C) Double salt (D) None of these
2. Match compounds given in (X) with their uses in (Y)
X Y
A. Na2CO 3 I. Glass
B. Na2SiO 3 II. Bleach
C. NaOH III. SO 2 absorber
D. NaOCl IV. Detergent
Hence correct order is
A B C D
(A) IV I III II
(B) I III IV II
(C) II IV I III
(D) III II IV I
3. Baking powder contains
(A) NaHCO3, Ca(H2PO2)2 and starch (B) NaHCO 3, Ca(H2PO2)2
(C) NaHCO3, starch (D) NaHCO 3
4. When NO is passed into KOH solution, products are
(A) N2 (B) N2O
(C) Both (D) None of these
5. Lead as impurity in the extraction of silver is removed by which process?
(A) Cyanide process (B) Solvay process
(C) Parke’s process (D) Froth flotation process
6. The final step for the extraction of copper from copper pyrite in Bassemer converter involves the reaction
(A) Cu2S + 2FeO  2Cu + 2Fe + SO2 (B) Cu2S + 2Cu2O  6Cu + SO 2
(C) 4Cu2O + FeS  8Cu + FeSO 4 (D) 2Cu2O + FeS  4Cu + Fe + SO 2

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7. Bell metal is an alloy of
(A) Cu + Pb (B) Cu + Sn
(C) Cu + Zn (D) Cu + Ni
8. The incorrect statement about BCl3 and AlCl3 is
(A) BCl3 is a fuming liquid and AlCl3 is a solid
(B) Both exist as dimer state in vapour phase
(C) BCl3 on hydrolysis gives boric acid
(D) Anhydrous AlCl3 is a covalent compound and it does not conduct electricity in the fused state
9. W hich one of the following pair of reactants does not give disproportionation reaction?
(A) Cl 2 and hot conc. NaOH (B) Cl 2 and cold dilute NaOH
(C) F 2 and hot conc. NaOH (D) All of these
10. Which noble gas does not form clathrates compound?
(A) He (B) Ar
(C) Rn (D) All of these
11. Calgon is represented by
(A) [Na2[Na4(PO 3)6]] (B) [Na3(PO 4)2]
(C) Na2[Na3(PO 3)6] (D) Na4[Na2(PO 4)2]
12. Which compound is used to check the decomposition of H2O 2?
(A) Acetanilide (B) Orthophosphoric acid
(C) Dust particle (D) Both (A) and (B)

13.

2
14.

15.

16.

3
17.

18.

19.

4
20.

21.

22.

23.

24.

5
25.

26.

The following column, I, II, III represent the different type of stereoisomers in complex compounds.
Answer the questions that follow
Column-I - Number of Geometrical isomers
Column-II - Number of optically active isomers
Column-III - Pairs of Enantiomers
Column-I Column-II Column-III
Number of Geometrical Number of optically active Pairs of Enantiomers
isomers isomers
(I) 2 (i) 6 (P) 4
(II) 6 (ii) 3 (Q) 2
(III) 3 (iii) 4 (R) 3
(IV) 5 (iv) 2 (S) 1
Given answer of Q. 27 to 29
27. For [CrCl2(en)NH3)2]+ complex the only CORRECT combination is
(A) (III), (iii), (P) (B) (I), (iv), (P)
(C) (III), (iv), (S) (D) (III), (iv), (Q)

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28. For [PtCl2(NH3)2(py)2]+2 complex the only CORRECT combination is
(A) (II), (i), (S) (B) (II), (iii), (S)
(C) (IV), (iv), (R) (D) (IV), (iv), (S)
29. For [Co(gly) 3]0 complex the only CORRECT combination is
(A) (I), (iii), (R) (B) (I), (iii), (Q)
(C) (I), (iv), (Q) (D) (II), (iii), (Q)
30. When Ca3(PO4)2 is treated with H2SO4, superphosphate of lime is obtained. The composition of this fertilizer
is
(1) Ca3(PO4)2 + CaSO4 (2) Ca(H2PO4)2
(3) Ca(H2PO4)2.H2O + 2CaSO4.2H2O (4) Ca(H2PO4)2 + CaSO4
31. Match the columns.
Column I Column II
(A) PbS, CuS and CdS dissolve in (p) CH3COOH + KNO2
(B) BiCl3 gives black precipitate with (q) 50% HNO3
(C) Co2+ ion gives yellow precipitate with (r) Aqueous NH3
(D) Fe3+, Zn2+ and Cu2+ can be distinguished by (s) Alkaline Na2SnO2
(t) Yellow (NH4)2S2
32. Among the following compounds of cement which is present in the highest amount?
(A) Ca2SiO4 (B) Ca3SiO5
(C) AI2O3 (D) Ca3AI2O6
33. A pale yellow crystalline solid insoluble in water but soluble in CS2 is allowed to react with nitric oxide to
give X and Y. X is a colourless gas with pungent odour. X is further allowed to react in aqueous medium
with nitric oxide to yield Z and T. Compounds X, Z and T are
(A) SO3, H2SO3, N2O (B) SO2, H2SO4, N2O
(C) SiO2, H2SO4, N2 (D) SO3, H2SO3, N2
34. The correct statement(s) among the following is/are
(A) Argentite and magnetite are oxide ores
(B) Anglesite and barytes are sulphate ores
(C) Galena and cinnabar are sulphide ores
(D) Siderite and malachite are carbonate ores
35. Which of the following elements of group-13 has/have first ionisation energy greater than that of aluminium?
(A) Boron (B) Gallium
(C) Indium (D) Thallium
36. When (NH4)2 Cr2O7 is heated :
(A) there is oxidation of N (B) there is reduction of Cr
(C) net reaction is disproportionations (D) net reaction is neutralisation
37. For the reaction : H3PO4 + Ca(OH) 2 CaHPO4 + 2H2O
1 mol 1 mol
Which are true statements :
(A) equivalent weight of H3PO4 is 49
(B) resulting mixture is neutralised by 1 mol of KOH
(C) CaHPO 4 is an acid salt
(D) 1 mol of H3PO4 is completely neutralised by 1.5 mol of Ca(OH)2.

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38. 3H3PO2 PH3 + 2H3PO3 . In this reaction :
(A) H 3PO 2 undergoes disproportionation (B) equivalent weight of H 3PO 2 is 22
(C) equivalent weight of H3PO2 is 49.5 (D) NaH 2PO2 is not an acid salt
39. [Cr(H2O)6]Cl3 has a magnetic moment of 3.83 BM. Which of the following distribution of 3d electrons in
chromium ion of the complex is incorrect? [Atomic number of Cr = 24]
1 1 1
(A) 3d xy 3d x 2  y 2 3d z2 1
(B) 3d xy 1
3d yz 1
3d xz

1 1 1
1
(C) 3d xy 1
3d yz 3d z12 (D) 3d xy 3d x 2  y 2 3d xz

40. Which of the following can show disproportionation reaction in acidic medium?
(A) H3PO3 (B) NO2
(C) N2O 3 (D) H3PO2

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