Advanced Solid State HW1 2
Advanced Solid State HW1 2
1 Probability
(a) An electron has been observed to have its spin in the direction of the z-axis of a rectangular coordinate
system. Write its initial state |ψ0 ⟩.
(b) Calculate the probability P (θ) that a second observation (state |ψ1 ⟩) will show the spin to be directed in
x − z plane at an angle θ with respect to the z-axis.
(c) The total spin of the neutron and proton in a deuteron is a triplet state. The resultant spin of the deuteron
has been observed to be parallel to the z-axis of a rectangular coordinate system. In this framework, write
the initial spin state of the neutron-proton system in the base |s1 , m1 ⟩n |s2 , m2 ⟩p where s1 and s2 are the
spins of the neutron and proton respectively and m1 and m2 their projections onto the z-axis.
where u1 and u2 are eigenfunctions of the Hamiltonian with eigenvalues E1 and E2 . If the system is in the state
ψ = ϕ1 at time t = 0:
(a) After time evolution, express the wavefunction ψ(t) in terms of ϕ1 and ϕ2
(b) Show that the expectation value of A at time t can be written as:
a1 + a2 a1 − a2 (E1 − E2 )t
⟨A⟩ = + cos
2 2 h̄
Hints
1. To change basis, try using symmetric and antisymmetric of the eigenfunctions (keeping normalization!)
2.
e−iα + eiα
cos α = , h̄wj = Ej
2
(a) Prove that pz and px are constants of motion. Hint: remember than an operator is a constant of motion of the
system if it commutes with the Hamiltonian. Recall the fundamental commutations of quantum mechanics.
(b) Write the Schrodinger equation of the system, Ĥψ(x, y, z) = Eψ(x, y, z).
1
(c) Recalling that, because pˆx and pˆz are constants of motion, write ψ(x, y, z) as the product of plane waves
travelling in the x and z direction, and a function ϕ(y). Then, by using pˆy = −ih̄ ∂∂ŷ , find that the
Schrodinger equation gives :
(d) Remember the solutions for the quantum harmonic oscillator and find the energy levels of the system.
4 Particle in a box
A particle in the infinite square well which looks like this
(
0, 0≤x≤a
V (x) =
inf, everywhere else,
has the initial wave function
(
Ax, 0 ≤ x ≤ a/2,
Ψ(x, 0) =
A(a − x), a/2 ≤ x ≤ a.
(c) What is the probability that a measurement of the energy would yield the value E1 ?
Pinf
(d) Find the expectation value of the energy, i.e. ⟨H⟩ = n=1 |cn |2 En